Professional Documents
Culture Documents
Product Guide
Liquid Polybutadienes 6
Hydrocarbon Resins 8
SMA Resins 10
Crosslinking Monomers 12
Thermoplastic Urethanes 14
Reference Guide 16
Profile Contacts Around the World
Cray Valley Hydrocarbon Specialty Chemicals (HSC) is a global organization dedicated to supplying specialty Americas Europe & Africa Asia
materials. As part of the Total Group, Cray Valley HSC can leverage key petroleum feedstock positions to deliver
Cray Valley USA, LLC Cray Valley Cray Valley (Guangzhou) Chemical
high-quality products. The various product lines are marked by a diversity of chemistries, which enables a broad
Oaklands Corporate Center 16-32 rue Henri Regnault Co., Ltd.
spectrum of end-use opportunities.
468 Thomas Jones Way, Suite 100 La Défense 6 Room 2507-09, The South
Cray Valley HSC manufactures and supplies diene-based liquid homopolymers and copolymers, C5 and C9 Exton, PA 19341 92902 Paris La Défense Cedex Securities Building
hydrocarbon tackifying resins, styrene-maleic anhydride copolymers and derivatives, metallic monomer salts of USA France No. 140-148, Tiyu Dong Rd.
acrylic and methacrylic acid, and specialty monomer products. Tianhe District
Tel: 877-US1-CRAY (877-871-2729) Tel: +01 47 96 99 08
Guangzhou 510620 P.R. China
Cray Valley HSC sells these products under the Ricon®, Ricobond®, Krasol™, Poly bd®, Wingtack®, Norsolene®, Fax: 610-363-4198 Fax: +01 47 96 99 86
and SMA® brand names. E-mail: TechSupport@crayvalleyus.com Tel: +86 20 38879156
Fax: +86 20 28878495
The Hydrocarbon Specialty Chemicals organization focuses on two main markets, Rubber and Adhesives,
while also supporting other traditional markets and new opportunities in the electronics, coatings, and plastics
modification areas.
The many applications of Cray Valley HSC products include: plasticizing polymeric systems; crosslinking saturated
and unsaturated polymers or other resins systems; adhesion aids or components of adhesives and sealants;
Global Presence
chemical intermediates including polyols for polyurethane synthesis; additives to improve the dispersion of fillers,
• • • •
pigments, or other materials; and additives used in the compounding of thermoplastic resins.
Headquarters Laboratories Manufacturing Sites Sales Offices
The HSC Business Unit continues to create synergies between the core product lines and provide increased value
to the market, building on a strong technology and manufacturing base, which enables Cray Valley HSC to grow Exton, Pa., USA Exton, Pa., USA Grand Junction, Colo., USA Exton, Pa., USA
together with our customers. Paris, France Verneuil, France Channelview, Texas, USA Paris, France
Guangzhou, China Kralupy, Czech Republic Beaumont, Texas, USA Yokohama, Japan
Chatom, Ala., USA São Paolo, Brazil
Stratford, Conn., USA Guangzhou, China
Carling, France
Kralupy, Czech Republic
Main Trademarks Ravenna, Italy
• Ricon® • Wingtack®
• Ricobond® • Norsolene®
• Krasol™ • SMA®
• Poly bd® • Dymalink®
2 3
Main Markets
Market Breakdown
Adhesives and Sealant Market
Cray Valley HSC is a well-known supplier of hydrocarbon
resins to the adhesives marketplace. Wingtack and Norsolene Rubber Adhesives & Sealants Thermoplastics Specialty Markets
grades tackifying resins are specified in a variety of adhesive
applications, including hot melt adhesives, pressure sensitive Packaging, Coatings,
Ricon®
tape and label adhesives, and formulated mastics. Electronics
Crosslinking Coatings,
Monomers Sporting Goods
4 5
Liquid Polybutadienes
Cray Valley HSC offers a diverse selection of specialty liquid polybutadiene grades including low and high vinyl polybutadiene
homopolymers and poly(styrene-butadiene) copolymers. Ricon grades offer a complete selection of microstructures, which
translates to a wide spectrum of glass transition temperatures. In addition to the base product line, functional derivatives are
available. The Ricon MA and Ricobond series include maleic anhydride grafted grades. Poly bd hydroxyl-terminated polyb-
utadienes are available, and our unique Krasol product line consists of both unsaturated and fully hydrogenated telechelic
polybutadiene diols.
The products are used in an equally broad spectrum of markets and applications. Low-viscosity liquid polybutadienes are
used as processing aids, and the wide Tg range allows for modification of tire performance properties. In addition, high vinyl
grades are useful as coagents for the peroxide cure of rubber. Functional grades expand the utility of the polybutadiene res-
ins to many other applications, including polyurethanes, hydrophobic sealants and coatings, and thermoplastic modification.
