Al Ms App Catalog Thinfilms PDF

253
Materials for
Thin Films/Microelectronics
Anhydrous Halides Ordered by Element – High Purity Metals/Elements . . . . . . . . . . . . . . . . . . .330
69 Different Element Listings . . . . . . . . . . . . . . . . . . .255 Metals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .330
Mixed-Metal Halides . . . . . . . . . . . . . . . . . . . . . . . .289 Alloys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .347
CVD & ALD Precursors . . . . . . . . . . . . . . . . . . . . . . . . .290 Polyamic Acids for High κ Dielectrics . . . . . . . . . . . . .347
Anhydrous Metal Nitrates . . . . . . . . . . . . . . . . . . . .290 Polyelectrolytes for SAMS:
High Purity Gases for CVD . . . . . . . . . . . . . . . . . . . .291 See Materials for Lithography/Nanopatterning . . . . .190
Gas Equipment: Semiconductors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .348
See Equipment . . . . . . . . . . . . . . . . . . . . .513 Cyclopentadienyl Lanthanide Dopants:
Deuterated Gases . . . . . . . . . . . . . . . . . . . . . ..293 See Metal-Organic Precursors . . . . . . . . . . . . . . . . .303
Halogenated Gases . . . . . . . . . . . . . . . . . . . . .294 Sol-Gel Precursors Ordered by Element –
Metal Alkoxides: 52 Different Element Listings . . . . . . . . . . . . . . . . . . .349
See Sol Gel Precursors . . . . . . . . . . . . . . . .347 Lithium Containing Precursors:
Materials for Thin Films/

Microelectronics
Metal β-Diketonates . . . . . . . . . . . . . . . . . . . . . . . .295 See Metal-Organic Precursors . . . . . . . . . . . . . .158
Acetylacetonates (ACAC) . . . . . . . . . . . . . . . . .295 Other Silanes:
See Silane Coupling Agents/
Heptafluorodimethyloctanedionates (FOD) . . . . .300 Adhesion Promoters . . . . . . . . . . . . . . . . . . . . .227
Tetramethylheptanedionates (TMHD) . . . . . . . . .301 Other Silanes:
Metal-Organic Precursors Ordered by Element – See Inks for Microcontact Printing . . . . . . . . . . .208
44 Different Element Listings . . . . . . . . . . . . . . . . . .303
Polymeric Precursors for SiC Films & Fibers . . . . . . . .330
254
An introductory overview of barrier materials, high k dielectric materials, and atomic layer deposition (ALD) is provided in the Technical Appendix
section.
Thin films for microelectronics are generally formed by one of three techniques, deposition techniques, solution-gelation (sol-gel), or self-assembly of
monolayers (SAM). Deposition is currently the most studied of these techniques and can be divided into two main categories: chemical vapor
deposition (CVD) and physical vapor deposition (PVD). Physical vapor deposition involves such techniques as molecular beam epitaxy (MBE), where a
material is vaporized and vacuum-sprayed onto a surface.
In CVD a material is volitalized as in PVD, but undergoes a chemical change (typically loss of functional groups) in order to deposit on a surface. Atomic
layer deposition (ALD) is a subcategory of CVD, where films are deposited one layer at a time. A number of articles have been published on CVD and
ALD techniques.1-4
www.sigma-aldrich.com/safc
High k Dielectric Materials

For almost 50 years, the semiconductor industry has been based on the properties of silicon. One of the basic structures in microcoelectronics is the
capacitor, which is defined by the electrically stable Si/SiO2/Metal materials stack (see Figure 1). As integrated circuit design shrinks, elements of the
circuit must be miniaturized. This relentless miniaturization has led to enhanced chip performance in terms of processing speeds and to expanded
memory capacities at diminishing unit costs. Previously, limits on miniaturization were largely technological in nature, whereas now the fundamental
properties of silicon dioxide itself are restricting further device size reduction.
Competitive Quotes on Larger Quantities/Custom Synthesis: Sigma-Aldrich Fine Chemicals
Microelectronics
Figure 1. Cross-sectional view of a typical integrated circuit showing details of the Si/SiO2/Metal materials stack forming the gate capacitor structure in the inset.
Candidate Materials
According to ITRS (International Technology Roadmap for Semiconductor) data the best candidate for gate material should possess a dielectric
constant, k, in the 10 - 25 range. Material for memory capacitor should have much higher k value. Table 1 shows the relevant properties of some high
k dielectric candidates.
Conduction
Relevant Properties of High-k Dielectric Candidates band
Conduction Dielectric Band gap offset to Si Crystal
band Material constant k Eg (eV) Ec (eV) structure
Dielectric Band gap offset to Si Crystal Al2O3 9 8.7 2.8* Amorphous
Material constant k Eg (eV) Ec (eV) structure Y2O3 15 5.6 2.3* Cubic
SiO2 3.9 8.9 3.2 Amorphous La2O3 30 4.3 2.3* Hexagonal,
Si3N4 7 5.1 2 Amorphous cubic
255
High k Dielectric Materials
Candidate Materials
al. Surface Coating Tech. 1997, 17, 147. (4) Holstein, W.L. Prog. Cryst.
Conduction
Growth Cha. Mat. 1992, 24, 111. (5) Vogel, E.M. High-k Gate
band
Dielectric Band gap offset to Si Crystal Dielectrics, MRS Workshop, New Orleans, LA., June1-2, 2000.
Material constant k Eg (eV) Ec (eV) structure
Ta2O5 26 4.5 1-1.5 Orthorhombic
TiO2 80 3.5 1.2 Tetragonal
(rutile, anatase) Anhydrous Halides
HfO2 25 5.7 1.5* Monoclinic, For an application overview and listing of ultra-pure inorganics and
tetragonal, metals for high-technology please request your copy of the AAPL,
cubic Aldrich-APL brochure.
ZrO2 25 7.8 1.4* Monoclinic,
tetragonal,
cubic Aluminum
*Calculated by Robertson2
Aluminum bromide
Table 1. Candidates for high k dielectrics and their relevant properties.
Your local Sigma-Aldrich office: See Back Cover

CAS No. 7727-15-3
AlBr3 FW 266.7
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97 C (lit.)
Chemical Vapor Deposition Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.205 g/mL (lit.)
R: 14-34 S: 26-36/37/39-43-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Several different techniques are used for deposition of barrier layers. 44,960-1 anhydrous, powder, 99.999% 5g
Reactive sputtering is the oldest technique, and it has been the main Packaged under argon in ampules 25 g
process for depositing tantalum nitride films. Sputtered films are usually H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
quite free from impurities and have low resistivity, but the step coverage . . . . . . . . . . . . . . . . . . . . . . . . . . . .
is poor. 40,121-8 99.99+% 5g
25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
21,007-2 powder and chunks 5g
Microelectronics
Chemical Vapor Deposition (CVD) method is the main technique Vapor pressure. . . . . . . .1 mm Hg ( 81.3 C) 25 g
currently used for deposition of metal nitride layers for different 100 g
applications. The films made by CVD exhibit much better conformal
coverage than the films deposited by physical vapor deposition methods. Aluminum chloride
CAS No. 7446-70-0
Good deposition precursors should not only be volatile but should also AlCl3 FW 133.3
have predictable decomposition routes, with gaseous or highly volatile The vapor-phase co-reductions with other metal halides by
side products from decomposition. Metal organic precursors can be hydrogen results in finely divided intermetallics with
designed to meet all these needs, but care must be taken in their applications as structural materials or compounds with useful
synthesis. Scientists at Sigma-Aldrich ensure the high-purity standards thermoelectric, magnetic, and oxidation-resistance properties.
necessary for MOCVD precursors by using only the highest purity Aluminum nitride can be synthesized from the elemnts with
starting materials: metals, metal halides, or organometallic reagents as
800.558.9196 (USA)
AlCl3 added to help facilitate crystallization.
well as high-purity solvents and organic ligands. References
1. Sohn, H.T.; PalDey, S., J. Mater. Res. 13, 3060 (1998)
2. Haber, J.A. et al., J. Am. Chem. Soc. 119, 5455 (1997)
R: 34 S: 28-45-7/8
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
56,391-9 anhydrous, powder, 99.999% 5g
25 g
/ . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . 190 C (lit.) 25 g
Density. . . . . . . . . . . . . . . . 2.44 g/mL (lit.) Ordering/Pricing: www.sigma-aldrich.com
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
29,471-3 99.99% 5g
100 g
500 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
49,535-2 granules, 99.9+% 1 kg
mp . . . . . . . . . . . . . . . . . . 190 C (S) (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.44 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
23,705-1 99%, mp 190 C 5g
Vapor pressure. . . . . . . . 1 mm Hg ( 100 C) 100 g
500 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,691-1 98% 5g
Vapor pressure. . . . . . . 1 mm Hg ( 100 C) 100 g
mp . . . . . . . . . . . . . . . . . . .190 C (lit.) 1 kg
Density. . . . . . . . . . . . . . . 2.44 g/mL (lit.)
The highest quality components are used for the syntheses of MOCVD precursors
in order to assure their purity.
References (1) Choy, K.L. Prog. Mat. Sci. 2003, 48, 57. (2) Yoon, D.-S.;
Roh, J.S. Critical Rev. Solid State Mat. Sci. 2002, 27, 143. (3) Safaie, S. et
256
Anhydrous Halides
Aluminum
Aluminum fluoride Antimony(V) chloride

CAS No. 7784-18-1 (Antimony pentachloride)
AlF3 FW 83.98 CAS No. 7647-18-9
R: 25-36/37/38 S: 26-36/37/39-45 SbCl5 FW 299.0
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.36 g/mL (lit.)
44,962-8 anhydrous, powder, 99.9+% 10 g
R: 34-51/53 S: 26-45-61
Packaged under argon in ampules 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Used extensively in the preparation of 45,167-3 anhydrous, 99.999+% 1g
doped fluoride glasses1 and in a mixed-metal fluoride Packaged under argon in ampules 10 g
catalyst for synthesis of HFC-134a.2 (1) Opt. Commun. bp. . . . . . . . . . . . . . . 92 C/30 mm Hg (lit.)
1996, 132, 73. J. Lumin. 1996, 69, 121. Appl. Phys. Lett. H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1996, 69, 2012. Electron. Lett. 1996, 32, 1586. (2) Catal.
33,887-7 99.99+% 5g
Lett. 1996, 41, 221. Vapor pressure. . . . . . . 1 mm Hg ( 22.7 C)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1 g/mL (lit.)
25 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,291-7 solid 10 g 21,517-1 99% 50 g
Vapor density. . . . . . . . . . . .>10.2 (vs air) 250 g
100 g
Vapor pressure. . . . . . . . . 0.13 psi ( 55 C) 1 kg
Vapor pressure. . . . . . . . 1 mm Hg ( 23 C)
Aluminum iodide bp. . . . . . . . . . . . . . . . . . . . . . . . . 92 C/30 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.8 C (lit.)
CAS No. 7784-23-8
AlI3 FW 407.7 Antimony(III) fluoride
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.98 g/mL (lit.)
(Antimony trifluoride)
R: 14-34-40-42/43 S: 22-26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7783-56-4
40,932-4 anhydrous, powder, 99.999% 1g SbF3 FW 178.8
Packaged under argon in ampules 5g R: 23/24/25-51/53 S: 7-26-45-61

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm 25 g

. . . . . . . . . . . . . . . . . . . . . . . . . . . . 38,129-2 powder, 99.8% 100 g
Pb. . . . . . . . . . . . . . . . . . . . . . contains 500 g
20,849-3 Technical Grade, 95% 25 g
Color. . . . . . . . . . . . . . off white to beige
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.38 g/mL (lit.)
bp. . . . . . . . . . . . 360 C/760 mm Hg (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,111-1 98% 100 g
mp . . . . . . . . . . . . . . . 235 C (dec.) (lit.) 500 g
Antimony Density. . . . . . . . . . . . . . .4.379 g/mL (lit.)
Antimony(III) bromide Antimony(V) fluoride

CAS No. 7789-61-9 (Antimony pentafluoride)
SbBr3 FW 361.5 CAS No. 7783-70-2
R: 14-34 S: 26-27-28-36/37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . . SbF5 FW 216.8
40,115-3 99.99% 5g Packaged in Teflon bottles
. . . . . . . . . . . . . . . . . . . . . . . . . . . . HF/SbF5 is an excellent medium for the preparation of
33,904-0 99% 10 g alkylidene oxonium salts. Minkwitz, R. et al. Inorg. Chem. 1999,
Vapor pressure. . . . . . . . . . 1 mm Hg ( 94 C) 50 g 38, 844.
Density. . . . . . . . . . . . . . . . 4.148 g/mL (lit.) Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . .2.2 (vs air)
Vapor pressure. . . . . . . . . . . . . . . . . . . . . . 10 mm Hg ( 25 C)
Antimony(III) chloride Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.993 g/mL (lit.)
R: 14-23/24/25-35 S: 26-27-28-36/37/39-45
(Antimony trichloride) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 10025-91-9 48,101-7 99.99% 5g
SbCl3 FW 228.1 liquid
Vapor pressure. . . . . . . . . . . . . . . . . . . . . 760 mm Hg ( 223 C) bp. . . . . . . . . . . . . . . . . . . . . . . 143 C/760 mm Hg (lit.)
R: 34-51/53 S: 26-45-61 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,736-6 99.999% 10 g 17,512-9 bp. . . . . . . . . . . 149.5 C/760 mm Hg (lit.) 5g
Vapor pressure. . . . . . . . 1 mm Hg ( 49.2 C) 50 g 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 g
33,737-4 99.99+% 10 g
Vapor pressure. . . . . . . 1 mm Hg ( 49.2 C) 100 g Antimony(V) fluoride on graphite
Density. . . . . . . . . . . . . . . 3.14 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
39,990-6 CAS No. 7783-70-2 5g
21,578-3 99% 500 g
Vapor pressure. . . . . . . . 1 mm Hg ( 49 C) SbF5 FW 216.8
2 kg
bp. . . . . . . . . . . .283 C/760 mm Hg (lit.) Extent of labeling: 50 wt. % SbF5
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73.4 C (lit.) R: 23/24/25-34 S: 26-27-28-36/37/39-45
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.14 g/mL (lit.)
257
Anhydrous Halides
Antimony
Antimony(III) iodide 44,963-6 anhydrous, beads, -10 mesh, 99.99% 5g

Packaged under argon in ampules 25 g
(Antimony triiodide) mp . . . . . . . . . . . . . . . . . . . . 563 C (lit.)
CAS No. 7790-44-5 Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.856 g/mL (lit.)
SbI3 FW 502.5 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 14-34-43 S: 26-27-28-36/37/39 R: 20/22 S: 28
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,056-7 anhydrous, -10 mesh, 99.999% 5g 44,965-2 anhydrous, beads, -10 mesh, 99.95% 10 g
Packaged under argon in ampules 25 g Packaged under argon in ampules 50 g
bp. . . . . . . . . . . . . 401 C/760 mm Hg (lit.) mp . . . . . . . . . . . . . . . . . . . . 963 C (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.856 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 4.921 g/mL (lit.) H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm R: 20-25 S: 45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
40,118-8 98% 10 g 34,292-0 -60 mesh, 99.9% 10 g
Density. . . . . . . . . . . . . . . . 4.92 g/mL (lit.) 50 g R: 20-25 S: 45 50 g
250 g
Antimony oxyiodide

Crystal Grade Barium fluoride See: Crystal Grade Inorganics Page 406
57,380-9 CAS No. 15513-75-4 1g

Barium fluoride
SbOI FW 264.7 5g
R: 20/22-36/37/38-51/53 S: 26-36/37-61
CAS No. 7787-32-8
BaF2 FW 175.3
R: 20/22 S: 28
Arsenic . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,274-6 99.99% 20 g
Arsenic(III) chloride Density. . . . . . . . . . . . . . . 4.89 g/mL (lit.) 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,007-7 CAS No. 7784-34-1 25 g 37,879-8 optical grade, random crystals, 99.9+% 25 g
AsCl3 FW 181.3 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
powder, 5 mm, 98%
Microelectronics
23,610-1 100 g

99.99%
Density. . . . . . . . . . . . . . . .4.89 g/mL (lit.) 500 g
Packaged in ampules
bp. . . . . . . . . . . . . . . . . . . . . . 130.2 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -16 C (lit.) Barium iodide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.15 g/mL (lit.)
R: 23/25-50/53 S: 20/21-28-45-60-61 41,361-5 CAS No. 13718-50-8 5g
BaI2 FW 391.1 25 g
Arsenic(III) iodide anhydrous, beads, -10 mesh, 99.995%
Packaged under argon in ampules
40,114-5 CAS No. 7784-45-4 5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 740 C (lit.)
AsI3 FW 455.6 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.15 g/mL (lit.)
99% H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.69 g/mL (lit.) R: 20/22 S: 28
800.558.9196 (USA)
R: 23/25-50/53 S: 20/21-28-45-60-61
Beryllium
Barium
Beryllium chloride
Barium bromide
20,119-7 CAS No. 7787-47-5 5g
41,360-7 CAS No. 10553-31-8 1g BeCl2 FW 79.92 25 g
BaBr2 FW 297.1 5g Purified by sublimation, 99%
anhydrous, beads, -10 mesh, 99.999% 25 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 399 C (lit.)
Packaged under argon in ampules Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.899 g/mL (lit.) Ordering/Pricing: www.sigma-aldrich.com
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm R: 49-25-26-36/37/38-43-48/23-51/53 S: 53-45-61
R: 20/22 S: 28
Barium chloride Bismuth
CAS No. 10361-37-2 Bismuth(III) bromide

BaCl2 FW 208.2
40,107-2 CAS No. 7787-58-8 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . BiBr3 FW 448.7 100 g
44,964-4 anhydrous, beads, -10 mesh, 99.999% 5 g 98+%
Packaged under argon in ampules 25 g Catalyzes the formation of cyclic carbonates which are
mp . . . . . . . . . . . . . . . . . . . . 563 C (lit.) important precursors for polycarbonates and other
Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.856 g/mL (lit.) polymeric materials.
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 5.7 g/mL (lit.)
R: 20/22 S: 28 R: 34 S: 22-26-27-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,273-8 99.999% 5g
mp . . . . . . . . . . . . . . . . . . . 963 C (lit.) 25 g
Density. . . . . . . . . . . . . . .3.856 g/mL (lit.) 100 g
R: 20-25 S: 45
258
Anhydrous Halides
Bismuth
Bismuth(III) chloride 30,761-0 99% 50 g

250 g
CAS No. 7787-60-2
BiCl3 FW 315.3 Bismuth(III) oxyiodide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.75 g/mL (lit.)
R: 36/38 S: 26-36 33,537-1 CAS No. 7787-63-5 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . BiIO FW 351.9
47,027-9 anhydrous, beads, -10 mesh, 99.999% 5 g R: 20/21/22-36/37/38 S: 26-37/39
mp . . . . . . . . . . . . . . . . . . . . 230 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Boron
Boron tribromide

bp. . . . . . . . . . . . . 447 C/760 mm Hg (lit.)
CAS No. 10294-33-4
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm BBr3 FW 250.5
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . .8.6 (vs air)
25,414-2 99.999% 25 g Vapor pressure. . . . . . . . . . . . . . . . . . . . . . 40 mm Hg ( 14 C)
125 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -46 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.65 g/mL (lit.)
22,483-9 98+% 25 g R: 14-26/28-35 S: 9-26-28-36/37/39-45
mp . . . . . . . . . . . . . . . . 230-232 C (lit.) 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
23,036-7 99.99+% 5g
500 g
Useful for the synthesis of precursors to 25 g
group 13-15 semiconductor materials. 100 g
Bismuth(III) fluoride
Lube, M.S. et al.
CAS No. 7787-61-3
BiF3 FW 266.0 Packaged under nitrogen in ampules
R: 34 S: 26-36/37/39-45 bp. . . . . . . . . . . . . . . . . . . . . . . . 90 C/760 mm Hg (lit.)

. . . . . . . . . . . . . . . . . . . . . . . . . . . . References
Microelectronics
40,152-8 99.99+% 5g Lube, M.S., Inorg. Chem. 35, 5007 (1996)

25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 20,220-7 99.9% 25 g
31,696-2 98% 25 g 2-kg and 250-g units packaged under 100 g
100 g nitrogen in Sure/Seal bottles, other 250 g
units in ampules 2 kg
Bismuth(V) fluoride liquid
Color. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . colorless
51,591-4 CAS No. 7787-62-4 25 g bp. . . . . . . . . . . . . . . . . . . . . . . 91.3 C/760 mm Hg (lit.)
BiF5 FW 304.0
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
41,950-8 99+% 100 g
99.9%
liquid 500 g
Packaged in Teflon bottles
Color. . . . . . . . . . . . . . colorless to amber
solid bp. . . . . . . . . . . . . . . . . . . . . . . . 90 C/760 mm Hg (lit.)
R: 8-34 S: 17-26-27-36/37/39
Boron trifluoride diethyl etherate
Bismuth(III) iodide
32,018-8 CAS No. 109-63-7 1L
CAS No. 7787-64-6
BF3 O(C2H5)2 FW 141.9
BiI3 FW 589.7
Packaged in poly-coated bottles
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 408 C (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . 4.2 mm Hg ( 20 C)
R: 34 S: 26-27-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.344 (lit.)
45,683-7 anhydrous, beads, -10 mesh, 99.999% 1 g bp. . . . . . . . . . . . . . . . . . . . . . . 126 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -58 C (lit.)
Packaged under argon in ampules 5g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118 F
Is used to make single crystals of alkyl 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.12 g/mL (lit.)
bismuth diiodides which are useful R: 10-20/22-34-48/23 S: 26-36/37/39-45-61
intermediates in synthetic organic chemistry. Mitzi, D.B.
Inorg. Chem. 1996, 35, 7614. Boron triiodide
Density. . . . . . . . . . . . . . . . . . . . . . . . . 5.778 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 30,762-9 CAS No. 13517-10-7 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,947-4 99.999% 10 g BI3 FW 391.5 5g
Density. . . . . . . . . . . . . . .5.778 g/mL (lit.) 100 g 98+% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 3.35 g/mL (lit.)
34,101-0 99% 25 g R: 23/24-34 S: 26-36/37/39-45
Density. . . . . . . . . . . . . . . 5.78 g/mL (lit.) 100 g See also halogenated gases See: Halogenated Gases Page 294
Bismuth(III) oxychloride
CAS No. 7787-59-9
BiOCl FW 260.4
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,948-2 99.99+% 10 g
50 g
259
Anhydrous Halides
Cadmium
Cadmium bromide 22,231-3 Technical Grade 25 g

Vapor pressure. . . . . . . 0.01 mm Hg ( 20 C) 1 kg
mp . . . . . . . . . . . . . . . . . . . 782 C (lit.) 5 kg
41,362-3 CAS No. 7789-42-6 1g
Density. . . . . . . . . . . . . . . 2.15 g/mL (lit.)
CdBr2 FW 272.2 5g
anhydrous, beads, -10 mesh, 99.999% 25 g
Packaged under argon in ampules Calcium
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 20/21/22-50/53 S: 60-61
Calcium bromide
Cadmium chloride CAS No. 7789-41-5
CaBr2 FW 199.9
CAS No. 10108-64-2 R: 38 S: 22-24/25
CdCl2 FW 183.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 45-46-60-61-25-26-48/23/25-50/53 S: 53-45-60-61 41,363-1 anhydrous, beads, -10 mesh, 99.98% 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
43,980-0 anhydrous, beads, -10 mesh, 99.999% 5 g Density. . . . . . . . . . . . . . . . .3.353 g/mL (lit.)
Packaged under argon in ampules 25 g H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm

Density. . . . . . . . . . . . . . . . 4.05 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 33,888-5 96% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . water. . . . . . . . . . . . . . . . . . . . . . <2% 250 g
20,290-8 99.99+% 10 g
Vapor density. . . . . . . . . . . . . . . 6.3 (vs air) 50 g
Vapor pressure. . . . . . . . 10 mm Hg ( 656 C) Calcium chloride
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 568 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 4.047 g/mL (lit.) CAS No. 10043-52-4
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CaCl2 FW 111.0
44,968-7 anhydrous, beads, -10 mesh, 99.9+% 10 g Packaged under argon in ampules
Packaged under argon in ampules 50 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.15 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . 568 C (lit.) R: 36 S: 22-24
Density. . . . . . . . . . . . . . . . . . . . . . . . . 4.047 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
42,975-9 anhydrous, beads, -10 mesh, 99.99+% 1g
Microelectronics
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cadmium fluoride
mp . . . . . . . . . . . . . . . . . . . . 772 C (lit.) 10 g
CAS No. 7790-79-6 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CdF2 FW 150.4 44,970-9 anhydrous, beads, -10 mesh, 99.9+% 2g
R: 45-46-60-61-25-26-48/23/25-50/53 S: 53-45-60-61 mp . . . . . . . . . . . . . . . . . . . . 772 C (lit.) 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm 50 g
22,951-2 99.98% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
30,763-7 98% 25 g Calcium fluoride
Cadmium iodide CAS No. 7789-75-5
CaF2 FW 78.08
800.558.9196 (USA)
CAS No. 7790-80-9 R: 20/22-36/37/38 S: 26-36
CdI2 FW 366.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 388 C (lit.) 37,880-1 random crystals, optical grade, 99.99% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.67 g/mL (lit.)
R: 23/25-33-50/53-68 S: 22-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Packaged under argon in ampules 25 g
44,969-5 anhydrous, beads, -10 mesh, 99.999% 5 g Employed in a study of selectivity and
Packaged under argon in ampules 25 g response time of ion-selective electrodes,1 and in the
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm development of novel bioactive bone cements.2 (1) Aust.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . J. Chem. 1996, 49, 897. (2) Bioceram. Proc. Int. Symp.
20,291-6 99.999% 10 g
Ceram. Med. 1994, 7, 279.
50 g
Ordering/Pricing: www.sigma-aldrich.com
. . . . . . . . . . . . . . . . . . . . . . . . . . . . bp. . . . . . . . . . . . . . . . . . . . . . 2500 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.18 g/mL (lit.)
22,851-6 99% 50 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
bp. . . . . . . . . . . . 787 C/760 mm Hg (lit.) 250 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
23,794-9 powder, -325 mesh, 99.5+% 5g
Calcium chloride Density. . . . . . . . . . . . . . . .3.18 g/mL (lit.) 100 g
500 g
CAS No. 10043-52-4
CaCl2 FW 111.0 Calcium iodide
R: 36 S: 22-24
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
38,315-5 -30-+80 mesh, 97% 100 g CAS No. 10102-68-8
Density. . . . . . . . . . . . . . . .2.15 g/mL (lit.) 500 g CaI2 FW 293.9
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 61 S: 53-22-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
38,314-7 96+%, ‡96.0%, ACS reagent 100 g
43,979-7 anhydrous, beads, -10 mesh, 99.999% 5 g
desiccant 500 g
Titr. base. . . . . . . . . . . . . . .£0.006 meq/g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
23,922-4 Technical Grade, -4-+30 mesh 25 g
Porous. An effective desiccant 500 g
Vapor pressure. . . . . . 0.01 mm Hg ( 20 C) 2.5 kg
mp . . . . . . . . . . . . . . . . . . . 779 C (lit.)
mp . . . . . . . . . . . . . . . . . . 782 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.15 g/mL (lit.)
260
Anhydrous Halides
Calcium
(Continuation of) Carbon-13C tetrachloride

Calcium iodide
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 48,848-8 CAS No. 32488-50-9 500 mg
59,070-3 99% 10 g CCl4 FW 153.8
50 g 99 atom % 13C
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.46 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 76-77 C/760 mm Hg (lit.)
Carbon mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -23 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.604 g/mL (lit.)
Bromotrichloromethane R: 23/24/25-40-48/23-52/53-59 S: 23-36/37-45-59-61
Carbon tetarafluoride See: Halogenated Gases Page 294
B8,225-1 CAS No. 75-62-7 100 g
BrCCl3 FW 198.3 500 g
99% Tetrabromomethane
Chain transfer agent for radical polymerization of
C1,108-1 (Carbon tetrabromide) 5g
methacrylates. Brominating reagent.
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . 6.85 (vs air)
CAS No. 558-13-4 100 g
Vapor pressure. . . . . . . . . . . . . . . . . 38.4 mm Hg ( 25 C) CBr4 FW 331.6 500 g
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5065 (lit.)
99%
bp. . . . . . . . . . . . . . . . . . . . . . . 105 C/760 mm Hg (lit.) Vapor pressure. . . . . . . . . . . . . . . . . . .40 mm Hg ( 96 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -6 C (lit.) bp. . . . . . . . . . . . . . . . . . . . . . . 190 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.012 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88-90 C (lit.)
R: 20/21/22 S: 36/37 R: 20/21/22 S: 28
Carbon-13C tetrabromide Tetraiodomethane
48,846-1 CAS No. 72802-79-0 500 mg 26,922-0 (Carbon tetraiodide) 5g

CBr4 FW 331.6 CAS No. 507-25-5 25 g
99 atom % 13C CI4 FW 519.6

bp. . . . . . . . . . . . . . . . . . . . . . . 190 C/760 mm Hg (lit.) 97%
Microelectronics
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88-90 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 168 C (dec.) (lit.)

Manufactured by ISOTEC INC. R: 36/37/38 S: 26-36
R: 20/21/22-36/37/38 S: 26-37/39
Trichlorofluoromethane
Carbon tetrachloride
(CFC-11; Freon 11; Fluorotrichloromethane)
(Tetrachloromethane) CAS No. 75-69-4
CAS No. 56-23-5 Cl3CF FW 137.4
CCl4 FW 153.8 Vapor pressure. . . . . . . . . . . . . . . . . . . . . . . 12.85 psi ( 20 C)
liquid n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3821 (lit.)
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.32 (vs air) bp. . . . . . . . . . . . . . . . . . . . . . . . . . 23.7 C/760 mm Hg (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . . . . . 91 mm Hg ( 20 C) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -111--110 C (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . . . . 143 mm Hg ( 30 C) Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.494 g/mL (lit.)
n20 R: 20-59 S: 23-24/25-59-61
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.46 (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
bp. . . . . . . . . . . . . . . . . . . . . . . . . .76-77 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -23 C (lit.) 25,499-1 99+% 100 mL
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.594 g/mL (lit.) Packaged in Sure/Seal bottles 800 mL
R: 23/24/25-40-48/23-52/53-59 S: 23-36/37-45-59-61 Vapor density. . . . . . . . . . . . 5.04 (vs air)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor pressure. . . . . . . . . . . . . . . . . . . .39.19 psi ( 55 C)
27,065-2 99.9+%, HPLC grade 100 mL . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under nitrogen, bottles are 1L 32,630-5 NMR grade, 99.5+% 5g
Sealed for Quality Packaged in ampules 25 g
Vapor pressure. . . . . . . . . . 39.17 psi ( 55 C)
Purified by Glass distillation
water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <0.010%
Residue upon evaporation. . . . . . . . . . . . . . . . . <0.0004%
Absorbance (l). . . . . . . . . . . . . . . . . . . . . . . . . . in H2O
Cerium
265 nm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.00 Cerium(III) bromide See: Crystal Grade Inorganics Page 406
270 nm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.30
280 nm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.07
290 nm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.02
Cerium(III) bromide
300-400 nm. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.01
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 14457-87-5
31,996-1 99.9%, ACS reagent 500 mL CeBr3 FW 379.8
1L R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
28,911-6 anhydrous, 99.5+% 100 mL 44,972-5 anhydrous, powder, 99.9% 1g
Packaged under nitrogen in Sure/ 1L Packaged under argon in ampules 5g
Seal bottles 6 · 1L mp . . . . . . . . . . . . . . . . . . . . . 730 C (lit.)
Residue upon evaporation. . . <0.0003% H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
2L . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . <0.005%(100 mL Pkg) 4 · 2 L
40,099-8 99% 5g
H2O. . . . . . . . . . . . . . . . . <0.002%
25 g
Cerium chloride See: Crystal Grade Inorganics Page 406
261
Anhydrous Halides
Cerium
Cerium(III) chloride Cesium chloride

(Cerous chloride) CAS No. 7647-17-8
CAS No. 7790-86-5 CsCl FW 168.4
CeCl3 FW 246.5
Packaged under argon in ampules . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 848 C (lit.) 20,302-5 99.999+% 10 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.97 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . . 645 C (lit.) 50 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm Density. . . . . . . . . . . . . . . 3.988 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 44,973-3 anhydrous, beads, -10 mesh, 99.999% 5 g
45,073-1 anhydrous, beads, -10 mesh, 99.9+% 5g Packaged under argon in ampules 25 g
25 g mp . . . . . . . . . . . . . . . . . . . . 645 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.988 g/mL (lit.)
29,819-0 anhydrous, beads, -10 mesh, 99.9% 10 g H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,075-8 anhydrous, beads, -10 mesh, 99+% 10 g Packaged under argon in ampules 50 g

50 g mp . . . . . . . . . . . . . . . . . . . . 645 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.988 g/mL (lit.)
Cerium(III) fluoride H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7758-88-5
50 g
CeF3 FW 197.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
S: 22-24/25 28,932-9 99.9% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,955-5 anhydrous, powder, 99.99% 2g 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 10 g 22,176-7 optical grade, 99+% 5g
Density. . . . . . . . . . . . . . . . 6.16 g/mL (lit.) 50 g mp . . . . . . . . . . . . . . . . . . . 645 C (lit.) 25 g
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm Density. . . . . . . . . . . . . . .3.988 g/mL (lit.) 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
280 nm. . . . . . . . . . . . . . . . . . . . <0.02
23,793-0 powder, 5 mm, 99% 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
250 g 56,259-9 Cabot High-Purity grade 1 kg
Product of Cabot Performance Materials 5 kg
Cerium(IV) fluoride mp . . . . . . . . . . . . . . . . . . . . . . . 645 C
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.988 g/mL
43,593-7 CAS No. 10060-10-3 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CeF4 FW 216.1 25 g 56,260-2 Cabot technical grade 1 kg
99% Product of Cabot Performance Materials 5 kg
R: 20/21/22-32-36/37/38 S: 26-36 mp . . . . . . . . . . . . . . . . . . . . . . . 645 C
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.988 g/mL
Cerium(III) iodide
Cesium dichloroiodide
CAS No. 7790-87-6
800.558.9196 (USA)
CeI3 FW 520.8 57,478-3 CAS No. 15605-42-2 5g
R: 61-42/43 S: 53-26-36/37/39-45 Cl2CsI FW 330.7 15 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 99.999%
45,682-9 anhydrous, powder, 99.99% 1g R: 36/37/38 S: 26-36
mp . . . . . . . . . . . . . . . . . . . . . 750 C (lit.) 5 g Cesium fluoride See: Crystal Grade Inorganics Page 406
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,608-5 anhydrous, beads, -10 mesh, 99.9% 1g
5g Cesium fluoride
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
42,707-1 anhydrous, powder, 99.9% 1g CAS No. 13400-13-0
5g CsF FW 151.9 Ordering/Pricing: www.sigma-aldrich.com
Used in the successful synthesis of a single-crystal Dion-
Jacobson phase, CsLaTa2O7, that has applications in
Cesium photocatalysis and superconductivity.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 682 C (lit.)
Cesium bromide Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.115 g/mL (lit.)
R: 23/24/25-34 S: 26-36/37/39-45
CAS No. 7787-69-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CsBr FW 212.8 28,934-5 99.9% 5g
R: 36/37/38 S: 26-36 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 g
42,939-2 anhydrous, beads, -10 mesh, 99.999% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10 g 19,832-3 99% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . 682 C (lit.) 100 g
20,301-7 99.999% 10 g Density. . . . . . . . . . . . . . . 4.115 g/mL (lit.)
50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 56,249-1 Cabot High-Purity grade 1 kg
45,076-6 anhydrous, beads, -10 mesh, 99.9% 10 g Product of Cabot Performance Materials 5 kg
mp . . . . . . . . . . . . . . . . . . . . 636 C (lit.) 57,231-4 Cabot technical grade 1 kg
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Product of Cabot Performance Materials 5 kg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cesium iodide See: Crystal Grade Inorganics Page 406
20,214-2 99.9% 25 g
mp . . . . . . . . . . . . . . . . . . . 636 C (lit.) 100 g
262
Anhydrous Halides
Cesium
Cesium iodide Chromium(III) chloride

CAS No. 7789-17-5 CAS No. 10025-73-7
CsI FW 259.8 CrCl3 FW 158.4
Frequently used in devices such as phosphor screens for medical The vapor-phase co-reductions with other metal halides by
imaging, scintillators, calorimeters and a variety of particle hydrogen results in finely divided intermetallics with
detectors. applications as structural materials or compounds with useful
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.51 g/mL (lit.) thermoelectric, magnetic, and oxidation-resistance properties.2
R: 43 S: 24-36/37 References
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Sohn, H.Y., PalDey, S., J. Mater. Res. 13, 3060 (1998)
42,938-4 anhydrous, beads, -10 mesh, 99.999% 1 g R: 21/22-26-34-43 S: 22-26-28-36/37/39-45
Used as a dimensional reduction agent to 45,079-0 anhydrous, flakes, 99.99% 5g
give unprecedented soluble rhenium-selenium or Packaged under argon in ampules 25 g

rhenium-sulfur clusters such as Cs4Re6Se8I6. Long, J.R. et Density. . . . . . . . . . . . . . . . 2.87 g/mL (lit.)
al. J. Am. Chem. Soc. 1996, 118, 4603. H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 20,005-0 Purified by sublimation, 99% 25 g
20,213-4 99.9% 25 g water. . . . . . . . . . . . . . . . . . . . . <0.2% 100 g
mp . . . . . . . . . . . . . . . . . . . 626 C (lit.) 100 g Density. . . . . . . . . . . . . . . 2.76 g/mL (lit.)
Cesium tribromide Chromium(II) fluoride
52,943-5 CAS No. 14023-00-8 5g 39,989-2 CAS No. 10049-10-2 1g

CsBr3 FW 372.6 25 g CrF2 FW 89.99 10 g
99.99% 97%
R: 34 S: 26-27-28-36/37/39-45
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 87.6-92.3 C (lit.)
R: 36/37/38 S: 26-36 Chromium(III) fluoride

Microelectronics
Cesium triiodide 44,976-8 CAS No. 7788-97-8 2g

CrF3 FW 109.0 10 g
57,477-5 CAS No. 12297-72-2 5g anhydrous, powder, 99.99%
CsI3 FW 513.6 25 g Packaged under argon in ampules
99.99+% Used in the preparation of a mixed-metal fluoride catalyst
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 C for synthesis of HFC-134a. Catal. Lett. 1996, 41, 221.
R: 36/37/38-42/43 S: 26-36 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 3.8 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 20/21/22-31-34 S: 26-27-28-36/37/39-45
Chromium
Chromyl chloride
Chromium(II) chloride
CAS No. 14977-61-8
CAS No. 10049-05-5 CrO2Cl2 FW 154.9
CrCl2 FW 122.9 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
The vapor-phase co-reductions with other metal halides by 20,004-2 99.99+% 1g
bp. . . . . . . . . . . . . 117 C/760 mm Hg (lit.) 10 g
hydrogen results in finely divided intermetallics with
mp . . . . . . . . . . . . . . . . . . . -96.5 C (lit.)
applications as structural materials or compounds with useful Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.911 g/mL (lit.)
thermoelectric, magnetic, and oxidation-resistance properties. R: 49-46-8-35-43-50/53 S: 53-45-60-61
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 824 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2.9 g/mL (lit.) 36,274-3 5% wt. on alumina 5g
References R: 45-8-23/24/25-34 S: 53-17-26-27-36/37/39-
Sohn, H.Y., PalDey, S., J. Mater. Res. 13, 3060 (1998) 45
R: 22-36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,078-2 anhydrous, powder, 99.99% 1g Cobalt
Used to make bis(indenyl)chromium dimer 25 g Cobalt(II) bromide, anhydrous
and related products. Heinemann, O. et al.
Organometallics 1996, 15, 5462. 42,713-6 CAS No. 7789-43-7 1g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm CoBr2 FW 218.7 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
anhydrous, beads, -10 mesh, 99.99%
24,480-5 95% 5g
insoluble matter. . . . . . . . . . . . . . . .~1-3% 25 g
Used in the preparation of a new complex, Co(OESPz),
which offers the possibility of intermolecular
ferromagnetic interactions. Ricciardi, G. et al. Inorg.
Chem. 1999, 38, 1422.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.909 g/mL
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 20/21/22 S: 36
High Purity
INORGANICS
Sigma-Aldrich Fine Chemicals is the premier
source for high-purity inorganic materials and
metals in bulk, manufactured using proprietary
technologies by Aldrich-APL, LLC, a joint venture
between Aldrich Chemical Company and APL
Engineered Materials. These materials are used
for high-technology applications, ranging from
telecommunications and electronics to
superconductors and medical imaging devices.
Many of these products are also used in the
pharmaceutical industry as catalysts and
reducing or oxidizing agents in the synthesis of
intermediates.
AAPL specializes in a number of areas including:

• High purity Ba, Ca, Sr (99.99% to 99.9999%, trace element basis)
• Metal halides such as cesium and sodium iodide
• Anhydrous metal fluorides
• Custom eutectic salt mixtures
AAPL advantage gives products with:

• Easy-to-handle, free-flowing bead form
• Low water, hydroxide, and oxide content
• Consistent quality monitored by Inductively Coupled
Plasma- Mass Spectrometry (ICP-MS), Atomic Absorption (AA)
spectrophotometry, and Karl-Fischer titration
• Custom packaging in heavy-wall glass ampules
To discuss your specific requirement or to obtain more information, please contact Mike Willis
at mwillis@sial.com. (414) 298 7910 or Prashant Savle at psavle@sial.com. (414) 298 7924.
Contact us to get your products to market faster with a partner you can trust.
SIGMA-ALDRICH FINE CHEMICALS • BOX 14508 • ST. LOUIS • MISSOURI • 63178 • USA
A Member of the Sigma-Aldrich Family
264
Anhydrous Halides
Cobalt
Copper
Cobalt(II) chloride
Copper(I) bromide
(Cobaltous chloride)
CAS No. 7646-79-9 25,418-5 (Cuprous bromide) 10 g
CoCl2 FW 129.8 CAS No. 7787-70-4 100 g
The vapor-phase co-reductions with other metal halides by CuBr FW 143.5
hydrogen results in finely divided intermetallics with 99.999%
applications as structural materials or compounds with useful Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.72 g/mL (lit.)
thermoelectric, magnetic, and oxidation-resistance properties. S: 22-24/25
References
Sohn, H.Y., PalDey, S., J. Mater. Res. 13, 3060 (1998) Copper(II) bromide
R: 49-22-42/43-50/53 S: 53-22-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
(Cupric bromide)
CAS No. 7789-45-9
CuBr2 FW 223.4
Precursor for five-coordinate, heteroleptic Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.77 g/mL (lit.)
thiolate/N complexes which are potential models for R: 36/37/38 S: 26-36
cysteine-ligated metalloenzyme activity. Shoner, S.C. et al. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Inorg. Chem. 1998, 37, 5721. 43,786-7 99.999% 5g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 724 C (lit.) 25 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.37 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 22,177-5 99% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . 498 C (lit.) 100 g
44,977-6 anhydrous, beads, -10 mesh, 99.9% 5g 500 g
mp . . . . . . . . . . . . . . . . . . . . 740 C (lit.) Copper(I) bromide methylsulfide complex
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.37 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 23,050-2 (Cuprous bromide methylsulfide complex) 10 g

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 54678-23-8 50 g
Microelectronics
23,269-6 97% 5g
Vapor pressure. . . . . . . . .40 mm Hg ( 0 C) 100 g CuBr CH3SCH3 FW 205.6
500 g 99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 132 C (dec.) (lit.)
R: 20/21/22 S: 36/37
Cobalt(II) fluoride
CAS No. 10026-17-2 Copper(I) chloride
CoF2 FW 96.93
R: 25-34 S: 26-36/37/39-45
(Cuprous chloride)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7758-89-6
47,676-5 anhydrous, powder, 99.99% 2g CuCl FW 99.00
10 g Shows unique character as an initiator of radical reactions such
. . . . . . . . . . . . . . . . . . . . . . . . . . . . as the hydrostannation of a,b-unsaturated ketones. Ooi, T. et
23,612-8 powder 5g al. Tetrahedron Lett. 1999, 40, 2133.
25 g Vapor pressure. . . . . . . . . . . . . . . . . . . . . 1.3 mm Hg ( 546 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 430 C (lit.)
Cobalt(III) fluoride Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.14 g/mL (lit.)
R: 22-50/53 S: 22-60-61
23,613-6 (Cobaltic fluoride) 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 10026-18-3 25 g 22,962-8 99.995+% 10 g
CoF3 FW 115.9 100 g 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . 3.88 g/mL (lit.)
R: 34 S: 26-36/37/39-45
22,433-2 purified, 99+% 25 g
100 g
Cobalt(II) iodide
Copper(II) chloride
CAS No. 15238-00-3
CoI2 FW 312.7 (Cupric chloride)
R: 20/21/22-36/37/38 S: 26-36 CAS No. 7447-39-4
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CuCl2 FW 134.5
42,974-0 anhydrous, beads, -10 mesh, 99.999% 1g Will react with potassium alkoxytitanates to form precursors to
5g novel titanium-containing ceramics. Effective catalyst for the
. . . . . . . . . . . . . . . . . . . . . . . . . . . . tetrahydropyranylation of alcohols, using mild conditions and in
high yields.
5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 620 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.386 g/mL (lit.)
34,314-5 95% 10 g
References
100 g 1. Veith, M., Inorg. Chem. 36, 2391 (1997)
2. Veith, M. et al., Inorg. Chem. 36, 2391 (1997)
3. Bhalerao, U.T. et al., Synth. Commun. 26, 3081 (1996)
R: 22-36/37/38-50/53 S: 26-36-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,314-9 99.999% 10 g
50 g
265
Anhydrous Halides
Copper
45,166-5 anhydrous, powder, 99.995+% 5g Dysprosium(III) iodide

H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm 42,933-3 CAS No. 15474-63-2 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,201-1 97% 50 g DyI3 FW 543.2 5g
250 g anhydrous, flakes, 99.99%
R: 42/43-63 S: 22-26-36
1 kg
Copper(II) fluoride Erbium

21,790-5 (Cupric fluoride) 20 g
Erbium(III) bromide
CAS No. 7789-19-7 100 g
CuF2 FW 101.5 44,978-4 CAS No. 13536-73-7 1g
98% ErBr3 FW 407.0 5g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 950 C (dec.) (lit.) anhydrous, powder, 99.99%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.23 g/mL (lit.) R: 36/37/38 S: 26-36
Loss on drying. . . . . . . . . . . . . . . . . . . <0.5%, 105 C, 1h

R: 20/22 S: 36
Erbium(III) chloride
Copper(II) hydroxyfluoride CAS No. 10138-41-7
ErCl3 FW 273.6
20,315-7 CAS No. 13867-72-6 5g
Starting material for new edge-bridged octahedral M6 cluster
HCuFO FW 99.55 25 g
compounds such as CsErTa6Cl18, for which electron and
99.999%
stability studies were performed. Ogliaro, F. et al. Inorg. Chem.
solid
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <2 ppm 1998, 37, 6199.
Si. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <2 ppm mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 774 C (lit.)
B. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <2 ppm Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4.1 g/mL (lit.)
Ag. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.5 ppm R: 36/37/38 S: 26-37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
Copper(I) iodide Packaged under argon in ampules 25 g
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
21,555-4 (Cuprous iodide) 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CuI FW 190.5 25 g 32,559-7 anhydrous, powder, 99% 5g
99.999% 100 g 25 g
Vapor pressure. . . . . . . 10 mm Hg ( 656 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 605 C (lit.) Erbium(III) fluoride
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.62 g/mL (lit.)
R: 22-36/37/38 S: 26-36 43,215-6 CAS No. 13760-83-3 5g
ErF3 FW 224.3 25 g
anhydrous, powder, 99.99%
Dysprosium Packaged under argon in ampules
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
800.558.9196 (USA)
Dysprosium(III) bromide R: 23/24/25-32 S: 26-36/37/39-45
42,937-6 CAS No. 14456-48-5 1g

Erbium(III) iodide
DyBr3 FW 402.2 5g
anhydrous, powder, 99.99% CAS No. 13813-42-8
ErI3 FW 548.0
Dysprosium(III) chloride R: 61 S: 53-26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 10025-74-8 45,681-0 anhydrous, powder, 99.99% 1g
DyCl3 FW 268.9 Density. . . . . . . . . . . . . . . . . . 5.5 g/mL (lit.) 5 g
Packaged under argon in ampules . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ordering/Pricing: www.sigma-aldrich.com
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm 43,978-9 anhydrous, powder, 99.9% 1g
R: 36/37/38 S: 26-36 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
5g Europium
25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Europium(II) Bromide
mp . . . . . . . . . . . . . . . . . . . . 680 C (lit.) 25 g 55,529-0 CAS No. 13780-48-8 1g
Density. . . . . . . . . . . . . . . . 3.67 g/mL (lit.) EuBr2 FW 311.8 5g
99.99%
Dysprosium(III) fluoride S: 22-24/25
CAS No. 13569-80-7

Europium(II) chloride
DyF3 FW 219.5
R: 36/37/38 S: 26 43,185-0 CAS No. 13769-20-5 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,084-7 anhydrous, powder, 99.99% 5g EuCl2 FW 222.9 5g
25 g 99.99%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Packaged under argon in ampules
37,258-7 99.9% 5g Zn. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <0.1%
25 g S: 22-24/25
266
Anhydrous Halides
Europium
Europium(III) chloride Gadolinium(III) iodide

CAS No. 10025-76-0 46,629-8 CAS No. 13572-98-0 1g
EuCl3 FW 258.3 GdI3 FW 538.0 5g
Packaged under argon in ampules anhydrous, powder, 99.99%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Packaged under argon in ampules
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 926 C (lit.)
42,973-2 anhydrous, powder, 99.99% 1g H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . .<100 ppm 5 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 61-42/43 S: 53-36/37/39-45
23,806-6 powder, 99.9+% 1g
mp . . . . . . . . . . . . . . . . . . . . 850 C (lit.) 10 g
Density. . . . . . . . . . . . . . . . 4.89 g/mL (lit.)
Gallium
Europium(III) fluoride Gallium(III) bromide
CAS No. 13765-25-8 CAS No. 13450-88-9

EuF3 FW 209.0 GaBr3 FW 309.4
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.69 g/mL (lit.)
R: 20/21/22-36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 14-20/21/22-34 S: 26-27-36/37/39
23,614-4 99+% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 45,086-3 anhydrous, powder, 99.999% 1g
44,980-6 anhydrous, powder, 99.99% 1g Packaged under argon in ampules 5g
Packaged under argon in ampules 5g bp. . . . . . . . . . . . . 279 C/760 mm Hg (lit.) 25 g
Used in the preparation of novel mixed- mp . . . . . . . . . . . . . . . . . . . 121.5 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
metal fluorides1 and in studies on fluoride glasses.2 (1) Z. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Anorg. Allg. Chem. 1996, 622, 1601. (2) Ferroelectr., Lett. 38,135-7 99.999% 1g
Sect. 1995, 20, 59. ibid. 1996, 21, 111. J. Lumin. 1995, 10 g
66, 290. J. Appl. Phys. 1996, 80, 1965. J. Non-Cryst.
Solids 1996, 197, 8. Gallium(II) chloride

Microelectronics
bp. . . . . . . . . . . . . . . . . . . . . . 2280 C/760 mm Hg (lit.)

