PROBLEMS 3. 32 33 34 35 The initial state of one mole of a monatomic ideal gas is P = 10 atm and T = 300 K. Calculate the change in the entropy of the gas for (a) an isothermal de- crease in the pressure to 5 atm, (b) a reversible adiabatic expansion to a pres- sure of 5 atm, (c) a constant-volume decrease in the pressure to 5 atm. One mole of a monatomic ideal gas is subjected to the following sequence of steps: a. Starting at 300 K and 10 atm, the gas expands freely into a vacuum to triple its volume. b. The gas is next heated reversibly to 400 K at constant volume. c. The gas is reversibly expanded at constant temperature until its volume is again tripled. d. The gas is finally reversibly cooled to 300 K at constant pressure. Calculate the values of q and w and the changes in U, H, and S. One mole of a monatomic ideal gas undergoes a reversible expansion at con- stant pressure during which the entropy of the gas increases by 14.41 J/K and the gas absorbs 6236 joules of heat. Calculate the initial and final temperatures of the gas. One mole of a second monatomic ideal gas undergoes a reversible isothermal expansion during which it doubles its volume, performs 1729 joules of work and increases its entropy by 5.763 J/K. Calculate the temperature at which the expansion was conducted. Calculate the change in the enthalpy and the change in entropy when 1 mole of SiC is heated from 25°C to 1000°C. The constant pressure molar heat capacity of SiC varies with temperature as } Cp = 50.79 + 1.97 X 10->7 ~ 4.92 x 10°T~? + 8.20 X 10°77} S/mole-K One mole of copper at a uniform temperature of 0°C is placed in thermal con- tact with a second mole of copper which, initially, is at a uniform temperature of 100°C. Calculate the temperature of the 2 mole system, which is contained in an adiabatic enclosure, when thermal equilibrium is attained. Why is the common uniform temperature not exactly 50°C? How much heat is transferred,3.6 and how much entropy is produced by the transfer? The constant pressure mo- lar heat capacity of solid copper varies with temperature as Cp = 22.64 + 6.28 x 10-77 S/mole-K A reversible heat engine, operating in a cycle, withdraws heat from a high- temperature reservoir (the temperature of which consequently decreases). per- forms work w, and rejects heat into a low-temperature reservoir (the temperature of which consequently increases). The two reservoirs are, initially, at the tem- peratures T, and T> and have constant heat capacities C, and C», respectively. Calculate the fina! temperature of the system and the maximum amount of work which can be obtained from the engine.TW Joo Vo = REN Sy Cooreep (30> = O46 % \o a Ty Ts 300 He = Go. een = Aad ae we 7 m= &-B = oO = = = Gn ( 482 zw = Sev ones a = Cesta 9220) On ($82) = me 5 = % some = su 3 7 Bon k bY Peversble Miobatic: 9 = sad OS ENE + Sino + Adlebatic ~* & 20 Reversible —» Swe =O O80 ¢) Tre RM = GOA = soe ne CO coateos) = 8 wr. + = 3 (eae & (>) = - Beg 4 | .fa Goa = idtos| n = Amel Fo= wom Tr wk Wo = RTH = CCo0¢204r¢209 = 72.46 L a ee a) HT = Borde | P= WET, = C1909 C509 - 3:35.chn Va 138 ° Abo = - &= 6 AA = ACOIPVD = aut arora = 949 = 0 ° 65 = Bele aye i 1 Renn Werle Aida layce Aahaaims By carte Hews tan quant my Reversible Borst Corte wicks om {ray 2 mer Bo Hy = OCR Car be 138) = 940 5 ' AS = Venam ame ay o a aus 310, 00 > Tye do METS = (1900.082069 C4009 = 4.45 lm Vy V2 45 = revert = 1(3 Jeena (400 - 009 = yar ys ts = Jrav = 0 on a ea aH =m opt = OZ) C4) C4o9-4009 = DO S = 4 * » \grar = Byeawd() = 30 2CY Ter Gt Aoste 5 Vaz 3% = ld 2 Re = MEE 2 haa alm MG ow owed =0 on = nfeeet tN = 36, ew = fev = rer PCM = (17214) C400) Da * I ACE D = (VG tas Oe ES Bs = & = 8 - ary 3 + eo te ay Ty = Bok = ae ahm, Ve > DES = (1) Gov) Cr = 6.42 . 2. 5 ae woe {eo % » {oat = ACE ees Cr-a009 = 2078S I b= few = POMS = 1AECO=22.14) (0129 = ~S.8 5, Ou = 4-2 = ~219+eR = -lp4e I SH &— = ~207" 3 AS = w( gear be mer & (Ter) = ON CB Yer9H) BEL) = -s48 Te kaoe Cao > teal 9 = anal Raersitte weaned - = = . Pp are Pee vt G>btw9 = \ Va BS = fe 2 xlqds = n@h(by 5) (esp (I ‘ e . 3) - (2) to (B)- tos BCT) = Hai moe I %- naar = SlomCy-T) = bm T 2.8 (%-T) = 8276 T-ty = yee {+ eet ee wm @ wee (etn) = 4a Bdott, a. | 7 Tos yok bee Te. = Ttde + boa ke = gn ~ tel Reversible mM = 1 mol 2 es | mrt =? | 7 2 ..T We MAS as fay 923 Y, a a os A 2 lym, 5 7is \ sie "= aml T= 25% = MK 2 “ 7 aw = > Serer | St He. Me Iwel —_—_—___— Tee ps2? 2 = WB Bre to ~ te ec neat = { (5075 $197KI9 T ~ 4 are io TP 4 e QoxtoT 2 AT mae - ‘ = 9.19 (103-mED+ wa Cen aty- anrv CL Ly = Cy ry ute e +82or ir yy Cy rye gage = away oF Oss i : 3 63 “4 Co + Mio = aqaniey 4 @20%07 ) AT Ay t Don fin EP) tania (03-2087 acer Tey Gs) Sr me + e200 1 onal ) " ca9 Aas alaW © cam | cuts wel wal, mk 3 <3 Cy. Cues) = 2.64 46.2810 T - RpaupByome = Te ~ tiaedchanennnchd@ = evimidedinnngand O | ¥ © | \e at =- Vee ar # | 27 a | | 4 “> 2 2 Dua (Teme I+ be CTI = -[ arses d+ batee "Cre 3199} z 2 ->_% mo P24 Th ~ IRL fH BKIe Te — 234 = — 92.64 Tp + BMS — B.MKIO Tet 437 | 52 2600 Te + 45.28Tp 15297 =o | Te = 323.33 kK = 50.33 ¢ 1 _. { u T yaneroAu “sp Wasa ose ews angers nn Yo netad rianawy 299 Sudgquugdewdl ynero: | xt lin = J oma vin = 1933-1 . mm. | ] ' tye & oar > Sarr = 22.64 Ba P2299 ., « v\ Sat (226 + Greve yar a 0B ) | oy n> + 6.28410" (32333-2939 = a x Aw Ft . ‘ = Ee moar = [ORM weemitgsy = arse m (RED) 31 + bx (0? (209-45 — 399) = 73.55Tey ae ca Gree = 4-1) 4G Te TY