Professional Documents
Culture Documents
net/publication/300466234
CITATIONS READS
3 958
2 authors, including:
Thanh-Son Dao
General Motors Company
33 PUBLICATIONS 487 CITATIONS
SEE PROFILE
Some of the authors of this publication are also working on these related projects:
All content following this page was uploaded by Thanh-Son Dao on 24 August 2016.
6.2 Stack Figure 11. Battery parameters used for curve fitting.
The user can wire the individual cells to create a The plots in Figure 12 show that the simulation
stack model easily. This can be done using MapleSim’s results closely resemble experiment data.
advanced graphical user interface or based on standard
Modelica descriptions. As an example, the Modelica
script for n lithium-ion cells wired in series as shown in
Figure 10 is written as follows:
model Main
public // cell definitions
Electrochem.LiIon Cell1(chem_pos = …, chem_neg = …);
Electrochem.LiIon Cell2(chem_pos = …, chem_neg = …);
Electrochem.LiIon Cell3(chem_pos = …, chem_neg = …);
…
Electrochem.LiIon Celln(chem_pos = …, chem_neg = …);
equation // cell connections
connect(Cell1.p, …);
connect(…, Celln.n);
…
connect(Cell3.p, Cell2.n);
connect(Cell2.p, Cell1.n);
end Main;
8 Applications
Figure 10. Lithium-ion cells connected in series. The structure and robustness of the battery components
make them useful for many applications.
7 Battery parameter estimation Example 1:
The Battery Component Library in MapleSim includes The example in Figure 13 shows an electric vehicle
worksheets programmed in the Maple language, for powered by a 30Ah Lithium Iron Phosphate (LFP)
estimating battery parameters, based on experiment battery pack which has a maximum voltage of 390V
measurements. when fully charged. The LFP cathode and Lithium
The global optimization technique of Differential Titanate (LTO) anode are chosen for their good
Evolution Algorithm is implemented in the worksheet thermal stability. The model also features an
to effectively perform the search for multiple asynchronous induction motor. The combined
parameters and find the best possible solution. This efficiency of the motor and power electronics is
algorithm is part of the Global Optimization Toolbox modeled using an efficiency map, which allows the
(a) (b)
Figure 16. Current through each string of cells connected in
series (a) and cell temperatures (b).
(a) (b)
Figure 14. Vehicle speed (a) and battery SOC (b).
Example 2:
The following example (Figure 15) shows the
simulation of the thermal exchange between lithium-
ion cells connected in a series/parallel structure. The 6
cells used in the model exchange heat between the
adjacent cells that are in contact with them through
thermal conductivity.
The differences in cell temperatures result in an
imbalance in the cell voltages (i.e., some cells have
Figure 17. Stack voltage.
lower voltages than the other cells), causing the
currents through the series strings to vary (see Figure
16). In extreme cases, the “weak” cells (i.e., cells 9 Conclusion
having lower voltages) can become over-heated due to In this paper, we have shown two methods of
short-circuiting and have to be remedied using a generating battery model. While equivalent electrical
balancing current. The stack voltage is shown in Figure models attempt to model the electrochemical physics
17. of a battery using only electrical components, the
resulting battery component, which is computationally M.B. Pinson and M.Z. Bazant. Theory of SEI Formation in
inexpensive to incorporate into system models, has Rechargeable Batteries: Capacity Fade, Accelerated
many limitations. Aging, and Lifetime Prediction. Journal of the
Electrochemical models on the other hand, are the Electrochemical Society, 160(2):A243-A250, 2013.
most accurate because they describe the physics of a A. Seaman, T.-S. Dao, and J. McPhee. A Survey of
battery by explicitly representing the chemical Mathematics-Based Equivalent-Circuit and
Electrochemical Battery Models for Hybrid and Electric
processes that take place within it. Starting with PDEs
Vehicle Simulation. Journal of Power Sources. 256:410-
to describe these electrochemical processes, symbolic 423, 2014.
techniques are then applied to approximate the PDEs
Modelon Battery Library [Web]:
using Galerkin’s method, to arrive at the final set of
http://www.modelon.com/products/modelica-
reduced equations. libraries/battery-library-release-information/
Capacity fade is incorporated into both the
equivalent circuit and electrochemical battery List of symbols
components, with simulation results showing that � specific surface area [m2m-3]
battery life achieved by the components is a close fit �� factor for reaction rate equation [m s-1]
with experiment measurements. The battery ����� Bruggeman’s coefficient
components also incorporate thermal effects, and �� concentration in electrolyte phase [mol m ]
-3
include Maple language-based worksheets for battery
�� concentration in solid phase [mol m ]
-3
parameter estimation, based on experiment
��,��� maximum concentration in solid phase [mol m ]
-3
measurements.