41,308-9 CAS No. 13498-12-9 1g
Europium(II) iodide Ga2Cl4 FW 281.3 5g
anhydrous, 99.999%
47,477-0 CAS No. 22015-35-6 1g Packaged under argon in ampules
EuI2 FW 405.8 5g Applied in the preparation of a novel gallium(I) species
anhydrous, powder, 99.9% terminally coordinated to ruthenium. Harakas, G.N.
Packaged under argon in ampules Whittlesey, B.R. Inorg. Chem. 1997, 36, 2704.
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 61-36/38-42/43 S: 53-26-36/37/39-45 R: 34 S: 26-36/37/39-45
Gadolinium Gallium(III) chloride

CAS No. 13450-90-3
Gadolinium(III) bromide GaCl3 FW 176.1
Lower-temperature solvothermal techniques using GaCl3 and
48,502-0 CAS No. 13818-75-2 2g
GdBr3 FW 397.0 10 g NaN3 or Li3N result in nanocrystalline GaN.
product is packed in vials
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.47 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 770 C (lit.)
References
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
1. Xie, Y. et al. , Science 272, 1926 (1996)
R: 36/37/38 S: 26-36
2. Kouvetakis, J., Inorg. Chem. 36, 1792 (1997)
3. McMurran, J., Inorg. Chem. 37, 6638 (1998)
Gadolinium(III) chloride 4. Grocholl, L. et al., Chem. Mater. 13, 4290 (2001)
R: 14-34 S: 26-27-28-36/37/39-45
43,977-0 CAS No. 10138-52-0 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
GdCl3 FW 263.6 25 g 42,712-8 anhydrous, beads, -10 mesh, 5g
anhydrous, powder, 99.99% 99.999+% 25 g
Packaged under argon in ampules Packaged under argon in ampules 100 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm H2O. . . . . . . . . . . . . . . . . . . . <100 ppm
R: 36/37/38 S: 26-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
25,419-3 99.99+% 5g
Gadolinium(III) fluoride Vapor pressure. . . . . . . . . 1 mm Hg ( 48 C) 50 g
mp . . . . . . . . . . . . . . . . . . . . . 78 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
43,216-4 CAS No. 13765-26-9 5g 45,089-8 anhydrous, beads, -10 mesh, 99.99% 5g
GdF3 FW 214.2 25 g Packaged under argon in ampules 25 g
anhydrous, powder, 99.99% mp . . . . . . . . . . . . . . . . . . . . . 78 C (lit.) 50 g
Packaged under argon in ampules H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
Employed in the synthesis of non-oxide glasses. J. Non-
Cryst. Solids 1996, 203, 127. J. Mater. Sci. 1996, 32, 741.
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 36/37/38 S: 26-36
267
Anhydrous Halides
Gallium
Gallium(III) fluoride Germanium(II) iodide

45,163-0 CAS No. 7783-51-9 1g 38,326-0 (Germanium diiodide) 1g
GaF3 FW 126.7 5g CAS No. 13573-08-5 5g
anhydrous, powder, 99.99+% GeI2 FW 326.4
Packaged under argon in ampules 99.99+%
Employed in the preparation and study of optical Reagent forms stable ionic adducts with carbenes. Inorg.
fluorogallate glasses. J. Mater. Res. 1996, 11, 2633. Chem. 1993, 32, 1541.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.47 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.37 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm R: 34 S: 23-26-27-36/37/39-45
R: 20/21/22 S: 36
Germanium(IV) iodide
Gallium(III) iodide
38,325-2 CAS No. 13450-95-8 5g
CAS No. 13450-91-4 GeI4 FW 580.3
GaI3 FW 450.4 99.99%
R: 34-42/43-63 S: 22-26-27-36/37/39-45

R: 34 S: 23-26-27-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
42,934-1 anhydrous, powder, 99.999% 1g See also halogenated gases See: Halogenated Gases Page 294
H2O. . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Gold
39,911-6 99.99% 10 g
mp . . . . . . . . . . . . . . . . . . 345 C (S) (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.15 g/mL (lit.)
Gold(I) chloride
48,113-0 CAS No. 10294-29-8 1g
Germanium AuCl FW 232.4 5g
99.9%
Germanium(II) bromide solid
Microelectronics
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 289 C (dec.) (lit.)
57,265-9 CAS No. 24415-00-7 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 7.57 g/mL (lit.)
R: 34-43 S: 26-27-36/37/39-45
GeBr2 FW 232.4
97%
solid
Gold(III) chloride
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120-125 C
CAS No. 13453-07-1
R: 34 S: 26-36/37/39-45
AuCl3 FW 303.3
Germanium(IV) bromide Nanocrystalline superlattices in gold colloid solution have been
prepared by ligand-induction using AuCl3 reduced with sodium
38,136-5 CAS No. 13450-92-5 10 g borohydride. Lin, X.M. et al. Chem. Mater. 1999, 11, 198.
GeBr4 FW 392.3 R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
bp. . . . . . . . . . . . . . . . . . . . . . 186.5 C/760 mm Hg (lit.)
37,994-8 99.99+% 250 mg
800.558.9196 (USA)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26.1 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.13 g/mL (lit.)
1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,404-9 99% 500 mg
5g
Germanium(IV) chloride
(Germanium tetrachloride)
Gold(I) iodide
CAS No. 10038-98-9 39,841-1 CAS No. 10294-31-2 1g
GeCl4 FW 214.5 AuI FW 323.9 5g
Used in the microwave preparation of Ge2Cl6, a colorless 99.9%
crystalline material which was included in a further study of mp . . . . . . . . . . . . . . . . . . . . . . . . . . 120 C (dec.) (lit.)
low-valent germanium compounds. Beattie, I.R. et al. Inorg. Density. . . . . . . . . . . . . . . . . . . . . . . . . . 8.25 g/mL (lit.)
Chem. 1998, 37, 6032. R: 36/37/38 S: 26-37/39
R: 14-34 S: 26-27-36-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Gold(III) iodide
25,583-1 99.999% 1g
Vapor pressure. . . . . . . . . 76 mm Hg ( 20 C) 10 g
50820 CAS No. 13453-24-2 1g
Density. . . . . . . . . . . . . . . . 1.88 g/mL (lit.) 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . AuI3 FW 577.7 5g
20,845-0 99.99% 5g purum, ‡34% as Au
Vapor pressure. . . . . . . . 76 mm Hg ( 21 C) 25 g R: 34-43 S: 26-36/37/39-45
bp. . . . . . . . . . . . . 83 C/760 mm Hg (lit.) 100 g
mp . . . . . . . . . . . . . . . . . . -49.5 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.844 g/mL (lit.)
Germanium chloride dioxane complex (1:1)

57,351-5 CAS No. 28595-67-7 10 g
C4H8Cl2GeO2 FW 231.7
solid
R: 20-34-40 S: 22-26-36/37/39-45
268
Anhydrous Halides
Hafnium
Hafnium bromide Holmium(III) iodide

49,642-1 CAS No. 13777-22-5 2g 43,975-4 CAS No. 13813-41-7 1g
HfBr4 FW 498.1 10 g HoI3 FW 545.6 5g
anhydrous, powder, 99.99% (Purity anhydrous, flakes, 99.99%
excludes ~0.2% zirconium.) R: 61-36/37/38 S: 53-22-26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 424 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 4.9 g/mL (lit.) Indium
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 34 S: 26-27-36/37/39-45 Indium(I) bromide
Hafnium(IV) chloride 46,060-5 CAS No. 14280-53-6 5g

InBr FW 194.7 25 g
CAS No. 13499-05-3 anhydrous, beads, -10 mesh, 99.999%
HfCl4 FW 320.3 Packaged under argon in ampules
R: 36/38 S: 26-36/37 bp. . . . . . . . . . . . . . . . . . . . . . . 656 C/760 mm Hg (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220 C (lit.)
59,059-2 99.9%, Purified by sublimation 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.96 g/mL (lit.)
25 g H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22-36/37/38 S: 26-36
25,820-2 98% 10 g
Indium(III) bromide
Hafnium(IV) fluoride CAS No. 13465-09-3
InBr3 FW 354.5
39,986-8 CAS No. 13709-52-9 5g R: 36/37/38 S: 26-36
HfF4 FW 254.5 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
zirconium. . . . . . . . . . . . . . . . . . . . . .1% 54,508-2 99.999% 5g

R: 32-36/37/38-41 S: 26-36 solid 25 g
Microelectronics
bp. . . . . . . . . . . . . 656 C/760 mm Hg (lit.)

Hafnium iodide mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.96 g/mL (lit.)
45,843-0 CAS No. 13777-23-6 2g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
HfI4 FW 686.1 10 g 30,828-5 99% 10 g
Vapor density. . . . . . . . . . . . . . . >1 (vs air) 50 g
anhydrous, 99%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 5.6 g/mL (lit.) Indium(I) chloride
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 61 S: 53-36/37/39-45 44,921-0 CAS No. 13465-10-6 2g
InCl FW 150.3 10 g
Holmium Packaged under argon in ampules
Used to prepare cage, dinuclear complexes (In-
Holmium(III) bromide cyclodiphophazanes) which possess interesting metal-
metal interactions. Grocholl, L. et al. Inorg. Chem. 1998,
43,976-2 CAS No. 13825-76-8 1g 37, 2496.
HoBr3 FW 404.6 5g bp. . . . . . . . . . . . . . . . . . . . . . . 608 C/760 mm Hg (lit.)
anhydrous, powder, 99.99% mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 C (lit.)
R: 36/37/38 S: 26-36 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.19 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Holmium(III) chloride R: 36/37/38 S: 26-36
CAS No. 10138-62-2 Indium(II) chloride

HoCl3 FW 271.3
R: 36/37/38 S: 26-37/39 54,845-6 CAS No. 13465-11-7 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . InCl2 FW 185.7 10 g
45,090-1 anhydrous, powder, 99.9% 1g solid
Packaged under argon in ampules 5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . 262 C (dec.) (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . <100 ppm R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,572-4 99.9% 1g
Indium(III) chloride
10 g
CAS No. 10025-82-8
Holmium(III) fluoride InCl3 FW 221.2
R: 23/24/25-34 S: 22-26-36/37/39-45
43,207-5 CAS No. 13760-78-6 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
HoF3 FW 221.9 10 g 42,941-4 anhydrous, powder, 99.999+% 5g
anhydrous, powder, 99.99% Packaged under argon in ampules 25 g
Packaged under argon in ampules H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 23/24/25-32 S: 26-36/37/39-45 20,344-0 99.999% 1g
Density. . . . . . . . . . . . . . . . 3.46 g/mL (lit.) 10 g
50 g
269
Anhydrous Halides
Indium
33,406-5 98% 10 g Iron

Density. . . . . . . . . . . . . . . . 3.46 g/mL (lit.) 50 g
Iron(II) bromide
Indium(III) fluoride
(Ferrous bromide)
43,584-8 CAS No. 7783-52-0 1g CAS No. 7789-46-0
InF3 FW 171.8 5g FeBr2 FW 215.7
99.9+% mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 684 C (lit.)
Employed in the synthesis of non-oxide glasses., Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.63 g/mL (lit.)
Employed in the synthesis of non-oxide glasses. J. Non- R: 20-36/37/38 S: 26-36
Cryst. Solids 1996, 203, 127. Eur. J. Solid State Inorg.
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Chem. 1996, 33, 879. 43,400-0 anhydrous, beads, -10 mesh, 99.999% 1g
H2O. . . . . . . . . . . . . . . . . . . . . .<100 ppm
Promotes chemoselective addition of TMSCN to aldehydes . . . . . . . . . . . . . . . . . . . . . . . . . . . .
forming the respective cyanohydrins. Loh T-P. et al. Synlett 40,083-1 98% 10 g
1998, 369. bp. . . . . . . . . . . . . 934 C/760 mm Hg (lit.) 50 g

References
1. Loh, T.-P. et al., Synlett 369 (1998) Iron(III) bromide
2. J. Non-Cryst. Solids 203, 127 (1996)
3. Eur. J. Solid State Inorg. Chem. 33, 879 (1996) 21,788-3 (Ferric bromide) 10 g
R: 31-36/37/38 S: 26-36
CAS No. 10031-26-2 50 g
FeBr3 FW 295.6
Indium(I) iodide 98%
R: 36/37/38 S: 26-37/39
CAS No. 13966-94-4
InI FW 241.7
R: 22-36/37/38-42/43 S: 22-26-36/37-45
Iron(II) chloride
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
41,365-8 anhydrous, beads, -10 mesh, 99.999% 1g (Ferrous chloride)
Packaged under argon in ampules 5g CAS No. 7758-94-3
Microelectronics
H2O. . . . . . . . . . . . . . . . . . . . . .<100 ppm FeCl2 FW 126.8
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.16 g/mL (lit.)
57,860-6 anhydrous, powder, 99.999% 2g R: 22-34 S: 26-36/37/39-45
10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Indium(III) iodide Packaged under argon in ampules 10 g
Used in the synthesis of a novel cis-
41,366-6 CAS No. 13510-35-5 1g Fe(BPE5)2Cl2 (BPE5=1,2-diphospholanoethane) complex,
InI3 FW 495.5 5g which has potential application in many types of reactions
anhydrous, powder, 99.998% such as intra- or intermolecular activation. Field, L.D. et al.
Packaged under argon in ampules Inorg. Chem. 1998, 37, 612.
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 42/43-63 S: 22-26-36/37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
800.558.9196 (USA)
Iridium Used in the synthesis of a novel cis-
Fe(BPE5)2Cl2 (BPE5=1,2-diphospholanoethane) complex,
Iridium(III) chloride which has potential application in many types of reactions
such as intra- or intermolecular activation. Field, L.D. et al.
CAS No. 10025-83-9 Inorg. Chem. 1998, 37, 612.
IrCl3 FW 298.6 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 677 C (lit.)
R: 36/37/38 S: 26-36 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
52,072-1 99.9+% 1g 45,094-4 anhydrous, beads, -10 mesh, 99.9% 10 g Ordering/Pricing: www.sigma-aldrich.com
solid Packaged under argon in ampules 50 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 763 C (lit.) Used in the synthesis of a novel cis-
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Fe(BPE5)2Cl2 (BPE5=1,2-diphospholanoethane) complex,
33,680-7 crystals 500 mg
which has potential application in many types of reactions
2g
such as intra- or intermolecular activation. Field, L.D. et al.
Inorg. Chem. 1998, 37, 612.
Iridium(IV) iodide mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 677 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
58,719-2 CAS No. 7790-45-6 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
IrI4 FW 699.8 5g 37,287-0 98% 25 g
crystals, 99.95% 250 g
solid
270
Anhydrous Halides
Iron
Iron(III) chloride Lanthanum fluoride

45,164-9 (Ferric chloride) 1g 44,985-7 CAS No. 13709-38-1 5g
CAS No. 7705-08-0 5g LaF3 FW 195.9 25 g
FeCl3 FW 162.2 anhydrous, powder, 99.99% 100 g
anhydrous, powder, 99.99+% Packaged under argon in ampules
The vapor-phase co-reductions with other metal halides Employed extensively in the preparation and study of
by hydrogen results in finely divided intermetallics with fluoride glasses. J. Lumin. 1996, 69, 121. Electron. Lett.
applications as structural materials or compoounds with 1996, 32, 1586. J. Mater. Sci. Lett. 1996, 15, 21. J. Non-
useful thermoelectric, magnetic, and oxidation-resitance Cryst. Solids 1996, 204, 188.
properties. Density. . . . . . . . . . . . . . . . . . . . . . . . . 5.936 g/mL (lit.)
Packaged under argon in ampules H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304 C (lit.) S: 22-24/25

Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.8 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Lanthanum iodide
References
Sohn, H.Y., PalDey, S., J. Mater. Res. 13, 3060 (1998) 41,367-4 CAS No. 13813-22-4 1g
R: 22-34 S: 26-27-36/37/39 LaI3 FW 519.6 5g
Iron(II) fluoride Packaged under argon in ampules
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
39,984-1 (Ferrous fluoride) 10 g R: 36/37/38 S: 26
CAS No. 7789-28-8 50 g
FeF2 FW 93.84
98% Lead
R: 34 S: 26-36/37/39-45
Lead(II) bromide
Iron(III) fluoride
CAS No. 10031-22-8

Microelectronics
28,865-9 (Ferric fluoride) 10 g PbBr2 FW 367.0

CAS No. 7783-50-8 50 g R: 61-20/22-33-50/53-62 S: 53-45-60-61
FeF3 FW 112.8 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
98% 46,058-3 anhydrous, beads, -10 mesh, 99.999% 1g
R: 20/21/22-34 S: 22-26-27-36/37/39-45 Packaged under argon in ampules 5g
bp. . . . . . . . . . . . . 892 C/760 mm Hg (lit.) 25 g
mp . . . . . . . . . . . . . . . . . . . . 371 C (lit.)
Iron(II) iodide Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 6.6 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
40,085-8 (Ferrous iodide) 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7783-86-0 10 g 39,885-3 99.999% 5g
FeI2 FW 309.7 Density. . . . . . . . . . . . . . . . 6.66 g/mL (lit.) 25 g
anhydrous, beads, -10 mesh, 99.99+% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 21,114-1 98+% 100 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.32 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . 373 C (lit.) 500 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Density. . . . . . . . . . . . . . . 6.66 g/mL (lit.)
R: 61-20/21/22-36/37/38 S: 53-22-26-36/37/39-45
Lead(II) chloride
Lanthanum CAS No. 7758-95-4
Lanthanum bromide See: Crystal Grade Inorganics Page 406 PbCl2 FW 278.1
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.85 g/mL (lit.)
Lanthanum chloride See: Crystal Grade Inorganics Page 406 R: 22-62-63 S: 53-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lanthanum chloride 44,986-5 anhydrous, beads, -10 mesh, 99.999% 5 g
CAS No. 10099-58-8 mp . . . . . . . . . . . . . . . . . . . . 501 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
LaCl3 FW 245.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 20,357-2 99.999% 10 g
R: 36/37/38 S: 26-36 Vapor pressure. . . . . . . . . 1 mm Hg ( 547 C) 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . bp. . . . . . . . . . . . . 950 C/760 mm Hg (lit.)
29,818-2 anhydrous, beads, -10 mesh, 99.9% 10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 501 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,869-0 powder, 98% 5g
24,457-0 anhydrous, beads, -10 mesh, 98% 10 g Vapor pressure. . . . . . . 1 mm Hg ( 547 C) 250 g
mp . . . . . . . . . . . . . . . . . . . . 860 C (lit.) 50 g
1 kg
Density. . . . . . . . . . . . . . . . 3.84 g/mL (lit.)
Lead(II) fluoride
CAS No. 7783-46-2
PbF2 FW 245.2
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 824 C (lit.)
R: 61-20/22-33-50/53-62 S: 53-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,972-5 99.99% 25 g
Density. . . . . . . . . . . . . . . . 8.445 g/mL (lit.)
271
Anhydrous Halides
Lead
23,615-2 powder, 5 mm, 99+% 100 g 43,137-0 ReagentPlus, 99.99% 50 g

500 g Meets A.C.S. reagent specifications. 250 g
Lead(II) iodide See: Crystal Grade Inorganics Page 406 insolubles. . . . . . . . . . . . . . . . . . £0.01%
total metallic impurities. . . . . . . . . . . . . . . . . . . <100 ppm
Titr. base. . . . . . . . . . . . . . . . . . . . . . . . . £0.008 meq/g
Lead(II) iodide Loss on drying. . . . . . . . . . . . . . . . . . . . . . . . . . . £1.0%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 613 C (lit.)
CAS No. 10101-63-0 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.07 g/mL (lit.)
PbI2 FW 461.0 NO3-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 954 C/760 mm Hg (lit.) SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 402 C (lit.) Ba. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.003%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.16 g/mL (lit.) Ca. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
R: 61-20/22-33-50/53-62 S: 53-45-60-61 Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
20,360-2 99.999% 10 g K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
50 g Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.20%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Trademark of Sigma-Aldrich Co.
21,116-8 99% 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .

250 g 44,988-1 anhydrous, beads, -10 mesh, 99.9+% 10 g
mp . . . . . . . . . . . . . . . . . . . . 605 C (lit.)
Lithium Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.068 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Lithium bromide
Lithium fluoride
CAS No. 7550-35-8
LiBr FW 86.85 CAS No. 7789-24-4
R: 22 S: 36 LiF FW 25.94
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 23/24/25-32-36/38 S: 22-26-36/37/39-45
42,946-5 anhydrous, beads, -10 mesh, 99.999% 5 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 25 g 44,990-3 anhydrous, powder, 99.99+% 2g
Microelectronics
Density. . . . . . . . . . . . . . . . 3.46 g/mL (lit.) Packaged under argon in ampules 10 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Used in the preparation of hypersensitive 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . thermoluminescent materials,1
22,973-3 99.995+% 25 g dosimeters,2 and in the room-temperature oxidation of
mp . . . . . . . . . . . . . . . . . . . 550 C (lit.) 125 g
Density. . . . . . . . . . . . . . .3.464 g/mL (lit.)
noble metals using fluorine in anhydrous HF.3 (1) Radiat.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Prot. Dosim. 1996, 66, 423, 431. (2) ibid., 1996, 66, 101,
44,987-3 anhydrous, beads, -10 mesh, 99.9+% 25 g 255. (3) Eur. J. Solid State Inorg. Chem.1996, 33, 809.
Packaged under argon in ampules 100 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 845 C (lit.)
mp . . . . . . . . . . . . . . . . . . . 550 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.635 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.464 g/mL (lit.) H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,364-5 powder, 5 mm, 99.99+% 5g
mp . . . . . . . . . . . . . . . . . . . . 845 C (lit.) 25 g
Lithium chloride
800.558.9196 (USA)
Density. . . . . . . . . . . . . . . 2.635 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7447-41-8 34,301-3 fused, pieces, 3-6 mm, 99.9% 50 g
LiCl FW 42.39 Suitable for vacuum deposition. 250 g
Used in formation of an active Mn(0) species useful for radical Density. . . . . . . . . . . . . . . 2.64 g/mL (lit.)
cyclization reactions, Tang, J. et al. Tetrahedron 1999, 55, . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1893. 37,882-8 optical grade, random crystals 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 22-36/37/38 S: 26
23,796-5 powder, 5 mm 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . .848 C (lit.) 1 kg
42,945-7 anhydrous, beads, -10 mesh, 99.998% 5 g Density. . . . . . . . . . . . . . . 2.64 g/mL (lit.)
Density. . . . . . . . . . . . . . . . 2.07 g/mL (lit.) Lithium iodide
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 10377-51-2
20,363-7 99.99+% 10 g LiI FW 133.8
mp . . . . . . . . . . . . . . . . . . . 605 C (lit.) 50 g R: 61-36/38 S: 53-22-26-36/37/39-45
Density. . . . . . . . . . . . . . .2.068 g/mL (lit.) 100 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Controls regioselectivity in palladium
catalyzed allylic alkylation reactions. Kawatsura, M. et al.
Chem. Commun. 1998, 217.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 446 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.49 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
272
Anhydrous Halides
Lithium
(Continuation of) Magnesium

Lithium iodide
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Magnesium bromide
Packaged under argon in ampules 25 g CAS No. 7789-48-2
Controls regioselectivity in palladium MgBr2 FW 184.1
catalyzed allylic alkylation reactions. Kawatsura, M. et al. R: 36/37/38 S: 26-36
Chem. Commun. 1998, 217. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 446 C (lit.) 49,509-3 anhydrous, powder, 99.995% 1g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.49 g/mL (lit.) Packaged under argon in ampules 5g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Metals purity does not include Tungsten
. . . . . . . . . . . . . . . . . . . . . . . . . . . . which is a by-product of the method of manufacture.
51,801-8 powder, 99.9% 10 g Tungsten should not interfere with use of product.
mp . . . . . . . . . . . . . . . . . . . . 469 C (lit.) 50 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 711 C (lit.)

Density. . . . . . . . . . . . . . . . 3.494 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.72 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
21,821-9 beads, 99% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Controls regioselectivity in palladium 50 g 36,007-4 98% 10 g
catalyzed allylic alkylation reactions. 250 g 50 g
Kawatsura, M. et al. Chem. Commun.
1998, 217. Magnesium chloride
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 446 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.49 g/mL (lit.) CAS No. 7786-30-3
MgCl2 FW 95.21
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 714 C (lit.)
Lutetium Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.32 g/mL (lit.)
S: 26
Lutetium(III) bromide . . . . . . . . . . . . . . . . . . . . . . . . . . . .
58,713-3 CAS No. 14456-53-2 1g Packaged under argon in ampules 50 g

Microelectronics
LuBr3 FW 414.7 5g H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
anhydrous, 99.99%
solid
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
Lutetium(III) chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,833-7 powder, -325 mesh 100 g
45,096-0 CAS No. 10099-66-8 1g Total impurities. . . . . . . . . . . . . . . . <5% 1 kg
LuCl3 FW 281.3 5g 5 kg
Packaged under argon in ampules Magnesium fluoride
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 905 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.98 g/mL (lit.) CAS No. 7783-40-6
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
MgF2 FW 62.30
R: 36/37/38 S: 26-36
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lutetium(III) fluoride 37,883-6 optical grade, random crystals, 5g
99.99+% 25 g
43,211-3 CAS No. 13760-81-1 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
LuF3 FW 232.0 5g 34,318-8 pieces, 3-6 mm, 99.9% 25 g
anhydrous, powder, 99.99% Suitable for vacuum deposition. 250 g
Packaged under argon in ampules Density. . . . . . . . . . . . . . . 3.15 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 23/24/25-32 S: 26-36/37/39-45
20,831-0 98% 500 g
2 kg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lutetium(III) iodide 39,429-7 Technical Grade 500 g
Density. . . . . . . . . . . . . . . 3.15 g/mL (lit.) 1 kg
46,057-5 CAS No. 13813-45-1 1g
LuI3 FW 555.7 5g Magnesium iodide
Packaged under argon in ampules CAS No. 10377-58-9
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 5.6 g/mL (lit.) MgI2 FW 278.1
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
When reacted with cyclic sulfates of vic-diols, produces the
R: 61 S: 53-22-36/37/39-45
corresponding olefins in excellent yields. Jang, D.O. Joo, Y.H.
Synth. Commun. 1998, 28, 871.
R: 61-42/43 S: 53-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . 637 C (dec.) (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.43 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
273
Anhydrous Halides
Magnesium
46,610-7 powder, 99.998% 1g Manganese(II) iodide

mp . . . . . . . . . . . . . . . . . 637 C (dec.) (lit.) CAS No. 7790-33-2
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.43 g/mL (lit.) MnI2 FW 308.7
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm R: 61 S: 53-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
39,459-9 98% 5g 43,973-8 anhydrous, flakes, 99.99% 2g
25 g Packaged under argon in ampules 10 g
mp . . . . . . . . . . . . . . . . . 80 C (dec.) (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.01 g/mL (lit.)
Manganese H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Manganese(II) bromide 55,161-9 anhydrous, powder, 99.9% 1g
22,364-6 CAS No. 13446-03-2 25 g H2O. . . . . . . . . . . . . . . . . . . . . .<100 ppm
MnBr2 FW 214.7 100 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
98% 34,321-8 99% 10 g

Density. . . . . . . . . . . . . . . . . . . . . . . . . 4.385 g/mL (lit.)
R: 20/21/22 S: 36
Mercury
Manganese(II) chloride
Mercury(I) bromide
CAS No. 7773-01-5
MnCl2 FW 125.8 48,323-0 (Mercurous bromide) 5g
A novel, high-spin, hexanuclear Mn(III) cluster, CAS No. 15385-58-7 25 g
[NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation Hg2Br2 FW 561.0
with simultaneous NaOMe promoted aggregation. This cluster 99.9+%
has an unprecedented cyclic structure and 24 unpaired solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 445 C (lit.)
electrons in its ground state.1 Also used in the formation of an
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 7.31 g/mL (lit.)
active Mn(0) speciesuseful for radical cyclization reactions.2 (1)
Microelectronics
R: 26/27/28-33-50/53 S: 13-28-45-60-61
Abbati, G.L. et al. Inorg. Chem. 1998, 37, 1430. (2) Tang, J. et
al. Tetrahedron 1999, 55, 1893. Mercury(II) bromide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.98 g/mL (lit.)
R: 22-52 (Mercuric bromide)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,099-5 anhydrous, beads, -10 mesh, 99.999% 5 g CAS No. 7789-47-1
Packaged under argon in ampules 25 g HgBr2 FW 360.4
mp . . . . . . . . . . . . . . . . . . . . 652 C (lit.) R: 26/27/28-33-50/53 S: 13-28-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
42,944-9 anhydrous, beads, -10 mesh, 99.99% 5g Packaged under argon in ampules 25 g
Packaged under argon in ampules 25 g bp. . . . . . . . . . . . . 322 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . 652 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 6.109 g/mL (lit.)
800.558.9196 (USA)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
24,458-9 99+% 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
43,785-9 99.998% 5g
50 g
Vapor pressure. . . . . . . . 1 mm Hg ( 136.5 C) 25 g
250 g mp . . . . . . . . . . . . . . . . . . . . 236 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . 6.109 g/mL (lit.)
32,814-6 beads, 98% 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
500 g 40,075-0 crystalline powder 25 g
2 kg Density. . . . . . . . . . . . . . . .6.05 g/mL (lit.) 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
41,647-9 flakes, 97% 500 g
2 kg
Mercury(I) chloride Ordering/Pricing: www.sigma-aldrich.com
44,919-9 (Mercurous chloride; Calomel) 5g

Manganese(II) fluoride CAS No. 10112-91-1 25 g
33,928-8 CAS No. 7782-64-1 10 g Hg2Cl2 FW 472.1
MnF2 FW 92.93 50 g anhydrous, powder, 99.999%
98% Packaged under argon in ampules
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 400 C (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 856 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 7.15 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.98 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 20/21/22-36/37/38 S: 26-37/39
R: 22-36/37/38-50/53 S: 13-24/25-46-60-61
Manganese(III) fluoride
33,929-6 CAS No. 7783-53-1 10 g
MnF3 FW 111.9 50 g
Starting material for solid state preparation
of Na3MnF6 for further high pressure structural
determination studies. Carlson, S. et al. Inorg Chem.
1998, 37, 1486.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.54 g/mL (lit.)
R: 8-20/21/22-36/37/38 S: 17-26-36/37/39
274
Anhydrous Halides
Mercury
Mercury(II) chloride Molybdenum(III) chloride

(Mercuric chloride) 33,933-4 CAS No. 13478-18-7 2g
CAS No. 7487-94-7 MoCl3 FW 202.3 10 g
HgCl2 FW 271.5 Density. . . . . . . . . . . . . . . . 3.58 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.44 g/mL (lit.) R: 36/37/38 S: 26-37/39
R: 28-34-48/24/25-50/53 S: 36/37/39-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Molybdenum(V) chloride
Packaged under argon in ampules 25 g CAS No. 10241-05-1
mp . . . . . . . . . . . . . . . . . . . . 277 C (lit.)
MoCl5 FW 273.2
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Hexaalkoxytriphenylenes are obtained from o-dialkoxybenzenes
by oxidative trimerization using MoCl5. Kumar, S. Manickam,
20,377-7 99.999% 50 g
Vapor pressure. . . . . . .1.3 mm Hg ( 236 C) 250 g M. Chem. Commun. 1997, 1615.
bp. . . . . . . . . . . . 302 C/760 mm Hg (lit.) Vapor pressure. . . . . . . . . . . . . . . . . . . . . 131 mm Hg ( 250 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277 C (lit.) Vapor pressure. . . . . . . . . . . . . . . . . . . . . 1.75 mm Hg ( 25 C)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194 C (lit.)
42,972-4 anhydrous, powder, 99.998% 1g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.928 g/mL (lit.)
Packaged under argon in ampules 10 g R: 29-34 S: 26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . 277 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 24,193-8 99.9+% 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Packaged in ampules 100 g
45,100-2 anhydrous, beads, -10 mesh, 99.9+% 5g bp. . . . . . . . . . . . .268 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . 277 C (lit.) 20,835-3 98% 25 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm insoluble matter. . . . . . . . . . . . . . . <0.5% 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
41,344-5 98+% 100 g Molybdenum(VI) dichloride dioxide
500 g
37,371-0 CAS No. 13637-68-8 1g

Microelectronics
Mercury(I) fluoride MoCl2O2 FW 198.8 10 g

Density. . . . . . . . . . . . . . . . 3.31 g/mL (lit.)
33,931-8 CAS No. 13967-25-4 5g R: 34 S: 26-27-36/37/39-45
Hg2F2 FW 439.2 25 g Molybdenum(VI) fluoride See: High-Purity Gases for CVD Page 292
Technical Grade
R: 26/27/28-33-50/53 S: 13-28-45-60-61
Molybdenum(VI) tetrachloride oxide
Mercury(II) fluoride
37,372-9 (molybdenum(VI) oxychloride) 5g
33,932-6 (Mercuric fluoride) 10 g CAS No. 13814-75-0 25 g
CAS No. 7783-39-3 50 g MoCl4O FW 253.8
HgF2 FW 238.6 R: 36/37/38 S: 26-37/39
97%
R: 26/27/28-33-50/53 S: 13-28-45-60-61
Neodymium
Mercury(II) idodide red See: Crystal Grade Inorganics Page 406
Neodymium(III) bromide
Mercury(II) iodide red
CAS No. 13536-80-6
20,378-5 (Mercuric iodide red) 25 g NdBr3 FW 384.0
CAS No. 7774-29-0 R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
HgI2 FW 454.4
99.999%
bp. . . . . . . . . . . . . . . . . . . . . . . 354 C/760 mm Hg (lit.)
5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259 C (lit.) 43,971-1 anhydrous, powder, 99.9% 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 6.094 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . . 684 C (lit.) 25 g
R: 26/27/28-33-50/53 S: 13-28-45-60-61
Density. . . . . . . . . . . . . . . . . 5.3 g/mL (lit.)
Mercury(I) iodide yellow Neodymium(III) chloride

40,074-2 (Mercurous iodide yellow) 10 g CAS No. 10024-93-8
CAS No. 15385-57-6 50 g NdCl3 FW 250.6
Hg2I2 FW 655.0 R: 36/37/38 S: 26-37/39
99% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.7 g/mL (lit.) 44,993-8 anhydrous, beads, -10 mesh, 99.99+% 1g
R: 26/27/28-33-50/53 S: 13-28-45-60-61 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
44,994-6 anhydrous, powder, 99.99+% 5g
Molybdenum mp . . . . . . . . . . . . . . . . . . . . 784 C (lit.) 25 g
Density. . . . . . . . . . . . . . . 4.134 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Molybdenum(III) bromide 29,827-1 anhydrous, beads, -10 mesh, 99.9% 2g
40,076-9 CAS No. 13446-57-6 1g 10 g
MoBr3 FW 335.7 10 g 50 g
98%
R: 36/37/38 S: 26-36
275
Anhydrous Halides
Neodymium
Neodymium(III) fluoride Nickel(II) chloride

CAS No. 13709-42-7 CAS No. 7718-54-9
NdF3 FW 201.2 NiCl2 FW 129.6
R: 20/21/22-36/37/38 S: 26-36 The vapor-phase co-reductions with other metal halides such as
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
44,995-4 anhydrous, powder, 99.99% 10 g aluminum chloride (Aldrich product 44,959-8) by hydrogen
Packaged under argon in ampules 50 g results in finely divided intermetallics with applications as
Used extensively in the preparation and structural materials or compounds with useful thermoelectric,
study of fluorinated glasses. J. Mater. Sci. Lett. 1996, 15, magnetic, and oxidation-resistance properties. Used in the
1854. J. Non-Cryst. Solids 1996, 204, 178. Ferroelect., synthesis of semiconducting metal-containing polymers in
Lett. Sect. 1996, 21, 111. J. Appl. Phys. 1996, 79, 3477. J. which the polypyrrole backbone has a conformational energy
Alloys Compd. 1996, 232, 53. minimum and is nearly planar.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.55 g/mL (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 2300 C/760 mm Hg (lit.)
References
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.65 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 1. Mathis, M. et al., Chem. Mater. 10, 3568 (1998)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. Sohn, H.Y., PalDey, S., J. Mater. Res. 13, 3060 (1998)

30,916-8 powder 10 g 3. Sohn, H.Y.; PalDey, S., J. Mater. Res. 13, 3060 (1998)
50 g R: 45-22-43-50/53 S: 53-36/37-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Neodymium(III) iodide Packaged under argon in ampules 25 g
Used in the synthesis of semiconducting
42,710-1 CAS No. 13813-24-6 1g
metal-containing polymers in which the polypyrrole
NdI3 FW 525.0 5g
backbone has a conformational energy minimum and is
R: 42/43-63 S: 22-26-36 nearly planar. Mathis, M. et al. Chem. Mater. 1998, 10,
3568.
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Nickel 33,935-0 98% 50 g
Microelectronics
250 g
Nickel(II) bromide
CAS No. 13462-88-9 Nickel(II) fluoride
NiBr2 FW 218.5
34,221-1 CAS No. 10028-18-9 10 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 963 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.098 g/mL (lit.)
NiF2 FW 96.69 50 g
R: 45-36/37/38-42/43 S: 53-26-36/37/39-45 99%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.72 g/mL (lit.)
44,915-6 anhydrous, powder, 99.99+% 1g R: 45-36/37/38-42/43 S: 53-26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . . 963 C (lit.) 5 g
Density. . . . . . . . . . . . . . . . 5.098 g/mL (lit.) Nickel(II) iodide
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 40,077-7 CAS No. 13462-90-3 5g
56,114-2 anhydrous, powder, 99.9+% 2g NiI2 FW 312.5 25 g
800.558.9196 (USA)
10 g powder
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.83 g/mL (lit.)
21,789-1 98% 10 g
R: 45-61-42/43 S: 53-22-26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . 963 C (lit.) 50 g
Density. . . . . . . . . . . . . . .5.098 g/mL (lit.) 250 g
Niobium
Nickel(II) bromide ethylene glycol dimethyl ether complex
Niobium(V) bromide
40,634-1 CAS No. 28923-39-9 1g
NiBr2O2C4H10 FW 308.6 5g 36,277-8 CAS No. 13478-45-0 10 g
97%
NbBr5 FW 492.4 50 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 F
98%
R: 11-20/21/22-36/37/38 S: 16-22-26-36/37/39-45
R: 20/21/22-34 S: 26-27-28-36/37/39-45
CH
3
O
NiBr
2
Niobium(III) bromide-ethylene glycol dimethyl ether
O complex
CH
3
36,595-5 CAS No. 126083-88-3 1g
NbBr3O2C4H10 FW 422.7
R: 34 S: 26-27-28-36/37/39-45
Nickel(II) bromide 2-methoxyethyl ether complex
45,967-4 CAS No. 312696-09-6 5g
NiBr2O(CH2CH2OCH3)2 FW 352.7 10 g
R: 45-60-61-11-36/37/38-42/43 S: 53-16-22- 25 g
36/37/39-45
276
Anhydrous Halides
Niobium
Niobium(V) chloride Palladium

(Niobium pentachloride) Palladium(II) bromide
CAS No. 10026-12-7
NbCl5 FW 270.2 20,587-7 CAS No. 13444-94-5 2g
R: 20/21/22-34 S: 26-27-28-36/37/39 PdBr2 FW 266.2 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
99%
51,069-6 anhydrous, powder, 99.999% 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . 5.173 g/mL (lit.)
Used to form mixed chloro-aryloxide Palladium(II) chloride
compounds, such as [Nb(OC6H3-2,6-i-Pr2)2Cl3]2, which
form pyridine or phosphine adducts with a distortedsix- CAS No. 7647-10-1
coordinate geometry. Clark, J.R. et al. Inorg. Chem. 1997, PdCl2 FW 177.3
36, 3623. Used in the synthesis of semiconducting metal-containing

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
polymers in which the polypyrrole backbone has a
33,660-2 99.9+% 10 g
Density. . . . . . . . . . . . . . . . 2.75 g/mL (lit.) 50 g conformational energy minimum and is nearly planar.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
21,579-1 99% 10 g
32,337-3 99.999% 1g
bp. . . . . . . . . . . . . 254 C/760 mm Hg (lit.) 50 g
Density. . . . . . . . . . . . . . . . . . . 4 g/mL (lit.) 5 g
mp . . . . . . . . . . . . . . . . . . . 204.7 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.75 g/mL (lit.)
52,065-9 Engelhard code S3120, 99.9+% 1g
solid 5g
Niobium(IV) chloride tetrahydrofuran complex Pd 59-60% 25 g
mp . . . . . . . . . . . . . . . . . 678-680 C (lit.)
32,636-4 (tetrachlorobis(tetrahydrofuran)niobium) 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 g/mL (lit.)
CAS No. 61247-57-2 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
NbCl4(CO4H8)2 FW 378.9 20,588-5 99% 1g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 93 C (dec.) (lit.) 5g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121 F 25 g
Microelectronics
R: 11-34 S: 16-26-27-36/37/39-45
150 g
1 kg
Niobium(III) chloride–1,2-dimethoxyethane complex
Palladium(II) iodide
32,635-6 (Niobium trichloride 1,2- 5g
DimethoxyethaneComplex; trichloro(1,2- 25 g CAS No. 7790-38-7
dimethoxyethane)niobium) PdI2 FW 360.2
CAS No. 110615-13-9 Density. . . . . . . . . . . . . . . . 6.003 g/mL (lit.)
NbCl3 C4H10O2 FW 289.4 S: 22-24/25
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 230 C (dec.) (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 34 S: 26-36/37/39-45 20,396-3 99.998% 2g
NbCl
3
CH OCH CH OCH
3 2 2 3
mp . . . . . . . . . . . . . . . . 350 C (dec.) (lit.) 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,467-8 97% 2g
mp . . . . . . . . . . . . . . . . . . . . 350 C (lit.) 10 g
Niobium(V) fluoride
Phosphorus
31,699-7 CAS No. 7783-68-8 5g
NbF5 FW 187.9 25 g Phosphorus oxybromide
98%
Packaged in Teflon bottles 37,694-9 (Phosphorus oxide bromide; Phosphoryl 25 g
R: 20/21/22-34 S: 26-27-28-36/37/39-45 bromide)
CAS No. 7789-59-5
Niobium(V) iodide POBr3 FW 286.7
bp. . . . . . . . . . . . . . . . . . . . . . . 192 C/760 mm Hg (lit.)
40,079-3 CAS No. 13779-92-5 5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 C (lit.)
NbI5 FW 727.4 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.82 g/mL (lit.)
-8 mesh R: 14-34 S: 26-36/37/39-43-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.)
R: 34 S: 22-26-27-36/37/39-45
Osmium
Osmium trichloride
39,859-4 CAS No. 13444-93-4 100 mg
OsCl3 FW 296.6 500 mg
99.9%
R: 23/24/25-34 S: 26-36/37/39-45
277
Anhydrous Halides
Phosphorus
Phosphorus oxychloride 25,653-6 99% 5g

mp . . . . . . . . . . . . . . . . . . . -40 C (lit.) 100 g
(Phosphoryl chloride; Phosphorus oxide chloride) Density. . . . . . . . . . . . . . . 2.88 g/mL (lit.) 500 g
CAS No. 10025-87-3
POCl3 FW 153.3 27,682-0 Phosphorus tribromide solution 100 mL
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . .5.3 (vs air) PBr3 FW 270.7 800 mL
Vapor pressure. . . . . . . . . . . . . . . . . . . . . . 28 mm Hg ( 20 C) 1.0 M in dichloromethane
Vapor pressure. . . . . . . . . . . . . . . . . . . . . 104 mm Hg ( 50 C) Packaged under nitrogen in Sure/Seal bottles
bp. . . . . . . . . . . . . . . . . . . . . . . . . .105.8 C/760 mm Hg (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.488 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.25 C (lit.) R: 14-34-37-40 S: 26-36/37/39-45
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.645 g/mL (lit.)
R: 14-22-26-29-35-48/23 S: 26-45-7/8 Phosphorus trichloride
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,209-9 99.999% 10 g CAS No. 7719-12-2
High purity POCl3 is used as an n-type 50 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.574 g/mL (lit.)
dopant in the semiconductor industry in 100 g
applications such as solar cell fabrication. 31,011-5 Phosphorus trichloride 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .

