DEPARTMENT OF METALLURGY @ TPRIALS F SCP eRe Hot OF UNGINEPRING « pan ING & EMERGING TECHNOL Oni URSLLY OF THE Puy 1" PAR oe a KSHTY OF TH HORE-54890, PAKISTAN 5 4 ter: 32 Date: 09. 94-2 xy durin read out the follow ne. drtcies from hermal Ineversibte Work done Endhalpy. 1 eifle heat at constant pressure. Molar Speific he ‘ble Wark dome; Carnot emgine, E, rey of Cormen calculations Universal Gas Constant ~ R~ BIN J. me lta! Foniet 1 {sothermal Reversible Work done = Variable Pressure %O-01: Find change io Inenal energy, heat and work done if 2 moles of b Pressure expand isothermal bt SO°C and reversby to a presure of bat, (Anzeer: 0.5. 594d 5945 Wo goth ropen at} etm £Q02: Catculne i reduced betaves i 7 mt 0 dee = 4 PQ-03: Calculste the work do isothermally from 2 sim. t0 10 201797 g mole} (Answer: 87524) Topics 2: ermal Reversible Wark done - Variable Ve & What is the maxjwem work which can be obtained by the isothermal Sxpansion of two moles hues foes of en dea gas 275 Krom 1.13 lire to 112 res? s a answer PQ-0S: Find the work Jone when 2 motes of en ideal gas expand isotherally from 2 ares to res against a Constont pressure of I atm at 298 K (Ansmer: 4 $4085) Tonics 3: fatten, athe Deere 2 If one gram of water (373 5 is converted into steam atthe sume temperature. The ‘volume of water Becomes 1671 rl on boiling. Calculate the change tv te iseral energy of if the Feat of vaporization is 2259.36 J.g" (Molecular TROIS the sy =y, PQ-67;sFor the resction Hos gy — He) Fle) | 71 aioe tereston sop, on Frei AL 2: “Cfo the combustion of 1 mole of liquid benzene the beat hee gute is given by ee an Cle () + 73040) — seo) ND | ane oe ~ 59.4124 bvmoke wh 25° C. Calcul pent of resction tc i a (aaswefs S268 80) Lv faiteficiney of Camot engine wo how mach ets gen ied ire Costin is 180 ROC and tire “ cn $00 K sd 880K he Answers 16> 44 latent 1 Gaaswer {1.30145a geTMENT OF METALLL Gy & MATERIALS ENGINEERI op OF ENGIN eRaiNG TECH ' “OL UERSITY OF THE PUNJAB, LALORE PAKISTAN a so.03 ster Dat m ry, Entropy ft oe Cinb Free Emerg ith Vion variables erie Universal Gax Constant = R= BALA Jmol! 6 PQ-OL: Co! ren | mole of Belium 1 constant press in entropy eof helium i un molar heat capacit _ PODS: Wrat is the chant at constant pressure whe Entropy = Constant Temperature favolved in thermodynamic es at 303K. ¢ (Answer: 3.950 expansion of 2 moles of 8 the entropy change i of § litres to a volume of $0 li 13.29 JK Tires (Answer: 3 2 fies t2 20 phen 28 g of Nz gas expands reversibly from son 14 g.wcle™) aleulate OS ular mass of tro the entropy changes 93 K from a pressurd of 10 aim (0 P Enteony — Constant Volume when 3 moles of on ideal & 39-94 J. Lol az change in entsp # eotame with C vogs FfFAW: Foe the reacto ©()~ 0x8) COs) : 1 enthalpy changes and fee. energy. chang) ar 1 15609 bs at 28°C Calculate the val uy change st x (4) 30% = 207 Cg) " 33.089 end kd eespoctvely.€ S Yalues of enthalpy changes °C Calculate the satus nd 56.69 kd ve ~66.944 and 11.84 ks 0K, if AM and 4S remain con Answers -€9 544 t Fs does of neal gas can expand reversibly and isothermay “wert of atm ta presure of 0.1 am, What nthe change oT ‘Answers 8 etiee I: Gibbs Free Energy = Constant Temperature with variable Vo CLUE four oles ofan ideal gas expand fcihemally from Lee eo aleulae the change in fee energy ofthe a Answer: 37 LeMENTOR MEN ATE! VERIALS ENGINE per a carbon monaxide (CO) and cb a S. fall teaction: ooder of [SOs] ard [0, reer q a 201 C10 = ClO H.C Earn [e103 (or fp Write the a constant (k)? zbon monoid Experiment ais 6 aes ABI oR iT nd Teo aye IU fr he above rected ON fe i te tion? (@) Dy CAnssers (a) tan x PQ00: The following data vere . 5 " 101 Tatil Re (iy ot Le 198 c wet ‘ Pig(Ans aL Reves Vtt Lite Sembine to form mote Kg nd-order Feaction jg © completion ther § [N04 5 it will Answer: 00 se th one-t An Hh completed in 39 Minutes. ¢, SS comnpretcg culate the tim, *5 5 minutes for th © Initia co minute 'o became 0.19, HE Constant of the ta a Would OAT, (Answer: iyWI seco) ; smodyaamies and Kinitind Courts Boater Pner Armen Farry DEPARTMENT OF METAUT YS MATERIALS FSG SUE LRENG Col Lat OF ENGINEERING & EMERGING TECH iL OG LINIVERSITY OF THE PUNJAB, LAHORL PINAL TERM EXAM SYLLABUS netics Semester: 3% ; Materials Thermodynamics and B Subjec 1 sothonne! Qos eisivle Work done 2 Isothermal lnucversible Work done x Enthelpy LAP Heat Capacit 5, Molar Specific heat U6” Molar SpocitTe heat at constant pressure 7% Molar Spe-itic heat at constant volume “Adiabatic Reversible Work done 96 Camot engin: “10. Efficiency of Camot engine (Practice Questions Set-04) V6 Third Law of thermodynamics Az Entropy "3% Entropy change with Temperature and Volume as variables (Cons _J4 Entropy change with Temperature and Pressure as variables (Const JS: Entropy changes at Constant Volum: Aé-Entropy changes at Constant Pressuze (W3eEntropy chonges at Constant Temperature JS Gibb’s Free Energy JW Gibb's Free Energy with Pressure variables 26. Gibb's Free Energy with Volume variables, (Practice Questions Set-03) Ht Biliegham Diagram . (Assignment No | aud MCQ’s Quiz) SE Chemical Kin 25. Asrhienius Equation 20 Eosrgy profile 1S. poweston Energy typ of © OP Hana of 24 eave law as ovo gquemians 29, Drser at woastion J Seeactions (Homogeneous aud Noa-Homogensus) Page bot?namics and K Course Ingty Hetoy } Fitst Ordey Reaction a, nd Secand Org, (Prac Questions Ser-06) Sw wy ““* Questions — 40 mcgr, ~20 Marks Namericat * Descriptive Short Questions - 20 Marks