Krasol* Diol
Krasol LBH 2000 Hydroxyl-Terminated Polybutadiene 2,100 65 13,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH-P 2000 Hydroxyl-Terminated Polybutadiene (Primary-OH) 2,100 65 13,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH 3000 Hydroxyl-Terminated Polybutadiene 3,000 65 20,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Krasol LBH-P 3000 Hydroxyl-Terminated Polybutadiene (Primary-OH) 3,200 65 20,000 @ 25 °C -35 0.89 -- 1.9 -- US, EU, Asia
Hydrogenated
Krasol HLBH-P2000 Hydroxyl-Terminated Hydrogenated Polybutadiene 2,100 -- 1,750 @ 60 °C -46 0.88 -- 1.9 -- US, EU, Asia
Krasol HLBH-P3000 Hydroxyl-Terminated Hydrogenated Polybutadiene 3,100 -- 3,000 @ 60 °C -46 0.88 -- 1.9 -- US, EU, Asia
6 7
Hydrocarbon Resins
Cray Valley’s hydrocarbon resin products complete a diverse portfolio. The Wingtack and Norsolene lines cover a wide
spectrum of aliphatic, aromatic, and pure monomer resin grades. The Wingtack grades are high-quality, low-color
C5 resins. The Norsolene A, S, and M series include a range of low to high softening point C9 and C5-C9 resins. In
addition, the Norsolene W series are colorless pure monomer resins.
The main outlet for Cray Valley HSC hydrocarbon resins is the adhesives market, including hot melt, pressure sensitive
tapes and labels, construction mastics, and specialty adhesives applications. In addition, the hydrocarbon resins
are useful tackifiers and compatibilization aids for the rubber market. Other main areas of utility include coatings and
thermoplastic modification.
Norsolene
Norsolene A-90 C9 Hydrocarbon Resin 97 Yellow solid 5.6 1.10 750 46 US, EU, Asia
Norsolene A-100 C9 Hydrocarbon Resin 104 Yellow solid 5.6 1.10 800 53 US, EU, Asia
Norsolene A-110 C9 Hydrocarbon Resin 108 Yellow solid 5.6 1.10 850 64 US, EU, Asia
Norsolene S-85 C9 Hydrocarbon Resin 87 Yellow solid 6.5 1.07 650 45 US, EU, Asia
Norsolene S-95 C9 Hydrocarbon Resin 97 Yellow solid 6.5 1.07 700 46 US, EU, Asia
Norsolene S95e C9 Hydrocarbon Resin 93 Yellow solid 6.0 1.07 600 40 US, EU, Asia
Norsolene S-105 C9 Hydrocarbon Resin 106 Yellow solid 6.5 1.07 750 55 US, EU, Asia
Norsolene S105e C9 Hydrocarbon Resin 104 Yellow solid 6.0 1.07 650 50 US, EU, Asia
Norsolene S-115 C9 Hydrocarbon Resin 115 Yellow solid 6.5 1.07 800 65 US, EU, Asia
Norsolene S115e C9 Hydrocarbon Resin 115 Yellow solid 6.0 1.07 750 60 US, EU, Asia
Norsolene S-125 C9 Hydrocarbon Resin 125 Yellow solid 6.5 1.07 850 71 US, EU, Asia
Norsolene S125e C9 Hydrocarbon Resin 125 Yellow solid 6.0 1.07 850 70 US, EU, Asia
Norsolene S-135 C9 Hydrocarbon Resin 133 Yellow solid 6.5 1.07 950 82 US, EU, Asia
Norsolene S135e C9 Hydrocarbon Resin 135 Yellow solid 6.0 1.07 900 80 US, EU, Asia
Norsolene S-145 C9 Hydrocarbon Resin 143 Yellow solid 6.5 1.07 1050 92 US, EU, Asia
Norsolene S-155 C9 Hydrocarbon Resin 152 Yellow solid 6.5 1.07 1100 104 US, EU, Asia
Norsolene M1080 C9 Hydrocarbon Resin 93 Yellow solid 6.0 1.10 600 40 US, EU, Asia
Norsolene M1090 C9 Hydrocarbon Resin 103 Yellow solid 5.5 1.10 650 50 US, EU, Asia
Norsolene M1100 C9 Hydrocarbon Resin 112 Yellow solid 5.5 1.10 750 60 US, EU, Asia
Norsolene W-85 Pure Monomer Resin 85 Colorless solid <1 1.06 600 35 US, EU, Asia
Norsolene W-90 Pure Monomer Resin 90 Colorless solid <1 1.06 650 40 US, EU, Asia
Norsolene W-100 Pure Monomer Resin 100 Colorless solid <1 1.06 750 50 US, EU, Asia
Norsolene W-110 Pure Monomer Resin 110 Colorless solid <1 1.06 850 60 US, EU, Asia
Norsolene W-120 Pure Monomer Resin 120 Colorless solid <1 1.06 950 70 US, EU, Asia
Norsolene W-130 Pure Monomer Resin 130 Colorless solid <1 1.06 1100 80 US, EU, Asia
Norsolene W-140 Pure Monomer Resin 140 Colorless solid <1 1.06 1200 90 US, EU, Asia
8 9
SMA Resins
Cray Valley HSC produces a line of low molecular weight styrene-maleic anhydride copolymer resins with an extended
range of monomer ratios. Based on these platforms, a number of value-added derivatives are formed, including
specialty esters and imides. In addition, the base products can be esterified to form a variety of water-soluble salts.