(Phosphorus(III) chloride) 100 g
32,045-5 99% 1L PCl3 FW 137.3 500 g
Packaged in poly-coated bottles 99.999%
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,117-0 99% 5g Vapor pressure. . . . . . . . . . . . . . . . . . 100 mm Hg ( 20 C)
250 g Vapor pressure. . . . . . . . . . . . . . . . . . 385 mm Hg ( 55 C)
1 kg R: 14-26/28-29-35-48/20 S: 26-36/37/39-45-7/8
Phosphorus pentabromide 27,681-2 Phosphorus trichloride solution 100 mL

PCl3 FW 137.3 800 mL
22,673-4 CAS No. 7789-69-7 25 g 2.0 M in dichloromethane
PBr5 FW 430.5 100 g Packaged under nitrogen in Sure/Seal bottles
95% Vapor pressure. . . . . . . . . . . . . . . . . . . . 6.58 psi ( 20 C)
Microelectronics
R: 14-23/24/25-34 S: 26-27-28-36/37/39-45 Vapor pressure. . . . . . . . . . . . . . . . . . . .23.32 psi ( 55 C)
R: 14-26/28-35-40-48/20 S: 26-36/37/39-45-7/8
Phosphorus pentoxide
Phosphorus triiodide
(Phosphorus(V) oxide; Phosphoric anhydride)
CAS No. 1314-56-3 24,155-5 (Phosphorus(III) iodide) 10 g
P2O5 FW 141.9 CAS No. 13455-01-1 50 g
R: 35 S: 22-26-45 PI3 FW 411.7
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 99%
41,711-4 99.9999% 50 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 C (lit.)
Packaged under nitrogen in ampules Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.18 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340 C (lit.) R: 14-34-37 S: 26-36/37/39-45
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.3 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
800.558.9196 (USA)
25,605-6 99.998% 25 g Platinum
Vapor density. . . . . . . . . . . . . . 4.9 (vs air) 100 g
Vapor pressure. . . . . . . 10 mm Hg ( 238 C)
Vapor pressure. . . . . . . . . . . . . . . . . . .1 mm Hg ( 384 C)
Platinum(II) bromide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.39 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 20,612-1 CAS No. 13455-12-4 1g
43,141-9 99.99+%, ReagentPlus 50 g PtBr2 FW 354.9 5g
Meets A.C.S. reagent specifications. 250 g 98%
Vapor density. . . . . . . . . . . . . . 4.9 (vs air) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 250 C (dec.) (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . .1 mm Hg ( 384 C) Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.65 g/mL (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . 10 mm Hg ( 238 C) Ordering/Pricing: www.sigma-aldrich.com
insolubles. . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.02% Platinum(II) chloride
total metallic impurities. . . . . . . . . . . . . . . . . . . <100 ppm
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.3 g/mL (lit.) CAS No. 10025-65-7
Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% PtCl2 FW 266.0
NH4+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 581 C (dec.) (lit.)
Trademark of Sigma-Aldrich Co. Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.05 g/mL (lit.)
R: 34-42/43 S: 26-27-36/37/39-45
Phosphorus tribromide . . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,231-5 99.99+% 1g
CAS No. 7789-60-8 solid
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Phosphorus tribromide solid 5g
(Phosphorus(III) bromide) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
PBr3 FW 270.7 20,609-1 98% 250 mg
Vapor pressure. . . . . . . . . . . . . . . . . . .10 mm Hg ( 48 C) 1g
bp. . . . . . . . . . . . . . . . . . . . . . . 175 C/760 mm Hg (lit.) 5g
R: 14-34-37 S: 26-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
28,846-2 99.99+% 10 g
Vapor pressure. . . . . . . . . . 0.27 psi ( 54 C) 50 g
mp . . . . . . . . . . . . . . . . . . . -41.5 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.85 g/mL (lit.)
278
Anhydrous Halides
Platinum
Platinum(IV) chloride 40,931-6 99.999% 25 g

mp . . . . . . . . . . . . . . . . . . . 770 C (lit.) 100 g
(Platinum tetrachloride) Density. . . . . . . . . . . . . . . 1.98 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 13454-96-1
20,409-9 99.99+% 50 g
PtCl4 FW 336.9 mp . . . . . . . . . . . . . . . . . . . 770 C (lit.) 250 g
R: 22-34-42/43 S: 26-27-36/37/39-45 Density. . . . . . . . . . . . . . .1.984 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
52,064-0 Engelhard code S3053, 99.9+% 1g 45,102-9 anhydrous, beads, -10 mesh, 99.99% 10 g
solid 5g Packaged under argon in ampules 50 g
Pt 55-58% Total impurities. . . . . . . . . . . . . . <100 ppm
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 370 C (dec.) (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 770 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 4.303 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.98 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,984-0 99.99+% 250 mg 37,885-2 optical grade, random crystals, 99.98% 10 g

1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 31,012-3 -30 mesh, 98+% 1 kg
20,611-3 98% 250 mg mp . . . . . . . . . . . . . . . . . . . . 770 C (lit.) 5 kg
mp . . . . . . . . . . . . . . 370 C (dec.) (lit.) 1g Density. . . . . . . . . . . . . . . .1.984 g/mL (lit.)
Density. . . . . . . . . . . . . 4.303 g/mL (lit.) 5g
Potassium fluoride
Platinum(II) iodide
CAS No. 7789-23-3
20,605-9 CAS No. 7790-39-8 1g KF FW 58.10
PtI2 FW 448.9 5g A versatile fluoride ion source used in a study of ion-specific
98% swelling and de-swelling of ampholytic polymer gels, in the
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 360 C (dec.) (lit.) room temperature oxidation of noble metals in HF, and in the
Density. . . . . . . . . . . . . . . . . . . . . . . . . 6.403 g/mL (lit.) measurement of electronic polarizabilities of ions in polymers of
alkali halides.
R: 23/24/25 S: 26-45
Potassium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics

Potassium bromide Packaged under argon in ampules 25 g
mp . . . . . . . . . . . . . . . . . . . . 858 C (lit.)
CAS No. 7758-02-3 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.48 g/mL (lit.)
KBr FW 119.0 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 36/37/38 S: 26 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 22,981-4 99.99% 10 g
44,996-2 anhydrous, powder, 99.999% 10 g mp . . . . . . . . . . . . . . . . . . . 858 C (lit.) 100 g
Packaged under argon in ampules 50 g Density. . . . . . . . . . . . . . . 2.48 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . 734 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.75 g/mL (lit.) 30,759-9 Purified by spray-dried, 99% 50 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Fluorinating agent with decreased 250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . moisture sensitivity and enhanced 1 kg
22,979-2 99.99% 10 g reactivity. J. Fluorine Chem. 1990, 50,
Vapor pressure. . . . . . . <0.01 mm Hg ( 20 C) 50 g 371. Chimia 1988, 42, 67.
Vapor pressure. . . . . . . . . 1 mm Hg ( 795 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 734 C (lit.)
Potassium fluoride on alumina
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.75 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,101-0 anhydrous, powder, 99.95% 25 g 31,638-5 40 wt. % on alumina 25 g
R: 22 S: 24/25 100 g
mp . . . . . . . . . . . . . . . . . . . 734 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.75 g/mL (lit.) Potassium fluoride on celite
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,255-2 (Potassium fluoride on Celite) 10 g
37,884-4 optical grade, random crystals, 99.9+% 5g KF-Celite 100 g
25 g 50 wt.% on Celite, Technical Grade
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Registered trademark of Celite Corp.
44,997-0 anhydrous, beads, -10 mesh, 99.9+% 25 g R: 20/21/22-34 S: 26-27-28-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . 734 C (lit.)
Potassium iodide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.75 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
CAS No. 7681-11-0
KI FW 166.0
Potassium chloride Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.13 g/mL (lit.)
CAS No. 7447-40-7 . . . . . . . . . . . . . . . . . . . . . . . . . . . .

KCl FW 74.55 42,942-2 anhydrous, beads, -10 mesh, 99.998% 5 g
S: 22-24/25 Packaged under argon in ampules 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
Packaged under argon in ampules 50 g 20,410-2 99.99+% 10 g
mp . . . . . . . . . . . . . . . . . . . . 770 C (lit.) Vapor pressure. . . . . . . . 1 mm Hg ( 745 C) 50 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.98 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . 681 C (lit.) 250 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
279
Anhydrous Halides
Praseodymium
Praseodymium(III) bromide Rhodium

43,970-3 CAS No. 13536-53-3 2g Rhodium(III) chloride
PrBr3 FW 380.6 10 g
anhydrous, powder, 99.99% 30,786-6 CAS No. 10049-07-7 500 mg
R: 36 S: 26-36 RhCl3 FW 209.3 2.5 g
98%
Praseodymium(III) chloride Hydrophobic form
R: 22
CAS No. 10361-79-2
PrCl3 FW 247.3
Packaged under argon in ampules Rubidium
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm
R: 36 S: 26-37/39 Rubidium bromide
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,121-5 anhydrous, beads, -10 mesh, 99.99% 1g 33,614-9 CAS No. 7789-39-1 10 g
mp . . . . . . . . . . . . . . . . . . . . 786 C (lit.) 5g RbBr FW 165.4 50 g

25 g 99.7%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.35 g/mL (lit.)
29,829-8 anhydrous, powder, 99.99% 5g S: 22-24/25
25 g
Rubidium chloride
Praseodymium(III) fluoride
CAS No. 7791-11-9
43,209-1 CAS No. 13709-46-1 1g RbCl FW 120.9
PrF3 FW 197.9 5g S: 22-24/25
anhydrous, powder, 99.99% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 23/24/25-32 S: 26-36/37/39-45 20,425-0 99.99% 1g
mp . . . . . . . . . . . . . . . . . . . . 718 C (lit.) 10 g
Praseodymium(III) iodide Density. . . . . . . . . . . . . . . . . 2.8 g/mL (lit.) 50 g
Microelectronics
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,632-8 CAS No. 13813-23-5 1g 21,526-0 99.8% 10 g
PrI3 FW 521.6 5g mp . . . . . . . . . . . . . . . . . . . . 718 C (lit.) 50 g
anhydrous, powder, 99.9+% Density. . . . . . . . . . . . . . . . . 2.8 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 61-42/43 S: 53-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 715 C (lit.)
Rhenium Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.76 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Rhenium(III) chloride
Rubidium fluoride See: Crystal Grade Inorganics Page 406
30,918-4 CAS No. 13569-63-6 1g
ReCl3 FW 292.6 5g Rubidium iodide
800.558.9196 (USA)
Starting material for peralkylated benzene-
metal complexes that act as electron reservoirs. 25,144-5 CAS No. 7790-29-6 10 g
Organometallics 1989, 8, 2243. RbI FW 212.4 50 g
R: 36/37/38 S: 26-37/39 99.9%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.55 g/mL (lit.)
Rhenium(V) chloride S: 22-24/25
30,919-2 CAS No. 13596-35-5 1g

ReCl5 FW 363.5 5g Ruthenium
Starting material for rhenium porphyrins1
Ruthenium(III) bromide
and alkyne complexes of rhenium.2 (1) Z. Naturforsch., B:
Chem. Sci. 1990, 45, 518. (2) ibid. 1990, 45, 1227.
R: 36/37/38 S: 26-37/39 44,928-8 CAS No. 14014-88-1 1g
RuBr3 FW 340.8 5g
Rhenium(VI) fluoride
Ruthenium(III) chloride
43,561-9 CAS No. 10049-17-9 25 g
ReF6 FW 300.2 20,852-3 CAS No. 10049-08-8 2g
99% RuCl3 FW 207.4 10 g
R: 14-32-35 S: 53-9-23-30-36/37/39-43-45 Density. . . . . . . . . . . . . . . . 3.11 g/mL (lit.)
R: 34 S: 26-36/37/39-45
Rhenium(III) iodide
Ruthenium(III) iodide
57,506-2 CAS No. 15622-42-1 1g
44,925-3 CAS No. 13896-65-6 1g
ReI3 FW 566.9 5g
R: 36/37/38 S: 26-36 RuI3 FW 481.8
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 590 C (dec.) (lit.)
R: 61-36/37/38 S: 53-22-36/37/39-45
280
Anhydrous Halides
Samarium
Samarium(III) bromide Scandium chloride

CAS No. 13759-87-0 CAS No. 10361-84-9
SmBr3 FW 390.1 ScCl3 FW 151.3
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,123-1 anhydrous, beads, -10 mesh, 99.99% 1g 45,126-6 anhydrous, powder, 99.99% 1g
10 g 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
41,663-0 anhydrous, powder, 99.9% 5g 40,935-9 anhydrous, powder, 99.9% 250 mg
25 g 1g
5g
Samarium(III) chloride
Scandium fluoride
CAS No. 10361-82-7
SmCl3 FW 256.7 43,210-5 CAS No. 13709-47-2 1g
Packaged under argon in ampules ScF3 FW 102.0 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.46 g/mL (lit.) anhydrous, powder, 99.99%
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm Packaged under argon in ampules
R: 36/37/38 S: 26-36 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 23/24/25-32 S: 26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . 686 C (lit.) 5g Scandium iodide
25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,125-8 anhydrous, beads, -10 mesh, 99.9% 5g 43,967-3 CAS No. 14474-33-0 1g
25 g ScI3 FW 425.7 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . anhydrous, powder, 99.999%
40,061-0 anhydrous, powder, 99.9% 2g Packaged under argon in ampules
10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 920 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Microelectronics
50 g
R: 61-36/37/38 S: 53-22-36/37/39-45
Samarium(III) fluoride
43,208-3 CAS No. 13765-24-7 1g Selenium
SmF3 FW 207.4 5g
anhydrous, powder, 99.99% Diselenium dichloride
R: 23/24/25-32 S: 26-36/37/39-45
32,351-9 CAS No. 10025-68-0 5 mL
Se2Cl2 FW 228.8
Samarium(II) iodide
99%
R: 23/24/25-34 S: 22-26-36/37/39-45
40,934-0 CAS No. 32248-43-4 1g
SmI2 FW 404.2 5g
anhydrous, powder, 99.9+%
Selenium oxychloride
Packaged under argon in ampules 33,615-7 (seleninyl chloride) 10 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 11-19-36/37 S: 16-29-33
CAS No. 7791-23-3
SeOCl2 FW 165.9
Samarium(III) iodide 97%
bp. . . . . . . . . . . . . . . . . . . . . . . 180 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.43 g/mL (lit.)
48,403-2 CAS No. 13813-25-7 1g
R: 14-23/24/25 S: 23-26-36/37/39-45
SmI3 FW 531.1 5g
anhydrous, powder
R: 36/37/38 S: 26-36
Selenium tetrabromide
40,062-9 CAS No. 7789-65-3 1g
Scandium SeBr4 FW 398.6 10 g
-8 mesh, 99%
R: 23/24/25-34-40 S: 22-26-27-36/37/39-45
Scandium bromide
51,752-6 CAS No. 13465-59-3 1g Selenium tetrachloride
ScBr3 FW 284.7
32,352-7 CAS No. 10026-03-6 10 g
anhydrous, powder, 99.99+%
SeCl4 FW 220.8 50 g
Density. . . . . . . . . . . . . . . . . 2.6 g/mL (lit.)
Employed in solid state synthesis of unusual clusters, R: 23/24/25-34 S: 22-26-36/37/39-45
Sc19Br28Z4, (Z=Mn, Fe, Ru or Os). These clusters are of
interest for their structure and magnetic properties.
Steinwand, S.J. et al. Inorg. Chem. 1997, 36, 6413.
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
281
Anhydrous Halides
Silicon
Dichlorosilane Trichlorosilane
CAS No. 4109-96-0 17,555-2 CAS No. 10025-78-2 5g
Cl2SiH2 FW 101.0 Cl3HSi FW 135.5 100 g
Packaged in lecture bottles 99% 500 g
The use of stainless steel control valve Z14,695-1 is Vapor density. . . . . . . . . . . . . . . 1 (vs air)
recommended. Vapor pressure. . . . . . . . . . . . . . . . . . . . 9.75 psi ( 20 C)
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . .3.5 (vs air) Vapor pressure. . . . . . . . . . . . . . . . . . . .30.79 psi ( 55 C)
Vapor pressure. . . . . . . . . . . . . . . . . . . . . 1254 mm Hg ( 20 C) bp. . . . . . . . . . . . . . . . . . . . . . 31-32 C/760 mm Hg (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 8.3 C/760 mm Hg (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 F
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -122 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.342 g/mL (lit.)
R: 12-14-23-34 S: 26-36/37/39-45 R: 12-14-17-20/22-29-35 S: 16-26-36/37/39-43-45-7/9
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,339-5 99.99+% (Purity based on metals 227 g
analysis) Silver
film resistivity. . . . . . . . . . . . . . . . . . . . . . . . . >50 W-cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Silver bromide

29,522-1 97+% 227 g
22,680-7 CAS No. 7785-23-1 5g
Silicon tetrabromide AgBr FW 187.8 25 g
99.999%
(Tetrabromosilane) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 432 C (lit.)
SiBr4 FW 347.7 S: 22-24/25
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 153 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 C (lit.) Silver chloride
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2.8 g/mL (lit.)
R: 34 S: 26-27-28-36/37/39 CAS No. 7783-90-6
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
49,410-0 99.995% 5 mL AgCl FW 143.3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 455 C (lit.)
Microelectronics
liquid 25 mL
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.56 g/mL (lit.)
33,346-8 99% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor density. . . . . . . . . . . . . . . 2.8 (vs air) 50 g
Silicon tetrachloride H2O. . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 10026-04-7 20,438-2 99.999% 1g
Packaged under nitrogen in Sure/Seal bottles Applied in controlled assembly of one- 5g
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.86 (vs air) dimensional and three-dimensional silver(I) 25 g
Vapor pressure. . . . . . . . . . . . . . . . . . . . 420 mm Hg ( 37.7 C) thiolates. Hong, M. et al. Inorg. Chem.
28,938-8 Silicon tetrachloride 100 mL 1999, 38, 600.
(Tetrachlorosilane) 800 mL
800.558.9196 (USA)
SiCl4 FW 169.9
Silver(I) fluoride
99.998%
Semiconductor grade CAS No. 7775-41-9
bp. . . . . . . . . . . . . . . . . . . . . . . 57.6 C/760 mm Hg (lit.)
AgF FW 126.9
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -70 C (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 435 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.483 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.852 g/mL (lit.)
R: 14-36/37/38 S: 26-7/8
R: 23/24/25-34 S: 26-28-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
24,992-0 Silicon tetrachloride solution 100 mL 22,685-8 99.9+% 1g
Cl4Si FW 169.9 5g
1.0 M in dichloromethane 25 g
Vapor pressure. . . . . . . . . . . . . . . . . 420 mm Hg ( 37.8 C) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.34 g/mL (lit.) 22,686-6 99% 5g
R: 20/21/22-34-40 S: 26-27-28-36/37/39-45 25 g
Silicon tetraiodide Silver(II) fluoride
46,575-5 CAS No. 13465-84-4 5g 20,092-1 (Silver difluoride) 10 g
SiI4 FW 535.7 25 g CAS No. 7783-95-1 50 g
99.9+% AgF2 FW 145.9
bp. . . . . . . . . . . . . . . . . . . . . . 287.4 C/760 mm Hg (lit.)
98+%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120.5 C (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 690 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 4.198 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.57 g/mL (lit.)
R: 61-24/25-34-42/43 S: 53-26-36/37/39-45
R: 8-14-23/24/25-34 S: 17-26-36/37/39-45
Silver(I) hydrogenfluoride
43,600-3 CAS No. 12249-52-4 5g
HAgF2 FW 146.9
97%
R: 23/24/25-31-34 S: 26-27-36/37/39-45
282
Anhydrous Halides
Silver
Silver iodide Sodium fluoride

CAS No. 7783-96-2 CAS No. 7681-49-4
AgI FW 234.8 NaF FW 41.99
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Starting material for solid state preparation of Na3MnF6 for
20,440-4 99.999% 1g further high pressure structural determination studies. Carlson,
Density. . . . . . . . . . . . . . . . 5.68 g/mL (lit.) 10 g S. et al. Inorg. Chem. 1998, 37, 1486.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 993 C (lit.)
22,682-3 99% 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.558 g/mL (lit.)
25 g R: 25-32-36/38 S: 22-36-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
100 g 45,002-2 anhydrous, powder, 99.99% 5g
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm

Sodium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
21,530-9 99.99% 10 g
Sodium bromide 50 g
250 g
CAS No. 7647-15-6
NaBr FW 102.9 Sodium hydrogen difluoride
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,059-1 anhydrous, beads, -10 mesh, 99.999% 5 g (Sodium bifluoride)
CAS No. 1333-83-1
mp . . . . . . . . . . . . . . . . . . . . 747 C (lit.) NaHF2 FW 61.99
Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.203 g/mL (lit.) R: 25-34 S: 22-26-37-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 31,017-4 pellets, diam. ca. 5 mm · length 5 mm, 100 g
22,988-1 99.99+% 10 g 99%
Vapor pressure. . . . . . . . 1 mm Hg ( 806 C) 100 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . >68 C (dec.) (lit.)

mp . . . . . . . . . . . . . . . . . . . 755 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.21 g/mL (lit.)

43,764-6 granules, 98% 1 kg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Material may agglomerate over time
22,034-5 99+% 25 g Employed recently in the room temperature synthesis of
Vapor pressure. . . . . . . . 1 mm Hg ( 806 C) 500 g fluoride glasses. J. Non-Cryst. Solids 1995, 184, 166.
mp . . . . . . . . . . . . . . . . . . . 755 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.203 g/mL (lit.) Starting material for solid state preparation of Na3MnF6
for further high pressure structural determination studies.
Sodium chloride Carlson, S. et al. Inorg. Chem. 1998, 37, 1486.
CAS No. 7647-14-5 Sodium iodide See: Crystal Grade Inorganics Page 406
NaCl FW 58.44
Facilitates the cross-coupling of organostannanes with iodides Sodium iodide
without using palladium. Kang, S-K. et al. J. Org. Chem. 1997,
62, 4208. CAS No. 7681-82-5
NaI FW 149.9
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 36/38 S: 26
Packaged under argon in ampules 25 g 43,968-1 anhydrous, beads, -10 mesh, 99.999% 5 g
mp . . . . . . . . . . . . . . . . . . . . 801 C (lit.) Packaged under argon in ampules 25 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.165 g/mL (lit.) Density. . . . . . . . . . . . . . . 3.667 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,443-9 99.999% 5g 22,991-1 99.99+% 1g
Vapor pressure. . . . . . . . 1 mm Hg ( 865 C) 20 g Vapor density. . . . . . . . . . . . . . >1 (vs air) 10 g
mp . . . . . . . . . . . . . . . . . . . 801 C (lit.) 100 g mp . . . . . . . . . . . . . . . . . . . 661 C (lit.) 100 g
Density. . . . . . . . . . . . . . .2.165 g/mL (lit.) Density. . . . . . . . . . . . . . .3.667 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,001-4 anhydrous, beads, -10 mesh, 99.99% 25 g 32,245-8 98% 100 g
Packaged under argon in ampules 100 g Vapor density. . . . . . . . . . . . . .>1 (vs air) 500 g
mp . . . . . . . . . . . . . . . . . . . 801 C (lit.) H2O. . . . . . . . . . . . . . . . . . . . . . <2% 2.5 kg
Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.165 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm Sodium periodate
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,886-0 optical grade, random crystals, 99.99% 10 g
36,364-2 (Sodium (meta)periodate) 25 g
50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7790-28-5
31,016-6 80 mesh, 98+% 1 kg NaIO4 FW 213.9
Vapor pressure. . . . . . . . . 1 mm Hg ( 865 C) 5 kg 10 wt. % in silica gel
mp . . . . . . . . . . . . . . . . . . . . 801 C (lit.) R: 8-36/37/38 S: 17-26-36/37/39
Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.165 g/mL (lit.)
283
Anhydrous Halides
Strontium
Strontium bromide 33,984-9 Sulfur dichloride solution 100 mL

SCl2 FW 103.0
CAS No. 10476-81-0 80%, Technical Grade, 1.0 M in dichloromethane
SrBr2 FW 247.4 Packaged under nitrogen in Sure/Seal bottles
Reagent for facile synthesis of poly(phenylcarbyne), a precursor Vapor pressure. . . . . . . . . . . . . . . . . . . . 7.64 psi ( 20 C)
to diamond-like carbon. Vapor pressure. . . . . . . . . . . . . . . . . . . .25.67 psi ( 55 C)
R: 36/37/38 S: 26-36 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.355 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 23/24/25-34-40 S: 26-27-28-36/37/39-45
5g Sulfur monochloride
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
43,068-4 anhydrous, powder, 99.995% 1g 15,775-9 (Sulfur chloride) 50 g
Packaged under argon in ampules 5g CAS No. 10025-67-9 250 g
H2O. . . . . . . . . . . . . . . . . . . . . . <100 ppm S2Cl2 FW 135.0 1 kg
98%
Strontium chloride Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . 4.7 (vs air)
Vapor pressure. . . . . . . . . . . . . . . . . . 6.8 mm Hg ( 20 C)

CAS No. 10476-85-4 Vapor pressure. . . . . . . . . . . . . . . . . . .44 mm Hg ( 55 C)
SrCl2 FW 158.5 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.67 (lit.)
R: 36/37/38 S: 26-36 bp. . . . . . . . . . . . . . . . . . . . . . . 138 C/760 mm Hg (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -80 C (lit.)
45,128-2 anhydrous, beads, -10 mesh, 99.995% 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.688 g/mL (lit.)
25 g R: 14-20-25-29-35-50 S: 26-36/37/39-45-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
43,966-5 anhydrous, powder, 99.99+% 5g Sulfuryl chloride solution
Density. . . . . . . . . . . . . . . . . . 3 g/mL (lit.) 25 g
27,850-5 CAS No. 7791-25-5 100 mL
Strontium fluoride SO2Cl2 FW 135.0 800 mL
1.0 M in dichloromethane
CAS No. 7783-48-4 Packaged under nitrogen in Sure/Seal bottles
Microelectronics
SrF2 FW 125.6 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.352 g/mL (lit.)
R: 20/21/22 S: 36 R: 14-34-40 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,003-0 anhydrous, powder, 99.99% 10 g
Packaged under argon in ampules 50 g Sulfuryl chloride fluoride
bp. . . . . . . . . . . . 2489 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.24 g/mL (lit.)
43,799-9 CAS No. 13637-84-8 25 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm SO2ClF FW 118.5
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Technical Grade, 90+%
20,447-1 99.99% 10 g Packaged in cylinders
Density. . . . . . . . . . . . . . . . 4.24 g/mL (lit.) 50 g Used in the preparation of novel fluorinated
. . . . . . . . . . . . . . . . . . . . . . . . . . . . alkanesulfonyloxaziridines,1 and in the alkoxylation of
34,220-3 powder, 1 mm 100 g
fullerene C60.2 (1) J. Fluorine Chem. 1994, 68, 277. (2)
500 g
Mater. Res. Soc. Symp. Proc. 1992, 247, 293.
800.558.9196 (USA)
R: 14-23/24/25-34 S: 26-27-28-36/37/39-45
Strontium iodide
CAS No. 10476-86-5 Tantalum
SrI2 FW 341.4
Packaged under argon in ampules Tantalum(V) bromide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.55 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm 40,046-7 CAS No. 13451-11-1 10 g
R: 14-34 S: 22-26-27-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Br5Ta FW 580.5
40,069-6 anhydrous, beads, -10 mesh, 99.99+% 1g 98%, powder, -8 mesh Ordering/Pricing: www.sigma-aldrich.com
10 g R: 20/21/22-34 S: 22-26-27-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,633-6 anhydrous, powder, 99.99+% 2g Tantalum(V) chloride
mp . . . . . . . . . . . . . . . . . . . . 515 C (lit.) 10 g
(Tantalum pentachloride)
CAS No. 7721-01-9
Sulfur TaCl5 FW 358.2
R: 22-34 S: 26-36/37/39-45
Sulfur dichloride . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 10545-99-0 Packaged under argon in ampules 25 g
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.55 (vs air) Used to form mixed chloro-aryloxide
compounds, such as [Ta(OC6H3-2,6-i-Pr2)2Cl3]2, which
33,032-9 Sulfur dichloride 50 g form pyridine or phosphine adducts with a distortedsix-
(Dichloro sulfide) 250 g coordinate geometry.1 Also used as a starting material for
SCl2 FW 103.0 1 kg new edge-bridged octahedral M6 cluster compounds such
Technical Grade, 80% as CsErTa6Cl18, for which electron and stability studies
Vapor pressure. . . . . . . . . . . . . . . . . . 170 mm Hg ( 20 C)
were performed.2 (1) Clark, J.R. et al. Inorg. Chem. 1997,
sulfur monochloride. . . . . . . . . . . . . . . . . . predominantly
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.621 g/mL (lit.)
36, 3623. (2) Ogliaro, F. et al. Inorg. Chem. 1998, 37,
R: 14-34-50 S: 26-36/37/39-45-61 6199.
284
Anhydrous Halides
Tantalum
(Continuation of) Terbium

Tantalum(V) chloride
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Terbium(III) bromide
40,047-5 99.99% 5g
Density. . . . . . . . . . . . . . . . 3.68 g/mL (lit.) 25 g 46,634-4 CAS No. 14456-47-4 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . TbBr3 FW 398.6 5g
21,863-4 99.8% 5g
Density. . . . . . . . . . . . . . . 3.68 g/mL (lit.) 25 g
100 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 827 C (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
Tantalum(V) fluoride
Terbium(III) chloride
31,700-4 CAS No. 7783-71-3 10 g
TaF5 FW 275.9 25 g CAS No. 10042-88-3

98% TbCl3 FW 265.3
Packaged in Teflon bottles Packaged under argon in ampules
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.74 g/mL (lit.) H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm
R: 34 S: 26-27-28-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tantalum(V) iodide 45,130-4 anhydrous, powder, 99.99% 1g
mp . . . . . . . . . . . . . . . . . . . . 588 C (lit.) 10 g
51,298-2 CAS No. 14693-81-3 5g Density. . . . . . . . . . . . . . . . 4.35 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
TaI5 FW 815.5 25 g
99.9+%
R: 61 S: 53-36/37/39-45 10 g
Terbium(III) fluoride
Tellurium
43,206-7 CAS No. 13708-63-9 1g

Tellurium dichloride, compound with thiourea (1 to 2) TbF3 FW 215.9 5g
Microelectronics

38,877-7 CAS No. 207737-98-2 1g Useful for the preparation of fluoride glasses.
TeCl2 2SC(NH2)2 FW 350.7
R: 25-38-40-43-51/53 S: 53-26-36/37-61 Packaged under argon in ampules
For the preparation of electroluminescent thin films and
Tellurium tetrabromide luminescent zinc sulfide. Samokhvalov, M.K. Zh. Prikl.
Spektrosk. 1995, 62, 182. Chem. Abstr. 1996, 124,
CAS No. 10031-27-3 159253k. Adams, R.M. et al. Mater. Res. Soc. Symp. Proc.
TeBr4 FW 447.2 1995, 378 Chem. Abstr. 1995, 123, 353533w.
R: 34 S: 22-26-27-36/37/39-45 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36
bp. . . . . . . . . . . . . 420 C/760 mm Hg (lit.)
Terbium(III) iodide
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~380 C (lit.)
42,709-8 CAS No. 13813-40-6 1g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm TbI3 FW 539.6 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . anhydrous, flakes, 99.99%
45,157-6 anhydrous, beads, -10 mesh, 99.995% 5g R: 42/43-63 S: 22-26-36
25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
40,048-3 99% 10 g Thallium
mp . . . . . . . . . . . . . . . . . . . . 380 C (lit.)
Thallium(I) bromide
Tellurium tetrachloride
CAS No. 7789-40-4
CAS No. 10026-07-0 TlBr FW 284.3
TeCl4 FW 269.4 R: 26/28-33-51/53 S: 13-28-45-61
R: 34 S: 26-36/37/39-45 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
51,819-0 99.999+% 5g Packaged under argon in ampules 50 g
solid 25 g mp . . . . . . . . . . . . . . . . . . . ~460 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.5 g/mL (lit.)
20,533-8 99% 25 g H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
bp. . . . . . . . . . . . 380 C/760 mm Hg (lit.) 100 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . 224 C (lit.) 17,764-4 99% 10 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.26 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . >300 C (lit.) 100 g
Tellurium tetraiodide Thallium(I) chloride

40,049-1 CAS No. 7790-48-9 10 g CAS No. 7791-12-0
TeI4 FW 635.2 TlCl FW 239.8
R: 20/21/22-34 S: 22-26-27-36/37/39-45 R: 26/28-33-51/53 S: 13-28-45-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
25 g
285
Anhydrous Halides
Thallium
22,996-2 99.999% 10 g Tin

Density. . . . . . . . . . . . . . . . . . 7 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Tin(II) bromide
22,489-8 99% 25 g
Vapor pressure. . . . . . . 10 mm Hg ( 517 C) 100 g 30,925-7 CAS No. 10031-24-0 10 g
Density. . . . . . . . . . . . . . .7.004 g/mL (lit.) SnBr2 FW 278.5 50 g
Density. . . . . . . . . . . . . . . . 5.12 g/mL (lit.)
Thallium(I) fluoride R: 34 S: 26-27-28-36/37/39-45
39,983-3 CAS No. 7789-27-7 5g Tin(IV) bromide

TlF FW 223.4 25 g
99% 21,596-1 (Stannic bromide) 50 g
R: 26/28-33-51/53 S: 13-28-45-61 CAS No. 7789-67-5 250 g
SnBr4 FW 438.3
Thallium(III) fluoride 99%
bp. . . . . . . . . . . . . . . . . . . . . . . 202 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 C (lit.)

39,982-5 CAS No. 7783-57-5 5g
TlF3 FW 261.4 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.34 g/mL (lit.)
R: 14-34-37 S: 26-36/37/39-45-7/8
99%
R: 26/28-33-51/53 S: 13-28-45-61
Tin(II) chloride
Thallium Iodide See: Crystal Grade Inorganics Page 406
(Stannous chloride)
Thallium(I) iodide CAS No. 7772-99-8
SnCl2 FW 189.6
30,922-2 CAS No. 7790-30-9 50 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.95 g/mL (lit.)
TlI FW 331.3 R: 22-34-37 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
99.9%
R: 26/28-33-51/53 S: 13-28-45-61
Microelectronics
Synthesis of tin(IV) octaethylcorroles was
Thulium accomplished with this reagent. These new compounds
exhibit reversible oxidation only at the conjugated ring
Thulium(III) bromide system, not at the metal center. Kadish, K. et al. Inorg.
Chem. 1998, 37, 4573.
43,963-0 CAS No. 14456-51-0 1g bp. . . . . . . . . . . . . . . . . . . . . . . 606 C/760 mm Hg (lit.)
TmBr3 FW 408.6 5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246 C (lit.)
anhydrous, powder, 99.99% H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
S: 26-36
20,472-2 99.99+% 10 g
50 g
Thulium(III) chloride
43,964-9 CAS No. 13537-18-3 1g Tin(IV) chloride
800.558.9196 (USA)
TmCl3 FW 275.3 5g
CAS No. 7646-78-8
Packaged under argon in ampules 21,791-3 Tin(IV) chloride 5g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm (Stannic chloride fuming) 25 g
S: 26-36 SnCl4 FW 260.5 100 g
99.995%
Thulium(III) fluoride Doping polyaniline, an intensively studied polymer, with
SnCl4 stabilizes its solution in nitromethane and allows
43,214-8 CAS No. 13760-79-7 1g
solution processing.
TmF3 FW 225.9 5g
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . 9 (vs air)
anhydrous, powder, 99.99% Vapor pressure. . . . . . . . . . . . . . . . . . .20 mm Hg ( 22 C)
Packaged under argon in ampules Vapor pressure. . . . . . . . . . . . . . . . . 18.6 mm Hg ( 20 C)
Used to improve ultraviolet and visible upconversion bp. . . . . . . . . . . . . . . . . . . . . . 114.1 C/760 mm Hg (lit.)
fluorescence in fluorinated glasses. J. Appl. Phys. 1996, mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -33 C (lit.)
80, 1965. Adv. Mater. Res. (Zug. Switz.) 1994, 1-2, 101. Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.226 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm R: 34 S: 26-45-7/8
R: 23/24/25-32 S: 26-36/37/39-45
Tin(IV) chloride solution
Thulium(III) iodide (Stannic chloride; Tin tetrachloride)
SnCl4 FW 260.5
43,962-2 CAS No. 13813-43-9 1g Packaged under nitrogen in Sure/Seal bottles
TmI3 FW 549.6 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
24,995-5 1.0 M in dichloromethane 100 mL
Density. . . . . . . . . . . . . .1.419 g/mL (lit.) 800 mL
Packaged under argon in ampules R: 34-40-52/53 S: 26-36/37/39-45-61-7/8
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 61-36/37/38 S: 53-22-36/37/39-45 35,749-9 1.0 M in heptane 100 mL
Fp. . . . . . . . . . . . . . . . . . . . . . . 34 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.874 g/mL (lit.)
R: 11-23/24/25-34 S: 16-26-36/37/39-45
286
Anhydrous Halides
Tin
Tin(II) fluoride 30,779-3 98% 5g

25 g
33,462-6 (Stannous fluoride) 5g 100 g
CAS No. 7783-47-3 100 g
SnF2 FW 156.7 500 g Titanium(II) chloride
99%
solid 45,173-8 CAS No. 10049-06-6 1g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.57 g/mL (lit.) TiCl2 FW 118.8 5g
R: 22-38-41 S: 26-39 anhydrous, powder, 99.98%
Tin(IV) fluoride H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 14/15-17-34 S: 16-24-26-36/37/39-45
33,347-6 CAS No. 7783-62-2 2g
SnF4 FW 194.7 10 g Titanium(III) chloride

R: 20/21/22 S: 26-27-36-36/39
(Titanium trichloride)
Tin(II) iodide CAS No. 7705-07-9
TiCl3 FW 154.2
CAS No. 10294-70-9 Used for the vapor-phase formation of intermetallic
SnI2 FW 372.5 compounds with ultrafine particle size.
R: 61-20/21/22-36/37/38-42/43 S: 53-22-26-36/37/39-45 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 440 C (dec.) (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . References
40,930-8 anhydrous, beads, 99.999%, -10 mesh 5 g Sohn, H.T.; Paldey, S., Metall. Mater. Trans. B 29B, 457 (1998)
Packaged under argon in ampules 25 g R: 14-17-34 S: 6-26-27-30-36/37/39-45
Density. . . . . . . . . . . . . . . 5.285 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 51,438-1 99.999% 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . solid 5g
46,635-2 powder, 99.999% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 5g 22,097-3 powder 5g

Used in a convenient, new, two-step method Density. . . . . . . . . . . . . . . . 2.64 g/mL (lit.) 25 g
Microelectronics
for preparing organic-inorganic perovskite thin films

which exhibit uniform surfaces and strong Titanium(IV) chloride
photoluminescence. Liang, K. et al. Chem. Mater. 1998,
10, 403. 25,431-2 (Titanium tetrachloride) 10 g
Total impurities. . . . . . . . . . . . . . . . . . . . . . . . <100 ppm CAS No. 7550-45-0 50 g
bp. . . . . . . . . . . . . . . . . . . . . . . 714 C/760 mm Hg (lit.) TiCl4 FW 189.7
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320 C (lit.) 99.995+%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.28 g/mL (lit.) Vapor pressure. . . . . . . . . . . . . . . . . . 9.6 mm Hg ( 20 C)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor pressure. . . . . . . . . . . . . . . . . . .50 mm Hg ( 55 C)
34,217-3 95% 25 g bp. . . . . . . . . . . . . . . . . . . . . . 136.4 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . 5.28 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -24 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.73 g/mL (lit.)
Tin(IV) iodide R: 14-34-36/37 S: 26-45-7/8
(Stannic iodide) Titanium(III) fluoride

CAS No. 7790-47-8
SnI4 FW 626.3 39,981-7 (Titanium trifluoride) 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.47 g/mL (lit.) CAS No. 13470-08-1 25 g
R: 20/21/22-34-42/43 S: 26-28-36/37/39-45 TiF3 FW 104.9
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 3.4 g/mL (lit.)
R: 14-32-34 S: 26-36/37/39-45
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Titanium(IV) fluoride
34,218-1 95% 10 g
tin(II) iodide. . . . . . . . . . . . . . . . . . . <2% 50 g 33,323-9 CAS No. 7783-63-3 10 g
TiF4 FW 123.9 100 g
Density. . . . . . . . . . . . . . .2.798 g/mL (lit.)
Titanium R: 20/21/22-34 S: 26-27-28-36/37/39-45
Titanium(IV) bromide Titanium(IV) iodide
(Titanium tetrabromide) (Titanium tetraiodide)

CAS No. 7789-68-6 CAS No. 7720-83-4
TiBr4 FW 367.5 TiI4 FW 555.5
Used for the formation of titanium silicide thin films on Si Used in the CVD of titanium nitride films with optimized
substrates. characteristics.
References Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4.3 g/mL (lit.)
Grillo, V.A. et al., J. Mater. Synth. Process. 6, 55 (1998) References
R: 14-34 S: 26-36/37/39-45 Faltermeier. C.G. et al., J. Electrochem. Soc. 145, 676 (1998)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 61-34-35-42/43 S: 53-22-26-27-36/37/39-45
45,160-6 anhydrous, powder, 99.99% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 5g 45,844-9 anhydrous, powder, 99.99% 2g
bp. . . . . . . . . . . . . . 230 C/760 mm Hg (lit.) Packaged under argon in ampules 10 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 C (lit.) mp . . . . . . . . . . . . . . . . . . . . 150 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.25 g/mL (lit.) H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
287
Anhydrous Halides
Titanium
41,359-3 98% 5g Vanadium(III) chloride

25 g
20,827-2 CAS No. 7718-98-1 5g
VCl3 FW 157.3 25 g
Tungsten Density. . . . . . . . . . . . . . . . . . 3 g/mL (lit.)
R: 22-34 S: 26-27-28-36/39-45
Tungsten(V) bromide
Vanadium(IV) chloride
40,051-3 CAS No. 13470-11-6 1g
WBr5 FW 583.4 5g 36,661-7 CAS No. 7632-51-1 100 g
R: 34 S: 22-26-27-36/37/39-45 VCl4 FW 192.8
Packaged under nitrogen in Sure/Seal bottles
Tungsten(IV) chloride bp. . . . . . . . . . . . . . . . . . . . . . . 154 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -28 C (lit.)
26,397-4 (tungsten tetrachloride) 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.816 g/mL (lit.)
CAS No. 13470-13-8 25 g R: 14-23/24/25-34 S: 26-27-36/37/39-45
WCl4 FW 325.7

97% Vanadium(III) chloride tetrahydrofuran complex (1:3)
Used in the synthesis of new triply-bonded ditungsten
phosphine complexes. Cotton, F.A. et al. Inorg. Chem. 39,538-2 (trichlorotris(tetrahydrofuran)vanadium) 5g
1997, 36, 80. CAS No. 19559-06-9 25 g
R: 34 S: 26-27-28-36/37/39-45 VCl3 3OC4H8 FW 373.6
97%
Tungsten(VI) chloride mp . . . . . . . . . . . . . . . . . . . . . . . . . . 265 C (dec.) (lit.)
R: 20/21/22-34 S: 26-27-28-36/37/39-45
24,191-1 (Tungsten hexachloride) 10 g
CAS No. 13283-01-7 100 g Vanadium(IV) fluoride
WCl6 FW 396.6
99.9+% 20,222-3 CAS No. 10049-16-8 10 g
Microelectronics
Vapor pressure. . . . . . . . . . . . . . . . . . 43 mm Hg ( 215 C) VF4 FW 126.9
bp. . . . . . . . . . . . . . . . . . . . . . . 347 C/760 mm Hg (lit.) R: 23/24/25-34 S: 22-26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275 C (lit.)
R: 34 S: 26-36/37/39-45 Vanadium(III) iodide
Tungsten(VI) dichloride dioxide 40,055-6 CAS No. 15513-94-7 1g

VI3 FW 431.7
38,319-8 CAS No. 13520-76-8 1g 99%
WCl2O2 FW 286.7 10 g R: 34 S: 22-26-27-36/37/39-45
99%
R: 36/37/38 S: 26-36 Vanadium(V) oxychloride
Tungsten(VI) fluoride See: High-Purity Gases for CVD Page 293
(Vanadyl trichloride; Vanadium(V) oxytrichloride)
CAS No. 7727-18-6
800.558.9196 (USA)
Tungsten(VI) oxychloride VOCl3 FW 173.3
Vapor pressure. . . . . . . . . . . . . . . . . . . . . 13.8 mm Hg ( 20 C)
26,501-2 (Tungsten(VI) oxide chloride; Tungsten(VI) 5g Vapor pressure. . . . . . . . . . . . . . . . . . . . . . 69 mm Hg ( 55 C)
chloride oxide) 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.84 g/mL (lit.)
CAS No. 13520-78-0 R: 14-25-34 S: 26-27-28-36/37/39-45
WOCl4 FW 341.7 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
98% 25,604-8 99.995% 10 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211 C (lit.) bp. . . . . . . . . . 126-127 C/760 mm Hg (lit.) 50 g
R: 36/37/38 S: 26-37/39 mp . . . . . . . . . . . . . . . . . . . . -77 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,089-1 99% 100 g Ordering/Pricing: www.sigma-aldrich.com
Vanadium Packaged under nitrogen in Sure/Seal

bottles
bp. . . . . . . . . . . . . . . . . . . . . . . 127 C/760 mm Hg (lit.)
Vanadium(III) bromide
40,054-8 CAS No. 13470-26-3 2g Vanadium(V) oxyfluoride
VBr3 FW 290.7 10 g
39,994-9 (Vanadyl trifluoride; Vanadium(V) 5g
99%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 g/mL (lit.)
oxytrifluoride) 25 g
R: 34 S: 22-26-27-36/37/39-45 CAS No. 13709-31-4
VOF3 FW 123.9
Vanadium(II) chloride 99%
R: 20/21/22-32-34 S: 26-36/37/39-45
42,237-1 CAS No. 10580-52-6 1g
VCl2 FW 121.8 5g
95%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.09 g/mL (lit.)
R: 20/21/22-34 S: 26-27-36/37/39-45
288
Anhydrous Halides
Ytterbium
Ytterbium(III) bromide Yttrium chloride

45,132-0 CAS No. 13759-89-2 1g CAS No. 10361-92-9
YbBr3 FW 412.8 5g Cl3Y FW 195.3
anhydrous, powder, 99.99% Will react with potassium alkoxotitanates to form precursors to
Packaged under argon in ampules novel titanium-containing ceramics.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) Packaged under argon in ampules
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 721 C
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.670 g/mL
Ytterbium(III) chloride mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 721 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.67 g/mL (lit.)
CAS No. 10361-91-8 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm
YbCl3 FW 279.4 References
Packaged under argon in ampules Veith, M. et al., Inorg. Chem. 36, 2391 (1997)
R: 36/37/38 S: 26-37/39
Applied with NiCl2 to form a very effective catalyst for the . . . . . . . . . . . . . . . . . . . . . . . . . . . .
reductive dehalogenation of aryl halides. Zhang, Y. et al. Synth. 45,136-3 anhydrous, powder, 99.99% 10 g
Commun. 1997, 27, 4327. 50 g
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36 45,010-3 anhydrous, beads, -10 mesh, 99.99% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 g
mp . . . . . . . . . . . . . . . . . . . . 875 C (lit.) 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Yttrium fluoride
CAS No. 13709-49-4
25 g
YF3 FW 145.9
R: 20/21/22-36/37/38 S: 26-37/39
Ytterbium(III) fluoride . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 13760-80-0 Packaged under argon in ampules 50 g

YbF3 FW 230.0
Microelectronics
Recent applications include studies of InF3-

Packaged under argon in ampules 1
based glasses and optical characterization of YF3 thin
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <100 ppm
films.2 (1) J. Non-Cryst. Solids 1996, 204, 260. (2) Proc.
R: 23/24/25-32 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . SPIE-Int. Soc. Opt. Eng. 1996, 2776, 366.
43,212-1 anhydrous, powder, 99.99% 10 g H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Employed in the preparation and study of 50 g
34,326-9 fused, pieces, 3-12 mm, 99.9% 10 g
fluorinated glasses. J. Non-Cryst. Solids . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1996, 203, 127. J. Mater Sci. 1996, 31, 2981. 32,606-2 99.9% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 g
Density. . . . . . . . . . . . . . . . 4.01 g/mL (lit.) 50 g
Yttrium iodide
Ytterbium iodide 41,301-1 CAS No. 13470-38-7 1g
YI3 FW 469.6 5g
49,437-2 CAS No. 13813-44-0 1g
anhydrous, flakes, 99.9%
YbI2 FW 426.8
powder, 99.9+%
Starting material for YBCO superconducting materials in a
lower temperature preparation. Baney, R.H. et al. Chem.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~999 C (lit.)
R: 36/37/38 S: 26-36 Mater. 1992, 4, 984. Applied in the solid-state synthesis of
a new compound, Y21I18C14B7, which is the first example
of a rare earth metal halide with interstitial halogen atoms
Yttrium with misfit characteristics. Oeckler, O. et al. J. Am. Chem.
Soc 1998, 38, 1767.
Yttrium bromide H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
R: 40-42/43 S: 22-26-36/37/39
CAS No. 13469-98-2
YBr3 FW 328.6
R: 36/37/38 S: 26-36 Zinc
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,008-1 anhydrous, beads, -10 mesh, 99.9% 1g Zinc bromide
5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7699-45-8
45,135-5 anhydrous, powder, 99.9% 1g ZnBr2 FW 225.2
10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 394 C (lit.)
R: 34 S: 22-26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
bp. . . . . . . . . . . . . 650 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 4.5 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
23,002-2 99.999% 10 g
Density. . . . . . . . . . . . . . . 4.201 g/mL (lit.) 50 g
289
Anhydrous Halides
Zinc
Zinc chloride Zirconium

CAS No. 7646-85-7 Zirconium(IV) bromide
Zinc chloride 40,056-4 CAS No. 13777-25-8 10 g
ZnCl2 FW 136.3 Br4Zr FW 410.8 50 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293 C (lit.)
R: 34-50/53 S: 28-45-60-61-7/8
98%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22-34 S: 22-26-27-36/37/39-45
Packaged under argon in ampules 25 g Zirconium(IV) chloride
Density. . . . . . . . . . . . . . . 2.907 g/mL (lit.)
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm (Zirconium tetrachloride)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 10026-11-6
42,943-0 anhydrous, powder, 99.995+% 5g ZrCl4 FW 233.0
Packaged under argon in ampules 25 g R: 14-22-34 S: 26-36/37/39-45
Density. . . . . . . . . . . . . . . . 2.91 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 35,740-5 99.9+% 10 g

