Tsomerism. . a. Ader) the chain, position. metamar,pumctiorol group, tapg-chain igomen ram “The following, pains. © CHs@H, CHsCh Cts Om Cty C—CHy CH @ Cty-S-CtycH, CH, > CH CH, © CH, CHg @ CHs -S-ChyCteCls . CHC, ClCH, SH @ CHyCH= CUCHS A ’ @CHy-CH-CHy - CHa. | CHy-CU:CHCHa = NH 1 NBs Cus, 4. @ CHsCHeCH2-CHy-CHy cu C — Cus Cty Cus, —CUp—CH2— CHe - CHs, \ oe 7a C CMs GI Se Cts chain isomen. Because their amatecnlart pon malo am game {C5He). Beet there ts difertonee longest carbon chain. ak pe@ D Chg -CHCH CHa —, CHyCHy CH, CHs CHy- 9-CHa- CH Cs Gnd Cy - CH) -9- CH, CH cae both positional isomen. cad meloren: Because the molecular sormula cree gore (Cy Hie). Bet the position ¢ Sulben is chonged. For that the length 4 carbon chain te.chapa o} both side q the polyvalent eubstarce ip chonged- Gi) CHyS-CHCHGHy , CHC HCH, CHL SH Mdeculare forenula is Gone (04 H405) » jst 6 moleeele i» Theyol arour and ind molecule is) Thao qroup, The molcoules arte Funct onal group isomen, id® o- Weer =CHCHs ue el. 3 pA cugecH =cH = CH ond w/ Nou i ' d o THRs chain {SOME 3 Te molecular Joronelox arte Sarne (@4Hs) Bud the 16) molecede is im chain atreucttate and the 2nd molecule is in TUNG sheuctore, @ cup carOh ene ae ee s on Cotes wip a ok Penge CH CH= nie vcd stg saa Np i ree - A of Na, 2S - Ferghbios am ad eke vptahi cet igd Be = are positional Worker gPe s. oA. MEA Eten, is Some (GMss oe Conthon ‘hain alse some yw@ 2. Wich shuctuore Can ave geomelrcé cal Isomen. Br cH 4 Do So \ got ek per y Vy 1) Se \ ee Ce 7 u B CHs Wa CH TK Bry yHs c= 7 Nu sherte io teotucton in rotetHion eyeter Rolerhien of the-melecetete-reasticted And no similarc atom in omy cattbon. So, the molecule Con give geo rical isomen. a { y yom There 19) restriction in sin has sgimilan A uor fo, sheets | not ae Geeretical isomer,®@ Or Melo” Or aa There 12 reastreicltion 19 rotation n aystem : And ro similar group in om} carbon. Se, the molecule Com ave geomentical too mer. Cus a ye Bee nt ‘HA The mdccke is of gy clict olrectaee . | aanbon. The molecule has MO china So, + con mot giv geomateical chs V \ bs Py we e We —CHs The molecule fs of yee gyelic shracture- isome!nt. a has 2 chinal caithon. 0, the molecule can Ge Geometrical isomer.i H-C@ —C— ( | 02 The molecole 1S o} gyclic Strucurte. No chimal. Carbon 16 prugent inthis molecals . Se 1 aan mot a qeometical feomen. aw Bre u ; The molecule 1S of gyelic structtace. And 2 chiral carbon 19 prusent in this qroleewle. So, + can gee Geematrscal isomell. Ba@ £ Tdert fy the Elz, Cis- trars , Syn ~ ont 'Sormert a WS, ye trom the Follow? “anche ; ; 2 e a Eee v1 ee fj Neb Wa Cee 2 CN \ Su COdH He OCH a 2 2 PN E o gO: 13, oe py ines Pek OH / of AEE Sed ag hs Ar Se Gls 2g gl 2 7H =O Cee =S a 1. or vA “ Nu, » = Je or(oy IS ¢ A 7iN a® Osx Ce \ /¢ N 7 COOH C2 GN. e Or 7 & ee ee o @ Ist pide Aroups aie in sdene, side. 20, the wrcleanle to Z isomer. 0 i He @ Eo n.6% Q f= y re Cmax NH, Br ae Ort Vn (es @ y® 3 Ist PROS AN OwPe ana ig di + side. So, the moleeute “ig E tsomert. 1 ea nM Cte 2 Ge WC ~¢0 Oy bay toe CPC i Mie Tx y., sai of C2 Osh pu Br, 2 2 pie & Ngai , ee @ Or Ziel i It proarcty. Groups are in some vide. ‘i the molecule is Z tsarmen,=. @ ON a Similone groupe og combons ane in opposite side. So, the pee ts ae Trams 1somer. on DP og # f OND ee Na te ee ee eae oe i E, Be ¥ fk 7 ee IN Pe y Tae Coon Ae ‘ N-H a Ce FO 5 @ vee a ef 2h pegs foe nt So, the, root, is 2 eeThe molecole 1S an. aldaxine, H and OH are in 4 opposite side So, the moleaute is Ants igomen. 