———
pos
» H+ + HOU
HOT HO HOt 3 Bt 40
CH,COOH | CHs(007 CH,COOH sy H+ 4 Otjlo07
HaP O41 HiPOy Hy POY a3 HY + HOOP
NH I NHS Nig uy Wt + NH,
3 Amphelerie substanceeo belie eee etch
Dalint ey
Ils @ subshowce
theb
2 geih oxb
eos pany
Can aither gas om preter with calahive
east, 06 lose 8 proten with alahiv sate
a ”
Relove case means, that ak can hoppy 1m aqueous Soluhien~
examples:
MIP PY HOW ay couple Ha J HO™
O + Ht > Hot a couple Hso* / +h0
4 Aad - Base ReacHous:
ALA Dehachen:
belween two
Wits a traslermabion due to an exchenge
of profer H+ or more,
chemecal specis, ome & on ad, the other is
ore dose. th needs two Acid-Base couples (parts).
Fiesb couple: Waa 1 Ag
Second couple + HAw/. Ay
Roe eat hleu, _ balween
First of all,
welte
each
HAg] Ma ond
the named. Hel tase hte
BAT Ae.
corcespon ding, be
acd ~ base couple .( q WAy and AT ent wi bially )
” fe
HA,
Ss Nt +A,
® Ag + ut = WA
ond Sew wetke the bolanud raachtoy G1) + (2).
4.3 Exomple s »
Reaction between HO and NH
HO Ss HY + HOT
NH, + Ht SNAG
The baled actd-bese ceachtion bebween Hed and NE iy
Ho + NU, > HO + NUE
- E PH of an aqueas soluhios
a. pH ¢
ALA
a Defarhes +
PBHE 1s m grander. eluted ty thy mctar concentration vt High ions
Cor HEY fe the celuhn by the celahinship bellow:
Eujor] = 107PH aewenee
or pHa Log CH,ofI Rk eat
‘Ao
Remarks ; -
G)e PH 1 & posikve scaler withoul oniks.
Gi. PH clepends on tha demperatare af dhe Sohahion,
Gy. pH decreases if CHOtY decceases and the Solehion
- becomes more acid.
a Measuring pH eo] an oqueous sduhon.
Q uashiont
How 1s pl measured @
Answec i
pH 04 on aqueses sduion can be meamered 1m
a voriety of ways.
The mest eommor way oses & pitmmmeter ( pH-seasihite)
vst y a pH~ senghve lectede reference.
ATremativelly methods for defecmaining De ph +
oe solukton ace:
G. Indicators = indicators ace sateriah that ane Specialty,
desigral 1 chouge dor whey opated
fo differest pl values.
The Color foc 9 wetted sample pal
is matched to @ toler ey 2 tater
chact be wher om pH value.
pH paper is available for narrow
ph canges | foc ecowmpe; 3,0 40.5.5 ph
HS to FS pH and 6Olo BO ph) andTE — oe
favely
IN
fs
we
Pwre
r
wide pH ranges =| 1040 14 pH. 7 nA
7 yarn
eee yok an
PH paper ts typically vse foe peelinninayy aud
Small volume measuring, 1b wan ned be used
for conkinows monitoring, af process.
A ehhchy 5
Rajustenet of ph-wetee vein o buffer Soutien
A soubor of Wy deoger chloride Wi cncentradi oy
AO woh. has. pH = %
Calculate Hhe tontenbeahlas of oxoniviy ious Hyg -
The obsdute uncertainty dice to the meature 3
4 Aplt s 0, OS
Frame the volun 4 CH ord
Deduce the absolule uncerhanity « A CHO)
Caleulate the accuracy of the device.
Put, 24.00 ml of G2 20 md I of hy drogen
chloride sduhew 15 a beaclar A), Using pl-meher
ove fond phat.
Dub Vas 100m) of Crs AP md-!? af ethowod antes
soluhin CHgCOOHay 8 a beacker (8), Yet URInG phoebe
cue found pH: 3.4.
which couple Mtervene th the datclattos of each
aed 2 Dede The reacher bebe each acd aud
watec™
Calculate the inth'ol amsunt of matter of acd wt cact
beacker.
Draw. the chumical esepiptiin table CC DT) coctorpoday
fo. cach = ceachous da
; wkange®
—
panes
4 Gaileulede fle Graal concerdealion of Oxon ORS
oh, “RO, ech — solublon, aud dadua . the fuot
wer advan went “foc wach ceachiou
4-5 Calealahe XL the Malina! advencanunt for
each reaction .
4-6 Ge Whe lourpecton of coch chemi od Gitta
MQ) an &) benckers
aL Tetal trontfemotlen = Limihed Traspowoticns
4 Toto tromvfor mohlour.
a.’ Defies :
Hs Phe troasformahen for whieh the advanteucsut 4
become) mMaxturadl ? % = Xm, Sep ene Cagedh
Litton.
Ky feel advormvent (effective valine J.
Key maximal odvanwement ( Uroreteal value J
2 Limaihd transforma hou .
La Defuihen:
Ns) the brausformohia, for which the advencennad 2 not
maximum , So 7 none af the ceagesks 15 Linihelnt one.
that means: xy # Xia
Y , 1 tee dronsformeattion 15
tolal , and one of the teagenfs ii Limifonk.
+
ee
4 T 24. dhe KS xa, The trauspormah'es 1%
United , and none of the teagods vi Litsitomd.
ax The Limifed drmsfomohea sd a
Reyecrible one-
A. Remracle + ta ZA taphes Thab the hrouglormotie
is Minvhed .
2. Aedwihys
Dat Zoml in two beaches (A) and C8) oi
C= NAOT md 17 of ethanorg acid solution vhich hag
pH = 3.4. ;
a. After addiag, two deeps 4 pece tthowad acd to(a)
the PH becomes Silb-
be. Affe aldbvsg Jeo deeps of Sedimn hydertd telubiow
48), the pH Becanuey 3,4.
Querhonrg :
oe Give tha caaction of the dt itolaftor of efhawad
add in wake.
a- da whieh wy the Howsfoc mation 15 displeud
i when dhe add 13 added Jo dhe ypharns
Zl Iw which way the Jrowslormahtey as
displaced whay tha sodium hydewrteh XS added’4
What
What alos Fr. ?
out toed, Shy Tak tory ni
ohou 7,
tote
e ' or Cie hed 7
ste by .
pase 7
et?
h narana
notT- 04- --
oi os Chemical Equiltbeium
To The Findamentel of chemin
walibejun
The Last Lesser shows that a cevacnible chimiak
Framstocmatoy cau be seieplons 1 ane Sek of in
Ibe opposite one. it :
: Ses (4)
The ceachor used to dascedb” tha revecihslit, is thal
a the di ssolw of hance acd id wetler
This ceachton