. . . . . . . . . . . . . . . . . . . . . . . . . . . . For applications in organozirconium 100 g
45,011-1 anhydrous, beads, -10 mesh, 99.99% 5g chemistry.
Packaged under argon in ampules 10 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.8 g/mL (lit.)
Density. . . . . . . . . . . . . . . 2.907 g/mL (lit.) 50 g References
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm Aldrichimica Acta 18, 31 (1985)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,999-7 99.999% 10 g 22,188-0 99.5+% 5g
Vapor pressure. . . . . . . . . 1 mm Hg ( 428 C) 50 g Suitable for nuclear reactor applications. 100 g
Density. . . . . . . . . . . . . . . 2.907 g/mL (lit.) Vapor pressure. . . . . . . . 1 mm Hg ( 190 C) 500 g
Density. . . . . . . . . . . . . . . 2.803 g/mL (lit.)
Zinc chloride solution
ZnCl2 FW 136.3
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Zirconium(IV) chloride–Tetrahydrofuran complex
27,683-9 1.0 M in diethyl ether 100 mL
Microelectronics
Packaged under nitrogen in poly-coated 800 mL 39,542-0 (tetrachlorobis(tetrahydrofuran)zirconium; 5g
Sure/Seal bottles Zirconium tetrachloride tetrahydrofuran
Material may separate at room temperature. Store in complex)
freezer to homogenize CAS No. 21959-01-3
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -40 F ZrCl4 2OC4H8 FW 377.2
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.835 g/mL (lit.) 99%
R: 12-34-66-67 S: 16-26-33-36/37/39-45-7/9 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 175-177 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22-34 S: 22-26-36/37/39-45
36,637-4 0.5 M in tetrahydrofuran 100 mL
Packaged under nitrogen in Sure/Seal 800 mL Zirconium(IV) fluoride
bottles
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -4 F CAS No. 7783-64-4
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.948 g/mL (lit.) F4Zr FW 167.2
800.558.9196 (USA)
R: 11-34 S: 16-26-33-36/37/39-45-7/9 R: 34 S: 26-27-28-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Zinc fluoride 56,146-0 powder, 99.99% 5g
25 g
20,556-7 CAS No. 7783-49-5 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
ZnF2 FW 103.4 100 g 31,146-4 99.9% 25 g
powder, 5 mm, 99% 500 g 100 g
Vapor pressure. . . . . . . . 1 mm Hg ( 970 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 872 C (lit.) Zirconium(IV) iodide
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.95 g/mL (lit.)
R: 37/38-41 S: 26-39 40,057-2 CAS No. 13986-26-0 1g Ordering/Pricing: www.sigma-aldrich.com
ZrI4 FW 598.8 5g
Zinc iodide anhydrous, powder, 99.9%
CAS No. 10139-47-6 H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
ZnI2 FW 319.2 R: 34 S: 22-26-27-36/37/39-45
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.74 g/mL (lit.)
R: 34 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Mixed-Metal Halides
Packaged under argon in ampules 25 g Cesium chloride/sodium chloride (2:1) eutectic
H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 55,528-2 CAS No. 15844-58-3 10 g
solid 50 g
Packaged under argon in ampules 25 g mp . . . . . . . . . . . . . . . . . . . >497-500 C
mp . . . . . . . . . . . . . . . . . . . . 445 C (lit.) R: 36 S: 26
H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
23,001-4 99.99+% 25 g
mp . . . . . . . . . . . . . . . . . . . 446 C (lit.) 250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,388-3 98+% 50 g
mp . . . . . . . . . . . . . . . . . . . 446 C (lit.) 250 g
290
Anhydrous Halides
Mixed-Metal Halides
Lithium chloride/potassium chloride eutectic Hexaamminecobalt(III) nitrate

47,933-0 CAS No. 65567-96-6 10 g 52,947-8 CAS No. 10534-86-8 5g
anhydrous, beads, 99.99% 50 g Co(NH3)6(NO3)3 FW 347.1 25 g
Packaged under argon in ampules 200 g 99.999%
Applied in separators for mixed transition- solid
metal oxide cathodes in thermal batteries. Guidotti, R. mp . . . . . . . . . . . . . . . . . . . . . . . . . . 300-304.2 C (lit.)
Reinhardt, F.W. Proc. Power Sources Conf. 1996, 37th, Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
251. R: 36/37/38 S: 26-36
LiCl 44 wt. %
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 357 C (lit.) Lead(II) nitrate
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.02 g/mL (lit.)
R: 22-36/37/38 S: 26 CAS No. 10099-74-8
Pb(NO3)2 FW 331.2
Titanium(III) chloride-aluminum chloride Several new polymeric complexes of lead with dialkylamino
derivatives of squaric acid were produced to study their
45,641-1 (aluminum titanium chloride) 50 g coordination modes as possible prototypes for studies of
CAS No. 12003-13-3 250 g lanthanide complexes.
(TiCl3)3 AlCl3 FW 596.0 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 470 C (dec.) (lit.)
1-3 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.53 g/mL (lit.)
R: 14-20/21/22-34 S: 26-36/37/39-45 R: 61-20/22-33-50/53-62 S: 53-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,358-0 99.999% 10 g
50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CVD & ALD Precursors 46,779-0 ReagentPlus, 99.99+% 50 g
‡99.0% 250 g
insolubles. . . . . . . . . . . . . . . . . £0.005%
Anhydrous Metal Nitrates total metallic impurities. . . . . . . . . . . . . . . . . . . <100 ppm

Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
Microelectronics
Ammonium cerium(IV) nitrate Ca. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%

Cu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
(Ceric ammonium nitrate) Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
CAS No. 16774-21-3
Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.02%
Ce(NH4)2(NO3)6 FW 548.2 Trademark of Sigma-Aldrich Co.
R: 8-36/37/38 S: 17-26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,954-7 99.99+% 10 g Silver nitrate
50 g
CAS No. 7761-88-8
250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . AgNO3 FW 169.9
43,133-8 ReagentPlus, 99.99% 50 g R: 34-50/53 S: 26-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Meets A.C.S. reagent specifications. 250 g
20,439-0 99.9999% 1g
total metallic impurities. . . . . . . . <100 ppm
insol. dil. H2SO4. . . . . . . . . . . . . . . . . . . . . . . . . £0.05%
mp . . . . . . . . . . . . . . . . . . . 212 C (lit.) 50 g
Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
Density. . . . . . . . . . . . . . .4.352 g/mL (lit.) 250 g
PO43-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.02%
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Trademark of Sigma-Aldrich Co. 20,505-2 99.998% 10 g
mp . . . . . . . . . . . . . . . . . . . 212 C (lit.) 250 g
Barium nitrate Density. . . . . . . . . . . . . . .4.352 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,275-4 CAS No. 10022-31-8 25 g 47,090-2 99.995%, ReagentPlus 10 g
Ba(NO3)2 FW 261.3 100 g ‡99.0% 50 g
99.999% total trace metallic impurities. . . <50 ppm trace
water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £3% amount
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 592 C (lit.) free acid. . . . . . . . . . . . . . . . . . . . . . . . . . . passes test
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.24 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 212 C (dec.) (lit.)
Sr. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm Density. . . . . . . . . . . . . . . . . . . . . . . . . . 4.35 g/mL (lit.)
R: 8-20/22 S: 17-28 Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
trans-Dinitrobis(ethylenediamine)cobalt(III) nitrate Cu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £2 ppm
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £2 ppm
57,588-7 CAS No. 14240-12-1 5g Pb. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
C4H16CoN7O7 FW 333.1 25 g Trademark of Sigma-Aldrich Co.
mp . . . . . . . . . . . . . . . . . . . 253 C (dec.)
R: 36/37/38 S: 26-36 Tetraammineplatinum(II) nitrate
CAS No. 20634-12-2
H N
2
NH
2 (H2N)4Pt(NO3)2 FW 387.2
O N Co NO NO R: 5-8-36/37/38-43 S: 15-26-27-36/37/39
2 2 3
H N
2
NH
2
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,229-3 99.995% 250 mg
solid 1g
mp . . . . . . . . . . . . . . 262 C (dec.) (lit.)
291
CVD & ALD Precursors
Anhydrous Metal Nitrates
27,872-6 crystalline needles 1g Digermane

5g
46,307-8 CAS No. 13818-89-8 2.4 L
Thallium(I) nitrate Ge2H6 FW 151.3
10% in hydrogen, electronic grade
CAS No. 10102-45-1 Digermane is used for the deposition of amorphous and
TlNO3 FW 266.4 epitaxial germanium thin films. Digermane is also used in
R: 26/28-33-51/53 S: 13-28-45-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . . the formation of boron-doped SiGe alloy layers and with
20,460-9 99.999% 10 g diborane in the formation of B-doped Ge(001) films, both
mp . . . . . . . . . . . . . . . . . . . 206 C (lit.) 25 g by gas-source molecular-beam epitaxy (MBE).
125 g Precursor to germanium and germanium-silicon alloy thin
. . . . . . . . . . . . . . . . . . . . . . . . . . . . films.
30,923-0 99.9% 25 g Packaged in electropolished stainless steel lecture bottle
100 g with a stainless steel valve and CGA 350 outlet.
Requires 316 SS gas regulator Z17,395-9 or Z17,396-7.
Titanium(IV) nitrate 99.99% (excluding germane and trigermane)

9-11% (balance is hydrogen)
49,971-4 (tetranitratotitanium(IV)) 1g bp. . . . . . . . . . . . . . . . . . . . . . . 31.5 C/760 mm Hg (lit.)
CAS No. 12372-56-4 5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -109 C (lit.)
Ti(NO3)4 FW 295.9 Critical temperature. . . . . . . . . . . . . . . . . . . . . . 150.9 C
99.9+% References
CVD precursor for TiO2 thin films. 1. Cho, H. et. al. , Appl. Surf. Sci. 92, 128 (1996)
solid 2. Lu, Q. et. al., J. Appl. Phys. 80, 4458 (1996)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57-59 C (lit.) 3. Idem., Ibid. 78, 6027 (1995)
References R: 12-20/21/22-36/37/38 S: 16-24-26-36/37/39
Gilmer, D. C. et al., Mater. Res. Soc. Symp. Proc. 495, 45 (1998)
R: 8-29-34 S: 17-26-36/37/39-45 Disilane
Tris(ethylenediamine)cobalt(III) nitrate 46,304-3 CAS No. 1590-87-0 10 g
Microelectronics
Si2H6 FW 62.22 20 g
52,953-2 CAS No. 6865-68-5 5g electronic grade, 99.998%
C6H24CoN9O9 FW 425.2 25 g Disilane is used for the deposition of amorphous silicon,
99.99+% epitaxial silicon and silicon based dielectrics via rapid low-
solid temperature chemical vapor depsition (LTCVD). Disilane is
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >250 C (lit.) also used in the epitaxial growth of SiGe films by
molecular beam epitaxy (MBE) in conjunction with solid
sources of germanium. Precursor for the rapid, low
Tris(ethylenediamine)rhodium(III)nitrate temperature deposition of epitaxial silicon and silicon-
based dielectrics.
57,624-7 CAS No. 480445-39-4 500 mg
Packaged in electropolished stainless steel lecture bottle
Rh(H2NCH2CH2NH2)3(NO3)3 FW 385.2 2g
with stainless steel valve and CGA 350 outlet.
99.99%
800.558.9196 (USA)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C
bp. . . . . . . . . . . . . . . . . . . . . . -14.5 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . -132.6 C (lit.)
resistivity. . . . . . . . . . . . . . . . . . . . . . . . . . <1000 W-cm
High-Purity Gases for CVD Silane (SiH4). . . . . . . . . . . . . . . . . . . . . . . . . <1000 ppm
Gas Equipment See: Gas Equipment Page 513 Carbon dioxide (CO2). . . . . . . . . . . . . . . . . . . . . . <1 ppm
Argon (Ar) + Oxygen (O2). . . . . . . . . . . . . . . . . . . <1 ppm
Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Diborane Water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Siloxanes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm
46,305-1 CAS No. 19287-45-7 24 L Higher silanes. . . . . . . . . . . . . . . . . . . . . . . . . .<50 ppm
B2H6 FW 27.67 48 L Chlorosilanes. . . . . . . . . . . . . . . . . . . . . . . . . .<0.2 ppm
10% in hydrogen, electronic grade THC. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Dibroane gas is used primarily as a p-type dopant in the Critical temperature. . . . . . . . . . . . . . . . . . . . . . 150.9 C
deposition of eptaxial and amorphous silicon thin films. References
1. Lin, H.-Y. et. al., Solid-State Electron 39, 1731 (1996)
Packaged in electropolished stainless steel lecture bottle 2. Wado, H. et. al., J. Cryst. Growth 169, 457 (1996)
with a stainless steel valve and CGA 350 outlet. 3. Huange, G.W., et al., J. Appl. Phys. 81, 205 (1997)
R: 17-20/21-36/37/38-42 S: 16-24-26-36/37/39
Requires 316 SS gas regulators Z17,395-9 or Z17,396-7.
99.99% (diborane only)
9-11% (balance hydrogen)
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -92.5 C
bp. . . . . . . . . . . . . . . . . . . . . . -92.5 C/760 mm Hg (lit.)
R: 12-23/24/25-36/37/38 S: 9-16-36/37/39-45
292
High-Purity Gases for CVD
Germane Methylsilane
46,302-7 CAS No. 7782-65-2 5g 46,299-3 CAS No. 992-94-9 10 g
GeH4 FW 76.67 15 g CH3SiH3 FW 46.14 20 g
electronic grade, 99.997+% electronic grade, 99.9+%
Germane gas is used in the deposition of epitaxial and Precursor to silicon carbide or alloy thin films by chemical
amorphous SiGe alloy layers used in the production of vapor deposition (CVD) and molecular beam epitaxy
high performance devices including photovoltaic cells and (MBE).
integrated circuits (IC). Precursor to germanium- Methylsilane is used in the plasma-assisted CVD of silicon
containing thin films by chemical vapor deposition (CVD) carbide (SiC) and as a precursor to the epitaxial growth of
and molecular beam epitaxy (MBE). A CVD precursor for SiGeC alloy layers via rapid thermal CVD. Recent
germanium carbide semiconducting films. developments include the use of methylsilane as a
Packaged in electropolished stainless steel lecture bottle precursor to silicon-carbon-hydrogen polymer used as
with stainless steel valve and CGA 350 outlet. photoresists.
Requires 316 SS gas regulator Z17,395-9 or Z17,396-7. Packaged in electropolished stainless steel lecture bottle
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -88.4 C with a stainless steel valve and CGA 350 outlet.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -165 C
Vapor density. . . . . . . . . . . . . . . . . . 1.53 (-142 C, vs air)
Vapor density. . . . . . . . . . . . . . . . . . 0.628 (-58 C, vs air)
bp. . . . . . . . . . . . . . . . . . . . . . -88.4 C/760 mm Hg (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . -57 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -165 C (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -157 C (lit.)
Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . . <2 ppm Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . <10 ppm
Oxygen (O2). . . . . . . . . . . . . . . . . . . . . . . . . . <0.5 ppm Argon + Oxygen (Ar + O2). . . . . . . . . . . . . . . . . . .<2 ppm
Carbon dioxide (CO2). . . . . . . . . . . . . . . . . . . . . . <2 ppm Methane (CH4). . . . . . . . . . . . . . . . . . . . . . . . . <50 ppm
Hydrogen (H2). . . . . . . . . . . . . . . . . . . . . . . . . <50 ppm Carbon dioxide (CO2). . . . . . . . . . . . . . . . . . . . . <10 ppm
Water (H2O). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm Silane (SiH4). . . . . . . . . . . . . . . . . . . . . . . . . . .<50 ppm
THC. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Methylchlorosilane CH3SiH2Cl. . . . . . . . . . . . . . . <100 ppm
Digermane (Ge2H6). . . . . . . . . . . . . . . . . . . . . . <20 ppm
Dimethylsilane (CH3)2SiH2. . . . . . . . . . . . . . . . . . <100 ppm
Germoxanes. . . . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm
References
Chlorogermanes. . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm

Mi, J. et. al. , J. Vac. Sci. Technol., B 14, 1660 (1996)
Carbon monoxide + Trigermane (CO+Ge3H8). . . . . . . <1 ppm
Microelectronics
R: 12-14-20/21 S: 16-24-26-36/37/39
Critical temperature. . . . . . . . . . . . . . . . . . . . . . . . 35 C
References
1. Banzi, P., Chem. Mater. 14, 2506 (2002)
Molybdenum(VI) fluoride
2. Grant, J.M. et. al., Mat. Res. Soc. Symp. Proc. 429, 349 (1996)
3. Huang, G. W. et. al., J. Appl. Phys. 81, 205 (1997) 39,909-4 (Molybdenum hexafluoride) 227 g
R: 17-21/22-23 S: 16-24-26-36/37/39-45 CAS No. 7783-77-9
MoF6 FW 209.9
Methane 99.9+%
Packaged in cylinders
46,303-5 CAS No. 74-82-8 24 L A stainless steel control valve or gas regulator is
CH4 FW 16.04 48 L recommended.
electronic grade, 99.998+% bp. . . . . . . . . . . . . . . . . . . . . . . . 37 C/760 mm Hg (lit.)
Methane is used as a carbon source for the chemical vapor mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17.5 C (lit.)
deposition (CVD) of carbide and diamond thin films. Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.3 g/mL (lit.)
R: 34 S: 26-36/37/39-45
with a stainless steel valve and CGA 350 outlet. Requires
316 SS gas regulators Z17,395-9 or Z17,396-7.
Phosphine
A 316 stainless steel regulator is recommended. 29,564-7 CAS No. 7803-51-2 10 g
bp. . . . . . . . . . . . . . . . . . . . . . -161 C/760 mm Hg (lit.)
PH3 FW 34.00 50 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -183 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.716 g/mL (lit.) electronic grade, 99.9995+%
Carbon monoxide (CO). . . . . . . . . . . . . . . . . . . . .<2 ppm Phosphine is used primarily in the manufacture of III-IV
Carbon Dioxide (CO2). . . . . . . . . . . . . . . . . . . . . .<2 ppm semiconductor materials by OMCVD and as a dopant in
Water (H2O). . . . . . . . . . . . . . . . . . . . . . . . . . . <3 ppm crystalline and amorphous silicon.
Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm Precursor to III-V semiconductor thin films. Also useful as a
Ethane (C2H5). . . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm dopant for crystalline and amorphous silicon.
Critical temperature. . . . . . . . . . . . . . . . . . . . . . -82.1 C
R: 12 S: 9-16-33
with a stainless steel valve and CGA 350 outlet.
Precursor to III-V semiconductor thin films. Also useful as a
dopant for crystalline and amorphous silicon.
bp. . . . . . . . . . . . . . . . . . . . . . -87.5 C/760 mm Hg (lit.)
Carbon monoxide (CO). . . . . . . . . . . . . . . . . . . . .<1 ppm
Carbon dioxide (CO2). . . . . . . . . . . . . . . . . . . . . . <1 ppm
Water (H2O). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Methane (CH4). . . . . . . . . . . . . . . . . . . . . . . . . .<1 ppm
Argon (Ar). . . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Oxygen (O2). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Arsine (AsH3). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Critical temperature. . . . . . . . . . . . . . . . . . . . . . . 51.3 C
R: 17-18-26-37 S: 9-16-36/37/39-45
293
High-Purity Gases for CVD
Silane Tungsten(VI) fluoride

33,389-1 (silicon tetrahydride) 10 g 39,910-8 (Tungsten hexafluoride) 225 g
CAS No. 7803-62-5 50 g CAS No. 7783-82-6 450 g
SiH4 FW 32.12 WF6 FW 297.8
99.998+%, electronic grade 99.9+%
Silane is used in the deposition of amorphous silicon, Packaged in cylinders
epitaxial silicon and silicon based dielectrics. Polycrystalline A stainless steel control valve or gas regulator is
films can be deposited on silicon wafers and glass recommended.
substrates via remote plasma chemcial vapor deposition bp. . . . . . . . . . . . . . . . . . . . . . . 17.5 C/760 mm Hg (lit.)
(RPCVD) using a SiH4-SiF2-H2 gas mixture., Silane is used mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.3 C (lit.)
widely as a dopant in the formation of III-IV R: 23/24/25-34 S: 26-36/37/39-45
semiconductor materials.
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . 1.1 (vs air) Deuterated Gases
resistivity. . . . . . . . . . . . . . . . . . . . . . . . . . >1000 W-cm
Diborane-d6

bp. . . . . . . . . . . . . . . . . . . . . . -112 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -185 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.114 g/mL (lit.) CAS No. 20396-66-1
Carbon monoxide (CO). . . . . . . . . . . . . . . . . . . . .<1 ppm B2D6 FW 33.71
Water (H2O). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . . <2 ppm 46,313-2 10% in deuterium, electronic grade 24 L
THC. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm R: 12-23/24/25-36/37/38 S: 9-16-36/37/39-45 48 L
Hydrogen (H2). . . . . . . . . . . . . . . . . . . . . . . . <100 ppm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Chlorosilanes. . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm 46,314-0 10% in helium, electronic grade 24 L
Disilane (SiH6). . . . . . . . . . . . . . . . . . . . . . . . . . <5 ppm 9-11% (balance is helium) 48 L
Trisilane (SiH8). . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm R: 23/24/25-36/37/38 S: 9-16-36/37/39-45
Siloxanes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . <2 ppm
Critical temperature. . . . . . . . . . . . . . . . . . . . . . . -3.4 C Phosphine-d3
Microelectronics
References
1. Quinn, L.J. et. al., Thin Solid Films 296, 7 (1997) 46,312-4 CAS No. 13537-03-6 1g
2. Idem, Ibid. 289, 227 (1996) PD3 FW 37.02 5g
3. Hu, C. C. et. al. , Ibid. 288, 147 (1996) electronic grade, 98 atom % D
R: 12-17-20 S: 9-16-33-36/37/39
Trimethylboron 316 SS gas regulator Z17,395-9 or Z17,396-7.
46,309-4 CAS No. 593-90-8 5g Gas
bp. . . . . . . . . . . . . . . . . . . . . . -87.5 C/760 mm Hg (lit.)
B(CH3)3 FW 55.91 10 g R: 17-18-26-37 S: 9-16-36/37/39-45
electronic grade, 98.35+%
Trimethylboron is used as an organometallic precursor for Silane-d4
the CVD of boron-carbon containing films and as a boron
800.558.9196 (USA)
source in the deposition of borophosphosilicate glass 46,311-6 CAS No. 13537-07-0 1g
(BPSG). SiD4 FW 36.14 5g
Packaged in electropolished stainless steel lecture bottle electronic grade, 98 atom % D
with a stainless steel valve and CGA 350 outlet. Packaged in electropolished stainless steel lecture bottle
Precursor to boron carbide thin films by chemical vapor with stainless steel valve and CGA 350 outlet.
deposition (CVD). Mater. Lett. 1996, 27, 327. Requires 316 SS gas regulator Z17,395-9 or Z17,396-7.
<I> 99.9% chemical purity
Requires 316 SS gas regulator Z17,395-9 or Z17,396-7. bp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -112 C
bp. . . . . . . . . . . . . . . . . . . . . . -20.2 C/760 mm Hg (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -185 C
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . -161.5 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.114 g/mL (lit.) Ordering/Pricing: www.sigma-aldrich.com
Hydrogen (H2). . . . . . . . . . . . . . . . . . . . . . . . . <50 ppm R: 17-20/21-36/37/38-42 S: 16-24-26-36/37/39
Oxygen (O2). . . . . . . . . . . . . . . . . . . . . . . . . . . <1 ppm
Dimethylethylborane [B(CH3)2C2H5]. . . . . . . . . . . . . . <1.5% Trimethylboron-d9
Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . <10 ppm
Trimethylamine (TMA). . . . . . . . . . . . . . . . . . . <1000 ppm 46,342-6 CAS No. 6063-55-4 5g
Methane (CH4). . . . . . . . . . . . . . . . . . . . . . . . <100 ppm
B(CD3)3 FW 64.97 10 g
Carbon dioxide (CO2). . . . . . . . . . . . . . . . . . . . . <10 ppm
References
electronic grade, 99 atom % D
Lewis. J.S. et. al., Mater. Lett. 29, 327 (1996) The deposition of trimethylboron-d9 derived boron-carbon
R: 17-34 S: 7-23-26-36/37/39-43-45 films can result in increased device performance.
with a stainless steel valve and CGA 350 outlet.
99.4% chemical purity
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . 2.3 (vs air)
bp. . . . . . . . . . . . . . . . . . . . . . -20.2 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . -161.5 C (lit.)
R: 17-34 S: 7-23-26-36/37/39-43-45
294
High-Purity Gases for CVD: Halogenated Gases
Boron trichloride Germanium(IV) fluoride

29,501-9 CAS No. 10294-34-5 454 g CAS No. 7783-58-6
BCl3 FW 117.2 GeF4 FW 148.6
99.9% R: 34 S: 26-36/37/39-45
Packaged in lecture bottle
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,300-0 electronic grade, 99.9+% 5g
Used in the high-temperature synthesis of layered
Employed in studies on room-temperature 15 g
graphite-like material with p-type semiconductor
oxidation of noble metals1 and the
properties1. Highly acidic boronated aluminas derived
fabrication of SiGe crystallites on glass substrates.2 (1) Eur.
from BCl3 promote regio- and diastereoselectivity in Diels-
J. Solid State Inorg. Chem. 1996, 33, 809. (2) J. Non-Cryst.
Alder reactions2. (1) Kawaguchi, M. et al. Chem. Mater.
Solids 1996, 198-200, 879.
1996, 8, 1197. (2) McGinnis, M.B.et al. J. Org. Chem.
1996, 61, 3496.

Stainless steel, Z14,695-1 or Monel, Z14,697-8 control
316 SS gas regulator Z17,395-9 or Z17,396-7.
valves or stainless steel Z14,850-4, Z14,851-2 with T-
A 316 stainless steel regulator is recommended.
purge valve Z15,166-1 or Monel Z40,598-1, Z40,600-7
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -36.5 C (lit.)
gas regulators are recommended. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . 4.05 (vs air) 40,150-1 50 g
Vapor pressure. . . . . . . . . . . . . . . . . 1128 mm Hg ( 20 C)
Vapor pressure. . . . . . . . . . . . . . . . . 2815 mm Hg ( 55 C) Silicon tetrafluoride
bp. . . . . . . . . . . . . . . . . . . . . . . 12.5 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -107 C (lit.)
46,301-9 (Silicon(IV) fluoride) 20 g
R: 14-26/28-34 S: 9-26-28-36/37/39-45
CAS No. 7783-61-1 100 g
SiF4 FW 104.1
Boron trifluoride
CAS No. 7637-07-2 Silicon tetrafluoride is used in ion-implantation processes
and as a precursor to fluorinated silica via plasma-assisted
BF3 FW 67.81
bp. . . . . . . . . . . . . . . . . . . . . . . . . . -100 C/760 mm Hg (lit.) CVD. Mixtures of SiF4-SiH4-H2 have recently been used to
Microelectronics
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -127 C (lit.) deposit polycrystalline silicon thin films via remote plasma
R: 14-26-35 S: 9-26-28-36/37/39-45 chemical vapor deposition (RPCVD)., Such fluorinated thin
. . . . . . . . . . . . . . . . . . . . . . . . . . . . films show visible photoluminescence (PL) at room
46,308-6 electronic grade, 99.99+% 20 g temperature.
Packaged in electropolished stainless 100 g Packaged in electropolished stainless steel lecture bottle
steel lecture bottle with stainless steel with a stainless steel valve and CGA 330 outlet.
valve and CGA 330 outlet. Recently used to prepare low temperature silicon films by
Employed recently in a study of conductivity enhancement chemical vapor deposition (CVD). Diffus. Defect Data, Pt.
of CaF2 by grain boundary activation with Lewis acids. B 1996, 51-52, 149. J. Electrochem. Soc. 1996, 143,
Solid State Ionics 1996, 86-88, 581. 2640.
Requires 316 SS gas regulator Z17,395-9 or Z17,396-7. Requires 316 SS gas regulator Z17,395-9 or Z17,396-7.
Nitrogen(N2) + oxygen (O2). . . . . . . . . . . . . . . . . <10 ppm bp. . . . . . . . . . . . . . . . . . . . . . . -86 C/760 mm Hg (lit.)
Sulfur dioxide (SO2). . . . . . . . . . . . . . . . . . . . . . <10 ppm
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -90 C (lit.)
Carbon dioxide (CO2). . . . . . . . . . . . . . . . . . . . . <20 ppm
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 3.57 g/mL (lit.)
Silicon tetrafluoride (SiF4). . . . . . . . . . . . . . . . . . . <20 ppm
Hydrogen fluoride (HF). . . . . . . . . . . . . . . . . . . . <50 ppm
Critical temperature. . . . . . . . . . . . . . . . . . . . . . -12.3 C
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Nitrogen (N2). . . . . . . . . . . . . . . . . . . . . . . . . . . <3 ppm
Argon + oxygen (Ar + O2). . . . . . . . . . . . . . . . . . . <1 ppm
29,502-7 99.5+% 170 g
Methane (CH4). . . . . . . . . . . . . . . . . . . . . . . . . <10 ppm
Packaged in lecture bottles
Stainless steel, Z14,695-1 or Monel, Z14,697-8 control Carbon monoxide (CO). . . . . . . . . . . . . . . . . . . <0.5 ppm
valves or stainless steel Z14,850-4, Z14,851-2 with T- Critical temperature. . . . . . . . . . . . . . . . . . . . . . -14.2 C
purge valve Z15,166-1 or Monel Z40,598-1, Z40,600-7 References
gas regulators are recommended. 1. Quinn, L. J. et. al. , Thin Solid Films 296, 7 (1997)
Vapor density. . . . . . . . . . . . . . . . . . . . 2.38 (21 C, vs air) 2. Idem., Ibid. 289, 227 (1996)
3. Cicala, G. et. al., J. Appl. Phys. 80, 6564 (1996)
Carbon tetrafluoride R: 14-26/27/28-31-34 S: 23-26-36/37/39-45
Metal Alkoxides See: Sol-Gel Precursors Page 349
29,573-6 CAS No. 75-73-0 27 g
CF4 FW 88.00
99.9%
Packaged in lecture bottles
Brass control valve Z14,694-3 or either of brass regulators
Z14,670-6 and Z14,671-4 is recommended.
bp. . . . . . . . . . . . . . . . . . . . . . -130 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -184 C (lit.)
S: 38
295
Metal b-dikenonates: Acetylacetonates (ACAC)
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I) Barium hexafluoroacetylacetonate

42,915-5 CAS No. 12154-84-6 100 mg 40,343-1 CAS No. 314071-48-2 1g
C13H16IrO2 FW 396.5 500 mg Ba(C5HF6O2)2 FW 551.4 5g
R: 36/37/38 S: 26-36 mp . . . . . . . . . . . . . . . . . 250 C (dec.) (lit.)
CH R: 20/22 S: 28
3
C O
CH Ir Beryllium acetylacetonate
C O
CH
3 52,279-1 CAS No. 10210-64-7 25 g
Be(C2H7O2)2 FW 207.2 100 g
R: 49-25-26-36/37/38-43-48/23-51/53 S: 53-
45-61
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Cadmium acetylacetonate hydrate
33,502-9 CAS No. 12245-39-5 100 mg
51,758-5 CAS No. 307531-70-0 50 g

C13H16O2Rh FW 307.2 500 mg
Cd(C2H7O2)2 xH2O FW 310.6
99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 138-140 C (lit.) 99.9+%
R: 36/37/38 S: 26-37/39 R: 20/21/22-50/53 S: 60-61
Acetylacetone Calcium acetylacetonate hydrate
P775-4 (2,4-Pentanedione) 5 mL C10-7 (2,4-pentanedione calcium derivative) 5g

CAS No. 123-54-6 100 mL Ca(C2H7O2)2 xH2O FW 238.3 25 g
CH3COCH2COCH3 FW 100.1 500 mL 99.95%
99+% 1L Degree of hydration ~0.5
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >280 C (dec.) (lit.)
Transition-metal chelating agent
R: 22-36/37/38-63 S: 26-36/37/39
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . .3.5 (vs air)
Microelectronics
Vapor pressure. . . . . . . . . . . . . . . . . . . . . . . 6 mm Hg ( 20 C)
n20 Cerium(III) acetylacetonate hydrate
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.452 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . . .140.4 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -23 C (lit.) 38,140-3 (cerium(III) 2,4-pentanedionate) 50 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .94 F CAS No. 206996-61-4 250 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.975 g/mL (lit.) Ce(C2H7O2)3 xH2O FW 437.4
R: 10-22 S: 21-23-24/25 R: 36/37/38-63 S: 7-26-36/37/39
O
C CH Cesium acetylacetonate
CH 3
3
CH 39,153-0 (2,4-pentanedione cesium derivative) 5g

3
CAS No. 25937-78-4 25 g
O
CsC5H7O2 FW 232.0
800.558.9196 (USA)
H R: 20/21/22-36/37/38-40 S: 26-36/37/39
Chromium(III) acetylacetonate
(Chromium(III) 2,4-pentanedionate)
Aluminum acetylacetonate CAS No. 21679-31-2
Cr(C5H7O2)3 FW 349.3
20,824-8 (Aluminum 2,4-pentanedionate) 5g Used to modify the surface properties of solid polyurethanes
CAS No. 13963-57-0 100 g formed in its presence.
Al(C5H7O2)3 FW 324.3 500 g bp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340 C
99% mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 C Ordering/Pricing: www.sigma-aldrich.com
bp. . . . . . . . . . . . . . . . . . . . . . . 315 C/760 mm Hg (lit.) References
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 190-193 C (lit.) Lipatov, Y.S., J. Polym. Mater. 14, 263 (1997)
R: 25-36/37/38 S: 26-36/37/39-45 R: 20/21/22-36/37/38 S: 23-26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CH
3 57,408-2 99.99% 5g
C O
25 g
CH Al . . . . . . . . . . . . . . . . . . . . . . . . . . . .
C O
20,223-1 97% 5g
CH
3
3
bp. . . . . . . . . . . . 340 C/760 mm Hg (lit.) 100 g
mp . . . . . . . . . . . . . . . . . . . 210 C (lit.) 500 g
Chromium(III) trifluoroacetylacetonate
Barium acetylacetonate hydrate 49,569-7 CAS No. 14592-89-3 5g
Cr(C5H4F3O2)3 FW 511.2
33,905-9 (Barium 2,4-pentanedionate) 50 g 99.9+%
CAS No. 304695-31-6 250 g R: 20/21/22-36/37/38-63 S: 26-36
Ba(C5H7O2)2 xH2O FW 335.5
R: 20/22 S: 28
296
Cobalt(II) acetylacetonate Copper(II) trifluoroacetylacetonate

10,182-6 (1,1,1-trifluoro-2,4-pentanedione copper(II) 5 g
derivative) 25 g
22,712-9 Cobalt(II) acetylacetonate 50 g
CAS No. 14324-82-4
(2,4-pentanedione cobalt(II) derivative; 250 g
Cu(C5H4F3O2)2 FW 369.7
Cobaltous acetylacetonate)
97%
CAS No. 14024-48-7 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 198-199 C (lit.)
Co(C5H7O2)2 FW 257.1 R: 20/21/22-36/37/38 S: 26-36
97%
water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £3% (1,5-Cyclooctadiene)(hexafluoroacetylacetonato)silver(I)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 165-170 C (lit.)
R: 20/21/22-41 S: 7-22-26-37/39
34,819-8 CAS No. 38892-25-0 1g
34,461-3 Cobalt(II) acetylacetonate hydrate 50 g C13H12AgF6O2 FW 422.1 5g

CAS No. 123334-29-2 250 g 99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 122-124 C (lit.)
Co(C5H7O2)2 xH2O FW 257.1
Degree of hydration ~2
R: 20/21/22-40-41 S: 7-22-26-37/39 Dibutyltin bis(acetylacetonate)
52,058-6 CAS No. 22673-19-4 500 mL
Cobalt(III) acetylacetonate
C18H32O4Sn FW 431.2
49,453-4 (Cobalt(III) 2,4-pentanedionate; Cobaltic 5g 95%
R: 10-20/21/22-36/37/38-63 S: 16-26-36
acetylacetonate; Tris(2,4- 25 g
pentanedionato)cobalt)
CAS No. 21679-46-9
Dicarbonyl-acetylacetonato-rhodium(I)
Co(C5H7O2)3 FW 356.3 28,810-1 (Rhodium(I) dicarbonyl acetylacetonate; 1g
99.99+% Dicarbonylrhodium(I) 2,4-pentanedionate)
Used for the preparation of a new family of CAS No. 14874-82-9

Microelectronics
monoporphyrinates which are interesting for their Rh(CO)2(C5H7O2) FW 258.0

photochomical and magnetic properties and synthetic 98%
applications. mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 154-156 C (lit.)
solid R: 20/21/22-36/37/38-63 S: 22-26-36
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 210-213 C (lit.)
References Diisopropoxytitanium bis(acetylacetonate) solution
Spyroulias, G.A. et al., Chem. Commun. 783 (1997)
R: 40 S: 36/37
32,525-2 (TYZOR AA organic titanate) 5 mL
CAS No. 17927-72-9 100 mL
Cobalt(II) hexafluoroacetylacetonate hydrate ((CH3)2CHO)2Ti(C5H7O2)2 FW 364.3 500 mL
33,969-5 CAS No. 206986-92-7 5g 75 wt. % in 2-propanol
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4935 (lit.)
Co(C5HF6O2)2 xH2O FW 473.0 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 F
98% Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.995 g/mL (lit.)
Degree of hydration ~2-3 DuPont product
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 197 C (dec.) (lit.) R: 11-36/37/38-67 S: 16-24/25-26
R: 20/21/22-41 S: 26-36-37/39
Dysprosium(III) acetylacetonate hydrate
Copper(II) acetylacetonate
48,149-1 (2,4-pentanedione Dysprosium(III) 10 g
51,436-5 (2,4-Pentanedione copper(II) derivative; 10 g derivative)
Cupric acetylacetonate; Bis(2,4- 50 g CAS No. 18716-76-2
pentanedionato)copper(II)) Dy(C5H7O2)3 xH2O FW 459.8
CAS No. 13395-16-9 99.9%
Cu(C5H7O2)2 FW 261.8 solid
99.99+% mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 125-130 C (lit.)
solid R: 20/21/22-36/37/38-63 S: 26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . . . . 284-288 C (dec.) (lit.)
R: 36/37/38 S: 26-36 Erbium(III) acetylacetonate hydrate
Copper(II) hexafluoroacetylacetonate hydrate 48,399-0 (2,4-pentanedione erbium(III) derivative) 5g
CAS No. 70949-24-5
33,519-3 CAS No. 55556-00-8 5g Er(C5H7O2)3 xH2O FW 464.6
Cu(C5HF6O2)2 xH2O FW 477.6 25 g 97%
Degree of hydration £1 solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 130-134 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 125 C (dec.) (lit.)
R: 36/37/38 S: 26-37/39 R: 20/21/22-36/37/38-63 S: 26-36/37/39
Europium(III) acetylacetonate hydrate

39,321-5 CAS No. 22533-93-3 1g
Eu(C5H7O2)3 xH2O FW 449.3 5g
mp . . . . . . . . . . . . . . . . . 140 C (dec.) (lit.)
R: 20/21/22-36/37/38-40 S: 26-36/37/39
297
Gadolinium(III) acetylacetonate hydrate Lanthanum acetylacetonate hydrate

33,171-6 (2,4-pentanedione Gadolinium(III) 5g 32,575-9 (2,4-pentanedione lanthanum derivative; 10 g
derivative) 25 g Lanthanum 2,4-pentanedionate) 100 g
CAS No. 22498-65-3 CAS No. 64424-12-0
99.9% La(C5H7O2)3 xH2O FW 436.2
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 143 C (dec.) (lit.) R: 20/21/22-36/37/38-40 S: 26-36/37/39-45
R: 20/21/22-36/37/38-40 S: 26-36/37/39-45
Lead(II) acetylacetonate
Gallium(III) acetylacetonate
40,168-4 (2,4-pentanedione lead(II) derivative) 5g
39,354-1 (gallium(III) 2,4-pentanedionate) 5g CAS No. 15282-88-9 25 g
CAS No. 14405-43-7 25 g Pb(C5H7O2)2 FW 405.4
C15H21GaO6 FW 367.0 Technical Grade
99.99% mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141-144 C
mp . . . . . . . . . . . . . . . . . . . . . . . 196-198 C (dec.) (lit.) R: 61-20/22-33-50/53-62 S: 53-45-60-61
R: 20/21/22-36/37/38-40 S: 26-36/37/39

Lithium acetylacetonate
Holmium(III) acetylacetonate hydrate
41,304-6 (2,4-Pentanedione lithium derivative; 25 g
51,763-1 (2,4-pentanedione holmium(III) derivative) 5g Acetylacetone lithium derivative) 100 g
CAS No. 22498-66-4 CAS No. 18115-70-3
99.9+% CH3COCH:C(OLi)CH3 FW 106.0
solid 97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 130 C (dec.) (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 250 C (dec.) (lit.)
R: 20/21/22-36/37/38-63 S: 26-36 R: 20/21/22-36/37/38-63 S: 26-36/37/39
Indium(III) acetylacetonate Lutetium(III) acetylacetonate hydrate
Microelectronics
I-330-0 (2,4-pentanedione indium(III) derivative) 1g 51,765-8 CAS No. 86322-74-9 1g
CAS No. 14405-45-9 5g Lu(C5H7O2)3 xH2O FW 472.3
In(OCCH3CHOCCH3)3 FW 412.1 99.9+%
99.99+% solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187-189 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 158-163 C (lit.)
R: 20/21/22-36/37/38-40 S: 26-36 R: 20/21/22-36/37/38-63 S: 26-36
Iridium(III) acetylacetonate Magnesium acetylacetonate dihydrate

33,335-2 CAS No. 15635-87-7 500 mg 12,957-7 CAS No. 68488-07-3 5g
C15H24IrO6 FW 492.6 2.5 g Mg(C5H7O2)2 2H2O FW 258.6 25 g
97% 98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 269-271 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 265 C (dec.) (lit.)
800.558.9196 (USA)
R: 20/21/22-36/37/38-40 S: 45 R: 20/21/22-36/37/38-40 S: 26-36/37/39
Iron(II) acetylacetonate Magnesium hexafluoroacetylacetonate 1,2-dimethox-

41,340-2 (2,4-pentanedione iron(II) derivative; 10 g
yethane complex
ferrous acetylacetonate)
34,728-0 CAS No. 102428-54-6 5g
CAS No. 14024-17-0 Mn(C5HF6O2)2(O2C4H10) FW 528.5
C10H16FeO4 FW 256.1 R: 36/37/38 S: 26-37/39
99.95%
solid Magnesium trifluoroacetylacetonate hydrate
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 175 C (dec.) (lit.) Ordering/Pricing: www.sigma-aldrich.com
R: 20/21/22-36/37/38-40 S: 26-36 10,322-5 CAS No. 314075-05-3 1g
Mg(C5H4F3O2)2 xH2O FW 216.5 5g
Iron(III) acetylacetonate R: 37 S: 26-36
(2,4-Pentanedione iron(III) derivative; Ferric acetylacetonate; Manganese(II) acetylacetonate

Iron III 2,4-pentanedionate)
CAS No. 14024-18-1 24,576-3 (2,4-pentanedione manganese(II) 5g
Fe(C5H7O2)3 FW 353.2 derivative; Manganous acetylacetonate) 100 g
MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and CAS No. 14024-58-9 500 g
magnetic property measurements of these films. Mn(C5H7O2)2 FW 253.2
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182-185 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 261 C (dec.) (lit.)
References R: 20/21/22-36/37/38-40 S: 26-36
Mochizuki, S., J. Phys. IV 7(C1), 491 (1997)
R: 22-36 S: 26
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Manganese(II) hexafluoroacetylacetonate trihydrate
51,700-3 99.9+% 10 g
34,034-0 CAS No. 123334-26-9 5g
solid 50 g
Density. . . . . . . . . . . . . . . . 5.24 g/mL (lit.) Mn(C5HF6O2)3 3H2O FW 523.1
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . 173 C (dec.) (lit.)
F30-0 97% 25 g R: 36/37/38 S: 26-37/39
100 g
500 g
298
Neodymium(III) acetylacetonate hydrate Praseodymium(III) hexafluoroacetylacetonate hydrate

46,042-7 (2,4-pentanedione neodymium(III) 10 g 51,759-3 CAS No. 307531-71-1 5g
derivative; Neodymium(III) 2,4- 50 g Pr(C5HF6O2)3 xH2O FW 762.1
pentanedionate) 99.5+%
CAS No. 14589-38-9
Nd(C5H7O2)3 xH2O FW 441.6 Rhodium(III) acetylacetonate
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 143 C (dec.) (lit.)
R: 20/21/22-36/37/38-63 S: 26-36/37/39 28,277-4 (2,4-pentanedione rhodium(III) 250 mg
derivative) 1g
Nickel(II) acetylacetonate CAS No. 14284-92-5 5g
Rh(C5H7O2)3 FW 400.2
(2,4-Pentanedione nickel(II) derivative)
97%
CAS No. 3264-82-2 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 263-264 C (lit.)
Ni(C5H7O2)2 FW 256.9 R: 20/21/22-36/37/38-40 S: 26-36/37/39
R: 49-22-43 S: 53-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
28,365-7 95% 5g
Rubidium acetylacetonate
mp . . . . . . . . . . . . . . . . 240 C (dec.) (lit.) 25 g
39,261-8 CAS No. 66169-93-5 1g
50 g RbC5H7O2 FW 184.6 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,950-9 Technical Grade, 90% 25 g R: 20/21/22-36/37/38-40 S: 26-28-36/37/39-45
mp . . . . . . . . . . . . . . . .230 C (dec.) (lit.) 100 g
Ruthenium(III) acetylacetonate
Nickel(II) hexafluoroacetylacetonate hydrate
28,276-6 (2,4-Pentanedione ruthenium(III) derivative) 1 g
33,970-9 CAS No. 304695-77-0 1g CAS No. 14284-93-6 5g
Ni(C5HF6O2)2 xH2O FW 472.8 5g Ru(C5H7O2)3 FW 398.4
98% 97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 213 C (dec.) (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 260 C (dec.) (lit.)
Microelectronics
R: 45-20/21/22-36/37/38-42/43 S: 53-26-36/37/39-45 R: 36/37/38 S: 26-36
Palladium(II) acetylacetonate Samarium(III) acetylacetonate hydrate
20,901-5 ( Palladium(II) 2,4-Pentanedionate) 1g 51,766-6 CAS No. 86322-73-8 100 g

CAS No. 14024-61-4 5g Sm(C5H7O2)3 xH2O FW 447.7
Pd(C5H7O2)2 FW 304.6 99.9+%
99% solid
R: 36/37/38 S: 26-36 R: 20/21/22-36/37/38-63 S: 26-36
Palladium(II) hexafluoroacetylacetonate Scandium acetylacetonate hydrate
40,147-1 CAS No. 64916-48-9 1g 55,690-4 Sc(C5H7O2)3 xH2O FW 342.3 100 mg

Pd(C5HF6O2)2 FW 520.5 5g solid 500 mg
mp . . . . . . . . . . . . . . . . . . 174-186 C
Used in a redox transmetalation reaction to
R: 22-36/37/38 S: 22-26-36
enhance CVD alloying technology for copper. Also used in
the simultaneous etching of copper and deposition of Scandium hexafluoroacetylacetonate
palladium for applications in ultralarge-scale integrated
devices. Lin. W. et al. J. Am. Chem. Soc. 1996, 118, 5977. 54,181-8 CAS No. 18990-42-6 1g
R: 36/37/38 S: 26-36 Sc(C5HF6O2)3 FW 666.1 5g
solid
Platinum(II) acetylacetonate bp. . . . . . . . . . . . . . . . . . . . . . 93-96 C/760 mm Hg (lit.)
R: 36/37/38 S: 26-36
(2,4-Pentanedione platinum(II) derivative)
CAS No. 15170-57-7 Silver acetylacetonate
Pt(C5H7O2)2 FW 393.3
R: 20/21/22-36/37/38-63 S: 26-36/37/39 32,348-9 (2,4-pentanedione Silver Derivative) 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
52,303-8 99.99% 1g CAS No. 15525-64-1 5g
solid AgC5H7O2 FW 208.0
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250-252 C 98%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . 100 C (dec.) (lit.)
28,278-2 97% 500 mg R: 20/21/22-36/37/38-40
mp . . . . . . . . . . . . . . . 250-252 C (lit.) 5g
Sodium acetylacetonate monohydrate
Praseodymium(III) acetylacetonate hydrate
41,303-8 (Acetylacetone sodium derivative) 50 g
51,767-4 CAS No. 28105-87-5 5g CAS No. 86891-03-4 250 g
Pr(C5H7O2)3 xH2O FW 426.2 25 g CH3COCH:C(ONa)CH3 H2O FW 140.1
99.9+% 97%
R: 20/21/22-36/37/38-63 S: 26-36 mp . . . . . . . . . . . . . . . . . . . . . . . . . . 230 C (dec.) (lit.)
R: 20/21/22-36/37/38-40 S: 26-36/37/39
299
Sodium hexafluoroacetylacetonate Titanium(IV) bis(ethyl acetoacetato)diisopropoxide

43,618-6 CAS No. 22466-49-5 5g 38,815-7 (Titanium(IV) bis(ethyl 100 mL
NaC5HF6O2 FW 230.0 25 g acetoacetato)diisopropoxide) 500 mL
97% CAS No. 27858-32-8
Recently employed in the solid-phase synthesis of (C5H7O2)2Ti(OCH(CH3)2)2 FW 426.3
chromium b-diketonates,1 in the preparation of novel Technical Grade
catalytic ruthenium diphosphine complexes2 and in the Vapor pressure. . . . . . . . . . . . . . . . . . . . 1.07 psi ( 55 C)
preparation of a series of new copper chemical vapor n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.518 (lit.)
deposition (CVD) precursors.3 (1) Zh. Neorg. Khim. 1996, Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 F
41, 411. (2) Recl. Trav. Chim. Pays-Bas 1995, 114, 242. (3) Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.109 g/mL (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . . . 0.33 psi ( 20 C)
Organometallics 1995, 14, 2641.
R: 36/37/38 S: 26-36 R: 10-36/37/38 S: 16-26-36
OCH CH
2 3 CH
Strontium acetylacetonate C O
3
O CHCH
CH Ti 3
O CHCH

39,072-0 CAS No. 12193-47-4 5g C O 3
CH
3
C10H14O4Sr FW 285.8 25 g CH
3
2
97%
R: 20/21/22-36/37/38-40 S: 26-28-36/37/39-45
Terbium(III) acetylacetonate hydrate

Titanium oxyacetylacetonate monohydrate
48,400-8 (2,4-pentanedione terbium(III) derivative; 1g
Terbium 2,4-pentanedionate) 5g 33,083-3 (Titanyl acetylacetonate monohydrate) 10 g
Tb(C5H7O2)3 xH2O FW 456.2 CAS No. 14024-64-7 50 g
99.9% Ti(C5H7O2)2 H2O FW 280.1
Used in the preparation of a new family of mp . . . . . . . . . . . . . . . . . . . . . . . . . . 200 C (dec.) (lit.)
monoporphyrinates interesting for their photochemical R: 20/21/22-36/37/38-40 S: 7-22-26-37/39
Microelectronics
and magnetic properties and synthetic applications.
solid Vanadium(III) acetylacetonate
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 127 C (dec.) (lit.)
References 22,711-0 (2,4-Pentanedione vanadium(III) 10 g
Spyroulias, G.A. et al., Chem. Commun. 783 (1997) derivative) 50 g
R: 20/21/22-36/37/38-63 S: 26-36/37/39-45 CAS No. 13476-99-8 250 g
V(C5H7O2)3 FW 348.3
Thallium(I) acetylacetonate 97%
R: 36/37/38 S: 26-36
15,388-5 (2,4-pentanedione thallium(I) derivative) 5g
CAS No. 25955-51-5 25 g Vanadium(IV)-oxy acetylacetonate
TlC5H7O2 FW 303.5
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 C (lit.) (Vanadyl acetylacetonate)
800.558.9196 (USA)
R: 26/28-33-51/53 S: 13-28-45-61 CAS No. 3153-26-2
OV(C5H7O2)2 FW 265.2
Thallium(I) hexafluoroacetylacetonate mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .254-257 C
R: 22-36/37/38 S: 22-26-36
40,527-2 CAS No. 15444-43-6 1g CH
3
TlC5HF6O2 FW 1367 5g C O
R: 26/28-33-51/53 S: 13-28-45-61 CH VO
C O
Tin(IV) bis(acetylacetonate) dibromide CH
3
2
34,553-9 CAS No. 16894-10-3 5g

Sn(CH5O7)2Br2 FW 396.7
98% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 20/21/22-34-40 S: 26-27-28-36/37/39-45 57,456-2 99.99% 5g
25 g
Tin(IV) bis(acetylacetonate) dichloride . . . . . . . . . . . . . . . . . . . . . . . . . . . .
55,078-7 98% 10 g
mp . . . . . . . . . . . . . . . . .235 C (dec.) (lit.) 50 g
40,465-9 CAS No. 16919-46-3 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Sn(C5H7O2)2Cl2 FW 387.8 25 g 21,287-3 95% 10 g
98% 50 g
R: 20/21/22-34-40 S: 26-27-28-36/37/39
250 g
1 kg
Yttrium acetylacetonate hydrate

43,879-0 CAS No. 207801-29-4 5g
Y(C5H7O2)3 xH2O FW 386.2
99.99%
R: 36/37/38-63 S: 26-36
300
Yttrium hexafluoroacetylacetonate dihydrate Heptafluorodimethyloctanedionates (FOD)

34,560-1 CAS No. 33751-70-1 1g Barium bis(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-oc-
Y(C5HF6O2)3 2H2O FW 746.1 5g tanedionate)
98%
R: 36/37/38 S: 26-37/39 49,517-4 CAS No. 36885-31-1 5g
Ba(OCC(CH3)3CHCOCF2CF2CF3)2 FW 727.7 25 g
Zinc acetylacetonate hydrate 99.99%
solid
(Bis(2,4-pentanedionato)zinc)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92-96 C (lit.)
CAS No. 108503-47-5 R: 20/22 S: 28
Zn(C5H7O2)2 xH2O FW 263.6
CF CF CF
CVD precursor to highly transparent, conductive (based on film 2 2 3
C O
thickness) ZnO-In2O3 films. CH Ba
Novel MOCVD precursor for the preparation of high- C O
crystallinity (Zn,Fe)Fe2O4 films and magnetic property C(CH )
33
2
measurements of these films.
References
1. Minami, T. et al., J. Vac. Sci. Technol., A 15, 1069 (1997)
2. Mochizuki, S. et al., J. Phys. IV 7(C1), 491 (1997)
R: 20/21/22-36/37/38-63 S: 26-36/37/39-45 Calcium bis(6,6,7,7,8,8,8,-heptafluoro-2,2-dimethyl-3,5-oc-
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,099-1 99.995% 5g tanedionate)
solid 25 g
mp . . . . . . . . . . . . . . . . 136 C (dec.) (lit.) 49,515-8 CAS No. 36885-29-7 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Ca(OCC(CH3)3CHCOCF2CF2CF3)2 FW 630.4 25 g
13,230-6 powder 5g 99.9+%
mp . . . . . . . . . . . . .136-138 C (dec.) (lit.) 100 g solid
500 g mp . . . . . . . . . . . . . . . . . . . . . . . . . 189.1-193.5 C (lit.)

