METU-NCC CHM 107 GENERAL CHEMISTRY FIRST MIDTERM EXAMINATION April 12, 2014 Name, Surname: an Time given : 100 mins Signature: KE X Section: Student ID Constants and equations: N4~ 6.022x10™ units/mole; R = 0.0821(L.atm)/(K.mol) or 8.314 J/(K.mol); 0 °C correspond to 273.15 K; PV = nRT; [P + a(n’/V?)|[V — nb] = nRT T z K fe 070 c20 sa ST a | ee afc || ol] et | ne ape: | oor 1311 | 2011 | voor | se900| sae | 0 100 ae Spe ey ee Na | aa ats |e | s | al mw z2se0 | 240s 202 | za08s | s0s7s | sz00s | seasa| soe e | 20 | a] ae] a] me] we ee ee ae x | ca | se | m | v | c | mm | fe | co | N | cu | am | a | ce | a | co | oo | 30008 | 40.07 | 440s | a7as7 | so.e2| 51.906 | 64.006 | ss.aus| saas| seco | ease | eset | sozes| 7264 | 22) ress | resos| ea%a0 vps |e | ao] a |e po pw | ae | ae] a yey ey a] or) ee ro | os | oy | 2 | we | we | te | me | om | pa | ag | cs | in | sn | sy | om | 1 | xe 540s] e762 | s3006 | 01226] o2008| osce | 65) | soxa7| roaes | aoe | sora | sizer | reese | vier | sare | x27'00| rato | sat Spe par pm pe pm] te | ay re) we] ef a ae) eee ae ce | ee fue | ow | te | ow | me | oo | we | me | | | ot | |] ] | ee ssoa1| 3738 rant | we | sons | w030« | 10621 | 100.20 | 19222 | 19500 | 19887 | ooo | zoeae | aor | conse | cosy | cain | ce, a | 8 | a8 ftw | os Poe | or) woe] oe} mo) ait} aie] tia ft] ae |e te reo [ora | ac | opt | oe | sp | on | Me | ae | oe | Re | Uo | ua | wg | up | un be zs | aa | aan | aon | com | con | com | arm | ee | cory | arm | ass) | aoe | coe) | case) | 201 238) BTS, e ae Se Se “Lanthanises ce | m& | ni | pm | sm | ev | oa | we | oy | we | e& | im] wm | sora | raat | r4424 | cas) | 15036 | s5195 | 157-25] 156.93 | +6250 | venes | ve726 | 10800 | a7a04| sra07 * hatin Cc m | pa} u | ne | pu | am | cm | ee | ot | es | em | me | no | tr zs204| zara as80s | asm | aso | asm Loan | em | ey | osm | cen | asm | ase | Take two digits after the decimal point when you use atomic mass from the periodic table.1. (16 pts.)Consider the combustion of octane according to the following equation: 2CsHis(l) + 250r(g) > 16 CO2(g) + 18 H2O(1) Ifa reaction begins with 25.3 g octane and 104.1 g Op, theoretically.how many grams of water will be formed? is ‘Wy Atthe end of reaction if 28.56 of water i collected, what isthe percentage yield of 4 hy this reaction? ( Molar masses; CsHig: 114.23 g/mol; Oz: 32.00 gimol; CO> : 44.01 g/mol; HO: 18.02 g/mol ) i Avs | 4. Face Casa tye es = O.22\ wel Cehie C) 4 cgugs 25 25 cathe) « 3.15 wel Oo C iS w Stoiiomed vie valios Wee 222 = 12.5 Wea catyg Ss ’ cs peesent valio, 22% = ide 2% OLfs 24COSS, OULU Caty fs Eve Tents TO (3 mol Hoo WPorg) ee ge aaa Ca¥ve Jal “Tere Cgtbag)! \ Taatt = 35.84 4 Ho (tucorelieal aad) h aeay 2 ABSE hoo = 226" 7 ©) A HAs = Zo B4 we peCeWyd, + G2 “> Con + Hd 4 3-4 g 34.61 5 40g 2. (18 pts.) The combustion analysis of a 13.42 g sample of equilin ( which contains only carbon, hydrogen and oxygen) produced 39.61 g CO2 and 9.01 g HO. Find the simplest formula for equilin. The molar mass of equilin is 268.34 g/mol. Find the molecular formula for equilin. 