��,���� surface concentration in solid phase [mol m ]
-3
The battery components were implemented based on
the Modelica Standard Library specification 3.2.1, and �0 diffusion coefficient at standard conditions [m2s-1]
commercialized as part of the Battery Component
�� diffusion coefficient [m2s-1]
Library in MapleSim™. The battery library also comes
with a parameters identification worksheet which ��,��� reference diffusion coefficient [m2s-1]
ensures a high level of fidelity in the battery ���� electrolyte diffusion coefficient [m2s-1]
components, making them suitable for a wide range of �� activation energy [J mol-1]
applications. ��� activation energy for diffusion [J mol-1]
��� activation energy for diffusion [J mol-1]
References
�� activation energy for ionic conductivity [J mol-1]
M. Chen and G. Rincón-Mora. Accurate Electrical Battery
� applied current [A]
Model Capable of Predicting Runtime and I-V
Performance. IEEE Trans. On Energy Conversion. � wall-flux of ions [mol m2s-1]
21(2):504-511, 2006. � reaction rate constant [mol (mol-1m3)3/2]
T.-S. Dao, C.P. Vyasarayani, and J. McPhee. Simplification ���� rate constant of SEI formation [m s-1]
and Order Reduction of Lithium-Ion Battery Model � molar mass of SEI layer [kg mol-1]
Based on Porous-Electrode Theory. Journal of Power
Sources, 198:329-337, 2012. � radius of intercalatin particle [m]
M. Doyle, J. Newman, C. Schmutz, and J.M. Tarascon. � ideal gas constant [J K-1mol-1]
Comparison of Modeling Predictions with Experimental � thickness of SEI layer [m]
Data from Plastic Lithium Ion Cells. Journal of the � time, [s]
Electrochemical Society, 143(6):1890-1903, 1996.
�+ transference number in the electrolyte
M. Einhorn, F.V. Conte, C. Niklas,, H. Popp, and J. Fleig. A
Modelica Library for Simulation of Electric Energy � battery temperature [K]
Storages. The 8th International Modelica Conference, ����� temperature at standard conditions [K]
2011. � main dimension across the cell sandwich [m]
J. Gerl, L. Janczyk, I. Krueger, and N. Modrow. A Modelica �� basis function
Based Lithium Ion Battery Model. The 10th International
Modelica Conference, 2014. � porosity of electrode
P. Liu, J. Wang, J. Hicks-Garner, E. Sherman., S. Φ� electrical potential in solide phase [V]
Soukiazian, M. Verbrugge, H. Tataria, J. Musser, and P. Φ� electrical potential in electrolyte phase [V]
Finamore. Aging Mechanisms of LiFePO4 Batteries � Specific conductivity coefficien [m A-1]
Deduced by Electrochemical and Structural Analysis.
���� effective ionic conductivity of electrolyte [S m-1]
Journal of the Electrochemical Society, 157(4):A499-
A507, 2010. � over-potential [V]
J. Newman and W. Tiedeman. Porous-Electrode Theory �� time-dependent variable of the i-th basis function
with Battery Applications. AIChE Journal, 21(1):25-44, ���� density of SEI layer [kg m-3]
1975.
� electronic conductivity of in solid phase [S m-1]
Appendix A
OCP equations for LiCoO2 cathode and LiC6 anode:
�� = (−3.234 − 638.136� + 2387.637� 2 − 4027.7467� 3 + 4106.484� 4
(17)
− 2790.517� 5 + 1292.901� 6 − 401.8703962� 7 + 79.910� 8
− 9.1764� 9 + 0.463�10 )/(−1.411 − 160.70� + 604.048� 2
− 1008.0656� 3 + 1005.1301� 4 − 663.87� 5 + 299.134� 6 − 90.922� 7
+ 17.8147� 8 − 2.032� 9 + 0.1025�10 )
0.20114 0.2403
�� = 0.7222 + 0.1186� + 0.268� 0.5 − � + � 1.5
+ 0.2808exp(0.90 − (18)
12.8265�) − 0.798exp(0.3818� − 0.4108)
In both equations, � indicates the battery SOC.
Appendix B
Table 1. List of cathode materials for Lithium-ion cells
supported by MapleSim.
Common name,
Chemical composition
where given
LiCoO2 LCO
LiFePO4 LFP
LiMn2O4 LMO
LiMn2O4 – low plateau
Li1.156Mn1.844O4
LiNi0.8Co0.15Al0.05O2 NCA
LiNi0.8Co0.2O2
LiNi0.7Co0.3O2
LiNi0.33Mn0.33Co0.33O2 NMC
LiNiO2
LiTiS2
LiV2O5
LiWO3
NaCoO2