Microelectronics
Zinc hexafluoroacetylacetonate dihydrate Copperbis(6,6,7,7,8,8,8-Heptafluoro-2,2-dimethyl-3,5-oc-

tanedionate)
41,785-8 (Hexafluoroacetylacetone zinc derivative) 1g
CAS No. 16743-33-2 5g 54,176-1 CAS No. 80289-21-0 1g
Zn(C5HF6O2)2 2H2O FW 515.5 Cu(OCC(CH3)3CHCOCF2CF2CF3)2 FW 653.9 5 g
98% 99.99+%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 155 C (dec.) (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .59-61 C
R: 36/37/38 S: 26-36
Resolve-Al AgFOD
Zirconium(IV) acetylacetonate
22,466-9 ((6,6,7,7,8,8,8-Heptafluoro-2,2- 100 mg
33,800-1 (Tetrakis(2,4- 25 g dimethyl-3,5-octanedionato)silver(I); 1g
pentanedionato)zirconium(IV); 2,4- 100 g Silver(I) 6,6,7,7,8,8,8-heptafluoro-2,2- 5g
Pentanedione zirconium(IV) derivative; dimethyl-3,5-octanedionate; (2,2-
Zirconium(IV) 2,4-pentanedionate) Dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-
CAS No. 17501-44-9 octanedionato)silver(I); Ag(fod))
Zr(C6H7O2)4 FW 487.7 CAS No. 76121-99-8
98% Ag(OCC(CH3)3CHCOCF2CF2CF3) FW 403.0
Starting material for zirconium metallomesogens: mp . . . . . . . . . . . . . . . . . . . . . . . . . . 160 C (dec.) (lit.)
zirconium tetrakis-b-diketonate liquid crystals. Trzaska, S: 22-24/25
S.T. et al. Chem. Mater. 1999, 11, 130.
R: 20/21/22-36/37/38-40 Resolve-Al DyFOD
Zirconium(IV) trifluoroacetylacetonate 23,728-0 CAS No. 18323-98-3 100 mg
Dy(OCC(CH3)3CHCOCF2CF2CF3)3 1g
38,332-5 CAS No. 17499-68-2 1g FW 1048
Zr(C5H4F3O2)4 FW 707.6 10 g
97% Resolve-Al EuFOD
16,093-8 (Eu(fod)3; Sievers’ Reagent; 100 mg
Europium(III)-tris(1,1,1,2,2,3,3- 1g
heptafluoro-7,7-dimethyl-4,6- 5g
octanedionate); Tris(6,6,7,7,8,8,8-
heptafluoro-2,2-dimethyl-3,5-octanedionato)europium;
Eu(dpm)3)
CAS No. 17631-68-4
Eu(OCC(CH3)3CHCOCF2CF2CF3)3 FW 1037
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 203-207 C (lit.)
Licensed for use under Sievers’ U.S. Patent 3 700 410
S: 22-24/25
301
Metal b-dikenonates: Heptafluorodimethyloctanedionates (FOD)
Resolve-Al HoFOD Chromium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

23,727-2 CAS No. 18323-97-2 100 mg 46,822-3 CAS No. 14434-47-0 1g
Er(OCC(CH3)3CHCOCF2CF2CF3)3 1g Cr(OCC(CH3)3CHCOC(CH3)3)3 FW 601.8 5g
FW 1053 mp . . . . . . . . . . . . . . . . . . 228-233 C (lit.)
R: 20/21/22 S: 36
Resolve-Al YbFOD
Cobalt tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
22,583-5 (Yb[fod]3; tris(6,6,7,7,8,8,8- 100 mg
heptafluoro-2,2-dimethyl-3,5- 1g 46,821-5 CAS No. 14877-41-9 1g
octanedionato)ytterbium; Yb(fod)3) 5g Co(OCC(CH3)3CHCOC(CH3)3)3 FW 608.7 5g
CAS No. 18323-96-1 99%
Yb(OCC(CH3)3CHCOCF2CF2CF3)3 FW 1061 Precursor for aerosol-assisted CVD of mixed-conducting
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 108-111 C (lit.) ceramic films of Sr-Co-Fe perovskite phases.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 250 C (dec.) (lit.)
Resolve-Al PrFOD References
Xia, C. et al., J. Mater. Res. 13, 173 (1998)

16,135-7 (Pr(fod)3; Rondeau’s Reagent; 100 mg
Tris(6,6,7,7,8,8,8-heptafluoro-2,2- 1g Copper bis(2,2,6,6-tetramethyl-3,5-heptanedionate)
dimethyl-3,5- 5g
octanedionato)praseodymium) 34,508-3 (2,2,6,6-tetramethyl-3,5-heptanedione 1g
CAS No. 17978-77-7 copper(II) derivative) 5g
Pr(OCC(CH3)3CHCOCF2CF2CF3)3 FW 1026 CAS No. 14040-05-2
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 215-219 C (lit.) Cu(OCC(CH3)3CHCOC(CH3)3)2 FW 430.1
Licensed for use under Sievers’ U.S. Patent 3 700 410 99%
S: 22-24/25 mp . . . . . . . . . . . . . . . . . . . . . . . . . . 198 C (dec.) (lit.)
R: 36/37/38 S: 26-37/39
Strontium bis(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-
octanedionate) Erbium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
Microelectronics
49,516-6 CAS No. 36885-30-0 5g 43,407-8 CAS No. 35733-23-4 1g
Sr(OCC(CH3)3CHCOCF2CF2CF3)2 FW 678.0 25 g Er(OCC(CH3)3CHCOC(CH3)3)3 FW 717.1 5g
99.99% 99.9+%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95-100 C (lit.) Europium(III)-tris-(2,2,6,6-tetramethyl-3,5-heptanedio-
nate)
Tetramethylheptanedionates (TMHD) 46145 CAS No. 15522-71-1 250 mg
Eu(OCC(CH3)3CHCOC(CH3)3)3 FW 701.8 1g
Aluminum tris(2,2,6,6-tetramethyl-3,5-heptanedionate) purum p.a., for NMR-spectroscopy
S: 22-24/25
39,728-8 CAS No. 14319-08-5 1g
800.558.9196 (USA)
Al(OCC(CH3)3CHCOC(CH3)3)3 FW 576.8 5g Iron tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
98%
46,820-7 CAS No. 14876-47-2 1g
Barium bis(2,2,6,6-tetramethyl-3,5-heptanedionate) hy- Fe(OCC(CH3)3CHCOC(CH3)3)3 FW 605.6 10 g
drate R: 36/37/38 S: 26-36
36,294-8 CAS No. 17594-47-7 1g Lead bis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Ba(OCC(CH3)3CHCOC(CH3)3)2 xH2O 5g
FW 503.9 47,885-7 CAS No. 21319-43-7 5g
R: 20/22 S: 28 Pb(OCC(CH3)3CHCOC(CH3)3)2 FW 573.7 25 g
99.99+%
Bismuth tris(2,2,6,6-tetramethyl-3,5-heptanedionate) R: 61-33-40-48/22-50/53 S: 53-45-60-61
37,378-8 CAS No. 142617-53-6 1g Magnesium bis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Bi(OCC(CH3)3CHCOC(CH3)3)3 FW 758.8 5g hydrate
R: 20/21/22-36/37/38 S: 26-36
41,570-7 CAS No. 21361-35-3 1g
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc(II) 97%
R: 36/37/38 S: 26-37/39
41,773-4 CAS No. 14363-14-5 1g
Zn(OCC(CH3)3CHCOC(CH3)3)2 FW 431.9 5g Neodymium(III) tris(2,2,6,6-tetramethyl-3,5-heptanedio-
97% nate)
R: 36/37/38 S: 26-36
43,404-3 (Nd(thd)3; Nd(tmhd)3; Tris(2,2,6,6- 1g
Calcium bis(2,2,6,6-tetramethyl-3,5-heptanedionate) tetramethyl-3,5- 5g
heptanedionato)neodymium)
36,295-6 CAS No. 118448-18-3 1g CAS No. 15492-47-4
Ca(OCC(CH3)3CHCOC(CH3)3)2 FW 406.6 5g Nd(OCC(CH3)3CHCOC(CH3)3)3 FW 694.0
R: 36/37/38 S: 26-37/39 98%
R: 20/21/22-36/37/38 S: 26-36
302
Metal b-dikenonates: Tetramethylheptanedionates (TMHD)
Nickel(II) bis(2,2,6,6-tetramethyl-3,5-heptanedionate) Resolve-Al Yb

40,339-3 CAS No. 14481-08-4 1g 16,275-2 (tris(2,2,6,6-tetramethyl-3,5- 100 mg
Ni(OCC(CH3)3CHCOC(CH3)3)2 FW 425.2 5g heptanedionato)ytterbium; Yb(tmhd)3) 1g
97% CAS No. 15492-52-1 5g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 219-223 C (lit.) Yb(OCC(CH3)3CHCOC(CH3)3)3
R: 45-42/43 S: 53-22-36/37/39-45
FW 722.8
98%
Praseodymium(III) tris(2,2,6,6-tetramethyl-3,5-heptane- mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 165-168 C (lit.)
dionate)
Resolve-Al PR
81507 CAS No. 15492-48-5 1g
Pr(OCC(CH3)3CHCOC(CH3)3)3 FW 690.7 5g
16,088-1 CAS No. 15492-48-5 100 mg

purum Pr(OCC(CH3)3CHCOC(CH3)3)3 FW 690.7 1g
S: 22-24/25 99% 5g
S: 22-24/25
Resolve-Al Dy
Samarium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
16,273-6 CAS No. 15522-69-7 100 mg
Dy(OCC(CH3)3CHCOC(CH3)3)3 1g 43,627-5 CAS No. 15492-50-9 1g
FW 712.3 5g Sm(OCC(CH3)3CHCOC(CH3)3)3 FW 700.2 5g
98% 98%
Resolve-Al EuTMHD Scandium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

hydrate
15,697-3 (Europium(III)-tris-(2,2,6,6-tetramethyl- 100 mg
3,5-heptanedionate); Tris(2,2,6,6- 1g 51,760-7 CAS No. 307532-33-8 1g
tetramethyl-3,5- 5g Sc(OCC(CH3)3CHCOC(CH3)3)3 xH2O

heptanedionato)europium; Europium- FW 594.8
Microelectronics
tris(dipivaloylmethane); Eu(tmhd)3; europium tris(2,2,6,6- 99.9+%

tetramethyl-3,5-heptanedionate))
CAS No. 15522-71-1 Strontium bis(2,2,6,6-tetramethyl-3,5-heptanedionate) di-
Eu(OCC(CH3)3CHCOC(CH3)3)3 FW 701.8 hydrate
Lanthanide shift reagent used for determining
conformation by NMR. Aldrichimica Acta 1971, 4, 55. 37,381-8 CAS No. 314075-42-8 1g
ibid. 1977, 10, 54. Sr(OCC(CH3)3CHCOC(CH3)3)2 2H2O
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 187-189 C (lit.) FW 490.2
S: 22-24/25
98%
R: 36/37/38 S: 26-37/39
Resolve-Al Gd
Terbium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
23,729-9 (Gd(tmhd)3; gadolinium tris(2,2,6,6- 100 mg
tetramethyl-3,5-heptanedionate)) 1g 43,405-1 (Tb(tmhd)3) 1g
CAS No. 14768-15-1 CAS No. 15492-51-0 5g
Gd(OCC(CH3)3CHCOC(CH3)3)3 FW 707.1 Tb(OCC(CH3)3CHCOC(CH3)3)3 FW 708.7
99+% 98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 182-184 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 163-164 C (lit.)
Resolve-Al Ho Thulium tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

16,274-4 (Ho(tmhd)3; holmium tris(2,2,6,6- 100 mg 43,628-3 CAS No. 15631-58-0 1g
tetramethyl-3,5-heptanedionate)) 1g Tm(OCC(CH3)3CHCOC(CH3)3)3 FW 718.7 5g
CAS No. 15522-73-3 5g 97%
Ho(OCC(CH3)3CHCOC(CH3)3)3
FW 714.7 Titanium(IV) diisopropoxidebis(2,2,6,6-tetramethyl-3,5-
98% heptanedionate)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 175-180 C (lit.)
49,414-3 CAS No. 144665-26-9 5g
Resolve-Al La Ti(OCC(CH3)3CHCOC(CH3)3)2(OC3H7)2 25 g
FW 532.6
23,726-4 (La(tmhd)3; tris(2,2,6,6-tetramethyl-3,5- 100 mg
99.99%
heptanedionato)lanthanum) 1g
Titanium source precursor for good quality MOCVD of
CAS No. 14319-13-2
PNZT. Chen, I-S. et al. Chem. Mater. 1999, 11, 209.
La(OCC(CH3)3CHCOC(CH3)3)3 FW 688.7
solid
99%
mp . . . . . . . . . . . . . . . . . . . . . . . . 171.1-184.6 C (lit.)
C(CH ) CH
33 3
C O O CHCH
3
CH Ti
C O O CHCH
3
C(CH ) CH
33 3
2
303
Metal b-dikenonates: Tetramethylheptanedionates (TMHD)
Yttrium tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Triisobutylaluminum

37,382-6 CAS No. 15632-39-0 1g CAS No. 100-99-2
Y(OCC(CH3)3CHCOC(CH3)3)3 FW 638.7 5g
99.9%
A precursor for the formation of thin films of yttria by 25,720-6 Triisobutylaluminum 100 g
CECVD. The films have potential applications as electronic (Aluminumtriisobutanide) 1 kg
insulators, coatings, reaction barriers and [(CH3)2CHCH2]3Al FW 198.3
superconducting materials. Zhang, Y. Puddephatt, R. Packaged under nitrogen in Sure/Pac metal cylinders
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4494 (lit.)
Chem. Mater. 1999, 11, 148.
bp. . . . . . . . . . . . . . . . . . . . . . . . . 86 C/10 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 173-175 C (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-6 C (lit.)
R: 20/21/22-36/37/38 S: 26-37/39
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.786 g/mL (lit.)
Zirconium(IV) diisopropoxidebis(2,2,6,6-tetramethyl-3,5- R: 14-17-34 S: 16-26-27-36/37/39-45
heptanedionate) CH
3
CH CH CHCH
3 2 3

49,415-1 CAS No. 204522-78-1 5g CH CH CH Al
3 2
Zr(OCC(CH3)3CHCOC(CH3)3)2(OC3H7)2 25 g CH CHCH
2 3
FW 575.9 CH
3
99.99+%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98-107 C (lit.)
Triisobutylaluminum solution
Zirconium tetrakis(2,2,6,6-tetramethyl-3,5-heptanedio- [CH3)2CHCH2]3Al FW 198.3
CH
nate) CH
3
3 CH CHCH
2 3
CH CH CH Al
47,886-5 CAS No. 18865-74-2 5g 3 2
CH CHCH
Zr(OCC(CH3)3CHCOC(CH3)3)4 FW 824.3 25 g 2 3
CH
99.99+%
Microelectronics
3
Good precursor for zirconia thin films, with deposition at
lower temperatures promoted by Pd(hfac)2, or yttria- . . . . . . . . . . . . . . . . . . . . . . . . . . . .
stabilized zirconia films on silicon and on stainless steel 42,379-3 1.0 M in hexanes 100 mL
substrates. Zirconium source precursor for good quality Packaged under nitrogen in Sure/Seal 800 mL
MOCVD of PNZT. bottles
solid bp. . . . . . . . . . . . . . . . . . . . . . 68-69 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 332-339 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.695 g/mL (lit.)
References R: 11-14-17-34-48/20-51/53-62-65-67 S: 16-36/37/39-43-45-
1. Zhang, Y. et al., J. Amer. Chem. Soc. 119, 9295 (1997) 61-62
2. Bourhila, N. et al. , Proc. Electrochem. Soc. 97-25, 417 (1997) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36 25,721-4 25 wt. % in toluene 100 g
Packaged under nitrogen in Sure/Pac 1 kg
metal cylinders
800.558.9196 (USA)
Metal-Organic Precursors Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.848 g/mL (lit.)
R: 14-17-23/24/25-34 S: 16-26-36/37/39-45
Aluminum . . . . . . . . . . . . . . . . . . . . . . . . . . . .
19,271-6 25 wt. % in toluene 100 g
Alane-trimethylamine complex Packaged under nitrogen in poly-coated 700 g
Sure/Seal bottles
45,579-2 CAS No. 16842-00-5 5g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 F
AlH3 N(CH3)3 FW 89.12 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.848 g/mL (lit.)
R: 14-17-23/24/25-34 S: 16-26-36/37/39-45
95% Ordering/Pricing: www.sigma-aldrich.com
Organometallic chemical vapor deposition (OMCVD) in
Trimethylaluminum
the presence of borane-ammonia gives mixed aluminum
nitride/boron nitride (AlN/BN) thin films. Chem. Mater. (Aluminumtrimethanide)
1996, 8, 2839. CAS No. 75-24-1
R: 14/15-17-34 S: 16-26-36/37/39-45
(CH3)3Al FW 72.09
bp. . . . . . . . . . . . . . . . . . . . . . . . 125-126 C/760 mm Hg (lit.)
Triethylaluminum mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.752 g/mL (lit.)
CAS No. 97-93-8 R: 14-17-34 S: 16-43-45
Al(C2H5)3 FW 114.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 11-14-17-34-48/20-51/53-62-65-67 S: 9-16-33-43-45-61-62 59,777-5 electronic grade, 99.99999+% (ultra 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . pure)
46,258-6 electronic grade, 99.999% 50 mL . . . . . . . . . . . . . . . . . . . . . . . . . . . .
100 mL 46,257-8 99.999%, electronic grade 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 g
45,577-6 repurified, 99.0% 50 g
304
Metal-Organic Precursors: Aluminum
(Continuation of) Tris(dimethylamino)alane, dimer

Trimethylaluminum
46,994-7 CAS No. 32093-39-3 10 g
(Al(N(CH3)2)3)2 FW 318.4
Precursor to aluminum nitride (AlN) thin films by
organometallic chemical vapor deposition (OMCVD). J.
Vac. Sci. Technol. 1996, 14, 306.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82-84 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 F
R: 11-34 S: 16-26-36/37/39-45
R R
R N N NR
2 2
Al Al R = CH
3
R N N NR
2 2
R R
Antimony
Tris(dimethylamino)antimony
55,397-2 CAS No. 7289-92-1 25 mL
[(CH3)2N]3Sb FW 254.0
99.99%
liquid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.325 g/mL

R: 11-14-20/22-34-51/53 S: 16-26-36/37/39-45-61
Microelectronics
CH CH
3 3
1 CH N CH
H-NMR spectrum of Aldrich product 46,257-8, lot 92817LA 3 3
N Sb N
CH CH
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 3
25,722-2 97% 100 g

Packaged under nitrogen in Sure/Pac
metal cylinders
Storage below 20C may cause crystallization. Moving
Arsenic
container to a warm location should remelt the solid. The
warm liquid may be transferred using syringe techniques Ethylenebis(diphenylarsine)
Vapor pressure. . . . . . . . . . . . . . . . . 69.3 mm Hg ( 60 C)
bp. . . . . . . . . . . . . . . . . . . . 125-126 C/760 mm Hg (lit.)
32,770-0 (1,2-bis(diphenylarsino)ethane) 1g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 F CAS No. 4431-24-7 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.752 g/mL (lit.) C26H24As2 FW 486.3
94%
Tris(diethylamino)alane, dimer mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 103-108 C (lit.)
R: 23/25-50/53 S: 20/21-28-45-60-61
53,972-4 CAS No. 352546-72-6 1 mL
(Al(N(C2H5)2)3) FW 486.7 5 mL Tetraphenylarsonium chloride hydrate
solid
bp. . . . . . . . . . . . . . . . . . . . . . . . . 50 C/20 mm Hg (lit.) T2,530-5 CAS No. 507-28-8 2.5 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28-31 C (lit.) (C6H5)4As(Cl) aq FW 418.8 10 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 F 97%
R: 14/15-17-34 S: 26-36/37/39-45 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258-260 (lit.)
R R
R: 23/25-50/53 S: 20/21-28-45-60-61
R N N NR
2 2
Al Al R = CH CH
2 3
R N N NR
2 2
R R
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Teflon is a registered trademark of E.I. du Pont de Nemours & Co., Inc.
Features and Applications:
• New process for Electronic Grade, Ultra Pure, 99.99999%
• Eliminates contamination possiblitities
• Widely used in the Semiconductor industry
Availability:
Bulk - on demand, custom packaged in bubbler
Specifications:
Appearance Colorless Liquid
EDTA Titration 99.5% (Complexometric)
Cl Impurity <50 ppm (Ion Chromatography)
Metal Purity 99.99999%
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306
Metal-Organic Precursors: Arsenic
Tributylbismuthine
Trimethylarsine
48,546-2 CAS No. 3692-81-7 5g
55,131-7 CAS No. 593-88-4 1g C12H27Bi FW 380.3
As(CH3)3 FW 120.0 5g 97%
99.9% as chemical purity R: 17 S: 16-27-36/37/39
liquid
bp. . . . . . . . . . . . . . . . . . . . . . . . 51 C/760 mm Hg (lit.) Triphenylbismuth
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -13 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.133 g/mL (lit.) 39,895-0 CAS No. 603-33-8 5g
R: 23/25-50/53 S: 20/21-28-45-60-61
(C6H5)3Bi FW 440.3 25 g
99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78-80 C (lit.)
R: 20/21/22 S: 36/37
Bi
Triphenylbismuth carbonate
42,741-1 CAS No. 47252-14-2 1g
C19H15BiO3 FW 500.3 10 g
mp . . . . . . . . . . . . . . . . . 164-165 C (lit.)
Triphenylbismuth dichloride
Microelectronics
42,740-3 CAS No. 594-30-9 1g

C18H15BiCl2 FW 511.2 10 g
mp . . . . . . . . . . . . . . . . . 159-160 C (lit.)
Tris(2-methoxyphenyl)bismuthine
1
H-NMR spectrum of Aldrich product 55,131-7, lot 94813CO 48,527-6 CAS No. 83724-41-8 1g
C21H21BiO3 FW 530.4 10 g
Triphenylarsine
Boron
(Arsinetriphenyl)
CAS No. 603-32-7 Borane–ammonia complex
(C6H5)3As FW 306.2
R: 23/25-50/53 S: 20/21-28-45-60-61 28,771-7 CAS No. 13774-81-7 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . H3N BH3 FW 30.87 10 g
49,273-6 99.99% 5g 90%, Technical Grade
solid Mild, efficient, and stereoselective reducing agent for
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 58.5-63.5 C (lit.) aldehydes and ketones in protic or nonprotic media.
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
T8,190-6 97% 5g Tetrahedron Lett. 1980, 693, 697.
R: 5 S: 14-15-26-36/37/39
mp . . . . . . . . . . . . . . . . . . . . 60-62 (lit.) 25 g
100 g
Borane–tetrahydrofuran complex solution
Triphenylarsine oxide 43,687-9 CAS No. 14044-65-6 100 mL
C4H11BO FW 85.94 800 mL
11,589-4 CAS No. 1153-05-5 5g
1.5 M in tetrahydrofuran and 8L
(C6H5)3AsO FW 322.2 25 g
ether, Technical Grade 18 L
97% bp. . . . . . . . . . . 35 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 194-196 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -22 F
R: 23/25-50/53 S: 20/21-28-45-60-61
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.846 g/mL (lit.)
R: 11-14/15-19-22-36/37/38-66-67 S: 16-26-29-33-36
Bismuth
Bis(acetato-O)triphenylbismuth
48,572-1 CAS No. 7239-60-3 1g
C22H21BiO4 FW 558.4 10 g
98%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . ~170 C (D) (lit.)
307
Metal-Organic Precursors: Boron
Dicyclohexyliodoborane 17,990-6 1.0 M in tetrahydrofuran 100 mL

Packaged under nitrogen in Sure/Seal 800 mL
CAS No. 55382-85-9 bottles
Packaged under nitrogen in Sure/Seal bottles Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.834 g/mL (lit.)
41,691-6 Dicyclohexyliodoborane 25 mL R: 11-19-22-36/37/38 S: 16-26-36/37/39
C12H22BI FW 304.0
97% Tri-sec-butylborane solution
bp. . . . . . . . . . . . . . . . . . . . 198-200 C/1.25 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 F 17,896-9 CAS No. 1113-78-6 100 mL
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.325 g/mL (lit.) C12H27B FW 182.2
R: 10-14-34-40-42/43 S: 16-23-26-36/37/39-45 1.0 M in tetrahydrofuran
42,331-9 Dicyclohexyliodoborane solution 50 mL Packaged under nitrogen in Sure/Seal bottles
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 F
C12H22BI FW 304.0 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.799 g/mL (lit.)
0.5 M in hexanes R: 11-19-22-36/37/38 S: 16-26-36/37/39
R: 11-14-20/21/22-34-40 S: 16-26-27-36/37/39-45

Triethylborane
Diethyl(3-pyridyl)borane
CAS No. 97-94-9
31,636-9 (3-(diethylboryl)pyridine) 1g
CAS No. 89878-14-8 10 g 25,719-2 Triethylborane 100 g
C9H14BN FW 147.0 C6H15B FW 97.99
97% 95+%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 172-175 C (lit.) Packaged under nitrogen in Sure/Pac metal cylinders
R: 36/37/38 S: 26-37/39 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.397 (lit.)
CH CH bp. . . . . . . . . . . . . . . . . . . . . . . . 95 C/760 mm Hg (lit.)
B 2 3
CH CH
2 3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -93 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.677 g/mL (lit.)
N
R: 17-34 S: 7-23-26-36/37/39-43-45
Microelectronics
Triethylborane solution
(C2H5)3B FW 97.99
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Dimesitylborane 59,437-7 2.0 M in ether 100 mL
Density. . . . . . . . . . . . . . . . 0.703 g/mL
31,034-4 (bis(2,4,6-trimethylphenyl)borane) 250 mg R: 17-34 S: 7-23-26-36/37/39-43-45
CAS No. 51458-06-1 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
C18H23B FW 250.2 19,503-0 1.0 M in hexanes 100 mL
90% Packaged under nitrogen in Sure/Seal 800 mL
borane and monomesitylborane. . . . . . . . . . . . . . . . . . 5% bottles
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 160-163 C (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -9 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.675 g/mL (lit.)
Tetrakis(dimethylamino)diborane R: 11-34-48/20-51/53-62-65-67 S: 16-26-33-36/37/39-45-61-
800.558.9196 (USA)
62
47,667-6 CAS No. 1630-79-1 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
17,970-1 1.0 M in tetrahydrofuran 100 mL
C8H24B2N4 FW 197.9
Packaged under nitrogen in Sure/Seal 800 mL
97%
bottles
liquid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 F
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4756 (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.865 g/mL (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 55-57 C/2.5 mm Hg (lit.)
R: 11-19-34 S: 16-26-33-36/37/39-43-45
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.926 g/mL (lit.)
R: 36/37/38 S: 26-36 Trimesitylborane
22,517-7 CAS No. 7297-95-2 1g
Tributylborane
C27H33B FW 368.4 10 g
CAS No. 122-56-5 97%
29,842-5 Tributylborane 50 g Triphenylborane

C12H27B FW 182.2
Packaged under nitrogen in Sure/Pac metal cylinders CAS No. 960-71-4
bp. . . . . . . . . . . . . . . . . . . . . . . . 109 C/20 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.747 g/mL (lit.) T8,220-1 Triphenylborane 2.5 g
R: 17-34 S: 7-23-26-36/37/39-43-45 (C6H5)3B FW 242.1 10 g
bp. . . . . . . . . . . . . .203 C/15 mm Hg (lit.)
Tributylborane solution mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 (lit.)
C12H27B FW 182.2 R: 11 S: 16-22-24/25
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 44,244-5 Triphenylborane solution 25 mL

29,797-6 1.0 M in diethyl ether 100 mL C18H15B FW 242.1 100 mL
Packaged under nitrogen in poly-coated 800 mL 0.25 M in tetrahydrofuran
Sure/Seal bottles Packaged under nitrogen in Sure/Seal bottles
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -40 F bp. . . . . . . . . . . . . . . . . . . . . . 65-67 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.719 g/mL (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 F
R: 11-20/21/22-36/37/38-40 S: 16-26-36/37/39-45 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.898 g/mL (lit.)
R: 11-19-22-36/37/38 S: 16-26-33-36
308
Metal-Organic Precursors: Boron
Triphenylborane–Sodium hydroxide adduct solution Cobalt

26,414-8 CAS No. 12113-07-4 25 g Bis(cyclopentadienyl)cobalt
(C6H5)3B NaOH FW 282.1 100 g
6-10 wt. % in water 33,916-4 CAS No. 1277-43-6 1g
R: 34 S: 26-36/37/39-45 Co(C5H5)2 FW 189.1 2g
mp . . . . . . . . . . . . . .176-180 C (dec.) (lit.) 10 g
Tris(dimethylamino)borane R: 11 S: 16-33-7/9
27,973-0 CAS No. 4375-83-1 5g Co

B(N(CH3)2)3 FW 143.0 50 g
99%
50g units packaged under nitrogen in Sure/Seal bottles
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.446 (lit.)
bp. . . . . . . . . . . . . . . . . . . . 147-148 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -16 C (lit.) Bis(ethylcyclopentadienyl)cobalt
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -5 F
R: 11-36/37/38 S: 16-26-27-36/37/39
C14H12Co FW 239.2 5g
CH
3
NCH
3 Bis(pentamethylcyclopentadienyl)cobalt
CH N B NCH
3 3
CH
3
CH
3 40,178-1 (decamethylcobaltocene) 1g
CAS No. 74507-62-3
C20H30Co FW 329.4
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >210 C (lit.)
CH CH
Tris(pentafluorophenyl)borane 3 3
CH CH
3 3
CH
Co 3
44,259-3 CAS No. 1109-15-5 1g
Microelectronics
CH
3
CH CH
(C6F5)3B FW 512.0 5g 3 3
95% CH CH
3 3
A versatile reagent widely used in the preparation of d0
arene and other organometallic complexes useful as
polymerization catalysts. Cyclopentadienyl cobalt dicarbonyl
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 126-131 C (lit.)
R: 36/37/38 S: 26-36 24,525-9 (Dicarbonylcyclopentadienyl cobalt) 5g
CAS No. 12078-25-0 25 g
C5H5Co(CO)2 FW 180.0
Cerium Technical Grade
Packaged in ampules
Bis(cyclopentadienyl)chromium bp. . . . . . . . . . . . . . . . . . . . 139-140 C/710 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 F
38,100-4 (Di(cyclopentadienyl)chromium; 1g R: 10-23/24/25 S: 36/37/39-45
Chromocene)
CAS No. 1271-24-5 Co(CO)
2
Cr(C5H5)2 FW 182.2
95%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 168-170 C (lit.)
R: 20/21/22-36/37/38 S: 26-37/39
Erbium
Cr
Tris[N,N-bis(trimethysilyl)amide]erbium(III)
54,785-9 CAS No. 103457-72-3 1g
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 166-170 C (lit.)
Bis(pentamethylcyclopentadienyl)chromium R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8
47,516-5 CAS No. 74507-61-2 1g

Cr(C5(CH3)5)2 FW 322.4
96%
R: 20/21/22 S: 36
Tris(cyclopentadienyl)cerium
49,357-0 CAS No. 1298-53-9 1g
Ce(C5H5)3 FW 335.4 5g
99.9%
R: 11-14/15 S: 43-7/8
309
Metal-Organic Precursors: Erbium
Tris(butylcyclopentadienyl)erbium Gallium
49,599-9 CAS No. 153608-51-6 1g Tris(dimethylamino)gallane dimer
Er(C5H4C4H9)3 FW 530.9 5g
99.9% 54,653-4 (Ga(N(CH3)3)2)2 FW 403.9 1g
solid solid 5g
bp. . . . . . . . . . . . . . . . . . . . . . . .240 C/0.1 mm Hg (lit.) 98%
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 F mp . . . . . . . . . . . . . . . . . . . . . . . . . . 104-105.5 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.309 g/mL (lit.) R: 11-14-34 S: 16-26-36/37/39-45
R: 17 S: 16-36/37/39 R R
R R
R N N NR
2 2
Ga Ga R = CH
3
Er R N N NR
R = CH (CH ) CH 2 2
2 22 3 R R

Tris(cyclopentadienyl)erbium Germanium
49,191-8 CAS No. 39330-74-0 1g Hexaethyldigermanium
Er(C5H5)3 FW 362.5 5g
99.99% 44,761-7 CAS No. 993-62-4 1g
R: 11-14/15 S: 43-7/8 C12H30Ge2 FW 319.6 5g
97%
Tris(isopropylcyclopentadienyl)erbium R: 20/21/22 S: 36
49,598-0 CAS No. 130521-76-5 1g Hexamethyldigermanium

Er(C5H4CH(CH3)2)3 FW 488.8 5g
99.9% 44,760-9 CAS No. 993-52-2 1g
Microelectronics
S: 16-33 (CH3)3GeGe(CH3)3 FW 235.5
Technical Grade
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.456 (lit.)
Gadolinium bp. . . . . . . . . . . . . . . . . . . . 137-138 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -40 C (lit.)
Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.175 g/mL (lit.)
54,782-4 CAS No. 35789-03-8 1g R: 11-20/21/22 S: 16-36
Gd(N(Si(CH3)3)2)3 FW 638.4
98% Hexaphenyldigermanium
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .67-90 C
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F 44,762-5 CAS No. 2816-39-9 1g
R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8 C36H30Ge2 FW 607.9 5g
800.558.9196 (USA)
97%
Tris(cyclopentadienyl)gadolinium R: 20/21/22 S: 36
49,256-6 CAS No. 1272-21-5 1g Tetrabutylgermanium

Gd(C5H5)3 FW 352.5 5g
99.9% 40,420-9 CAS No. 1067-42-1 1g
R: 11-14/15 S: 43-7/8 Ge(C4H9)4 FW 301.1 5g
94%
Tris(ethylcyclopentadienyl)gadolinium R: 20/21/22 S: 36
51,743-7 CAS No. 307531-69-7 1g Tetraethylgermanium Ordering/Pricing: www.sigma-aldrich.com

C21H27Gd FW 436.7
99.9% 40,170-6 CAS No. 597-63-7 1g
solid Ge(C2H5)4 FW 188.9 5g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 F 99%
R: 11 S: 16 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.442 (lit.)
bp. . . . . . . . . . . . . . . . . . . . 163-164 C/760 mm Hg (lit.)
Tris(tetramethylcyclopentadienyl)gadolinium Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.998 g/mL (lit.)
51,136-6 CAS No. 308847-85-0 1g R: 10-22-36/37/38 S: 16-26-36
C27H39Gd FW 520.8
99.9%
R: 11-14 S: 16
310
Metal-Organic Precursors: Germanium
Tetramethylgermanium Bis(cyclopentadienyl)hafnium dihydride

39,635-4 CAS No. 865-52-1 1g 56,063-4 (Hafnocene dihydride; 5g
C4H12Ge FW 132.8 5g Bis(cyclopentadienyl)dihydridohafnium)
98% CAS No. 68183-87-9
CVD precursor to germanium oxide thin films. Thin Solid (C5H5)2HfH2 FW 310.7
Films 1990, 189, 293. mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226 C (dec.)
Vapor pressure. . . . . . . . . . . . . . . . . . . . 6.74 psi ( 20 C) R: 15-34 S: 16-26-27-36/37/39-45
Vapor pressure. . . . . . . . . . . . . . . . . . . .21.16 psi ( 55 C)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.389 (lit.) H Hf H
bp. . . . . . . . . . . . . . . . . . . . . . 43-44 C/740 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . -88 C (dec.) (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -35 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.978 g/mL (lit.)

R: 11-20/21/22-36 S: 16-26-36
Tetraphenylgermanium Bis(indenyl)dimethylhafnium
56,619-5 CAS No. 49596-06-7 1g
28,820-9 CAS No. 1048-05-1 1g
C24H20Ge FW 381.1 (C9H7)2Hf(CH3)2 FW 438.9 5g
98%
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107-109 C
R: 20/21/22-36/37/38 S: 26-36
Tetrapropylgermanium Dimethylbis(cyclopentadienyl)hafnium
44,756-0 CAS No. 994-65-0 1g 55,705-6 CAS No. 37260-88-1 1g

(C5H5)2Hf(CH3)2 FW 338.7 5g
C12H28Ge FW 245.0 10 g
97% solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118 C (dec.)
R: 20/21/22 S: 36
Microelectronics
Tributylgermanium hydride CH
3
Hf CH
3
40,917-0 CAS No. 998-39-0 250 mg

C12H28Ge FW 245.0 1g
99%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.45 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . 123 C/20 mm Hg (lit.) Tetrabenzylhafnium(IV)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
R: 20/21/22-41 S: 26-36 (C6H5CH2)4Hf FW 543.0 5g
97%
Triethylgermanium hydride mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99-104 C
42,996-1 CAS No. 1188-14-3 1g Tetrakis(diethylamino)hafnium

C6H16Ge FW 160.8 5g
98% 45,520-2 CAS No. 19962-12-0 10 g
R: 11-20/21/22 S: 16-36 Hf(N(CH2CH3)2)4 FW 467.0 100 g
99.99%
Triphenylgermanium hydride Purity excludes ~2000ppm zirconium.
bp. . . . . . . . . . . . . . . . . . . . . . . . . .130 C/0.01 mm Hg
42,483-8 CAS No. 2816-43-5 5g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 F
C18H16Ge FW 305.0 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.249 g/mL
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40-43 C (lit.) R: 11-14-36/37/38 S: 16-26-36
R: 20/21/22 S: 36 CH CH
3 2
CH CH
2 3
N
CH CH CH CH
3 2 2 3
N Hf N
Tris(trimethylsilyl)germanium hydride CH CH CH CH
3 2 N 2 3
CH CH CH CH
3 2 2 3
41,710-6 CAS No. 104164-54-7 250 mg
C9H28GeSi3 FW 293.2 1g
97% 5g
n20
D . . . . . . . . . . . . . . . . . . 1.4974 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.937 g/mL (lit.)
R: 20/21/22 S: 36
We can supply lab
glassware kits and
Hafnium components In Bulk at
Bis(tert-butylcyclopentadienyl)dimethylhafnium a substantial savings.
Please contact us for
49,370-8 CAS No. 68193-45-3 1g a quotation.
C20H26Hf FW 444.9 5g
95%
311
Metal-Organic Precursors: Hafnium
Tetrakis(dimethylamino)hafnium Indium
45,519-9 CAS No. 19962-11-9 5g Triethylindium
Hf(N(CH3)2)4 FW 354.8 25 g
99.99% 57,091-5 CAS No. 923-34-2
Purity excludes ~2000 ppm Zr. In(CH2CH3)3 FW 202.0
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26-29 C electronic grade
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 F R: 17-34 S: 6-16-26-27-36/37/39-45
R: 14-34 S: 26-36/37/39-43-45
CH
3
N
CH
3 Trimethylindium
CH CH
3 3
N Hf N
CH
3 CH 46,363-9 CAS No. 3385-78-2
N 3
CH
3
CH
3
In(CH3)3 FW 159.9
Iron

Tetrakis(ethylmethylamino)hafnium Bis(pentamethylcyclopentadienyl)iron
55,312-3 CAS No. 352535-01-4 5 mL 37,854-2 (Decamethylferrocene) 1g
Hf(N(CH3)C2H5)4 FW 410.9 25 mL CAS No. 12126-50-0 5g
99.99+% Fe(C5(CH3)5)2 FW 326.3
liquid 97%
bp. . . . . . . . . . . . . . . . . . . . . . . . 79 C/0.1 mm Hg (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 277 C (dec.) (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 F S: 22-24/25
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.324 g/mL (lit.)
CH CH
R: 11-34 S: 23-24/25 3 3
CH CH
CH CH CH 3 3
3 2 3 CH
N Fe 3
CH CH CH CH
3 2 3 3
N Hf N CH CH
Microelectronics
3 3
CH CH CH
3 2 N 3 CH CH
CH CH CH 3 3
3 2 3
Butylferrocene
32,523-6 CAS No. 31904-29-7 10 g
Fe(C5H5)(C5H4C4H9) FW 234.1 100 g
97%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.577 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.172 g/mL (lit.)
800.558.9196 (USA)
CH CH CH CH
2 2 2 3
Fe
tert-Butylferrocene
13
C-NMR spectrum of Aldrich product 55,312-3, lot 91823BO
46,902-5 CAS No. 1316-98-9 1g
Fe(C5H5)(C5H4C(CH3)3) FW 234.1 5g Ordering/Pricing: www.sigma-aldrich.com
97%
1,1’-Diethylferrocene
51,744-5 CAS No. 1273-97-8 5 mL
Fe(C5H4C2H5)2 FW 236.1
98%
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.58 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 284 C/760 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.18 g/mL (lit.)
CH CH
2 3
Fe
CH CH
3 2
1
H-NMR spectrum of Aldrich product 55,312-3, lot 91823BO
312
Metal-Organic Precursors: Iron
Ferrocene Bis(pentamethylcyclopentadienyl)magnesium
F40-8 (Di(cyclopentadienyl)iron; 5g 51,254-0 CAS No. 74507-64-5 1g
Bis(cyclopentadienyl)iron) 100 g C2OH30Mg FW 94.56 5g
CAS No. 102-54-5 500 g 99.999%, electronic grade
Fe(C5H5)2 FW 186.0 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 C (dec.)
98% R: 17 S: 16-26-36/37/39
Vapor pressure. . . . . . . . . . . . . . . . . . . . . 0.03 mm Hg ( 40 C) CH
3
CH
3
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 249 C/760 mm Hg (lit.) CH CH
3 3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174-176 C (lit.) Mg
CH
3
Absorbance (l). . . . . . . . . . . . . . . . . . . . . . . . . . . . . 358 nm CH
3
CH CH
R: 11-22 S: 16 3 3
CH CH
3 3
Fe
Bis(propylcyclopentadienyl)magnesium
47,945-4 CAS No. 114504-74-4 1g
Tricarbonyl(cyclooctatetraene)iron Mg(C5H4C3H7)2 FW 238.7 5g
96%
27,591-3 CAS No. 12093-05-9 250 mg R: 17 S: 16-36/37/39
C8H8Fe(CO)3 FW 244.0 1g
98%
R: 20/21/22 S: 36 Manganese
Acetylcyclopentadienylmanganese tricarbonyl
Lanthanum
52,984-2 CAS No. 12116-28-8 1g

Microelectronics
Tris(cyclopentadienyl)lanthanum C10H3MnO4 FW 242.1

solid
49,359-7 CAS No. 1272-23-7 1g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41-46 C (lit.)
La(C5H5)3 FW 334.2 5g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
99.9% R: 26/27/28 S: 26-28-36/37/39-45
R: 11-14/15 S: 43-7/8 O
C CH
Mn 3
Tris(tetramethylcyclopentadienyl)lanthanum OC
CO
CO
51,318-0 CAS No. 148607-23-2 1g

C27H39La FW 502.5
99.9%
R: 11-14 S: 16 Bis(cyclopentadienyl)manganese
49,371-6 CAS No. 73138-26-8 1g
Magnesium Mn(C5H5)2 FW 185.1 5g
97%
Bis(cyclopentadienyl)magnesium R: 36/37/38 S: 26-36
37,913-1 CAS No. 1284-72-6 1g Bis(ethylcyclopentadienyl)manganese