The product diversification allows for an equally broad spectrum of end-use applications. The inherent heat resistance
properties as well as reactive MA groups can provide value in polymer modification and electronics applications. The
liquid forms are excellent dispersants over a broad pH range, providing utility in the coatings, inks, and paper industry.
An abundance of MA groups allows SMA resins to be used in applications where targeted chemistry is required,
including reactive modification of thermoplastics.
Esters
SMA 1440 Ester Resin -- F 2,900 60 -- -- H, HLS, HK US, EU, Asia
SMA 17352 Ester Resin -- F, P 2,900 125 -- -- H US, EU, Asia
SMA 2625 Ester Resin -- F, P 3,100 110 -- -- H US, EU, Asia
SMA 3840 Ester Resin -- F 4,100 75 -- -- -- US, EU, Asia
Imides
SMA 1000I Imide Resin 1 P 2,100 85 -- 3.15 -- US, EU, Asia
SMA 2000I Imide Resin 2 P 2,700 88 -- 2.5 -- US, EU, Asia
SMA 3000I Imide Resin 3 P 3,050 90 -- 2.15 -- US, EU, Asia
SMA 4000I Imide Resin 4 P 3,600 90 -- 1.75 -- US, EU, Asia
Key
F Flake
P Powder
H Ammonia Hydrolyzed
HNa Sodium Hydrolyzed
MA Methyl Amine Amic Acid
HLS Ammonia Hydrolyzed Low Solids
HK Potassium Hydrolyzed
10 11
Crosslinking Monomers
Cray Valley HSC provides a selection of metallic monomers. Straight grade and scorch retarding rubber coagent
monomers are available for peroxide-cure applications, while our specialty monomers are used in a wide variety of
cure systems, including accelerated sulfur vulcanization and metal oxide cure.
Our products find utility in a variety of applications including tires, power transmission belts, rubber sealing systems,
coatings, thermoplastics, and adhesives.
Specialty Monomers Dymalink 1100 Acrylate Blend (Dry liquid version – 70% active) white powder 1.35 US, EU, Asia
12 13
Thermoplastic Urethanes
TPU
2035 TPU Polybutadiene TPU (insoluble) 82 560 950 1710 US, EU, Asia
14 15
Reference Guide
Glass Transition Temperature (Tg ) Cray Valley HSC and the Total Group
Cray Valley HSC is a division within Total’s Chemicals segment. Founded in 1924, Total is the world’s fifth-largest
Ricon® Norsolene® international oil and gas producer, with operations in more than 130 countries. Total engages in all aspects of the
petroleum industry, including upstream operations (oil and gas exploration, development and production, LNG)
and downstream operations (refining, marketing, trading, and shipping of crude oil and petroleum products). Total
Poly bd® Wingtack® also produces base chemicals and specialty chemicals for the industrial and consumer markets.
Total’s chemicals business is a leader in each of its markets: base chemicals (petrochemicals and fertilizers)
and specialty chemicals for the industrial and consumer markets (rubber processing, adhesives, resins,
Krasol™ and electroplating).
SMA®
Backed by the financial resources and technical services of the Chemicals segment of Total, Cray Valley HSC
provides a strong global approach to R&D, manufacturing, and customer support.
-100 -50 0 50 100 150 200
°C
Chemical Dispersion/
Norsolene® SMA® Plasticizer Crosslinking Adhesion Intermediate/ Surface Other
Polymerization Modification
Ricon®
Ricon®
Poly bd®
Wingtack® Poly bd®
Krasol™
Krasol™
Wingtack®
Norsolene®
100 1000 10000 100000
SMA®
g/mol in log scale
Crosslinking
Monomers
16 17
www.crayvalley.com
Email: TechSupport@crayvalleyus.com
The information in this bulletin is believed to be accurate, but all recommendations are made without warranty since the conditions of use are beyond Cray
Valley’s control. The listed properties are illustrative only and not product specifications. Cray Valley disclaims any liability in connection with the use of the
information and does not warrant against infringement by reason of the use of its products in combination with other material or in any process.
01/2013