4. Write down the Ginditighis a a dade to Ge / show tacdomenigm. To gine tacdomeriom the eile rohould be of X-Y2Z otructure. X carbon must hove allpha.hydregen. ond x Betting must be of Spo pchridrzation. 61 @ B, write down the tocdomens ere hu follower, wmoleoude =)” o We j t Taudemares of the we iv oH 2Qy Bp ae CH Gree: a Orch i = Pak a Jars vom aby rajeyae? TH goes - “t= et Oya ale, em Oo, 405 coy va M whee WG od aa ak pike me Geni. obi. de A ag ve Feast mr © Sechen FCoE! ao C= 0Hs oe a Oy 4y @ C ax = és ag \ tof ‘ee BAN 7 ehructure 1 preasent. x carbon has alpha eo But x*darbon~ is not eps hyeridized. ' So, the molecule Can nolgive tacdomertism. oO FO @ 20 x-Y 2Z otrechew is prasent 4sgeab x Conbon hos alpha hypragen. x Conbon is sp red zed. 50, the molecule COM [give rae Toutomen 6} the ere fe zo on or pyc CHE uke{> A Yet Sachin te presen o> » g ov CHs x22 shuclure is present. x carbon has alpha hepiagen x Carbon 1S Spe hybridized: 30, the molWweute oe eins pes or b of ie Cnn Hy es hee Lae i = f pe Des x 4 Le Cy - -cH “0 Tot oi 7 ght AV; + dae ges The ‘itlacthe is enol am ieig @ On XO-H | | N @ ry ‘en ee / \\ | f Cai er 1s eral. © The molecule 15 end! id sl X-Yez structure 19 By (ogra! _ preesent. BT iy a Ho a 80, the “mmolrcoule Gam @ive tanta ocet sak oe ‘ £a Gz Qs3—cO- 4 Cig x-Y 22 structure iS present alpha hydrggen HA» Sdofiban 48 absent So, the mole cute Can mot Give tautomer. git Ce of X) ws Cie oc Hs 9 OH & anclaeute hos H- aro) bet the vere bral Con Sugiedion, C reoteonte atso has H-bonding, but he con jugatian is Yop emalll. G&D molweule also has H- bondng but(r) the com segation io not 4oo long: A rote cule has H-bondine and the longest conjugation - So, A evrol io mote stalde. & Wrttte ay) the possible daulomuns at a CHs a CH, - é -CHg and find out Which A enol 19 rrore stable. Possible tatornens Ane - ce 4H is 1 CH = @_ Chass ais -H Qe 2. CH, “egcn@e atts o of ov > 3, CHG Cos wut a, bd O-H o 40 en : 1 2 Aogap yp 4. Cts -G@=0 > oo CHa” Pig BEEP Id and 4th ‘efol has bi bond ates TO Cony ation 2nd endl nes 4 Donding and the longest co Askeptioh i 50, 2nd enol is mote stable. ee bye_ = | 12. Tesch wich are Qhinal aanbon and PHaa active Usigg the Concept o} plane of oe aenter of a oe Neomnbert F chiral conbon. PA eh st Hy ee cea CHg ; de | die RAS oh Cc ae ee ey & 4 alba oa hf Z HO af a Ta Ky a yee Plame G} Sapremmettes. @ Is ater + 5 Ae eS Sb 7 arr t iweGbserbe HS 8 Number a dra Canbon = 2° Py So,the. rotecule is china and mtat CHy i C =? G03 | \ 2 oe | we Cts Plane 0} garments is present 15 Qusen - Center 4 eppremadg Noam bert 7) chiral Carbon =O So, the motkonte t ‘achiral and optical. inate, e Plane oe seromelissy is Hieany Center. of arorety is Obsent. ee wae chiral coithan 20 yt Oe ¥, The aie is ‘echureal ord Cet Inactve, ar Sih! 1 eee 1 Fie?CH Plane ¢) aymrmalsy 1s Present. Coster of sgvmees, ts ahgent. Num ber ¢ aural Cancbon = o. 4 ae oT mleaule js, achiral and optically iroctive H | ‘ peer C Pa he “oa Plane o} gyrvnetnny is present. day erate 1s absent. 1 Nigh of chirral Carbon : = ! Te molecule 18 Oahiral and 2 aly ineblive.. @ woe 4 Plane of geyrnwnet igs} fs absent. Canton >) ayrnmeing ae absent. Number 9} ehinal @atcbon |= We molecule is Chiral and opticalls, oative. - Br 1 pea 6) | i a<- - mn Plone o} gprmmelny is present. ey Bpmmatiy is absent. et gy chiral conbon +0 Te motecele is achiral and optically, Inoetive.at