Mg(C5H5)2 FW 154.5
97%, Purified by sublimation 51,063-7 CAS No. 101923-26-6 5g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 180 C (dec.) (lit.) Mn(C5H4C2H5)2 FW 241.2
R: 17 S: 16-36/37/39 liquid
bp. . . . . . . . . . . . . . . . . . . . . . . ~80 C/760 mm Hg (lit.)
Mg
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
R: 17-36/37/38 S: 17-26-36
CH CH
2 3
Mn
CH CH
3 2
Bis(ethylcyclopentadienyl)magnesium
47,944-6 CAS No. 114460-02-5 1g
Mg(C5H4C2H5)2 FW 210.6 5g
97%
R: 17 S: 16-36/37/39
313
Metal-Organic Precursors: Manganese
Bis(pentamethylcyclopentadienyl)manganese Manganese carbonyl

41,540-5 CAS No. 67506-86-9 1g 24,526-7 (Decacarbonyl dimanganese; Dimanganese 1 g
Mn(C5(CH3)5)2 FW 325.4 5g decacarbonyl; di-Manganese decacarbonyl) 10 g
Packaged under argon in ampules CAS No. 10170-69-1
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 230 C (dec.) (lit.) Mn2(CO)10 FW 390.0
CH CH
3 3 98%
CH CH mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 C (lit.)
3 3
CH
Mn 3 R: 23/24/25 S: 22-26-36/37/39-45
CH
3
CH CH OC CO CO
3 3 CO
CH CH OC Mn Mn CO
3 3 OC OC
OC CO
Bis(tetramethylcyclopentadienyl)manganese(II)
56,242-4 CAS No. 101932-75-6 1g (Methylcyclopentadienyl)manganese tricarbonyl

C18H26Mn FW 297.3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98-112 C 31,763-2 CAS No. 12108-13-3 1g
S: 22-24/25 C5H4CH3Mn(CO)3 FW 218.1 5g
97% 50 g
Cyclopentadienylmanganese tricarbonyl Vapor density. . . . . . . . . . . . . . . >1 (vs air)
Vapor pressure. . . . . . . . . . . . . . . . . 0.05 mm Hg ( 20 C)
28,805-5 CAS No. 12079-65-1 1g n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.584 (lit.)
C5H5Mn(CO)3 FW 204.1 5g bp. . . . . . . . . . . . . . . . . . . . 232-233 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . 72-76 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 C (lit.)
R: 26/27/28 S: 26-28-36/37/39-45 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.38 g/mL (lit.)
R: 23/24/25-40 S: 23-26-36/37/39-45
Mn
OC CO
Microelectronics
CO CH
3
Mn
OC CO
CO
Ethylcyclopentadienylmanganese tricarbonyl
52,985-0 CAS No. 12116-56-2 1g
Mercury
C10H5MnO3 FW 228.1
liquid Bis(trimethylsilylmethyl)mercury
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.579 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 245 C/760 mm Hg (lit.)
33,205-4 CAS No. 13294-23-0 1g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.363 g/mL (lit.) C8H22HgSi2 FW 375.0 5g
R: 26/27/28-33-50/53 S: 13-28-36-45-60-61
800.558.9196 (USA)
CH CH
2 3
Mn
OC
CO
CO Dimethylmercury
32,808-1 (Methylmercury) 10 g
CAS No. 593-74-8
(CH3)2Hg FW 230.7
Hydroxyisopropylcyclopentadienylmanganese tricarbonyl 95%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.543 (lit.)
52,986-9 CAS No. 33086-66-7 1g bp. . . . . . . . . . . . . . . . . . . . . . 93-94 C/760 mm Hg (lit.)
C11H7MnO4 FW 258.1 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -43 C (lit.) Ordering/Pricing: www.sigma-aldrich.com
96% Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 2.961 g/mL (lit.)
solid
R: 26/27/28-33-50/53 S: 13-28-36-45-60-61
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43-46 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F CH
3
Hg CH
3
R: 26/27/28 S: 26-28-36-45
CH
3
C OH
Mn
OC CO CH
CO 3
314
Metal-Organic Precursors: Molybdenum
(Bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum Cyclopentadienylmolybdenum tricarbonyl hydride

11,926-1 CAS No. 12146-37-1 1g 51,122-6 (tricarbonyl(cyclopentadienyl)hydridomolyb- 5 g
C11H4MoO4 FW 296.1 5g denum)
95% CAS No. 12176-06-6
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79-81 C (lit.) C8H2MoO3 FW 242.0
R: 20/21/22-36/37/38 S: 26-36 solid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
H
OC Mo CO Mo
OC CO
OC CO CO
Dicarbonyl(pentamethylcyclopentadienyl)molybdenum,
Bis(cyclopentadienyl)molybdenum dichloride dimer
25,644-7 CAS No. 12184-22-4 100 mg 48,664-7 CAS No. 12132-04-6 1g
C10H2Cl2Mo FW 289.0 500 mg C24H30Mo2O4 FW 574.4 5g
97% 97%
R: 36/37/38 S: 26-37/39 R: 26/27/28 S: 53-36/37/39-45
Cl Mo Cl Methylcyclopentadienylmolybdenum tricarbonyl, dimer

38,104-7 CAS No. 33056-03-0 1g
C18H6Mo2O6 FW 510.1 5g
97%
R: 20/21/22 S: 36
Bis(diethyldithiocarbamato)dioxomolybdenum(VI)
Microelectronics
Molybdenumhexacarbonyl
33,769-2 CAS No. 19680-83-2 5g
C10H22MoN2O2S4 FW 426.5 25 g (Hexacarbonylmolybdenum)
R: 20/21/22-36/37/38 S: 26-36 CAS No. 13939-06-5
Mo(CO)6 FW 264.0
[1,2-Bis(diphenylphosphino)ethane]tetracarbonylmolyb- R: 26 S: 36/37/39-45
denum OC CO
OC Mo CO
OC CO
34,805-8 CAS No. 15444-66-3 1g
C30H24MoO4P2 FW 606.4 5g
97%
R: 20/21/22 S: 36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
57,776-6 99.9+% 5g
(1,1’-Bis(diphenylphosphino)ferrocene)tetracarbonylmo- Purified by sublimation 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
lybdenum(0) 19,995-8 98% 10 g
55,511-8 CAS No. 67292-28-8 1g mp . . . . . . . . . . . . . . . 150 C (dec.) (lit.) 250 g
(CO)4Mo(P(C6H5)2C5H4)2Fe FW 762.4 5g Density. . . . . . . . . . . . . . . 1.96 g/mL (lit.)
96%
mp . . . . . . . . . . . . . . . . . . . . . . . 256 C (decomposition) (Propylcyclopentadienyl)molybdenum tricarbonyl dimer
Cyclopentadienylmolybdenum tricarbonyl, dimer 52,416-6 CAS No. 105046-05-7 1g

C22H16Mo2O6 FW 568.2 5g
11,760-9 CAS No. 12091-64-4 1g solid
C16H2Mo2O6 FW 482.1 10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 C (D) (lit.)
98% CH CH CH
2 2 3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222 C (D) (lit.) Mo(CO)
3
R: 20/21/22 S: 36 Mo(CO)
3
CH CH CH
2 2 3
Mo(CO)
3
Mo(CO)
3
cis-Tetracarbonylbis(piperidine)molybdenum
32,909-6 CAS No. 65337-26-0 5g
C14H20MoN2O4 FW 376.3
R: 20/21/22-36/37/38 S: 26-36
315
Metal-Organic Precursors: Molybdenum
Triamminemolybdenum tricarbonyl Bis(1,5-cyclooctadiene)nickel(0)

54,111-7 CAS No. 18177-91-8 1g 24,498-8 (Ni(COD)2) 2g
solid 5g CAS No. 1295-35-8
mp . . . . . . . . . . . . . . . . . . 220-225 C (lit.) C16H16Ni FW 267.0
R: 14 S: 43 Packaged under nitrogen in ampules
Catalyst for the cycloaddition of 1,3-dienes. J. Am. Chem.
Tricarbonyl(cycloheptatriene)molybdenum Soc. 1989, 111, 6432.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . .60 C (D) (lit.)
11,928-8 CAS No. 12125-77-8 1g R: 45-11 S: 53-16-22-36/37/39-45
C7H8Mo(CO)3 FW 272.1
98%
Ni
mp . . . . . . . . . . . . . . . . . . . . . . . 100-101 C (dec.) (lit.)
R: 20/21/22-36/37/38 S: 26-37/39

Mo
OC CO CO Bis(cyclopentadienyl)nickel
N752-4 (Di(cyclopentadienyl)nickel; Nickelocene) 1g
CAS No. 1271-28-9 5g
Ni(C5H5)2 FW 188.9
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171-173 C (lit.)
R: 49-11-22-43 S: 53-36/37/39-45
Neodymium
Tris(cyclopentadienyl)neodymium Ni
49,358-9 CAS No. 1273-98-9 1g
Microelectronics
Nd(C5H5)3 FW 339.5 5g
99.9%
R: 11-14/15 S: 43-7/8
Bis(ethylcyclopentadienyl)nickel
Tris(isopropylcyclopentadienyl)neodymium
51,048-3 CAS No. 31886-51-8 5g
49,601-4 CAS No. 69021-85-8 1g Ni(C5H4C2H5)2 FW 245.0
R: 20/21/22 S: 36
Nd(C5H4CH(CH3)2)3 FW 465.8 5g
99.9%
Bis(methylcyclopentadienyl)nickel
Tris(tetramethylcyclopentadienyl)neodymium 51,047-5 CAS No. 1293-95-4 1g
51,106-4 CAS No. 164528-22-7 1g Ni(C5H4CH3)2 FW 216.9 5g
97%
800.558.9196 (USA)
C27H39Nd FW 507.8
99.9% Volatile OMCVD precursor for the controlled growth of
R: 11-14 S: 16 nickel nanoparticles on silicon substrates. Possible uses for
metallic nickel nanoparticles embedded on silicon include
the manufacture of high-density storage media 9. Nickel
Nickel oxide thin films are generated via OMCVD in the presence
of O2 or H2O2.
Allyl(cyclopentadienyl)nickel solid
bp. . . . . . . . . . . . . . . . . . . . . . . 85-90 C/1 mm Hg (lit.)
52,427-1 CAS No. 12107-46-9 1g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34-36 C (lit.)
C8H7Ni FW 161.8 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150 F Ordering/Pricing: www.sigma-aldrich.com
97% References
liquid Kumagai, H. et al., J. Mater. Sci. Lett. 15, 1081 (1996)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.31 g/mL (lit.) R: 20/21/22 S: 16-33-36
R: 17-20/21/22 CH
3
Ni
Ni CH
3
Bis(pentamethylcyclopentadienyl)nickel
49,360-0 CAS No. 74507-63-4 1g
Ni(C5(CH3)5)2 FW 329.1 5g
R: 20/21/22 S: 36
316
Metal-Organic Precursors: Nickel
Bis(tetramethylcyclopentadienyl)nickel(II) Phosphorus
56,240-8 CAS No. 79019-60-6 1g Tri-tert-butylphosphine
C18H26Ni FW 301.1 5g
mp . . . . . . . . . . . . . . . . . . . . . 107-112 C 57,095-8 CAS No. 13716-12-6 1g
R: 20/21/22 S: 36 [(CH3)3C]3P FW 202.3 5g
solid 10 g
Bis(triphenylphosphine)nickel(II) dichloride 98%
bp. . . . . . . . . . . . . . . . . . . . . . >102-103 C/>13 mm Hg
52,962-1 (Nickel(II)-bis(triphenylphosphine) 10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >30-35 C
dichloride) R: 17-34 S: 16-26-27-36/37/39-43-45
CAS No. 14264-16-5 C(CH )
33
[(C6H5)3P]2NiCl2 FW 654.2
P
(CH ) C C(CH )
‡99.99% 33 33
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250 C (dec.)
R: 20/21/22 S: 36/37
Cyclopentadienylnickel carbonyl, dimer Tris(dimethylamino)phosphine

32,758-1 CAS No. 12170-92-2 1g (Hexamethylphosphorous triamide; HMPT)
C12H2Ni2O2 FW 295.5 5g CAS No. 1608-26-0
tech. P[N(CH3)2]3 FW 163.2
R: 45-23/24/25-36/37/38-42/43 S: 53-26-27-28-36/37/39-45 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.898 g/mL (lit.)
R: 10
Ni(CO) CH
3
Ni(CO) CH N CH
3 3
P N
CH N CH
3 3
CH
3
Microelectronics
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Osmium 39,329-0 97% 5 mL
Precipitate is unavoidable and should not 25 mL
Bis(pentamethylcyclopentadienyl)osmium affect use
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.466 (lit.)
44,205-4 CAS No. 100603-32-5 250 mg bp. . . . . . . . . . . . . . . . . . . . . . . 48-50 C/12 mm Hg (lit.)
Os(C5(CH3)5)2 FW 460.7 1g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 F
R: 36/37/38 S: 26-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
14,355-3 Technical Grade, 85% 10 g
Dodecacarbonyltetra-m-hydridotetraosmium n20
D . . . . . . . . . . . . . . . . . . . . . 1.463 (lit.) 50 g
bp. . . . . . . . . . . . . 55-58 C/15 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 F
51,145-5 CAS No. 12375-04-1 250 mg
C12H4O12Os4 FW 1101
solid Platinum
R: 36/37/38 S: 26-36
(1,5-Cyclooctadiene)dimethylplatinum(II)
Triosmium dodecacarbonyl
40,904-9 CAS No. 12266-92-1 250 mg
24,974-2 (tri-Osmium dodecacarbonyl; Osmium 250 mg
C10H14Pt FW 329.3 1g
carbonyl) 1g mp . . . . . . . . . . . . . . . 103-105 C (lit.)
CAS No. 15696-40-9 R: 36/37/38 S: 26-36
Os(CO)12 FW 906.8 CH CH
3 3
98% Pt
Starting material for N-oxide-containing complexes of
osmium with 1-hydroxypyridine-2-thione. Hung, J-T. et al.
Organometallics 1996, 15, 5605. Key raw material for the
synthesis of [Os(CO)4(SnPh2)]6, a compound with an
unprecedented 12-membered ring of metal atoms. Leong,
W.K. et al. Organometallics 1997, 16, 1079.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224 C (lit.)
R: 22-36/37/38 S: 22-26-36/37/39
317
Metal-Organic Precursors: Platinum
Tetrakis(triphenylphosphine)platinum Ruthenium
24,496-1 (Platinum-tetrakis(triphenylphosphine)) 250 mg Benzeneruthenium(II) chloride, dimer
CAS No. 14221-02-4 1g
Pt[(C6H5)3P]4 FW 1244 5g 34,156-8 CAS No. 37366-09-9 1g
97% C12H2Cl4Ru2 FW 490.1 5g
S: 22-24/25 R: 36/37/38 S: 26-37/39
Cl Cl
Ru Ru
Cl Cl
P Pt
Bis(cyclopentadienyl)ruthenium

26,245-5 CAS No. 1287-13-4 250 mg
Praseodymium C10H2Ru FW 223.2 1g
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 199-201 C (lit.)
Tris[N,N-bis(trimethylsilyl)amide]praseodymium(III) R: 36/37/38 S: 26-37/39
54,780-8 CAS No. 35789-00-5 1g
Ru
Pr(N(Si(CH3)3)2)3 FW 622.1
98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101-105 C
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F
R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8
Tris(cyclopentadienyl)praseodymium Bis(pentamethylcyclopentadienyl)ruthenium
Microelectronics
47,517-3 CAS No. 11077-59-1 1g 44,206-2 CAS No. 84821-53-4 100 mg
Pr(C5H5)3 FW 336.2 Ru(C5(CH3)5)2 FW 371.5 500 mg
99.9% 97%
R: 11-14/15 S: 43-7/8 R: 36/37/38 S: 26-36
Tris(isopropylcyclopentadienyl)praseodymium Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride
49,602-2 CAS No. 69021-86-9 1g 28,813-6 (Ruthenium(II)- 1g

Pr(C5H4CH(CH3)2)3 FW 462.4 bis(triphenylphosphine)dichlorocarbonyl;
99.9% Dichlorodicarbonyl-bis(triphenylphosphine)ruthenium(II))
S: 16-33 CAS No. 14564-35-3
[(C6H5)3P]2Ru(CO)2Cl2 FW 752.6
800.558.9196 (USA)
Tris(tetramethylcyclopentadienyl)praseodymium S: 22-24/25
51,092-0 CAS No. 308847-82-7 1g Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

C15H15Pr FW 336.2
99.9% 33,500-2 CAS No. 25360-32-1 500 mg
R: 11-14 S: 16 C55H47OP3Rh FW 919.8 1g
R: 20/21/22 S: 36 5g
Rhenium Tetrapropylammonium perruthenate

Dirhenium decacarbonyl 33,074-4 (TPAP) 250 mg
CAS No. 114615-82-6 1g
24,500-3 (Rhenium carbonyl) 500 mg (CH3CH2CH2)4NRuO4 FW 351.4
CAS No. 14285-68-8 5g 97%
Re2(CO)10 FW 652.5 mp . . . . . . . . . . . . . . . . . . . . . . . . . . 165 C (dec.) (lit.)
98% R: 5-8-36/37/38 S: 17-26-36
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 170 C (dec.) (lit.) CH CH CH
2 2 3
R: 20 S: 36 CH CH CH
3 2 2
N CH CH CH RuO
2 2 3 4
OC CO CO CH CH CH
CO 2 2 3
OC Re Re CO
OC OC
OC CO
318
Metal-Organic Precursors: Ruthenium
Triruthenium dodecacarbonyl Tris(butylcyclopentadienyl)scandium

24,501-1 (Ruthenium carbonyl; tri-Ruthenium 1g 52,738-6 CAS No. 312739-92-7 5 mL
dodecacarbonyl) 5g C27H39Sc FW 408.6
CAS No. 15243-33-1 99.9%
Ru3(CO)12 FW 639.3 Packaged in prescored ampule
99% liquid
Applied in improved catalysis of the allylic amination of n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.58 (lit.)
unactivated olefins by nitroarenes. Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 F
References Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.03 g/mL (lit.)
Ragaini, F. et al., Organometallics 18, 929 (1999) R: 17 S: 16-36/37/39
R: 11-20 CH (CH ) CH
2 22 3
CO 3
OC CO Sc
Ru
CO CO CO 3
OC Ru Ru CO
OC CO
CO CO
Tris(cyclopentadienyl)scandium
41,015-2 CAS No. 1298-54-0 1g
Samarium Sc(C5H5)3 FW 240.2
99.9%
Tris(N,N-bis(trimethylsilyl)amide]samarium(III) R: 11-14/15 S: 43-7/8
54,798-0 CAS No. 35789-01-6 1g

Sm(N(Si(CH3)3)2)3 FW 631.5 Selenium
98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93-106 C Di-tert-butyl selenide
Microelectronics
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F
R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8 51,150-1 CAS No. 34172-60-6 5g
Se(C(CH3)3)2 FW 193.2
Tris(cyclopentadienyl)samarium 99.99+%, electronic grade
R: 23/24/25 S: 23-36/37/39-45
55,399-9 CAS No. 1298-55-1 5g
(C5H5)3Sm FW 345.6 Diethyl selenide
99.9%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 C 55,043-4 CAS No. 627-53-2 5g
R: 11-14/15 S: 43-7/8 Se(C2H5)2 FW 137.1 25 g
99.999%, 99% as chemical purity
Tris(tetramethylcyclopentadienyl)samarium liquid
bp. . . . . . . . . . . . . . . . . . . . . . . 108 C/760 mm Hg (lit.)
51,126-9 CAS No. 148607-24-3 1g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 F
C27H39Sm FW 514.0 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.232 g/mL (lit.)
99.9% R: 10-23/25-33-50/53 S: 16-20/21-23-28-45-60-61
R: 11-14 S: 16
Dimethyl selenide
Scandium 41572 (Methyl selenide) 1 mL
CAS No. 593-79-3 5 mL
Tris[N,N-bis(trimethylsilyl)amide]scandium(III) (CH3)2Se FW 109.0
puriss., ‡99.0% (GC)
54,775-1 CAS No. 37512-28-0 1g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.408 g/mL
Sc(N(Si(CH3)3)2)3 FW 526.1 R: 23/25-33-50/53 S: 20/21-28-45-60-61
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169-174 C
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F Silicon
R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8
Chloropentamethyldisilane
49,040-7 CAS No. 1560-28-7 1g
CeSi2(CH3)5 FW 166.8 5g
97%
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4415 (lit.)
bp. . . . . . . . . . . . . . . . . . . . 134-136 C/760 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.862 g/mL (lit.)
R: 11-14-34 S: 16-26-36/37/39-45
CH CH
3 3
CH Si Si Cl
3
CH CH
3 3
319
Metal-Organic Precursors: Silicon
1,2-Dichlorotetramethyldisilane 2,4,6,8,10,12-Hexamethylcyclohexasiloxane
41,545-6 CAS No. 4342-61-4 5 mL 51,782-8 CAS No. 6166-87-6 25 mL
(ClSi(CH3)2)2 FW 187.2 (CH3SiHO)6 FW 360.8
95% 96%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.454 (lit.) liquid
bp. . . . . . . . . . . . . . . . . . . . 148-149 C/760 mm Hg (lit.) n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.394 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 F bp. . . . . . . . . . . . . . . . . . . . . . . . 34 C/0.1 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.005 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.999 g/mL (lit.)
R: 14-34 S: 26-27-36/37/39-45
H CH
O 3
CH CH
3 3 CH Si Si H
3 CH
Cl Si Si Cl H 3
O O
CH CH Si Si H
3 3
CH O O O
3
Si Si
H CH H CH3
3
1,2-Dimethyl-1,1,2,2-tetraphenyldisilane

Hexamethyldisilane
47,775-3 CAS No. 1172-76-5 1g
(SiCH3(C6H5)2)2 FW 394.7 5g 21,706-9 (Disilane M6) 5g
97% CAS No. 1450-14-2 10 g
R: 36/37/38 S: 26-36
(Si(CH3)3)2 FW 146.4 50 g
98%
Dodecamethylcyclohexasilane
Source material for vapor deposition during silicon carbide
43,749-2 CAS No. 4098-30-0 1g growth.
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.422 (lit.)
(Si(CH3)2)6 FW 348.9 5g
bp. . . . . . . . . . . . . . . . . . . . 112-114 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . 229 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 F
CH CH
3 3 CH Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.715 g/mL (lit.)
Microelectronics
CH
3 Si 3
CH
3
Si Si CH
3
References
CH
3
Si Si CH
3
Thin Solid Films 252, 13 (1994)
Si
CH
3 CH CH
CH
3
R: 11-43 S: 16-23-45
3 3
CH CH
3 3
CH Si Si CH
3 3
CH CH
3 3
1,2-Ethanediylbis(methylsilane)
52,222-8 CAS No. 4405-22-5 5g
CH3SiH2CH2CH2SiH2CH3 FW 118.3 Octaphenylcyclotetrasilane
98%
liquid 44,481-2 CAS No. 1065-95-8 1g
800.558.9196 (USA)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.422 (lit.) (Si(C6H5)2)4 FW 729.2
bp. . . . . . . . . . . . . . . . . . . . . . 95-96 C/760 mm Hg (lit.) 97%
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.725 g/mL (lit.)
R: 11 S: 16 2,4,6,8,10-Pentamethylcyclopentasiloxane
H H
CH Si CH CH Si CH
3
H
2 2
H
3 51,780-1 CAS No. 6166-86-5 25 mL
(CH3SiHO)5 FW 300.6
96%
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3908 (lit.)
1,2-Ethanediylbissilane bp. . . . . . . . . . . . . . . . . . . . . . . . . 54 C/10 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.992 g/mL (lit.)

52,197-3 CAS No. 4364-07-2 10 mL R: 10-36/37/38 S: 16-26-36
H3SiCH2CH2SiH2 FW 90.27 CH H
3
97% H O
Si
O CH
3
liquid Si Si
CH H
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4141 (lit.) 3 O O
bp. . . . . . . . . . . . . . . . . . . . . . 45-46 C/760 mm Hg (lit.) H
Si
O
Si
CH
3
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.697 g/mL (lit.) CH
3
H
R: 5 S: 16-36
Hexachlorodisilane See: Trichlorosilanes Page 230
320
Pentamethyldisilane Tetrakis(dimethylamino)silane
55,764-1 CAS No. 812-15-7 1 mL 47,507-6 CAS No. 1624-01-7 5g
(CH3)3SiSi(CH3)2H FW 104.3 5 mL Si(N(CH3)2)4 FW 204.4 10 g
97% 99%
bp. . . . . . . . . . . . . . . . . . . . . . . . . 98-99 C/760 mm Hg R: 10-14-20/21/22-34 S: 26-36/37/39-45
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.4240
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.722 g/mL
R: 11 S: 16-33-7/9
CH CH
3 3
CH Si Si H
3
CH CH
3 3
1,1,2,2-Tetrachloro-1,2-dimethyldisilane
36,896-2 CAS No. 4518-98-3 5g
Cl4SiSi(CH3)2 FW 228.1 25 g
96%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.469 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.269 g/mL (lit.)
R: 10-14-34 S: 26-27-28-36/37/39-45
Cl Cl
CH Si Si CH
3 3
Microelectronics
Cl Cl
1
H-NMR spectrum of Aldrich product 47,507-6, lot 91229EA
Tetraethylsilane
51,087-4 CAS No. 631-36-7 5 mL 2,4,6,8-Tetramethylcyclotetrasiloxane
Si(C2H5)4 FW 144.3 25 mL
99% 51,299-0 (TMCTS) 25 mL
liquid CAS No. 2370-88-9
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4263 (lit.)
(HSiCH3O)4 FW 240.5
bp. . . . . . . . . . . . . . . . . . . . 153-154 C/760 mm Hg (lit.) 99.5+%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -82.5 C (lit.) Precursor for gate dielectrics in thin-film transistors (TFT),
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 F and is a component of photochemically formed SiOx
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.761 g/mL (lit.) monolayers on TiO.
R: 10-36/37/38 S: 26-36
CH CH
2 3 liquid
CH CH
3 2
Si CH CH
2 3 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3871 (lit.)
CH CH
2 3
bp. . . . . . . . . . . . . . . . . . . . . . . 134 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -69 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.986 g/mL (lit.)
References
1,1,2,2-Tetraisopropyldisilane 1. Tada, H.; Tanaka, M., Thin Solid Films 281, 404 (1996)
2. Wang,A. W. et al., Mater. Res. Soc. Symp. Proc. 424, 281
43,946-0 CAS No. 19753-69-6 1g (1997)
Si(CH(CH3)2)4 FW 230.5 R: 10-36 S: 16-26-36
CH
97% H O
3
Si
H
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.477 (lit.) Si
CH
O
CH 3
bp. . . . . . . . . . . . . . . . . . . . . . . . 124 C/21 mm Hg (lit.) 3 O Si
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189 F H
Si O H
CH
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.815 g/mL (lit.) 3
CH CH
3 3
CH CH CHCH
3 3
CH CH Si Si CHCH
3 3
CH H H CH
3 3
321
1,1,2,2-Tetramethyldisilane Trimethyl(vinyl)silane
44,512-6 CAS No. 814-98-2 1g 49,430-5 (Ethenyltrimethylsilane; 25 mL
(CH3)2SiHSiH(CH3)2 FW 118.3 Vinyltrimethylsilane;
98% (Trimethylsilyl)ethylene)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.428 (lit.) CAS No. 754-05-2
bp. . . . . . . . . . . . . . . . . . . . . . 86-87 C/760 mm Hg (lit.)
(CH3)3SiCHCH2 FW 100.2
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -15 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.715 g/mL (lit.)
99.5+%
R: 11 S: 16-29-33 liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.392 (lit.)
CH CH
3 3 bp. . . . . . . . . . . . . . . . . . . . . . . . 55 C/760 mm Hg (lit.)
H Si Si H
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <-30 F
CH CH
3 3 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.684 g/mL (lit.)
R: 11-22-36/37/38 S: 16-26-33-36
CH
3
CH Si CH CH
3 2
Tetramethylsilane

CH
3
52,377-1 CAS No. 75-76-3 100 mL

Si(CH3)4 FW 88.22
liquid Tantalum
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.358 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 26-28 C/760 mm Hg (lit.) Pentakis(dimethylamino)tantalum
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -17 F
R: 12 S: 16-3/7-33-45
Ta(N(CH3)2)5 FW 401.3
99.9%
N,N¢,N¢¢-Tri-tert-butylsilanetriamine Volatile solid CVD precursor to tantalum nitride (TaN) thin
Microelectronics
47,538-6 CAS No. 205503-61-3 5 mL films. Also yields tantalum oxide (Ta2O5) thin films when
HSi(HNC(CH3)3)3 FW 245.5 10 mL O2, H2O, NO or H2O2 is present during the deposition
99.99% process., Ta2O5 thins films show promise as gate dielectric
liquid materials in the manufacture of integrated circuits.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.827 g/mL solid
n20 mp . . . . . . . . . . . . . . . . . . . . . . . . . . 100 C (dec.) (lit.)
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4289 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 76-80 C/0.3 mm Hg (lit.) References
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129 F 1. Son, K. -A. et. al., Appl. Phys. Lett. 72, 1187 (1998)
R: 10-34 S: 16-26-36/37/39-45 2. Son, K. -A. et. al., J. Vac. Sci. Technol., A 16, 1670 (1998)
CH CH
CH H CH 3 3
3 3 CH N CH
3 3
CH C NH Si NH C CH N N
3 3
CH Ta CH
CH NH CH 3 3
3 3
N N CH
800.558.9196 (USA)
CH C CH CH
3 3 3 3
CH CH CH
3 3 3
2,4,6-Trimethylcyclotrisiloxane Tris(diethylamino)(tert-butylimino)tantalum
51,779-8 CAS No. 13269-39-1 25 mL 52,128-0 ((tert- 5 mL

(HSiCH3O)3 FW 180.4 Butylimino)tris(diethylamino)tantalum)
liquid CAS No. 169896-41-7
bp. . . . . . . . . . . . . . . . . . . . . . . . . 34 C/78 mm Hg (lit.) (CH3)3CNTa(N(C2H5)2)3 FW 468.5 Ordering/Pricing: www.sigma-aldrich.com
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.972 g/mL (lit.) 99.99+%, 99% (chemical purity)
R: 11-36 S: 16-26-29-33-36 liquid
H CH
3
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 F
O
Si Si Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.252 g/mL (lit.)
CH H
3 O O R: 10-14-34 S: 26-36/37/39-43-45
Si
H CH CH CH CH CH
3 3 2 2 3
N CH
CH CH 3
3 2
N Ta N C CH
3
CH CH
3 2 N CH
3
CH CH CH CH
3 2 2 3
322
Metal-Organic Precursors: Tantalum
Tris(diethylamino)(ethylimino)tantalum Thallium
51,783-6 CAS No. 67313-80-8 5 mL Thallium cyclopentadienide
C2H5NTa(N(C2H5)2)3 FW 440.4
liquid 15,534-9 CAS No. 34822-90-7 1g
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.51 (lit.) C5H5Tl FW 269.5 10 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F 97% 50 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.31 g/mL (lit.) mp . . . . . . . . . . . . . . . . . . . . 300 C (lit.)
R: 11-34 S: 16-26-27-36/37/39 R: 26/28-33-51/53 S: 13-28-45-61
CH CH CH CH
3 2 2 3
CH CH N
3 2 Tl
N Ta NCH CH
2 3
CH CH N
3 2
CH CH CH CH
3 2 2 3
Thulium
Tellurium Tris(cyclopentadienyl)thulium
Diethyltelluride 55,398-0 CAS No. 1272-26-0 5g

(C5H5)3Tm FW 364.2
55,767-6 CAS No. 627-54-3 1g 99.9%
Te(CH2CH3)2 FW 185.7 5g mp . . . . . . . . . . . . . . . . . . . . 248-249 C (decomposition)
99.999% (trace metals analysis) R: 11-14/15 S: 43-7/8
liquid
bp. . . . . . . . . . . . . . . . . . . . . . . 137-138 C/760 mm Hg Tm
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108 F
R: 10-25 S: 45
Microelectronics
Terbium
Tris[N,N-bis(trimethylsilyl)amide]terbium(III) Tin
54,783-2 CAS No. 109433-86-5 1g
Tb(N(Si(CH3)3)2)3 FW 640.1
Allenyltributyltin
98% 49,985-4 CAS No. 53915-69-8 1g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162-165 C
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F
C15H30Sn FW 329.1 5g
R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8 Technical Grade, 80%
liquid
Tris(cyclopentadienyl)terbium n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 265 C/760 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
55,400-6 CAS No. 1272-25-9 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.107 g/mL (lit.)
(C5H5)3Tb FW 354.2 R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
99.9%
mp . . . . . . . . . . . . . . . . . . . . . . . 235 C (decomposition)
R: 11-14/15 S: 43-7/8
Allyltributylstannane
27,141-1 CAS No. 24850-33-7 5g
Tris(isopropylcyclopentadienyl)terbium CH2:CHCH2Sn(CH2CH2CH2CH3)3 25 g
49,600-6 CAS No. 312696-25-6 1g FW 331.1 100 g
Tb(C5H4CH(CH3)2)3 FW 480.4 5g 97%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.486 (lit.)
99.9% bp. . . . . . . . . . . . . . . . . . . . . . 88-92 C/0.2 mm Hg (lit.)
S: 16-33
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.068 g/mL (lit.)
Tris(tetramethylcyclopentadienyl)terbium R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
CH CH CH CH
52,506-5 CAS No. 148607-25-4 1g 3 2 2 2
CH CH CH CH Sn CH CH CH
C27H39Tb FW 522.5 3 2 2 2 2 2
CH CH CH CH
99.9% 3 2 2 2
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 C (lit.)
R: 11-14 S: 16
323
Metal-Organic Precursors: Tin
Allyltriphenylstannane Ethynyltributylstannane
33,236-4 (Allyltriphenyltin; 2-Propenyl- 10 g 27,506-9 (Tributylstannylacetylene) 1g
triphenylstannane) 50 g CAS No. 994-89-8 5g
CAS No. 76-63-1 HCCSn(CH2CH2CH2CH3)3 FW 315.1
CH2:CHCH2Sn(C6H5)3 FW 391.1 95%
97% n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.476 (lit.)
Reagent employed in the preparation of allyllithium. J. bp. . . . . . . . . . . . . . . . . . . . . . . . 70 C/0.2 mm Hg (lit.)
Am. Chem. Soc. 1981, 103, 1969. Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 F
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74-76 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.089 g/mL (lit.)
R: 23/24/25-50/53 S: 26-27-28-45-60-61 R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
Bis[bis(trimethylsilyl)amino]tin(II) Hexabutyldistannane
40,961-8 CAS No. 59863-13-7 5 mL 25,112-7 (Hexabutylditin; Bis(tributyltin)) 10 g

C12H36N2Si4Sn FW 439.5 25 mL CAS No. 813-19-4 50 g
Reagent for the conversion of aldehydes (CH3CH2CH2CH2)3SnSn(CH2CH2CH2CH3)3

and ketones to N,N-dialkyleneamines. Synlett 1993, 131. FW 580.1
J. Org. Chem. 1992, 57, 5063. 95%
n20 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.512 (lit.)
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.514 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 112 C/0.05 mm Hg (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37-38 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.148 g/mL (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 F R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.136 g/mL (lit.)
R: 36/37/38 S: 26-36 Hexamethyldistannane
Di-N-butyldiphenyltin 28,802-0 (Hexamethylditin) 1g

CAS No. 661-69-8 5g
53,015-8 CAS No. 6452-61-5 50 mL (CH3)3SnSn(CH3)3 FW 327.6
Microelectronics
C20H28Sn FW 387.1 99%
97% Packaged in prescored ampules
liquid bp. . . . . . . . . . . . . . . . . . . . . . . 182 C/756 mm Hg (lit.)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.562 (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23-24 C (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 270 C/760 mm Hg (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 F
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F R: 26/27/28-50/53 S: 26-27-28-45-60-61
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.17 g/mL (lit.) CH CH
3 3
R: 23/24/25-36/37/38-50/53 S: 26-27-45-60-61 CH
3
Sn Sn CH
3
CH CH
3 3
(Dimethylamino)trimethyltin
42,928-7 (Pentamethylstannanamine) 1g
CAS No. 993-50-0 5g Hexaphenylditin
C5H15NSn FW 207.9
800.558.9196 (USA)
Technical Grade 59,532-2 CAS No. 1064-10-4 5g
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.463 (lit.) C36H30Sn FW 581.3 25 g
bp. . . . . . . . . . . . . . . . . . . . . . . 126 C/760 mm Hg (lit.) solid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.274 g/mL (lit.) Tetraallylstannane
R: 26/27/28-50/53 S: 26-27-28-45-60-61
27,144-6 (Tetraallyltin) 1g
Dimethylbis(pentafluorophenyl)tin CAS No. 7393-43-3 5g
(H2C:CHCH2)4Sn FW 283.0 25 g
56,613-6 (Bis(pentafluorophenyl)dimethyltin; 1g
97% Ordering/Pricing: www.sigma-aldrich.com
Dimethylbis(pentafluorophenyl)stannane; 5g n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.539 (lit.)
Bis(pentafluorophenyl)dimethylstannane) bp. . . . . . . . . . . . . . . . . . . . . . 69-70 C/1.5 mm Hg (lit.)
CAS No. 801-79-6 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 F
(C6F5)2Sn(CH3)2 FW 482.9 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.179 g/mL (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 259-260 C/760 mm Hg S: 23-24/25
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.4910
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F Tetrabutyltin
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.827 g/mL
References T600-8 (Tin tetrabutyl) 5g
Angew. Chem. Int. Ed. Engl. 39, 1312 (2000)
CAS No. 1461-25-2 100 g
R: 20/21/22-36/37/38 S: 26-36
(CH3CH2CH2CH2)4Sn FW 347.2 500 g
93%, Technical Grade
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.474 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . . 127-145 C/10 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .-97 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.057 g/mL (lit.)
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
324
Tetraethyltin Tributyl(1-ethoxyvinyl)tin
22,922-9 CAS No. 597-64-8 1g 27,512-3 CAS No. 97674-02-7 1g
Sn(C2H5)4 FW 235.0 5g C16H34OSn FW 361.2 5g
97% 25 g 97% 25 g
n20
D . . . . . . . . . . . . . . . . . . . . . 1.473 (lit.) Reagent employed in palladium-catalyzed
bp. . . . . . . . . . . . . . . . . . . . . . . 181 C/760 mm Hg (lit.)
coupling reactions with sulfoxides,1 a-haloethers,2 and
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -112 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128 F
chlorocyclobutenones.3 Also used to convert acid
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.187 g/mL (lit.) chlorides to a-oxygenated enones.4 (1) Tetrahedron Lett.
R: 26/27/28-50/53 S: 26-27-28-45-60-61 1993, 34, 2429. (2) ibid. 1992, 33, 4885. (3) J. Am. Chem.
Soc. 1992, 114, 1412. (4) Aldrichimica Acta 1984, 17, 75.
Tetrakis(diethylamino)tin n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.476 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . 85-86 C/0.1 mm Hg (lit.)

39,732-6 CAS No. 1066-78-0 1g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.069 g/mL (lit.)
C16H40N4Sn FW 407.2 5g
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
n20
D . . . . . . . . . . . . . . . . . . . . . . . 1.49 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . .110 C/0.5 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 F Tributyl(3-methyl-2-butenyl)tin
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.125 g/mL (lit.)
R: 10-14-23/24/25-41 S: 16-26-36/37/39-45 49,984-6 CAS No. 53911-92-5 1g
C17H36Sn FW 359.2 5g
Tetramethyltin 90%
liquid
48,139-4 (Tin tetramethyl) 10 mL n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.488 (lit.)
CAS No. 594-27-4 50 mL bp. . . . . . . . . . . . . . . . . . . . . . . 283 C/760 mm Hg (lit.)
Sn(CH3)4 FW 178.8 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.069 g/mL (lit.)
95%
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.441 (lit.)
Microelectronics
bp. . . . . . . . . . . . . . . . . . . . . . 74-75 C/760 mm Hg (lit.)

Tributyl(phenylethynyl)tin
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -54 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 F 34,035-9 CAS No. 3757-88-8 10 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.291 g/mL (lit.) C20H32Sn FW 391.2 50 g
R: 26/27/28-50/53 S: 26-27-28-45-60-61 95%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.532 (lit.)
Tetraphenyltin Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.116 g/mL (lit.)
T2,672-7 (Tin tetraphenyl) 5g R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
CAS No. 595-90-4 100 g
Sn(C6H5)4 FW 427.1 500 g Tributylphenylstannane
97%
37,460-1 (Phenyltributylstannane; Phenyltributyltin) 1g
bp. . . . . . . . . . . . . . . . . . . . . . >420 C/760 mm Hg (lit.) CAS No. 960-16-7 10 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224-227 (lit.) C6H5Sn(CH2CH2CH2CH3)3 FW 367.2
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 F 97%
R: 23/24/25-50/53 S: 26-27-28-45-60-61 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.516 (lit.)
bp. . . . . . . . . . . . . . . . . . . . 125-128 C/0.14 mm Hg (lit.)
Tetravinyltin Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.125 g/mL (lit.)
32,866-9 CAS No. 1112-56-7 1g R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
Sn(CH:CH2)4 FW 226.9 5g
97% 25 g Tributyl(1-propynyl)tin
n20
D . . . . . . . . . . . . . . . . . . . . . 1.501 (lit.)
bp. . . . . . . . . . . . . . . . . . . . 160-163 C/760 mm Hg (lit.) 49,986-2 CAS No. 64099-82-7 1g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 F C15H30Sn FW 329.1 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.246 g/mL (lit.) 95%
R: 10-23/24/25 S: 36/37/39-45 liquid
CH CH
2
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.483 (lit.)
H C C H Sn CH CH
2 2
bp. . . . . . . . . . . . . . . . . . . . . . . 277 C/760 mm Hg (lit.)
CH CH
2
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.082 g/mL (lit.)
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
325
Tributyltin hydride Bis(diethylamino)bis(dimethylamino)titanium

23,478-8 CAS No. 688-73-3 10 g 55,651-3 CAS No. 123798-13-0 1 mL
(C4H9)3SnH FW 291.1 50 g Ti(N(CH3)2)2(N(CH2CH3)2)2 FW 280.3 5 mL
97% 500 g 99.99%
50g and 500g units packaged under 2 kg bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 80 C/0.1 mm Hg
nitrogen in Sure/Seal bottles 20 kg Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 F
contains 0.05% BHT as stabilizer Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.931 g/mL
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.473 (lit.)
R: 11-14-34 S: 16-26-36/37/39-45
bp. . . . . . . . . . . . . . . . . . . . . . . . 80 C/0.4 mm Hg (lit.) CH
3
CH
3
N
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 F CH
3
CH CH
2 3
N Ti N
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.082 g/mL (lit.) CH CH CH
3 N 2 3
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61 CH CH CH CH
3 2 2 3
Tributyl(vinyl)stannane
27,143-8 (Vinyltributylstannane; 1g

Tributylstannylethylene) 5g Bis(pentamethylcyclopentadienyl)titanium dichloride
CAS No. 7486-35-3 25 g
CH2:CHSn(CH2CH2CH2CH3)3 FW 317.1 49,361-9 CAS No. 11136-36-0 1g
97% C20H30Cl2Ti FW 389.2 5g
n20 97%
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.478 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . 104-106 C/3.5 mm Hg (lit.) solid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 C (D) (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.085 g/mL (lit.) R: 20/21/22-36/37/38 S: 26-36
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
Tetrakis(diethylamino)titanium
Tricyclohexyltin Hydride
CAS No. 4419-47-0
46,068-0 CAS No. 6056-50-4 250 mg Ti[N(C2H5)2]4 FW 336.4
Microelectronics
HSn(C6H11)3 FW 369.2 1g R: 14-34 S: 16-26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
97%
bp. . . . . . . . . . . . . . . . . . . . . . . . . .129 C/0.05 mm Hg
46,986-6 99.999% 5g
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.5409 Precursor to titanium nitride (TiN) thin films 25 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 F by organometallic chemical vapor
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61 deposition (OMCVD). Thin Solid Films 1994, 85, 2471
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.537 (lit.)
Trimethyl(phenylethynyl)tin bp. . . . . . . . . . . . . . . . . . . . . . . .112 C/0.1 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -18 F
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
42,995-3 CAS No. 1199-95-7 1g
40,739-9 Technical Grade 1g
C11H14Sn FW 264.9 5g
5g
97%
R: 26/27/28-50/53 S: 26-27-28-45-60-61
800.558.9196 (USA)
Tetrakis(dimethylamino)titanium
Trimethyl(phenyl)tin 46,985-8 CAS No. 3275-24-9 5g
Ti(N(CH3)2)4 FW 224.2 25 g
36,633-1 CAS No. 934-56-5 1g
99.999%
C9H14Sn FW 240.9 5g
Packaged in ampules
98%
n20 Precursor to titanium nitride (TiN) thin films by
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5357 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . . 88 C/16 mm Hg (lit.) organometallic chemical vapor deposition (OMCVD).
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -51 C (lit.) Chem. Mater. 1996, 8, 2712.
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 F bp. . . . . . . . . . . . . . . . . . . . . . . . 50 C/0.5 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.327 g/mL (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -22 F Ordering/Pricing: www.sigma-aldrich.com
R: 26/27/28-50/53 S: 26-27-28-45-60-61 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.947 g/mL (lit.)
R: 11-14-34 S: 16-26-36/37/39-45
Triphenyltin hydride CH
3
N
CH
3
CH CH
3 3
N Ti N
24,477-5 CAS No. 892-20-6 5g CH
3
CH
3
N
C18H16Sn FW 351.0 25 g CH
3
CH
3
n20
D . . . . . . . . . . . . . . . . . . . . . 1.632 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . 163-165 C/0.3 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.374 g/mL (lit.)
R: 23/24/25-50/53 S: 26-27-28-45-60-61
Titanium
Bis(tert-butylcyclopentadienyl)titanium dichloride
48,362-1 CAS No. 79269-71-9 1g
C18H20Cl2Ti FW 355.1 5g
97%
326
Metal-Organic Precursors: Titanium
(Continuation of) Bis(cyclopentadienyl)tungsten dihydride

Tetrakis(dimethylamino)titanium
51,080-7 CAS No. 1271-33-6 1g
C10H4W FW 308.0
97%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
H W H
Bis(isopropylcyclopentadienyl)tungsten dihydride
51,255-9 CAS No. 64561-25-7 2.5 g
(C5H4CH(CH3)2)2WH2 FW 394.2
Packaged in ampules
solid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.6 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 230 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 155 C (dec.) (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 F
R: 11 S: 16
CH
3
CHCH
3
H W H
CHCH
1 3
Microelectronics
H-NMR spectrum of Aldrich product 46,985-8, lot 95217AD CH

3
Tetrakis(ethylmethylamino)titanium
47,353-7 CAS No. 308103-54-0 5g Cyclopentadienyltungsten tricarbonyl, dimer
Ti(NCH3C2H5)4 FW 280.3 25 g
30,233-3 (bis(cyclopentadienyl)ditungsten 1g
hexacarbonyl) 5g
Precursor to titanium nitride (TiN) thin films by
CAS No. 12566-66-4
organometallic chemical vapor deposition (OMCVD).
C16H2O6W2 FW 657.9
Chem. Mater. 1997, 9, 76. mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258 C (D) (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . 80 C/0.1 mm Hg (lit.)
R: 20/21/22 S: 36
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.923 g/mL (lit.)
R: 11-14-34 S: 16-26-36/37/39-45 W(CO)
3
CH CH CH W(CO)
3 2 3 3
N
CH CH CH
3 2 3
N Ti N
CH CH CH
3 2 N 3
CH CH CH
3 2 3
Cyclopentadienyltungsten tricarbonyl hydride
Trimethoxy(pentamethylcyclopentadienyl)titanium(IV) 51,123-4 (tricarbonyl(cyclopentadienyl)hydridotung- 1g

sten) 5g
47,957-8 CAS No. 123927-75-3 1g CAS No. 12128-26-6
C13H24O3Ti FW 276.2 5g C8H2O3W FW 329.9
98%
solid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 F
Tungsten R: 11 S: 16
Bis(cyclopentadienyl)tungsten dichloride (Propylcyclopentadienyl)tungsten tricarbonyl dimer

47,521-1 CAS No. 12184-26-8 1g 52,668-1 CAS No. 312739-82-5 1g
C10H2Cl2W FW 376.9 C22H16O6W2 FW 744.0 5g
97% 97%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171 C (D) (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
327
Metal-Organic Precursors: Tungsten
Tetracarbonyl(1,5-cyclooctadiene)tungsten Tungsten(0) pentacarbonyl-N-pentylisonitrile