44.01 : Avao\C rage) _ Mass of C= (8,400 wel | oe): Wl 6 Awe | ‘ (34. sa (8,) Re hia } = 0. FO mol Mqoo = Bot g Hs} q Sel \= 6.500 wel Wr0 \b. og Lest 4h \ 4 Aah SES ef W = (>. Ceo mol tro YEE oe vel Awot Wad A wot te wo! erie Ce, 0 “o> Neg +408 mol © [y.Aoo Hit soo +) + y= 2X AH = UF OF \ A Rvap¥st _ Aweo\ = OOS mo [ooo Kass py 6. =) Nos Vbo4 aA > ¥, (Simplest formula acnss ce = beeen ergs) devs ao 3. (a) (9 pts.) If 75 mL of a sulfuric acid solution reactd $ith'&cess zinc metal to produce 15.58 liters of hydrogen gas(Hz) at STP, what is the molarity of the acid? Zn(s) + HpSOs(ag) > ZnSO«(aq) + He(g) ey _ Mooamlissstb) 2064 me A n 4 we Deedee 0 0K) Lraton| wri Ad) QT3-N5 IC) away = 0-64 wal PUA ore ae eH ott AVC R te Sarre cee iti ea seta 41eW WaSey> Oops ~ Loe (b) (7 pts.) The density of a 20.0 %by mass ethylene glycol (antifreeze), CoHsO., solution in water is 1.03 g/mL. Find the molarity of this solution.( Molar mass of CaH02= 62. 068 g/mol) 3 = 03 KO AL fol mass = Goo) xlt03) # a MaS$eL GUYOr= COmoylLo3ngs )= 706.04 CrHede Awo = 7 206.0 96NGOe eps DBZ mol Mewes y= 42.068 9(ps a J\- wb) =PT 4, (15 pts.) A storage tank containing nitrogen gas has a volume of 500.0 L and contains 98.6 kg of Nz gas at a temperature of 29,4 °C. Calculate the pressure using both the ideal gas law and the van der Waal’s equation(real gas equation) and compare the results,( For nitrogen; a= 1.390 atm .L? mol, b= 0.03913 Lamol') Anal, fas sane )elo.o621) (Boe59) ) Ge GB bxteg a JC a L855) Vdeq Vv (sso. °) = 35-72) wl care owl. = 3.52010 = A\S4. 4 akw- W290) osx e net ae iw Sth uo =r ais Teena een = ee Sanat GS revo )(.03'5) (Soa. = AMrze — 68-84 =13e. 37 oe Pid Pret ia deal \az-4 aig Yo ye UNAS EM ete = 148 th Wesvawow = yea Nery cena, 5. (16 pts.) A mixture of gas contains 4 moles O2, 5 moles Nz and 2 moles CO . The total pressure is 12.1 atm. What is the partial pressure of each gas? What is the density , in g/L, of this gas mixture at 25.0 °C? Pps 24 ate 5 she: ara 5 Bray = Kail Pegat Megat 2% = ase 4 Mere Ze ouses kz WO rae = = Fy 0-364 Wye ap = OeSHS Re Po = (g. 3's] Wat} = GU akny - Gy B =(9- se s4s) (ALA) = 5.8 ae = (o igi) Ur Ay Qc ake Nace uncle? Wass = (Foe 32 0) (ey & AB 9 = 2A.4 5 lmel = PMs | Gat G2-4) hse d. 16-0 gle XG pts QT * @es1) @aesy se ) + (ia)6. (a) (4 pts.) What is the final molarity of sodium ions if 50.0 mL of 0.25 M Na,SOx is combined with 50.0 mL of 1.00 M NaCI? Assume the total solution volume is exactly 100.0 mL. (so-oxi L) som) + (so oui EL) (U-0m) = Nad = 0.025 b OSD = V-OFS wort Nat mM. - 2:035uel 2 ots Ne Ooo (b) (6 pts.) An aqueous solution of sodium sulfide is added to an aqueous solution of Pb(NO3)2. Lead(Il) sulfide precipitates. Write the balanced molecular, total ionic and net ionic equations for this reaction. hac Stet) F PGs) 44) SSD TAMA DX wWetCagy Hs Slag +P ag) ANd glug) > PSG) FANE ee NDa (a4) S*agy PL ag) —s Pk SL) (©) (6 pts.) Calculate the following to the correct number of significant figures: i) 2.5019 +25,671-28.15=0.92 ii) [6.7365)x(1.306)x3.20) (4.259- 5. 6S G iii) [(53.02)x(0.0003320)x(6.70x10°))(6.235x10°) + 23500687 = Q__ (Bro (@) G@ pts.) Name the following: ) HNO: — NVtwee aud ii) HCIO, Pevellowte acid iii) HySOx : SurLuwe aad