51,128-5 CAS No. 12129-70-3 5g 53,556-7 CAS No. 347145-09-9 5 mL
C12H8O4W FW 400.0 C11H11NO5W FW 421.0
solid 99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 155-161 C (lit.) liquid
CO Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
CO
W Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.652 g/mL
CO
CO R: 23 S: 36/37/39-45
CO
OC CO
W
OC C N CH (CH ) CH
CO 2 23 3
Triamminetungsten tricarbonyl
54,110-9 CAS No. 58204-42-5 1g
C3H9N3O3W FW 319.0 5g
Vanadium

solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 227-231 C (lit.)
R: 14 S: 7 Bis(cyclopentadienyl)N,N-bis(trimethylsilyl)amidevana-
dium
Tricarbonyl(1,3,5-cycloheptatriene)tungsten
56,709-4 CAS No. 57603-39-1 1g
51,129-3 CAS No. 12128-81-3 1g ((CH3)3Si)2NV(C5H5)2 FW 341.5 5g
C10H2O3W FW 354.0
96% Bis(cyclopentadienyl)vanadium
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 C (D) (lit.) 37,915-8 CAS No. 1277-47-0 250 mg
V(C5H5) FW 181.1 1g
mp . . . . . . . . . . . . . . . 165-167 C (lit.)
Microelectronics
R: 11-23/24/25-36/37/38 S: 16-26-28-36/37/39-45
W
OC CO
CO
V
Tricarbonyl(mesitylene)tungsten
32,760-3 CAS No. 12129-69-0 500 mg
C6H3(CH3)3W(CO)3 FW 385.0 2.5 g Bis(ethylcyclopentadienyl)vanadium
98%
R: 20/21/22-36/37/38 S: 26-37/39 51,061-0 CAS No. 55940-04-0 1g
C14H12V FW 231.2 5g
Tungsten hexacarbonyl liquid
800.558.9196 (USA)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.12 g/mL (lit.)
CAS No. 14040-11-0
W(CO)6 FW 351.9 Bis(indenyl)vanadium
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.65 g/mL (lit.) 56,676-4 CAS No. 101834-69-9 1g
R: 11-23 S: 16-36/37/39-45 (C9H7)2V FW 281.2 5g
OC CO mp . . . . . . . . . . . . . . . . . . . . .67 C (Dec.)
OC W CO
OC CO
Bis(pentamethylcyclopentadienyl)vanadium (II)
57,437-6 CAS No. 74507-60-1 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . C20H30V FW 321.4 5g
47,295-6 99.9+%, Purified by sublimation 5g solid
25 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36
24,143-1 97% 10 g
Vapor pressure. . . . . . . . 1.2 mm Hg ( 67 C) Bromobis(indenyl)vanadium (III)
Mo. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <1%
57,432-5 CAS No. 196815-75-5 1g
C18H14BrV FW 361.1 5g
97%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 C (dec.)
Chlorobis(indenyl)vanadium (III)
57,431-7 CAS No. 480445-37-2 1g
C18H14ClV FW 316.7 5g
mp . . . . . . . . . . . . . . . . . . . . . . . >300 C
328
Metal-Organic Precursors: Vanadium
Iodobis(indenyl)vandium(III) Diethylzinc
57,433-3 CAS No. 108150-19-2 1g (Zincdiethyl)
C18H14IV FW 408.1 5g CAS No. 557-20-0
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C 25,678-1 Diethylzinc 100 g
R: 23/24/25-36/37/38 S: 26-36/37/39-45 (C2H5)2Zn FW 123.5
Packaged under nitrogen in Sure/Pac metal cylinders
Tetrakis(neopentyl)vandadium n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.498 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 117 C/760 mm Hg (lit.)
56,704-3 CAS No. 480444-86-8 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -28 C (lit.)
((CH3)3CCH2)4C FW 335.5 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.205 g/mL (lit.)
R: 14-17-34-50/53 S: 16-43-45-60-61
Ytterbium
Diethylzinc solution
Tris[N,N-bis(trimethylsilyl)amide]ytterbium(III) (C2H5)2Zn FW 123.5
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
54,787-5 CAS No. 41836-28-6 1g 40,602-3 1.0 M in heptane 100 mL
Y(N(Si(CH3)2)3 FW 570.1 bp. . . . . . . . . . . . 98 C/760 mm Hg (lit.) 800 mL
98% Fp. . . . . . . . . . . . . . . . . . . . . . . 12 F
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161-166 C Density. . . . . . . . . . . . . . . . . . . . . . . . . . 0.74 g/mL (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 F R: 11-14-20/21/22-34 S: 16-26-36/37/39-45
R: 11-14/15-34 S: 16-26-36/37/39-43-45-7/8 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
29,611-2 1.0 M in hexanes 100 mL
Tris(cyclopentadienyl)ytterbium Fp. . . . . . . . . . . . . . . . . . . . . . -10 F 800 mL
Density. . . . . . . . . . . . . 0.726 g/mL (lit.)
49,243-4 CAS No. 1295-20-1 1g R: 11-14/15-34-48/20-50/53-62-65-67 S: 9-16-29-33-36/37-43-
Yb(C5H5)3 FW 368.3 5g 60-61-62

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
99.9%
Microelectronics
22,080-9 15 wt. % in toluene 100 g

R: 11-14/15 S: 43-7/8 Fp. . . . . . . . . . . . . . . . . . . . . . . . 45 F 800 g
Density. . . . . . . . . . . . . . .0.915 g/mL (lit.)
R: 11-14/15-20-34-51/53 S: 16-26-33-36/37/39-43-45-60-61
Yttrium
Dimethylzinc solution
Tris(butylcyclopentadienyl)yttrium
(Zincdimethyl)
52,452-2 CAS No. 312739-77-8 5 mL CAS No. 544-97-8
Y(C5H4CH2(CH2)2CH3)3 FW 452.5 (CH3)2Zn FW 95.46
99.9% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged in ampules 41,724-6 1.0 M in heptane 50 mL
liquid Packaged under argon in Sure/Seal
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5685 (lit.) bottles
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135 F bp. . . . . . . . . . . . . . . . . . . . . . 44-46 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.11 g/mL (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 F
R: 17 S: 16-36/37/39 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.724 g/mL (lit.)
R R R: 11-14-34-50/53-65-67 S: 16-26-29-33-36/37/39-43-45-60-
61-62
Y
R = CH (CH ) CH
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
2 22 3
36,440-1 2.0 M in toluene 50 mL
R
Packaged under argon in poly-coated 500 mL
Sure/Seal bottles
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.931 g/mL (lit.)
Tris(cyclopentadienyl)yttrium R: 15-17-23/24/25-34 S: 16-26-27-36/37/39-45
49,196-9 CAS No. 1294-07-1 1g Diphenylzinc

Y(C5H5)3 FW 284.2 5g
99.9% 48,107-6 CAS No. 1078-58-6 1g
R: 11-14/15 S: 43-7/8 C12H10Zn FW 219.6 5g
92%
solid
Zinc benzene. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <7.5%
bp. . . . . . . . . . . . . . . . . . . . 280-285 C/760 mm Hg (lit.)
Bis(pentafluorophenyl)zinc mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 102-106 C (lit.)
R: 45-37/38-41-48/23/24/25 S: 53-22-26-36/37/39-45
56,674-8 CAS No. 1799-90-2 1g
(C6F5)2Zn FW 399.5 5g
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >100-105 C
329
Metal-Organic Precursors: Zirconium
Bis(cyclopentadienyl)dimethylzirconium Tetrakis(diethylamino)zirconium
48,365-6 CAS No. 12636-72-5 1g 45,315-3 CAS No. 13801-49-5 5 mL
(C5H5)2Zn(CH3)2 FW 251.5 5g Zr(N(C2H5)2)4 FW 379.7 25 mL
97% electronic grade, 99.99%
Packaged in ampules n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.51 (lit.)
solid bp. . . . . . . . . . . . . . . . . . . . . . . 128 C/0.05 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 170 C (dec.) (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.026 g/mL (lit.)
CH R: 11-14-36/37/38 S: 16-26-36
3
Zr
CH CH CH CH
3 2 2 3
CH N
3 CH CH CH CH
3 2 2 3
N Zr N
CH CH CH CH
3 2 N 2 3
CH CH CH CH
3 2 2 3
Bis(cyclopentadienyl)zirconium, dihydride

54,069-2 (zirconcene dihydride) 1g
CAS No. 37342-98-6 5g Tetrakis(dimethylamino)zirconium
C10H4Zr FW 215.4
solid CAS No. 19756-04-8
R: 11-15-34 S: 16-26-27-36/37/39 [(CH3)2]4Zr FW 267.5
solid
H Zr H
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57-60 C
R: 11-36/37/38 S: 16-26-36
CH CH
3 3
N
CH CH
3 3
N Zr N
CH CH
3 N 3
CH CH
3 3
Microelectronics
Bis(indenyl)dimethylzirconium
48,366-4 CAS No. 49596-04-5 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
C20H16Zr FW 347.6 5g 57,921-1 99.99%, electronic grade 1g
solid 5g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .106 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
44,566-5 crystals 5g
mp . . . . . . . . . . . . . . . . . . . . 57-60 C (lit.)
CH Zr CH
3 3
Tetrakis(2,2-dimethylpropyl)zirconium
53,669-5 CAS No. 38010-72-9 5g
C20H44Zr FW 375.8
solid
800.558.9196 (USA)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 111-112 C (lit.)
S: 22-24/25
Dimethylbis(pentamethylcyclopentadienyl)zirconium
51,079-3 CAS No. 67108-80-9 5g Tetrakis(ethylmethylamino)zirconium
C22H36Zr FW 391.7
55,313-1 CAS No. 175923-04-3 5g
rac-Ethylenebis(4,5,6-tetrahydro-1-indenyl)dimethylzirco- Zr(NCH3C2H5)4 FW 323.6 25 g
99+% as chemical purity
nium(IV) liquid
bp. . . . . . . . . . . . . . . . . . . . . . . . 81 C/0.1 mm Hg (lit.)
53,211-8 CAS No. 112243-80-8 100 mg Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 F
C22H32Zr FW 387.7 500 mg Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.049 g/mL (lit.)
solid R: 11-14-34 S: 16-26-36/37/39-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 150-155 C (lit.) CH CH CH
3 2 3
R: 36/37/38 S: 26-36 CH
N
CH CH
3 2 3
N Zr N
CH CH CH
Tetrabenzylzirconium(IV) 3 2 N 3
CH CH CH
3 2 3
59,245-5 CAS No. 24356-01-2 1g
C28H28Zr FW 455.7 5g
330
Polymeric Precursors for SiC Films & Fibers
Polyacenaphthylene 43,370-5 evaporation slug, diam. 6.3 mm · 5g

length 6.3 mm, 99.999% 25 g
18,125-0 CAS No. 25036-01-5 5g Weight of one slug. . . . . . . . . . . . . . ~0.5 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
(C12H8)n 10 g 51,858-1 flakes, 0.6 mm, 99.9% 500 g
Average Mw ~5,000-10,000, powder . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214 C 51,857-3 flakes, 1 mm, 99.99% 500 g
CH CH
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,659-0 foil, thickness 2.0 mm, 99.999% 13.6 g
13.6 g of 50 · 50 mm 54.4 g
54.4 g of 100 · 100 mm
n . . . . . . . . . . . . . . . . . . . . . . . . . . . .
27.2 g of 100 · 100 mm 27.2 g
6.8 g of 50 · 50 mm
Poly(carbodihydridosilane) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,106-8 CAS No. 74056-94-3 1g 13.6 g of 100 · 100 mm 13.6 g
(CH4Si)n 5g 3.4 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 10 S: 16
1.7 g of 50 · 50 mm 6.8 g
Polycarbomethylsilane 6.8 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
(Poly[(methylsilylene)methylene]; Polycarbosilane) 26,658-2 foil, thickness 1.0 mm, 99.99+% 6.8 g
CAS No. 62306-27-8 27.2 g of 100 · 100 mm 27.2 g
(C2H6Si)n 6.8 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Polymeric precursor of SiC ceramics.
32,686-0 foil, thickness 0.13 mm, 99.99+% 900 mg
Ceramic coating from polymer melt or solution. 3.6 g of 100 · 100 mm 3.6 g
900 mg of 50 · 50 mm
CH
3 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Si CH
2 32,692-5 ingot, 99.997% 100 g
Microelectronics
H n 500 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
51,860-3 needles, length ~4 mm, 99.9% 1 kg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32,694-1 pellets, 3-8 mesh, 99.999+% 5g
52,258-9 Average Mw ~800, electronic grade 25 g 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~79-84 C (lit.)
33,878-8 pellets, 3-8 mesh, 99.99+% 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
52,259-7 Average Mw ~1,400, electronic grade 25 g 20,258-4 powder, -200 mesh, 99.95+% 10 g
R: 15-17 S: 43-7/8 50 g
solid . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) 26,656-6 rod, diam. 12.7 mm, 99.999% 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
125 g of 5 of 75 mm 125 g
52,260-0 Average Mw ~2,000, electronic grade 25 g
25 g of 75 mm
solid . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) 32,691-7 rod, diam. 6.35 mm, 99.999% 4.3 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 1.1 g/mL (lit.) 17.2 g of 200 mm 17.2 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.3 g of 50 mm
52,261-9 Average Mw ~3,500, electronic grade 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
solid 20,257-6 rod, diam. 3.0 mm, length 100 mm, 10 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) 99.999% 50 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 1.1 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CVD of Nonmetals See: Books Page 496 26,652-3 shot, 5-15 mm, 99.9% 250 g
1 kg
The Chemistry of Metal CVD See: Books Page 498 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,655-8 wire, diam. 1.0 mm, 99.999% 10.5 g
10.5 g of 5 m 52.5 g
52.5 g of 25 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
High Purity Metals/Elements 32,688-7 wire, diam. 0.58 mm, 99.99+% 7g
35 g of 50 m 35 g
7 g of 10 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Metals 32,689-5 wire, diam. 0.25 mm, 99.99+% 2.6 g
13 g of 100 m 13 g
Aluminum 2.6 g of 20 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7429-90-5 32,690-9 wire, diam. 0.127 mm, 99.99+% 320 mg
Al FW 26.98 1.6 g of 50 m 1.6 g
320 mg of 10 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
42,480-3 discs, 0.5-1.7 mm, 99.99+% 5g 32,687-9 wire, diam. 1.5 mm, 99.99% 4.8 g
25 g 24 g of 5 m 24 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.8 g of 1 m
43,371-3 evaporation slug, diam. 6.3 mm · 5.3 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
length 1.2 cm, 99.999% 26.6 g 46,035-4 wire, diam. 1.0 mm, 99.9% 21 g
105 g of 50 m 105 g
21 g of 10 m
331
High Purity Metals/Elements
Metals
Antimony 20,281-9 powder, -100 mesh, 99.999+% 20 g

Vapor pressure. . . . . . .<0.1 mm Hg ( 20 C) 100 g
CAS No. 7440-36-0 mp . . . . . . . . . . . . . . . . . . . 271 C (lit.)
Sb FW 121.8 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 9.8 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 630 C (lit.) R: 11 S: 16
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.69 g/mL 25 C (lit.)
26,400-8 powder, -100 mesh, 99.99+% 25 g
R: 51/53 S: 60
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor pressure. . . . . . .<0.1 mm Hg ( 20 C) 100 g
20,263-0 pieces, 99.999% 10 g R: 11 S: 16
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . 630.74 C (lit.) 50 g
45,238-6 shot, 1-2 mm, 99.999% 10 g
Density. . . . . . . . . . . . . . . 6.684 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . 271 C (lit.)
26,484-9 powder, -100 mesh, 99.995% 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 9.8 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,547-0 shot, 4-30 mesh 100 g
26,483-0 shot, 99.9998%, 4-20 mesh 10 g tear-shaped 500 g
50 g Vapor pressure. . . . . . . <0.1 mm Hg ( 20 C)

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,234-3 shot, 1-2 mm, 99.999%, low oxide 10 g Boron
Applied in the solid state synthesis of a Zintl CAS No. 7440-42-8
phase, SrSn3Sb4, with an anionic channel framework of B FW 10.81
30-membered rings. Chow, D.T. et al. Inorg. Chem.1997, R: 11-22 S: 16
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
36, 3750. 26,661-2 crystalline, 99.999% 500 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 33,244-5 powder, (submicron), 99.995% 5g
26,660-4 shot, 1-2 mm, 99.999% 25 g
amorphous 25 g
100 g
Cadmium
Arsenic
Microelectronics
CAS No. 7440-43-9
CAS No. 7440-38-2
Cd FW 112.4
As FW 74.92 R: 45-20/21/22 S: 53-36-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 817 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . 5.727 g/mL 25 C (lit.) 26,544-6 foil, thickness 1.5 mm, 99.9998% 8g
R: 23/25 S: 20/21-28-45 32 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,265-7 pieces, 99.9998% 5g 34,857-0 foil, thickness 0.25 mm, 99.99+% 5.5 g
OSHA-regulated carcinogen see 29 CFR 25 g Density. . . . . . . . . . . . . . . . 8.64 g/mL (lit.) 22 g
Part 1910.1018 22 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5 g of 50 · 50 mm
26,796-1 powder, 99.999+% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
50 g 26,541-1 foil, thickness 0.5 mm, 99.99+% 11 g
800.558.9196 (USA)
11 g of 50 · 50 mm 44 g
Barium 44 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7440-39-3 34,858-9 foil, thickness 0.1 mm, 99.99+% 2.2 g
Density. . . . . . . . . . . . . . . . 8.64 g/mL (lit.) 8.8 g
Ba FW 137.3
2.2 g of 50 · 50 mm
Critical for the synthesis of pure Ba21M2O5Hx (M = Ge, SI, Ga, 8.8 g of 100 · 100 mm
In, Tl) suboxide Zintl phases.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 46,626-3 pellets, 6.35-6.35 mm, 99.999% 15.7 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3.6 g/mL (lit.) 50.2 g
R: 11-14-31-36/37/38 S: 16-26-36/37-43 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,545-4 rod, diam. 4.0 mm, 99.999% 10 g Ordering/Pricing: www.sigma-aldrich.com
47,471-1 Purified by distillation, dendritic 5g 10 g of 100 mm
pieces, 99.99% 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . 725 C (lit.) 34,859-7 rod, diam. 2.0 mm, 99.999% 2.5 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
44,188-0 Purified by distillation, dendritic 5g 20,288-6 shot, 3 mm, 99.999% 50 g
pieces, 99.9% 25 g mp . . . . . . . . . . . . . . . . . . . 320.9 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 8.642 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Bismuth 26,538-1 stick, thickness ~12.7 mm, 99.98% 115 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7440-69-9 38,538-7 stick, thickness 10 mm, 99.999+% 35 g
Bi FW 209.0 Density. . . . . . . . . . . . . . . 8.65 g/mL (lit.) 140 g
140 g of 200 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 g of 50 mm
20,283-5 pieces, elongated, 99.999% 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor pressure. . . . . . .<0.1 mm Hg ( 20 C) 250 g 26,540-3 wire, diam. 1.0 mm, 99.9998% 6.8 g
mp . . . . . . . . . . . . . . . . . . . 271 C (lit.) Density. . . . . . . . . . . . . . . . 8.64 g/mL (lit.) 34 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 9.8 g/mL (lit.) 34 g of 500 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.8 g of 100 cm
55,613-0 pieces, 1-12 mm, 99.999% 250 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,860-0 wire, diam. 1.0 mm, 99.999% 6.8 g
Density. . . . . . . . . . . . . . . . 8.64 g/mL (lit.) 34 g
34 g of 500 cm
6.8 g of 100 cm
332
Metals
(Continuation of) 35,689-1 foil, thickness 1.0 mm, 99.95% 5.6 g

22.4 g of 50 · 50 mm 22.4 g
Cadmium 5.6 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,861-9 wire, diam. 0.5 mm, 99.999% 860 mg
4.3 g of 250 cm
4.3 g Density. . . . . . . . . . . . . . . 8.92 g/mL (lit.) 11.2 g
860 mg of 50 cm
11.2 g of 50 · 50 mm
2.8 g of 25 · 25 mm
Calcium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
44,187-2 CAS No. 7440-70-2 5g 1.4 g of 25 · 25 mm 5.6 g
Ca FW 40.08 25 g 5.6 g of 50 · 50 mm
Purified by distillation, dendritic . . . . . . . . . . . . . . . . . . . . . . . . . . . .
pieces, 99.99% 35,686-7 foil, thickness 0.1 mm, 99.95% 2.2 g
Precursor to Ca8Al3 and Ca13Al14; intermetallics with new 8.8 g

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
metallic Zintl phases.7 20,307-6 powder, 99.995% 5g
Packaged under argon in ampules Employed in the synthesis of a metal-rich 25 g
Solid state synthesis with Mg and Sn resulted in a new layered telluride, TaCo2Te2, which
phase, Ca6.2Mg3.8Sn7, which has an unprecedented type possesses ideal characteristics for photovoltaic
of tin chain composed of square-planar tin units. Ganguli, applications, for surface scanning studies, and which may
A.K. et al. J. Am. Chem. Soc. 1998, 120, 1223. give clean and atomically flat surfaces. Neuhasen, J. et al.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 850 C (lit.)
Chem. Mater. 1998, 10, 3870.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.54 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 8.9 g/mL (lit.)
References
Huang, B, Corbett, J.D., Inorg. Chem. 37, 5827 (1998) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 15 S: 8-24/25-43 26,664-7 powder, -100 mesh, 99.9+% 50 g
Cerium See: Metals Page 185 Employed in the synthesis of a metal-rich 250 g
layered telluride, TaCo2Te2, which
Cesium possesses ideal characteristics for photovoltaic

applications, for surface scanning studies, and which may
Microelectronics
23,924-0 CAS No. 7440-46-2 1g give clean and atomically flat surfaces. Neuhasen, J. et al.
Cs FW 132.9 5g Chem. Mater. 1998, 10, 3870.
ingot, 99.95+% Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 8.9 g/mL (lit.)
Packaged in ampules . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,670-1 wire, diam. 1.0 mm, 99.995% 1.4 g
bp. . . . . . . . . . . . . . . . . . . . . . . 705 C/760 mm Hg (lit.)
1.4 g of 20 cm
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28.5 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.873 g/mL (lit.) 28,117-4 wire, diam. 0.5 mm, 99.995% 340 mg
R: 11-14/15-34 S: 8-16-26-36/37/39-43-45 1.7 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Chromium 52,345-3 wire, diam. 0.25 mm, 99.995% 435 mg
bp. . . . . . . . . . 2900 C/760 mm Hg (lit.) 2.2 g
CAS No. 7440-47-3 Density. . . . . . . . . . . . . . . 8.9 g/mL (lit.)
Cr FW 52.00 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38-43 S: 26-28-36 52,344-5 wire, diam. 0.1 mm, 99.995% 70 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . bp. . . . . . . . . . 2870 C/760 mm Hg (lit.) 350 mg
37,484-9 chips, thickness ~1 mm, 99.995% 50 g Density. . . . . . . . . . . . . . . 8.9 g/mL (lit.)
Density. . . . . . . . . . . . . . . 7.14 g/mL (lit.) 250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 35,705-7 wire, diam. 2.0 mm, 99.9+% 1.4 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,956-3 chunks, 99.99+% 20 g
Density. . . . . . . . . . . . . . . . 7.2 g/mL (lit.) 100 g
35,703-0 wire, diam. 0.5 mm, 99.9+% 900 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,666-3 rod, diam. 5.0 mm, 99.998% 3.4 g
26,628-0 crystallite, 99.996% 10 g 25.5 g of 150 mm
Density. . . . . . . . . . . . . . . . 7.14 g/mL (lit.)
8.5 g
3.4 g of 20 mm 25.5 g
Particle size. . . . . . . . . . . . . . . . . . . . . . . . . . . 1-15 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.5 g of 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
54,513-9 pieces, 99.99% 10 g 39,881-0 rod, diam. 5.0 mm, 99.95% 8.5 g
Density. . . . . . . . . . . . . . . . . 7.2 g/mL (lit.) 50 g
Density. . . . . . . . . . . . . . . 8.92 g/mL (lit.) 25.5 g
25.5 g of 150 mm
Cobalt 8.5 g of 50 mm
CAS No. 7440-48-4 Copper

Co FW 58.93
R: 42/43-53 S: 22-24-37-61 CAS No. 7440-50-8
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cu FW 63.55
26,669-8 foil, thickness 1.0 mm, 99.99+% 5.6 g
22.4 g of 50 · 50 mm 22.4 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.6 g of 25 · 25 mm 32,644-5 bar, random sizes, 99.999+% 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,638-0 foil, thickness 0.1 mm, 99.99+% 550 mg 250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . 8.92 g/mL (lit.) 2.2 g
43,368-3 evaporation slug, diam. 6.3 mm · 6.8 g
2.2 g of 50 · 50 mm
550 mg of 25 · 25 mm
length 6.3 mm, 99.999%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,667-1 foil, thickness 0.25 mm, 99.99+% 1.4 g 43,369-1 evaporation slug, diam. 6.3 mm · 6.8 g
1.4 g of 25 · 25 mm 5.6 g length 1.2 cm, 99.999%
5.6 g of 50 · 50 mm
333
Metals
36,941-1 foil, thickness 2.0 mm, 99.999% 11 g 36,532-7 rod, diam. 11 mm, 99.9999% 21.5 g
44 g Density. . . . . . . . . . . . . . . 8.94 g/mL (lit.) 172 g
176 g 172 g of 200 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 21.5 g of 25 mm
26,674-4 foil, thickness 1.0 mm, 99.999% 11 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11 g of 25 · 50 mm 88 g 26,485-7 rod, diam. 19 mm, 99.9998% 56 g
88 g of 100 · 100 mm 225 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,673-6 foil, thickness 0.5 mm, 99.999% 11 g 32,643-7 rod, diam. 3.1 mm, 99.999% 10 g
11 g of 50 · 50 mm 44 g Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.)
44 g of 100 · 100 mm 10 g of 1 · 150 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,639-9 foil, thickness 0.25 mm, 99.999% 5.5 g 26,610-8 rod, diam. 6.35 mm, 99.998% 28 g
Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.) 22 g Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.)
22 g of 100 · 100 mm 28 g of 100 mm
5.5 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 25,417-7 shot, 2-4 mm, 99.9995% 25 g
26,672-8 foil, thickness 0.1 mm, 99.999% 2.2 g Density. . . . . . . . . . . . . . . 8.94 g/mL (lit.) 125 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .

2.2 g of 50 · 50 mm 8.8 g
8.8 g of 100 · 100 mm 32,648-8 shot, 2-8 mm, 99.99+% 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . 8.94 g/mL (lit.) 250 g
28,991-4 foil, thickness 0.05 mm, 99.999% 1.1 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.1 g of 50 · 50 mm 34,922-4 wire, diam. 2.0 mm, 99.999% 7g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 8.96 g/mL (lit.) 42 g
32,640-2 foil, thickness 0.025 mm, 99.999% 2.2 g 42 g of 150 cm
Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.) 22 g 7 g of 25 cm
2.2 g of 100 · 100 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
22 g of 100 · 1000 mm 26,612-4 wire, diam. 1.0 mm, 99.999% 7g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.) 35 g
34,915-1 foil, thickness 0.5 mm, 99.98% 11 g 35 g of 500 cm
Density. . . . . . . . . . . . . . . . 8.96 g/mL (lit.) 99 g 7 g of 100 cm
11 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
99 g of 150 · 150 mm 32,641-0 wire, diam. 0.64 mm, 99.999% 5.8 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.)
34,917-8 foil, thickness 0.25 mm, 99.98% 5.5 g 5.8 g of 2 m
49.5 g of 150 · 150 mm 49.5 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.5 g of 50 · 50 mm 34,923-2 wire, diam. 0.5 mm, 99.999% 8.8 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . 8.96 g/mL (lit.) 35.2 g
34,918-6 foil, thickness 0.1 mm, 99.98% 2.2 g 35.2 g of 20 m
Density. . . . . . . . . . . . . . . 8.96 g/mL (lit.) 19.8 g 8.8 g of 5 m
19.8 g of 150 · 150 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 8.94 g/mL (lit.) 22 g
34,919-4 foil, thickness 0.05 mm, 99.98% 1.1 g 22 g of 50 m
Density. . . . . . . . . . . . . . . . 8.96 g/mL (lit.) 9.9 g 4.4 g of 10 m
1.1 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
9.9 g of 150 · 150 mm 26,611-6 wire, diam. 0.1 mm, 99.999% 700 mg
800.558.9196 (USA)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . 8.94 g/mL (lit.) 7g
34,920-8 foil, thickness 0.025 mm, 99.98% 5g 7 g of 100 m
Density. . . . . . . . . . . . . . . . 8.96 g/mL (lit.) 33 g 700 mg of 10 m
33 g of 150 · 1000 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5 g of 150 · 150 mm 34,921-6 wire, diam. 1.0 mm, 99.9+% 70 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . 8.96 g/mL (lit.) 350 g
34,914-3 foil, thickness 1.0 mm, 99.98% 22 g 350 g of 50 m
Density. . . . . . . . . . . . . . . 8.96 g/mL (lit.) 198 g 70 g of 10 m
198 g of 150 · 150 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
22 g of 50 · 50 mm 26,826-7 wire, diam. 0.5 mm, 99.9% 90 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 450 g of 250 m 450 g
31,140-5 granules, 99.90+%, ACS reagent, 10- 100 g
90 g of 50 m
40 mesh 500 g
‡99.90% Dysprosium
P. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
insol. dil. HNO3. . . . . . . . . . . . . . . . . . . . . . . . . £0.02% CAS No. 7429-91-6
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 8.94 g/mL (lit.) Dy FW 162.5
Ag. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
As. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm 26,302-8 chips, 99.9% 5g
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005% S: 22-24/25
Mn. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Pb. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005% 26,106-8 foil, 99.9%, thickness 0.25 mm 1.3 g
Sb and Sn. . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% S: 22-24/25 5.2 g
R: 11 S: 16 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,107-6 ingot, 99.9% 10 g
51,890-5 plate, thickness 6.3 mm, 99.999% 26 g S: 22-24/25 50 g
26 g of 20·20 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,303-6 powder, 40 mesh, 99.9% 10 g
20,312-2 powder, 99.999% 10 g R: 11 S: 16-33-36/37/39
Density. . . . . . . . . . . . . . . . 8.92 g/mL (lit.) 50 g
R: 11 S: 16
334
Metals
Erbium 20,334-3 chips, 3 mm, 99.999% 1g

R: 36/37/38 S: 26-36/39 5g
CAS No. 7440-52-0 25 g
Er FW 167.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32,739-5 powder, -100 mesh, 99.999+% 5g
26,305-2 chips, 99.9% 10 g Density. . . . . . . . . . . . . . . . 5.32 g/mL (lit.) 25 g
Density. . . . . . . . . . . . . . . 9.062 g/mL (lit.) 50 g R: 36/37/38 S: 16-26-33-36/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,108-4 ingot, 99.9% 10 g 20,335-1 powder, -100 mesh, 99.99+% 10 g
50 g R: 36/37/38 S: 16-26-33-36/39 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,304-4 powder, 99.9%, -40 mesh 5g Gold
R: 11 S: 43
CAS No. 7440-57-5

Europium Au FW 197.0
CAS No. 7440-53-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Eu FW 152.0 37,316-8 evaporation slug, diam. 0.6 cm · 6.4 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . length 1.2 cm, 99.99%
45,796-5 chips in mineral oil, 99.9% 1g Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . .6.4 g
mp . . . . . . . . . . . . . . . . . . . . . 822 C (lit.) 5 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . 5.24 g/mL (lit.) 37,317-6 evaporation slug, diam. 0.6 cm · 3.9 g
R: 14/15-17 S: 43-7/8 length 0.6 cm, 99.99%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . .3.9 g
26,110-6 Purified by distillation, 99.9% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,318-4 evaporation slug, diam. 0.3 cm · 800 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . length 0.6 cm, 99.99% 3.2 g
26,109-2 ingot, 99.9% 1g Weight of one slug. . . . . . . . . . . 800 mg
Packaged under oil 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 14/15-17 S: 43-7/8 26,582-9 foil, thickness 0.5 mm, 99.99% 6g
24 g of 50 · 50 mm 24 g
Microelectronics
Gadolinium 6 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7440-54-2 32,651-8 foil, thickness 0.25 mm, 99.99% 3g
12 g of 50 · 50 mm 12 g
Gd FW 157.3
3 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,308-7 chips, 99.9% 10 g
1.5 g of 25 · 25 mm 6g
Density. . . . . . . . . . . . . . . 7.886 g/mL (lit.) 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,111-4 ingot, 99.9% 10 g 26,581-0 foil, thickness 0.1 mm, 99.99% 1.2 g
50 g 1.2 g of 25 · 25 mm 4.8 g
4.8 g of 50 · 50 mm
Gallium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,927-5 foil, thickness 0.05 mm, 99.99% 600 mg
CAS No. 7440-55-3 2.4 g of 50 · 50 mm 2.4 g
Ga FW 69.72 600 mg of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
The wide liquid range of gallium was exploited recently when it 26,846-1 foil, thickness 0.025 mm, 99.99% 300 mg
was used as a solvent for the successful synthesis of ternary 1.2 g of 50 · 50 mm 1.2 g
silicides, SmNiSi3 and YNiSi3, without incorporating Ga in their 300 mg of 25 · 25 mm
structure – a promising new synthetic method. Chen, X.Z. et al. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Chem. Mater. 1999, 11, 75. 34,925-9 foil, thickness 0.1 mm, 99.9+% 1.2 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29.8 C (lit.) 1.2 g of 25 · 25 mm 4.8 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 5.904 g/mL 25 C (lit.) 4.8 g of 50 · 50 mm
R: 34 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 34,924-0 foil, thickness 0.25 mm, 99.9+% 3g
20,331-9 99.9999% 1g 12 g of 50 · 50 mm 12 g
5g 3 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
25 g 34,926-7 foil, thickness 0.025 mm, 99.9+% 300 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.2 g of 50 · 50 mm 1.2 g
26,327-3 99.999% 1g
300 mg of 25 · 25 mm
10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
50 g 32,659-3 powder, -20 mesh, 99.999+% 500 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
agglomerated 5g
26,326-5 99.99% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
50 g 25,573-4 powder, -20 mesh, 99.99+% 1g
Applied in the synthesis of new low-
Germanium dimensional, quaternary gold selenophosphate
compounds, A3AuP2Se8 (a=Rb, K, Cs) and A2Au2P2Se6
CAS No. 7440-56-4 (a=Rb, K).Chondroudis, K. et al. Inorg. Chem. 1997, 36,
Ge FW 72.64 2623.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 937 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.35 g/mL 25 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,323-0 chips, 3 mm, 99.9999% 10 g
R: 36/37/38 S: 26-36/39 50 g
335
Metals
26,577-2 powder, 99.99%, -325 mesh 500 mg Indium

Applied in the synthesis of new low- 2.5 g
dimensional, quaternary gold CAS No. 7440-74-6
selenophosphate compounds, A3AuP2Se8 (a=Rb, K, Cs) In FW 114.8
and A2Au2P2Se6 (a=Rb, K).Chondroudis, K. et al. Inorg. Vapor pressure. . . . . . . . . . . . . . . . . . . . <0.01 mm Hg ( 25 C)
Chem. 1997, 36, 2623. Density. . . . . . . . . . . . . . . . . . . . . . . . . . .7.3 g/mL 25 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,583-7 rod, diam. 3.0 mm, 99.99% 3g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
15 g of 11 cm 15 g 26,408-3 bar, 99.999+% 25 g
3 g of 2.2 cm Vapor pressure. . . . . . <0.01 mm Hg ( 25 C) 250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 7.3 g/mL (lit.)
32,658-5 spherical, powder, 1.5-3.0 mm, 500 mg R: 20/21/22-36/37/38 S: 26-36
99.9+% 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 35,727-8 foil, thickness 1.0 mm, 99.999% 4.6 g
28,977-9 sponge, 99.99% 500 mg Density. . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 18.4 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 18.4 g of 50 · 50 mm
32,654-2 shot, 1-6 mm, 99.999% 500 mg 4.6 g of 25 · 25 mm
5g R: 20/21/22-36/37/38 S: 26-36

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,929-1 wire, diam. 1.5 mm, 99.999% 680 mg 32,663-1 foil, thickness 0.5 mm, 99.999% 2.3 g
680 mg of 2 cm Vapor pressure. . . . . <0.01 mm Hg ( 25 C) 9.2 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 36.8 g
34,930-5 wire, diam. 1.0 mm, 99.999% 375 mg 2.3 g of 25 · 25 mm
1.5 g of 10 cm 1.5 g 36.8 g of 100 · 100 mm
375 mg of 2.5 cm 9.2 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22-36/37/38 S: 26-36
34,931-3 wire, diam. 0.5 mm, 99.999% 190 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
190 mg of 5 cm 950 mg 26,404-0 foil, thickness 0.25 mm, 99.999% 4.6 g
950 mg of 25 cm Vapor pressure. . . . . <0.01 mm Hg ( 25 C) 18.4 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 18.4 g of 100 · 100 mm
3 g of 5 cm 3g
Microelectronics
R: 20/21/22-36/37/38 S: 26-36
600 mg of 1 cm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,579-9 wire, diam. 1.0 mm, 99.99% 750 mg Density. . . . . . . . . . . . . . . . .7.3 g/mL (lit.) 7.2 g
7.5 g of 50 cm 7.5 g 1.8 g of 50 · 50 mm
750 mg of 5 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.2 g of 100 · 100 mm
R: 20/21/22-36/37/38 S: 26-36
31,098-0 wire, diam. 0.5 mm, 99.99% 380 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.9 g of 50 cm 1.9 g 35,728-6 foil, thickness 0.5 mm, 99.99% 9.2 g
380 mg of 10 cm 36.8 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 36.8 g
82.8 g of 150 · 150 mm 82.8 g
26,578-0 wire, diam. 0.25 mm, 99.99% 280 mg
9.2 g of 50 · 50 mm
2.8 g of 250 cm 2.8 g R: 20/21/22-36/37/38 S: 26-36
280 mg of 25 cm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,652-6 wire, diam. 0.127 mm, 99.99% 500 mg 35,729-4 foil, thickness 0.25 mm, 99.99% 4.6 g
800.558.9196 (USA)
Density. . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 18.4 g
2.5 g of 10 m 2.5 g 18.4 g of 100 · 100 mm 41.4 g
500 mg of 2 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.6 g of 50 · 50 mm
150 mg of 1 m 750 mg R: 20/21/22-36/37/38 S: 26-36
750 mg of 5 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,653-4 wire, diam. 0.25 mm, 99.9+% 280 mg Vapor pressure. . . . . . <0.01 mm Hg ( 25 C) 9.2 g
2.8 g of 250 cm 2.8 g Density. . . . . . . . . . . . . . . . .7.3 g/mL (lit.)
280 mg of 25 cm 2.3 g of 50 · 50 mm
9.2 g of 100 · 100 mm Ordering/Pricing: www.sigma-aldrich.com
R: 20/21/22-36/37/38 S: 26-36
Hafnium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,661-5 pieces, 99.99% 50 g
26,677-9 CAS No. 7440-58-6 2g Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C)
Hf FW 178.5 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.3 g/mL (lit.)
wire, diam. 1.0 mm, 99.9+% (Purity excludes ~2% approx. piece size. . . . . . . . . . . . . . . . . . . . . . . . 1=4 -2 in.
zirconium) R: 20/21/22-36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
20,343-2 powder, -60 mesh, 99.999% 5g
Holmium Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C) 25 g
mp . . . . . . . . . . . . . . . . . . . . 156 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.3 g/mL (lit.)
CAS No. 7440-60-0
R: 11-20-36/37/38 S: 9-16-36/37/39
Ho FW 164.9 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
S: 22-24/25 26,403-2 powder, -100 mesh, 99.99% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
45,795-7 chips, 99.9% 5g Some agglomeration possible 25 g
Density. . . . . . . . . . . . . . . . . 8.8 g/mL (lit.) 25 g Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 11-20-36/37/38 S: 9-16-36/37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,112-2 ingot, 99.9% 5g
27,795-9 powder, 99.99% (Purity excludes ~1% 10 g
Density. . . . . . . . . . . . . . . 8.799 g/mL (lit.) 25 g
Mg as anticaking agent) 50 g
Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C)
R: 11-20-36/37/38 S: 9-16-36/37/39
336
Metals
(Continuation of) Iridium

Indium
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7439-88-5
38,537-9 rod, diam. 10 mm, 99.9998% 26 g Ir FW 192.2
105 g of 200 mm 105 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26 g of 50 mm 44,922-9 evaporation slug, diam. 0.6 cm · 7.6 g
R: 20/21/22-36/37/38 S: 26-36 length 1.2 cm, 99.9%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . ~7.6 g
26,409-1 rod, diam. 6.0 mm, 99.999+% 20 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C) 35,732-4 foil, thickness 0.25 mm, 99.9% 3.5 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 3.5 g of 25 · 25 mm
20 g of 100 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 20/21/22-36/37/38 S: 26-36 20,968-6 powder, 99.9% 500 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36 S: 16-26-36/37/39 2.5 g
26,411-3 shot, diam. 2-5 mm, 99.999% 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C) 25 g 26,682-5 sponge, -20 mesh, 99.9% 1g
Density. . . . . . . . . . . . . . . . . 7.3 g/mL (lit.) R: 11-36 S: 16-26-36/37/39
R: 20/21/22-36/37/38 S: 26-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 35,710-3 wire, diam. 0.5 mm, 99.9% 130 mg
30,913-3 shot, diam. 2-5 mm, 99.99% 10 g 130 mg of 30 mm 650 mg
Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C) 50 g 650 mg of 150 mm
R: 20/21/22-36/37/38 S: 26-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,684-1 wire, diam. 0.15 mm, 99.9% 40 mg
32,660-7 shot, diam. 2-5 mm, 99.9+% 10 g 400 mg
Vapor pressure. . . . . . . <0.01 mm Hg ( 25 C) 50 g
R: 20/21/22-36/37/38 S: 26-36 Iron
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,706-5 wire, diam. 2.0 mm, 99.999% 4.5 g
Density. . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 22.5 g CAS No. 7439-89-6
22.5 g of 100 cm Fe FW 55.85
4.5 g of 20 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 20/21/22-36/37/38 S: 26-36
Microelectronics
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,794-5 chips, 99.98% 5g

35,707-3 wire, diam. 1.0 mm, 99.999% 5.6 g bp. . . . . . . . . . . 2872 C/760 mm Hg (lit.) 250 g
Density. . . . . . . . . . . . . . . . .7.3 g/mL (lit.) 28 g R: 25-36 S: 26-36/37/39-45 1 kg
28 g of 5 m . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.6 g of 1 m 41,305-4 granules, 10-40 mesh, 99.999% 5g
R: 20/21/22-36/37/38 S: 26-36 bp. . . . . . . . . . . . 2750 C/760 mm Hg (lit.) 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 7.86 g/mL (lit.)
26,406-7 wire, diam. 0.5 mm, 99.999% 2.8 g R: 11 S: 16-33
Vapor pressure. . . . . . <0.01 mm Hg ( 25 C) 14 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
14 g of 10 m 26,688-4 foil, thickness 1.0 mm, 99.99+% 5g
2.8 g of 2 m 20 g of 50 · 50 mm 20 g
R: 20/21/22-36/37/38 S: 26-36 5 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 25-36 S: 26-36/37/39-45
32,662-3 wire, diam. 0.25 mm, 99.999% 1.8 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor pressure. . . . . . <0.01 mm Hg ( 25 C) 26,687-6 foil, thickness 0.5 mm, 99.99+% 2.5 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.3 g/mL (lit.) R: 25-36 S: 26-36/37/39-45 10 g
1.8 g of 5 m . . . . . . . . . . . . . . . . . . . . . . . . . . . .
9 g of 25 m 33,814-1 foil, thickness 0.25 mm, 99.99+% 1.2 g
R: 20/21/22-36/37/38 S: 26-36 Density. . . . . . . . . . . . . . . . 7.86 g/mL (lit.) 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.2 g of 25 · 25 mm
27,831-9 wire, diam. 2.0 mm, 99.99% 5.6 g 5 g of 50 · 50 mm
Vapor pressure. . . . . . <0.01 mm Hg ( 25 C) 28 g R: 25-36 S: 26-36/37/39-45
28 g of 125 cm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.6 g of 25 cm 35,677-8 foil, thickness 1.0 mm, 99.9+% 5g
R: 20/21/22-36/37/38 S: 26-36 20 g of 50 · 50 mm 20 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 g of 25 · 25 mm
34,086-3 wire, diam. 1.5 mm, 99.99% 13 g R: 25-36 S: 26-36/37/39-45
Vapor pressure. . . . . . . <0.1 mm Hg ( 20 C) 65 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 35,678-6 foil, thickness 0.5 mm, 99.9+% 2.5 g
13 g of 1 m 10 g of 50 · 50 mm 10 g
65 g of 5 m 2.5 g of 25 · 25 mm 40 g
R: 20/21/22-36/37/38 S: 26-36 40 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 25-36 S: 26-36/37/39-45
26,407-5 wire, diam. 1.0 mm, 99.99% 5.6 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor pressure. . . . . . <0.01 mm Hg ( 25 C) 28 g 35,679-4 foil, thickness 0.25 mm, 99.9+% 1.2 g
Density. . . . . . . . . . . . . . . . .7.3 g/mL (lit.) 1.2 g of 25 · 25 mm 5g
28 g of 5 m 20 g of 100 · 100 mm 20 g
5.6 g of 1 m 5 g of 50 · 50 mm
R: 20/21/22-36/37/38 S: 26-36 R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,708-1 wire, diam. 0.5 mm, 99.95% 2.8 g 35,680-8 foil, thickness 0.1 mm, 99.9+% 2g
Density. . . . . . . . . . . . . . . . .7.3 g/mL (lit.) 14 g 2 g of 50 · 50 mm 8g
14 g of 10 m 8 g of 100 · 100 mm
2.8 g of 2 m R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 20/21/22-36/37/38 S: 26-36
25,563-7 powder, 99.99+% 10 g
Density. . . . . . . . . . . . . . . . 7.86 g/mL (lit.) 50 g
R: 11 S: 16-33
337
Metals
26,795-3 powder, 10 mm, 99.9+% 5g 26,591-8 foil, thickness 0.5 mm, 99.999% 14 g
R: 11 S: 16-33 250 g 14 g of 50 · 50 mm 56 g
1 kg 56 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22 S: 7-22-36-45
26,621-3 rod, diam. 6.3 mm, 99.98% 30 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
150 g of 5 · 125 mm 150 g 35,691-3 foil, thickness 0.25 mm, 99.999% 7g
30 g of 125 mm 28 g of 100 · 100 mm 28 g
R: 25-36 S: 26-36/37/39-45 7 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 61-33-40-48/22-50/53 S: 53-45-60-61
26,625-6 wire, diam. 1.0 mm, 99.99+% 3.1 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
15.5 g of 250 cm 15.5 g 35,692-1 foil, thickness 0.127 mm, 99.99+% 3.5 g
3.1 g of 50 cm 14 g of 100 · 100 mm 14 g
R: 25-36 S: 26-36/37/39-45 3.5 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22 S: 7-22-36-45
26,624-8 wire, diam. 0.5 mm, 99.99+% 750 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
7.5 g of 500 cm 7.5 g 36,974-8 ingot, 99.995% 50 g
750 mg of 50 cm R: 20/21/22 S: 7-22-36-45
R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,584-5 powder, -100 mesh, 99.999% 20 g

26,622-1 wire, diam. 0.25 mm, 99.99+% 200 mg R: 61-33-40-48/22-50/53-62 S: 53-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
2 g of 500 cm 2g
200 mg of 50 cm
39,135-2 powder, -100 mesh, 99.95% 25 g
R: 25-36 S: 26-36/37/39-45 R: 61-33-40-48/22-50/53-62 S: 53-45-60-61 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,681-6 wire, diam. 2.0 mm, 99.9+% 6.2 g 26,585-3 rod, diam. 5.0 mm, 99.9995% 22 g
24.8 g of 100 cm 24.8 g 22 g of 100 mm
6.2 g of 25 cm R: 20/21/22 S: 7-22-36-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,586-1 rod, diam. 9.0 mm, 99.999% 75 g
35,682-4 wire, diam. 1.0 mm, 99.9+% 6.2 g 75 g of 100 mm
31 g of 5 m R: 20/21/22 S: 7-22-36-45
31 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
6.2 g of 1 m
26,593-4 shot, 1-3 mm, 99.9995% 50 g
Microelectronics
R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22 S: 7-22-36-45 250 g
35,683-2 wire, diam. 0.5 mm, 99.9+% 1.5 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.5 g of 1 m 39,611-7 shot, 0.5 mm, 99.9% 500 g
7.5 g
7.5 g of 5 m R: 20/22 S: 7-22-36-45 2 kg
R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,589-6 wire, diam. 2.0 mm, 99.999% 18 g
35,684-0 wire, diam. 0.25 mm, 99.9+% 800 mg 18 g of 50 cm 90 g
4 g of 10 m 4g 90 g of 250 cm
800 mg of 2 m R: 20/21/22 S: 7-22-36-45
R: 25-36 S: 26-36/37/39-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,701-4 wire, diam. 0.5 mm, 99.999% 2.2 g
R: 20/21/22 S: 7-22-36-45 11 g
Lanthanum . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,588-8 wire, diam. 1.0 mm, 99.99% 8.9 g
800.558.9196 (USA)
CAS No. 7439-91-0 44.5 g of 500 cm 44.5 g
La FW 138.9 8.9 g of 100 cm
R: 20/21/22 S: 7-22-36-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,311-7 chips, 99.9% 25 g
Lithium
Packaged under argon
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 920 C (lit.)
CAS No. 7439-93-2
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.19 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Li FW 6.941
26,113-0 ingot, 99.9% 25 g A high-energy, new battery system using only inorganic
Packaged under oil 100 g constituents has been designed where Li and LiCoO2 serve as
. . . . . . . . . . . . . . . . . . . . . . . . . . . . the electrodes in a LiAlCl4-in-SO2 liquid electrolyte.,
26,310-9 powder, -40 mesh, 99.9% 25 g References
Packaged under oil and argon 100 g Doege, V. et al., Proc. Annu. Battery Conf. Appl. Adv., 10th 313 (1995)
R: 11 S: 16-33-36/37/39 R: 14/15-34 S: 8-43-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Lead 49,981-1 granules, 99.9+% 25 g
mp . . . . . . . . . . . . . . . . . . . 180 C (lit.) 100 g
CAS No. 7439-92-1
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,597-7 ingot, diam. 5.7 cm, 99.9% 115 g
Pb FW 207.2
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Packaged under argon 460 g
26,592-6 foil, thickness 1.0 mm, 99.9995% 28 g mp . . . . . . . . . . . . . . . . . . . 180 C (lit.)
112 g of 100 · 100 mm 112 g 115 g of 9 cm
28 g of 50 · 50 mm 460 g of 4 · 9 cm
R: 20/21/22 S: 7-22-36-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,598-5 ribbon, thickness 0.38 mm · width 25 g
35,723-5 foil, thickness 2.0 mm, 99.999% 14 g 23 mm, 99.9% 100 g
14 g of 25 · 25 mm 56 g Packaged under argon
56 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 20/21/22 S: 7-22-36-45 26,599-3 99.9%, thickness 0.75 mm · width 25 g
45 mm, ribbon 100 g
338
Metals
(Continuation of) 29,940-5 rod, diam. 6 mm, 99.9+% 10 g

Lithium Density. . . . . . . . . . . . . . . . 1.73 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,600-0 ribbon, 99.9%, thickness 1.5 mm · 25 g 10 g of 2 · 100 mm
50 g of 10 · 100 mm
width 100 mm 100 g
Packaged under argon . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
40,314-8 turnings, Average size 3=16 in., 99.98% 50 g
26,596-9 rod, diam. 12.7 mm, 99.9% 50 g
mp . . . . . . . . . . . . . . . . . . . 651 C (lit.) 250 g
Packaged under argon 250 g Density. . . . . . . . . . . . . . . 1.74 g/mL (lit.)
250 g of 25-30 rods
50 g of 5-6 rods . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 52,949-4 small turnings, Average size 1.6 mm, 50 g
22,091-4 wire, diam. 3.2 mm, 99.9% 25 g 99.98% 250 g
Packaged under argon 100 g mp . . . . . . . . . . . . . . . . . . 648.8 C (lit.)

sodium. . . . . . . . . . . . . . . . . . . ~0.01% Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.74 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180 C (lit.)
1 cm of ~45 mg Li wire (Unit weight is weight of contained metal)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,008-0 99.9%, thickness 0.75 mm · width 25 g Manganese
19 mm 100 g
CAS No. 7439-96-5
Fabricated for easy introduction through a
Mn FW 54.94
S.T.24/40 glass joint
R: 11 S: 22
Packaged under argon . . . . . . . . . . . . . . . . . . . . . . . . . . . .
ribbon 46,372-8 powder, 99.99% 25 g
Density. . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 100 g
Lutetium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,614-0 powder, -50 mesh, 99.9% 100 g
CAS No. 7439-94-3 500 g
Lu FW 175.0
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Mercury
Microelectronics
45,794-9 chips, 99.9% 250 mg

R: 11 S: 16-33-36/37/39 1g CAS No. 7439-97-6
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Hg FW 200.6
26,114-9 ingot, 99.9% 1g Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 (vs air)
Density. . . . . . . . . . . . . . . . 9.835 g/mL (lit.) Vapor pressure. . . . . . . . . . . . . . . . . . . . . . 1 mm Hg ( 126 C)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor pressure. . . . . . . . . . . . . . . . . . . . <0.01 mm Hg ( 20 C)
26,312-5 powder, 40 mesh, 99.9% (Purity 1g
R: 23-33-50/53 S: 7-45-60-61
excludes ~2-3% Ta inherent in . . . . . . . . . . . . . . . . . . . . . . . . . . . .
manufacturing process) 29,459-4 electronic grade, 99.9999% 50 g
R: 11 S: 16-33-36/37/39 250 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Magnesium 21,545-7 99.9995%, ACS reagent 100 g
Contains nonvolatile matter 500 g
CAS No. 7439-95-4 bp. . . . . . . . . . 356.6 C/760 mm Hg (lit.) 2 kg
Mg FW 24.31 mp . . . . . . . . . . . . . . . . -38.87 C (lit.)
R: 11-15 S: 43-7/8 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,101-7 99.99+% 250 g
25,411-8 chips, 99.98%, 4-30 mesh 25 g bp. . . . . . . . . . 356.6 C/760 mm Hg (lit.) 1 kg
Vapor pressure. . . . . . . 1 mm Hg ( 621 C) 250 g mp . . . . . . . . . . . . . . . . -38.87 C (lit.)
mp . . . . . . . . . . . . . . . . . . .648 C (lit.) 1 kg
Density. . . . . . . . . . . . . . . 1.74 g/mL (lit.) Molybdenum
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
47,475-4 Purified by distillation, dendritic 5g CAS No. 7439-98-7
pieces, 99.999% 25 g Mo FW 95.94
Solid state synthesis with Ca and Sn resulted in a new 35,720-0 foil, thickness 1.0 mm, 99.9+% 25.6 g
phase, Ca6.2Mg3.8Sn7, which has an unprecedented type 102.4 g of 100 · 100 mm 102.4 g
of tin chain composed of square-planar tin units. Ganguli, 25.6 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
A.K. et al. J. Am. Chem. Soc. 1998, 120, 1223. 35,721-9 foil, thickness 0.5 mm, 99.9+% 12.8 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 649 C (lit.) 115.2 g of 150 · 150 mm 51.2 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.738 g/mL (lit.) 12.8 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 115.2 g
51.2 g of 100 · 100 mm
46,599-2 Purified by distillation, dendritic 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
pieces, 99.99% 25 g 26,693-0 foil, thickness 0.25 mm, 99.9+% 6.4 g
Solid state synthesis with Ca and Sn resulted in a new 26,692-2 foil, thickness 0.1 mm, 99.9+% 10.2 g
phase, Ca6.2Mg3.8Sn7, which has an unprecedented type 10.2 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
of tin chain composed of square-planar tin units. Ganguli, 51,480-2 foil, thickness 0.05 mm, 99.9+% 1.2 g
A.K. et al. J. Am. Chem. Soc. 1998, 120, 1223. 5.1 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 648.8 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.738 g/mL (lit.) 35,722-7 foil, thickness 0.025 mm, 99.9+% 5.8 g
19.1 g of 150 · 500 mm 19.1 g
5.8 g of 150 · 150 mm
339
Metals
36,698-6 powder, 10 mm, 99.99+% 10 g 35,754-5 foil, thickness 1.0 mm, 99.98% 5.6 g
Used in the solid state synthesis of a 50 g Density. . . . . . . . . . . . . . . . 8.9 g/mL (lit.) 22.4 g
remarkable ternary, reduced molybdenum 22.4 g of 50 · 50 mm 89.6 g
oxide, Pr4Mo9O18, whose structure contains previously 5.6 g of 25 · 25 mm
89.6 g of 100 · 100 mm
unknown Mo7, Mo13and Mo19 clusters. The new cluster
R: 40-43 S: 22-36
product is a small band gap semiconductor. Tortelier, J. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Gougeon, P. Inorg. Chem. 1998, 37, 6229. 35,755-3 foil, thickness 0.5 mm, 99.98% 2.8 g
R: 11 S: 9-16-36/37/39 Density. . . . . . . . . . . . . . . . 8.9 g/mL (lit.) 11.2 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.2 g of 50 · 50 mm
51,009-2 powder, 1-2 mm, 99.9+% 50 g 44.8 g
2.8 g of 25 · 25 mm
R: 11 S: 9-16-36/37/39 250 g 44.8 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 40-43 S: 22-36
20,382-3 powder, -100 mesh, 99.9+% 100 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Used in the solid state synthesis of a 500 g 35,756-1 foil, thickness 0.25 mm, 99.98% 1.4 g
remarkable ternary, reduced molybdenum Density. . . . . . . . . . . . . . . . 8.9 g/mL (lit.) 5.6 g
oxide, Pr4Mo9O18, whose structure contains previously 1.4 g of 25 · 25 mm 22.4 g
unknown Mo7, Mo13and Mo19 clusters. The new cluster 22.4 g of 100 · 100 mm

5.6 g of 50 · 50 mm
product is a small band gap semiconductor. Tortelier, J.
R: 40-43 S: 22-36
Gougeon, P. Inorg. Chem. 1998, 37, 6229. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 11 S: 9-16-36/37/39 35,758-8 foil, thickness 0.1 mm, 99.98% 2.2 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . .8.9 g/mL (lit.) 8.8 g
26,690-6 wire, diam. 0.25 mm, 99.97% 10 g
2.2 g of 50 · 50 mm
10 g of 20 m 100 g 8.8 g of 100 · 100 mm
100 g of 200 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 40-43 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,691-4 wire, diam. 1.0 mm, 99.95% 40 g
26,825-9 foil, thickness 0.125 mm, 99.9+% 25 g
400 g 150 g of 6 · (150 · 150) mm 150 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
25 g of 150 · 150 mm
35,696-4 wire, diam. 0.5 mm, 99.95% 20 g
R: 40-43 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
Neodymium 20,390-4 powder, -100 mesh, 99.99% 25 g
Employed in the synthesis of a metal-rich 100 g
CAS No. 7440-00-8 layered telluride, TaNi2Te2, which 500 g
Nd FW 144.2 possesses ideal characteristics for
R: 11-36/37/38 S: 16-26-33-36/37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . . photovoltaic applications, for surface scanning studies,
26,314-1 chips, 99.9% 25 g and which may give clean and atomically flat surfaces.
bp. . . . . . . . . . . .3074 C/760 mm Hg (lit.) 100 g Neuhasen, J. et al. Chem. Mater. 1998, 10, 3870.
Density. . . . . . . . . . . . . . .7.003 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 8.9 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 10-17-36/37/38-40-42/43 S: 16-26-33-36
26,115-7 ingot, 99.9% 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
100 g 26,707-4 rod, diam. 6.35 mm, 99.99+% 14 g
Density. . . . . . . . . . . . . . . . . 8.9 g/mL (lit.) 42 g
Nickel See: Metals Page 150 14 g of 5 cm
42 g of 15 cm
800.558.9196 (USA)
Nickel R: 40-43 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7440-02-0 21,577-5 sphere, 6-16 mm, 99.95+% 250 g
Density. . . . . . . . . . . . . . . .8.9 g/mL (lit.) 1 kg
Ni FW 58.69
R: 40-43 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,759-6 wire, diam. 2.0 mm, 99.995% 1.4 g
43,365-9 evaporation slug, diam. 6.3 mm · 8.5 g
Density. . . . . . . . . . . . . . . . .8.9 g/mL (lit.) 7g
length 6.3 mm, 99.995% 1.4 g of 5 cm
Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . ~1.7 g 7 g of 25 cm
R: 40-43 S: 22-36 R: 40-43 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
27,896-3 evaporation slug, diam. 6.35 mm · 14 g 26,706-6 wire, diam. 1.0 mm, 99.995% 1.7 g
length 1 cm, 99.99% Density. . . . . . . . . . . . . . . . .8.9 g/mL (lit.) 6.8 g
R: 40-43 S: 22-36 1.7 g of 25 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
6.8 g of 100 cm
26,701-5 foil, thickness 1.0 mm, 99.995% 5.6 g R: 40-43 S: 22-36
22.4 g of 50 · 50 mm 22.4 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.6 g of 25 · 25 mm 26,705-8 wire, diam. 0.5 mm, 99.99+% 1.7 g
R: 40-43 S: 22-36 1.7 g of 100 cm 8.5 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
8.5 g of 500 cm
26,702-3 foil, thickness 0.5 mm, 99.995% 2.8 g R: 40-43 S: 22-36
11.2 g of 50 · 50 mm 11.2 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.8 g of 25 · 25 mm 26,703-1 wire, diam. 0.127 mm, 99.99+% 220 mg
R: 40-43 S: 22-36 Density. . . . . . . . . . . . . . . 8.9 g/mL (lit.) 1.1 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.1 g of 10 m
26,700-7 foil, thickness 0.25 mm, 99.995% 1.4 g 220 mg of 2 m
1.4 g of 25 · 25 mm 5.6 g R: 40-43 S: 22-36
5.6 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 40-43 S: 22-36 39,340-1 wire, diam. 2.0 mm, 99.9+% 2.8 g
Density. . . . . . . . . . . . . . . . . 8.9 g/mL (lit.) 14 g
14 g of 50 cm
2.8 g of 10 cm
R: 40-43 S: 22-36
340
Metals
(Continuation of) 20,399-8 granules, 99.99% 1g

R: 36/37/38 S: 16-26-36-7/9 5g
Nickel . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,761-8 wire, diam. 1.0 mm, 99.9+% 3.4 g 20,393-9 powder, 99.999% 1g
17 g of 250 cm R: 36/37/38 S: 16-26-36-7/9 5g
17 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.4 g of 50 cm
R: 40-43 S: 22-36 32,666-6 powder, (submicron), 99.9+% 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 36/37/38 S: 16-26-36-7/9 5g
35,762-6 wire, diam. 0.5 mm, 99.9+% 8.5 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
42.5 g of 25 m 42.5 g 32,665-8 powder, 1.0-1.5 mm, 99.9+% 1g
8.5 g of 5 m R: 36/37/38 S: 16-26-36-7/9 5g
R: 40-43 S: 22-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 46,465-1 powder, -200 mesh, 99.9% 5g
35,763-4 wire, diam. 0.25 mm, 99.9+% 2.2 g R: 36/37/38 S: 16-26-36-7/9 25 g
11 g of 25 m 11 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2 g of 5 m 34,699-3 rod, diam. 3.1 mm, 99.9+% 1.9 g
R: 40-43 S: 22-36 1.9 g of 2 cm 9.5 g
9.5 g of 10 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Niobium 34,698-5 99.9+%, rod, diam. 6.25 mm 7.6 g
38 g of 10 cm 38 g
26,548-9 (Columbium) 10 g 7.6 g of 2 cm
CAS No. 7440-03-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Nb FW 92.91 26,708-2 sponge, 99.9% 1g
rod, diam. 12.7 mm, 99.9+% R: 36/37/38 S: 16-26-36-7/9 5g
10 g of 1 cm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,668-2 shot, diam. 1-8 mm, 99.9+% 1g
5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Osmium
26,711-2 wire, diam. 1.0 mm, 99.9% 900 mg
9 g of 100 cm 9g
CAS No. 7440-04-2
900 mg of 10 cm
Microelectronics
Os FW 190.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 11-37/38-41 S: 16-26-36/37/39 34,869-4 wire, diam. 0.5 mm, 99.9% 960 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.8 g of 200 cm 4.8 g
37,276-5 powder, 99.995% 500 mg 960 mg of 40 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,325-7 powder, 99.9% 1g 32,669-0 wire, diam. 0.25 mm, 99.9% 600 mg
3 g of 5 m 3g
Palladium 600 mg of 1 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 7440-05-3 34,870-8 wire, diam. 0.1 mm, 99.9% 180 mg
Pd FW 106.4 180 mg of 2 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Platinum
37,319-2 evaporation slug, diam. 0.9 cm · 10.9 g
length 1.2 cm, 99.95% CAS No. 7440-06-4
Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . 10.9 g Pt FW 195.1
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,320-6 evaporation slug, diam. 0.6 cm · 2.4 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
length 0.6 cm, 99.95% 37,321-4 evaporation slug, diam. 0.6 cm · length 7 g
Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . .2.4 g 1.2 cm, 99.99%
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . . . 7 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,322-2 evaporation slug, diam. 0.6 cm · 4.3 g
1.9 g of 25 · 25 mm
length 0.6 cm, 99.99%
7.6 g Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . .4.3 g
7.6 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,713-9 foil, thickness 0.1 mm, 99.9+% 750 mg 37,323-0 evaporation slug, diam. 0.3 cm · length 1 g
3 g of 50 · 50 mm 0.6 cm, 99.99%
750 mg of 25 · 25 mm Weight of one slug. . . . . . . . . . . . . . . . . . . . . . . . . . 1 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,867-8 foil, thickness 1.0 mm, 99.9% 7.6 g 34,937-2 foil, thickness 1.0 mm, 99.99% 14 g
30.4 g 28 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
28,747-4 foil, thickness 0.5 mm, 99.9% 3.8 g 26,726-0 foil, thickness 0.5 mm, 99.99% 7g
15.2 g of 50 · 50 mm 14 g of 25 · 50 mm 14 g
15.2 g
3.8 g of 25 · 25 mm 7 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,670-4 foil, thickness 0.25 mm, 99.9% 1.9 g 34,932-1 foil, thickness 0.25 mm, 99.99% 3.5 g
1.9 g of 25 · 25 mm 14 g of 50 · 50 mm 14 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.5 g of 25 · 25 mm
41,145-0 foil, thickness 0.05 mm, 99.9% 375 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.5 g of 50 · 50 mm 1.5 g 34,934-8 foil, thickness 0.127 mm, 99.99% 1.7 g
375 mg of 25 · 25 mm 1.7 g of 25 · 25 mm 7g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 g of 50 · 50 mm
26,712-0 foil, thickness 0.025 mm, 99.9% 190 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
190 mg of 25 · 25 mm 760 mg 26,725-2 foil, thickness 0.1 mm, 99.99% 1.3 g
760 mg of 50 · 50 mm 1.3 g of 25 · 25 mm 5.3 g
5.3 g of 50 · 50 mm
341
Metals
34,935-6 foil, thickness 0.05 mm, 99.99% 600 mg 26,720-1 wire, diam. 0.5 mm, 99.99% 400 mg
2.4 g of 50 · 50 mm 2.4 g 2 g of 50 cm 2g
600 mg of 25 · 25 mm 400 mg of 10 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,936-4 foil, thickness 0.025 mm, 99.99% 350 mg 26,717-1 wire, diam. 0.25 mm, 99.99% 250 mg
1.4 g of 50 · 50 mm 1.4 g 2.5 g of 250 cm 2.5 g
350 mg of 25 · 25 mm 250 mg of 25 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
30,379-8 foil, thickness 0.05 mm, 99.9+% 1.5 g 26,716-3 wire, diam. 0.127 mm, 99.99% 270 mg
1.5 g of 38 · 38 mm 5g 1.3 g of 500 cm 1.3 g
5 g of 38 · 120 mm 270 mg of 100 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,741-7 foil, thickness 0.635 mm, 99.9% 8.5 g 35,736-7 wire, diam. 0.10 mm, 99.99% 180 mg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Suitable for thermocouple use 900 mg
30,518-9 foil, thickness 0.5 mm, 99.9% 7g 180 mg of 1 m
14 g of 25 · 50 mm 14 g 900 mg of 5 m
7 g of 25 · 25 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 34,939-9 wire, diam. 1.5 mm, 99.9+% 950 mg

3.8 g of 100 mm 3.8 g
14 g of 50 · 50 mm 14 g 950 mg of 25 mm
3.5 g of 25 · 25 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32,749-2 wire, diam. 1.0 mm, 99.9% 520 mg
32,743-3 foil, thickness 0.127 mm, 99.9% 1.7 g 2.6 g of 150 mm 2.6 g
1.7 g of 25 · 25 mm 7g 520 mg of 30 mm
7 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,722-8 wire, diam. 0.5 mm, 99.9% 1g
34,938-0 foil, thickness 0.1 mm, 99.9% 1.4 g 1 g of 25 cm 4g
1.4 g of 25 · 25 mm 5.6 g 4 g of 100 cm
5.6 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 34,940-2 wire, diam. 0.25 mm, 99.9% 250 mg
26,724-4 foil, thickness 0.025 mm, 99.9% 350 mg 1.5 g of 150 cm 1.5 g
1.4 g of 50 · 50 mm 1.4 g 250 mg of 25 cm
350 mg of 25 · 25 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,782-1 wire, diam. 0.127 mm, 99.9% 270 mg
29,810-7 gauze, 52 mesh, 99.9% 425 mg 1.3 g of 500 cm 1.3 g
1.7 g of 50 · 50 mm 1.7 g 270 mg of 100 cm
425 mg of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
29,809-3 gauze, 100 mesh, 99.9% 425 mg Potassium
1.7 g of 50 · 50 mm 1.7 g
425 mg of 25 · 25 mm 24,485-6 CAS No. 7440-09-7 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . K FW 39.10 5g
20,401-3 powder, 99.999% 1g ingot, 99.95% 25 g
R: 11 S: 16-33-7/9 Packaged in ampules
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor pressure. . . . . . . . . . . . . . . . . 0.09 mm Hg ( 260 C)
20,404-8 coarse powder, 99.99% 1g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 C (lit.)
R: 11 S: 16-33-7/9 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 0.86 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
800.558.9196 (USA)
R: 14/15-34 S: 8-43-45
32,744-1 powder, 0.5-1.2 mm, 99.9+% 500 mg
R: 11 S: 16-33-7/9 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Praseodymium
32,747-6 powder, 0.27-0.47 mm, 99.9% 500 mg
R: 11 S: 16-33-7/9 5g CAS No. 7440-10-0
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Pr FW 140.9
32,746-8 powder, 0.8-2.2 mm, 99.9% 500 mg
R: 11 S: 16-33-7/9 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,316-8 chips, 99.9% 5g
32,748-4 shot, 3 mm, 99.9+% 1g R: 17 S: 17 25 g
R: 11 S: 16-33-7/9 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ordering/Pricing: www.sigma-aldrich.com
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,117-3 ingot, 99.9% 10 g
26,715-5 99.9+% 1g R: 17 S: 17 50 g
R: 11 S: 16-33-7/9 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,317-6 powder, 40 mesh, 99.9% 5g
35,735-9 wire, diam. 0.20 mm, 99.99+% 700 mg R: 11 S: 16-33-7/9 25 g
Suitable for thermocouple use 3.5 g
3.5 g of 5 m Rhenium
700 mg of 1 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7440-15-5
35,737-5 wire, diam. 0.076 mm, 99.99+% 100 mg Re FW 186.2
Suitable for thermocouple use 500 mg
100 mg of 1 m . . . . . . . . . . . . . . . . . . . . . . . . . . . .
500 mg of 5 m 45,998-4 foil, thickness 1.0 mm, 99.98% 13 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . bp. . . . . . . . . . . . 5596 C/760 mm Hg (lit.) 52 g
44,468-5 wire, diam. 2.0 mm, 99.99% 1.4 g 13 g of 25 · 25 mm
1.4 g of 2 cm 7g 52 g of 50 · 50 mm
7 g of 10 cm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,723-6 wire, diam. 1.0 mm, 99.99% 350 mg 5.2 g
3.5 g of 20 cm 3.5 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
350 mg of 2 cm 26,731-7 foil, thickness 0.25 mm, 99.98% 3.3 g
13.2 g of 50 · 50 mm 13.2 g
3.3 g of 25 · 25 mm
342
Metals
(Continuation of) Samarium

Rhenium
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7440-19-9
26,729-5 foil, thickness 0.025 mm, 99.98% 330 mg Sm FW 150.4
1.3 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,121-1 chips, 99.9% 10 g
20,418-8 powder, 99.995% 1g Density. . . . . . . . . . . . . . . . 7.47 g/mL (lit.) 50 g
R: 11 S: 16 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,318-4 ingot, 99.9% 10 g
26,727-9 powder, 99.9+%, -100 mesh 5g 50 g
R: 11 S: 16 25 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,120-3 -40 mesh, 99.9% 1g
26,732-5 ribbon, thickness 0.025 mm · width 100 mg Radioactive for shipping purposes 10 g
0.75 mm, 99.99+% R: 33 50 g

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
44,948-2 rod, length 25 mm, diam. 4 mm, 6.9 g
Scandium
99.99%
A superior tip used in scanning tunneling microscopy. CAS No. 7440-20-2
Watanabe, M.O. Kinno, T. Jpn. J. Appl. Phys., Part 2 1995, Sc FW 44.96
34, L386.
6.9 g of 25 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 45,793-0 chips, 99.9% 250 mg
35,713-8 wire, diam. 1.0 mm, 99.9+% 400 mg bp. . . . . . . . . . 2836 C/760 mm Hg (lit.) 1g
1.6 g Density. . . . . . . . . . . . . . 2.99 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 11 S: 16-43
35,711-1 wire, diam. 0.5 mm, 99.9+% 200 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1 g of 25 cm 1g 26,124-6 dendritic pieces, Purified by distillation, 1 g
200 mg of 5 cm 99.9%
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 11 S: 16-43
26,728-7 wire, diam. 0.25 mm, 99.9+% 100 mg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1 g of 100 cm 1g 26,126-2 powder, 99.9% 250 mg

Microelectronics
100 mg of 10 cm Packaged under argon in ampules 1g

Density. . . . . . . . . . . . . . 2.99 g/mL (lit.)
Rhodium R: 5-11 S: 16-36/37/39-7/9
CAS No. 7440-16-6 Selenium

Rh FW 102.9
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7782-49-2
20,421-8 99.99% 250 mg Se FW 78.96
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217 C (lit.)
R: 11 S: 16-22-24/25 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.81 g/mL (lit.)
26,738-4 foil, thickness 0.25 mm, 99.9% 1.9 g R: 23/25-33-53 S: 20/21-28-45-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,737-6 foil, thickness 0.1 mm, 99.9% 750 mg 20,430-7 pellets, 2 mm, 99.999+% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 g
35,734-0 foil, thickness 0.025 mm, 99.9% 190 mg 100 g
190 mg of 25 · 25 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 20,964-3 pellets, 4 mm, 99.99+% 50 g
26,736-8 sponge, 99.9% 250 mg 250 g
R: 11 S: 16-22-24/25 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 22,986-5 powder, -100 mesh, 99.999% 5g
27,791-6 wire, diam. 1.0 mm, 99.9% 200 mg 20 g
1 g of 10 cm 1g 100 g
200 mg of 2 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,714-6 wire, diam. 0.5 mm, 99.9% 120 mg Silicon
120 mg of 5 cm 600 mg
600 mg of 25 cm CAS No. 7440-21-3
Si FW 28.09
Ruthenium bp. . . . . . . . . . . . . . . 2355 C/760 mm Hg (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.33 g/mL (lit.)
CAS No. 7440-18-8 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ru FW 101.1 20,432-3 pieces, 99.999+% 10 g
R: 11 S: 16-22-24/25 Density. . . . . . . . . . . . . . . . 2.33 g/mL (lit.) 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
54,502-3 powder, 99.99% 1g 34,325-0 pieces, 99.95% 50 g
5g Density. . . . . . . . . . . . . . . 2.33 g/mL (lit.) 500 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,740-6 sponge, -100 mesh, 99.9% 1g 47,523-8 powder, 99.9995% 5g
5g bp. . . . . . . . . . . . 2355 C/760 mm Hg (lit.) 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . 2.33 g/mL (lit.)
20,969-4 powder, -200 mesh, 99.9% 1g R: 11 S: 16-33-36
5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,741-4 powder, -60 mesh, 99.999% 5g
R: 11 S: 16-33-36 25 g
343
Metals
Silver 32,710-7 powder, -325 mesh, 99.99+% 10 g

50 g
CAS No. 7440-22-4 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Ag FW 107.9 26,550-0 powder, 99.99%, -60 mesh 10 g
mp . . . . . . . . . . . . . . . . . . . 960.5 C (lit.) 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,829-1 crystals, 8-20 mesh, 99.99+% 10 g 32,709-3 powder, 5-8 mm, 99.9+% 10 g
50 g 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,324-9 evaporation slug, diam. 0.6 cm · 4.1 g 32,708-5 powder, 2-3.5 mm, 99.9+% 10 g
length 1.2 cm, 99.99% 20.5 g 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Weight of one slug. . . . . . . . . . . . . 4.1 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 34,877-5 rod, diam. 3.2 mm, 99.98% 8g
32,707-7 flake, 10 mm, 99.9+% 10 g 32 g of 40 cm 32 g
8 g of 10 cm
50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,745-7 foil, thickness 2.0 mm, 99.99+% 13.2 g 34,876-7 rod, diam. 6.35 mm, 99.95+% 17 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 g of 50 mm 34 g

36,943-8 foil, thickness 1.0 mm, 99.99% 6.6 g 34 g of 100 mm 51 g
26.4 g of 50 · 50 mm 26.4 g 51 g of 150 mm
6.6 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32,704-2 rod, diam. 12.5 mm, 99.9+% 32.5 g
26,553-5 foil, thickness 0.5 mm, 99.99% 3.3 g 130 g of 100 mm 130 g
13.2 g of 50 · 50 mm 13.2 g 32.5 g of 25 mm
3.3 g of 25 · 25 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,562-4 rod, diam. 7.0 mm, 99.99% 10 g
34,871-6 foil, thickness 0.25 mm, 99.99% 6.6 g 40 g
26.4 g of 100 · 100 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
6.6 g of 50 · 50 mm 20,436-6 shot, 1-3 mm, 99.9999% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . 961 C (lit.) 25 g
13.2 g of 100 · 100 mm 32,705-0 shot, 1-3 mm, 99.99+% 10 g
Microelectronics
3.3 g of 50 · 50 mm 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,697-6 foil, thickness 2.0 mm, 99.9% 13.2 g 26,559-4 wire, diam. 1.0 mm, 99.99+% 4.1 g
13.2 g of 25 · 25 mm 52.8 g 20.5 g of 250 cm 20.5 g
52.8 g of 50 · 50 mm 4.1 g of 50 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,872-4 foil, thickness 1.5 mm, 99.9% 9.9 g 26,558-6 wire, diam. 0.5 mm, 99.99+% 2g
39.6 g 10 g of 500 cm 10 g
158.4 g 2 g of 100 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26.4 g of 50 · 50 mm 26.4 g 13 g of 25 m 13 g
6.6 g of 25 · 25 mm 2.6 g of 5 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,507-5 foil, thickness 0.5 mm, 99.9% 13.2 g 34,875-9 diam. 1.5 mm, 99.99+% 5g
800.558.9196 (USA)
13.2 g of 50 · 50 mm 52.8 g 20 g of 100 cm 20 g
52.8 g of 100 · 100 mm 5 g of 25 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26.4 g of 100 · 100 mm 33 g of 100 cm 33 g
26.4 g
6.6 g of 50 · 50 mm 6.6 g of 20 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,552-7 foil, thickness 0.1 mm, 99.9% 2.6 g 32,701-8 diam. 2.0 mm, 99.9% 16.5 g
10.4 g of 100 · 100 mm 16.5 g of 50 cm 82.5 g
10.4 g
2.6 g of 50 · 50 mm 82.5 g of 250 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,561-6 wire, diam. 1.5 mm, 99.9% 10 g
32,699-2 foil, thickness 0.075 mm, 99.9% 2g
8g 10 g of 50 cm 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 g of 250 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.2 g
5.2 g of 100 · 100 mm 41 g of 500 cm 41 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.2 g of 100 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
13 g of 100 · 500 mm
32,702-6 wire, diam. 0.5 mm, 99.9% 4g
2.6 g
20 g of 10 m 20 g
2.6 g of 100 · 100 mm 13 g 4 g of 2 m
650 mg of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
30,337-2 granules, +60 mesh, 99.99% 10 g 26,557-8 wire, diam. 0.25 mm, 99.9% 10.4 g
10.4 g of 20 m 52 g
50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 g of 100 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,103-2 needles, 99.99+%, 30-60 mesh 10 g
34,878-3 wire, diam. 0.1 mm, 99.9% 200 mg
50 g 200 mg of 2.5 m 800 mg
250 g 800 mg of 10 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
25,574-2 powder, -30 mesh, 99.999% 1g 26,555-1 wire, diam. 0.127 mm, 99.99% 330 mg
10 g 3.3 g of 25 m 3.3 g
330 mg of 2.5 m
344
Metals
(Continuation of) 26,284-6 powder, -325 mesh, 99.9% 25 g

Silver Employed in the synthesis of metal-rich 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . layered tellurides, TaNi2Te2 and TaCo2Te2,
29,574-4 99.9+% 5g which possess ideal characteristics for photovoltaic
25 g applications, for surface scanning studies, and which may
give clean and atomically flat surfaces.1 Starting material
Sodium for new edge-bridged octahedral M6 cluster compounds
such as CsErTa6Cl18, for which electron and stability
26,271-4 CAS No. 7440-23-5 1g studies were performed.2 (1) Neuhasen, J. et al. Chem.
Na FW 22.99 5g Mater. 1998, 10, 3870. (2) Ogliaro, F.et al. Inorg. Chem.
ingot, 99.95% 25 g 1998, 37, 6199.
Vapor pressure. . . . . . . . . 1 mm Hg ( 440 C) Vapor pressure. . . . . . . . . . . . . . . <0.01 mm Hg ( 537.2 C)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97.8 C (lit.)
R: 11-36/37/38 S: 16-26-33-36/37/39
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.968 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 14/15-34 S: 8-43-45 26,285-4 rod, diam. 6.35 mm, 99.9+% 25 g
125 g
Strontium . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,698-0 rod, diam. 3.2 mm, 99.9+% 6.5 g
CAS No. 7440-24-6 32.5 g of 25 cm 32.5 g
Sr FW 87.62 6.5 g of 5 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Used to make Strontium-potassium-niobate (Sr2KNb5O15, 35,699-9 wire, diam. 2.0 mm, 99.9+% 10 g
SKN). SKN is of great interest for pyroelectric sensors and 10 g of 20 cm
various electro-optic devices.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Packaged under argon in ampules 26,286-2 wire, diam. 1.0 mm, 99.9+% 13 g
Applied in the solid state synthesis of a Zintl phase, SrSn3Sb4, 13 g of 1 m 65 g
with an anionic channel framework of 30-membered rings. 65 g of 5 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Chow, D.T. et al. Inorg. Chem.1997, 36, 3750. 35,700-6 wire, diam. 0.5 mm, 99.9+% 3.3 g
References
3.3 g of 1 m 33 g
Sakamoto, W., J. Mater. Res. 14, 1495 (1999) 33 g of 10 m
Microelectronics
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,287-0 wire, diam. 0.25 mm, 99.9+% 4g
44,189-9 Purified by distillation, dendritic 5g 4 g of 5 m 40 g
pieces, 99.99% 25 g 40 g of 50 m
mp . . . . . . . . . . . . . . . . . . . . 757 C (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.6 g/mL (lit.) 26,290-0 wire, diam. 0.127 mm, 99.9+% 200 mg
R: 11-14-38 S: 16-26-36/37/39-7/9
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tellurium
46,034-6 Purified by distillation, dendritic 5g
pieces, 99.9% 25 g CAS No. 13494-80-9
mp . . . . . . . . . . . . . . . . . . . . 769 C (lit.)
Te FW 127.6
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.63 g/mL (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 990 C/760 mm Hg (lit.)
R: 11-14 S: 16-26-36/37/39-7/9
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 450 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.24 g/mL 25 C (lit.)
Tantalum . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,330-3 granules, -5-+50 mesh, 99.99% 25 g
CAS No. 7440-25-7 R: 11-26/27/28 S: 16-27-36/37/39-45
Ta FW 180.9 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,331-1 ingot, 99.999% 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 26/27/28 S: 22-36/37/39-45
26,288-9 foil, thickness 1.0 mm, 99.9+% 10.4 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10.4 g of 25 · 25 mm 41.6 g 20,454-4 pieces, 99.999% 20 g
41.6 g of 50 · 50 mm R: 26/27/28 S: 22-36/37/39-45 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,725-1 foil, thickness 0.5 mm, 99.9+% 20.8 g 26,486-5 powder, -40 mesh, 99.997% 5g
20.8 g of 50 · 50 mm 83.2 g R: 25 S: 22-28-36/37/39-45 25 g
83.2 g of 100 · 100 mm 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,289-7 foil, thickness 0.25 mm, 99.9+% 10.4 g 45,237-8 shot, 1-2 mm, 99.999% 5g
10.4 g of 50 · 50 mm 41.6 g Packaged under argon in ampules 25 g
41.6 g of 100 · 100 mm low oxide. . . . . . . . . . . . . . . . . . contains 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 26/27/28 S: 22-36/37/39-45
35,724-3 foil, thickness 0.05 mm, 99.9+% 2.1 g
18.9 g of 150 · 150 mm 8.4 g
2.1 g of 50 · 50 mm Terbium
18.9 g
8.4 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 7440-27-9
26,291-9 foil, thickness 0.025 mm, 99.9+% 9g Tb FW 158.9
31 g of 150 · 500 mm 31 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
9 g of 150 · 150 mm 26,320-6 chips, 99.9% 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . . 8.234 g/mL (lit.) 5 g
54,500-7 powder 10 g S: 22-24/25
R: 11-36/37/38 S: 16-26-33-36/37/39 50 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,127-0 ingot, 99.9% 1g
S: 22-24/25
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,321-4 powder, 99.9% 1g
R: 11 S: 16-33-36/37/39
345
Metals
Thulium 26,570-5 wire, diam. 1.0 mm, 99.999% 2.8 g

14 g of 250 cm 14 g
CAS No. 7440-30-4 2.8 g of 50 cm
Tm FW 168.9 R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,297-8 chips, 99.9% 1g 35,695-6 wire, diam. 0.5 mm, 99.999% 7g
Density. . . . . . . . . . . . . . . . 9.332 g/mL (lit.) 5 g Density. . . . . . . . . . . . . . . . 7.31 g/mL (lit.) 35 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 g of 25 m
26,128-9 ingot, 99.9% 1g 7 g of 5 m
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 36/37/38 S: 26-36
26,322-2 powder, 40 mesh, 99.9% 1g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 15-17-36/37 S: 26-36-43 5g 26,569-1 wire, diam. 0.25 mm, 99.99% 700 mg
R: 36/37/38 S: 26-36 3.5 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tin 27,635-9 wire, diam. 2.0 mm, 99.97% 5.6 g
56 g
CAS No. 7440-31-5
Sn FW 118.7 Titanium See: Metals & Alloys Page 47

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tungsten
26,565-9 bar, 99.999% 100 g
Density. . . . . . . . . . . . . . . 7.31 g/mL (lit.) 250 g
CAS No. 7440-33-7
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . W FW 183.8
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
18 g 46,041-9 foil, thickness 1.0 mm, 99.9+% 23.5 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
35,731-6 foil, thickness 0.1 mm, 99.999% 1.8 g 94 g
Density. . . . . . . . . . . . . . . . . 7.3 g/mL (lit.) 7.2 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.8 g of 50 · 50 mm
35,718-9 foil, thickness 0.5 mm, 99.9+% 6g
24 g of 50 · 50 mm 24 g
7.2 g of 100 · 100 mm
6 g of 25 · 25 mm 96 g
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 g of 100 · 100 mm
Microelectronics
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.5 g of 50 · 500 mm 26,754-6 foil, thickness 0.25 mm, 99.9+% 12 g
4.5 g
900 mg of 50 · 100 mm 12 g of 50 · 50 mm 48 g
48 g of 100 · 100 mm
R: 36/37/38 S: 26-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,575-6 foil, thickness 0.5 mm, 99.998% 9g 35,719-7 foil, thickness 0.127 mm, 99.9+% 6g
36 g of 100 · 100 mm 24 g of 100 · 100 mm 24 g
36 g
9 g of 50 · 50 mm 6 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,753-8 foil, thickness 0.05 mm, 99.9+% 2.4 g
2.4 g of 50 · 50 mm 9.6 g
46,038-9 foil, thickness 1.0 mm, 99.9% 19 g
mp . . . . . . . . . . . . . . . . . . . 231.9 C (lit.) 78 g 9.6 g of 100 · 100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . 7.31 g/mL (lit.)
35,742-1 powder, 10 mm, 99.99+% 10 g
19 g of 50 · 50 mm
800.558.9196 (USA)
R: 17-36/38 S: 6-26-36 100 g
78 g of 100 · 100 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36 20,476-5 powder, 100 mesh, 99.95% 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 17-36/38 S: 6-26-36
26,823-2 foil, thickness 0.33 mm, 99.9% 55 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
55 g of 150 · 150 mm 51,010-6 monocrystalline powder, 0.6-1 mm, 100 g
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 99.9+% 500 g
35,694-8 foil, thickness 0.127 mm, 99.9% 20.7 g R: 17-36/38 S: 6-26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . 7.31 g/mL (lit.)
26,751-1 powder, 12 mm, 99.9% 25 g
20.7 g of 150 · 150 mm
R: 17-36/38 S: 6-26-36 100 g
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 500 g Ordering/Pricing: www.sigma-aldrich.com
26,567-5 rod, diam. 6 mm, 99.998% 20 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36 27,632-4 rod, diam. 4.0 mm, 99.99% 24 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 g of 100 mm
20,469-2 shot, 99.999% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Applied in the solid state synthesis of a Zintl 50 g 26,756-2 wire, diam. 1.0 mm, 99.99% 15 g
15 g of 1 m
phase, SrSn3Sb4, with an anionic channel . . . . . . . . . . . . . . . . . . . . . . . . . . . .
framework of 30-membered rings. Chow, D.T. et al. 26,755-4 wire, diam. 0.25 mm, 99.9+% 9.5 g
Inorg. Chem. 1997, 36, 3750. 9.5 g of 10 m 95 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231.9 C (lit.) 95 g of 100 m
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 7.3 g/mL (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 36/37/38 S: 26-36 35,697-2 wire, diam. 0.5 mm, 99.9+% 18.9 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 18.9 g of 5 m 94.5 g
26,759-7 shot, 3 mm, 99.95% 25 g 94.5 g of 25 m
Applied in the solid state synthesis of a 100 g
Zintl phase, SrSn3Sb4, with an anionic
channel framework of 30-membered rings. Chow, D.T. et
al. Inorg. Chem. 1997, 36, 3750.
R: 36/37/38 S: 26-36
346
Metals
Ytterbium 26,760-0 foil, thickness 0.1 mm, 99.999% 900 mg

Vapor pressure. . . . . . 1 mm Hg ( 487 C) 7.2 g
CAS No. 7440-64-4 7.2 g of 100 · 100 mm
Yb FW 173.0 900 mg of 25 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,298-6 chips, 99.9% 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . 824 C (lit.) 25 g 34,943-7 foil, thickness 0.05 mm, 99.999% 900 mg
Density. . . . . . . . . . . . . . . . 6.76 g/mL (lit.) 3.6 g of 100 · 100 mm 3.6 g
R: 36/37/38 S: 26-36 900 mg of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
54,880-4 chunks, 99.9% 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp . . . . . . . . . . . . . . . . . . . . 824 C (lit.) 25 g 35,598-4 foil, thickness 1.0 mm, 99.9% 18 g
Density. . . . . . . . . . . . . . . . 6.76 g/mL (lit.) 18 g of 50 · 50 mm 72 g
R: 36/37/38 S: 26-36 72 g of 100 ·100 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,130-0 ingot, 99.9% 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 20/21/22 S: 36 25 g 35,599-2 foil, thickness 0.5 mm, 99.9% 9.2 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 g of 100 · 100 mm 36 g
46,606-9 powder, 99.9+% 2g 9.2 g of 50 · 50 mm
Density. . . . . . . . . . . . . . . . 6.54 g/mL (lit.) 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 11-20/21/22 S: 16-33-36
26,129-7 powder, -40 mesh, 99.9% 2g 18 g of 100 · 100 mm 18 g
4.5 g of 50 · 50 mm
Packaged under oil 10 g
R: 11-20/21/22 S: 16-33-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Yttrium 2.3 g of 50 · 50 mm 9.2 g
9.2 g of 100 · 100 mm
CAS No. 7440-65-5
Y FW 88.91 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
21,550-3 mossy, 99.99% 1 kg

. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
Vapor pressure. . . . . . . . . 1 mm Hg ( 487 C)

26,299-4 chips, 99.9% 5g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . 4.472 g/mL (lit.) 25 g 26,635-3 pieces, 2-14 mesh, 99.9% 500 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor pressure. . . . . . . 1 mm Hg ( 487 C) 2 kg
45,134-7 dendritic pieces, 99.9% 1g
R: 20/21/22 S: 16-27-33-36/37/39 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32,493-0 powder, -100 mesh, 99.998% 10 g
26,131-9 ingot, 99.9% 10 g High purity zinc was used in the solid state 50 g
50 g synthesis of a zinc-centered Zintl phase,
. . . . . . . . . . . . . . . . . . . . . . . . . . . . K8Tl10Zn, which has a distorted bicapped antiprismatic
26,132-7 powder, -40 mesh, 99.9% 5g
Tl10. Dong, Z-C. et al. Inorg. Chem. 1997, 36, 3559.
R: 20/21/22 S: 16-27-33-36/37/39 25 g Vapor pressure. . . . . . . . . . . . . . . . . . .1 mm Hg ( 487 C)
R: 15-17 S: 43-7/8
Zinc . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,763-5 shot, 5 mm, 99.9999% 25 g
CAS No. 7440-66-6 Vapor pressure. . . . . . . . 1 mm Hg ( 487 C) 100 g
Zn FW 65.39
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 26,487-3 shot, 5 mm, 99.995% 50 g
26,762-7 foil, thickness 1.25 mm, 99.999% 5.6 g Vapor pressure. . . . . . . . 1 mm Hg ( 487 C) 250 g
Vapor pressure. . . . . . . 1 mm Hg ( 487 C) 22.5 g
22.5 g of 50 · 50 mm
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.6 g of 25 · 25 mm 40,258-3 shot, 1-2 mm, 99.99% 250 g
mp . . . . . . . . . . . . . . . . . 419.5 C (lit.) 1 kg
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Density. . . . . . . . . . . . . . . 7.14 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
High purity zinc was used in the solid state 18 g
26,636-1 sticks, diam. 6-8 mm, 99.99% 500 g
synthesis of a zinc-centered Zintl phase, Vapor pressure. . . . . . . 1 mm Hg ( 487 C) 2 kg
K8Tl10Zn, which has a distorted bicapped antiprismatic
Tl10. Dong, Z-C. et al. Inorg. Chem. 1997, 36, 3559. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
18 g of 50 · 50 mm 26,793-7 wire, diam. 2.0 mm, 99.999% 4.4 g
4.5 g of 25 · 25 mm Vapor pressure. . . . . . . . 1 mm Hg ( 487 C) 22 g
22 g of 100 cm
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.4 g of 20 cm
High purity zinc was used in the solid state 9 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
synthesis of a zinc-centered Zintl phase, 26,792-9 wire, diam. 1.0 mm, 99.999% 1.4 g
K8Tl10Zn, which has a distorted bicapped antiprismatic Vapor pressure. . . . . . . . 1 mm Hg ( 487 C) 5.6 g
1.4 g of 25 cm
Tl10. Dong, Z-C. et al. Inorg. Chem. 1997, 36, 3559.
5.6 g of 100 cm
2.3 g of 25 · 25 mm
9 g of 50 · 50 mm . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 35,597-6 wire, diam. 0.25 mm, 99.999% 720 mg
26,761-9 foil, thickness 0.25 mm, 99.999% 4.5 g 3.6 g
18 g of 100 · 100 mm
4.5 g of 50 · 50 mm
347
Metals
35,596-8 wire, diam. 0.5 mm, 99.995% 1.4 g

1.4 g of 1 m 7g
Polyamic Acids for High k Dielectrics
7 g of 5 m
Poly(pyromellitic dianhydride-co-4,4¢-oxydianiline), amic
. . . . . . . . . . . . . . . . . . . . . . . . . . . . acid solution
26,791-0 wire, diam. 0.25 mm, 99.99% 360 mg
1.8 g CAS No. 25038-81-7
(C22H14N2O7)n
Zirconium O O
NH C C NH O
CAS No. 7440-67-7 n
Zr FW 91.22 HO C C OH
O O
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
49,742-8 crystal bar, turnings, 99.9+% 25 g
R: 15-17 S: 43-7/8 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26,767-8 foil, thickness 0.025 mm, 99.95% 100 mg 43,117-6 electronic grade 1g

100 mg of 25 · 25 mm 400 mg Semi-conductor material. Dielectric 10 g
400 mg of 25 · 100 mm component in thin films, high density
interconnect systems and multichip modules.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Filtered through 0.2mm medium
41,914-1 foil, thickness 0.1 mm, 99.98% 4.6 g High purity material with controlled metallic content.
13.8 g of 50 · 450 mm 13.8 g
4.6 g of 50 · 150 mm
Polyimide has good thermal, mechanical and electrical
properties.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Forms insoluble polyimide upon heating
26,769-4 wire, diam. 0.127 mm, 99.95% 80 mg liquid (viscous)
Purified by sub-micron filtration (0.2 mm medium)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.506 (lit.)
Viscosity. . . 10-12 poise (12 rpm,, 25 C, Brookfield, spindle #3)
Alloys
Microelectronics
(lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 174 C/760 mm Hg (lit.)
Gallium-indium eutectic Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 F
Tg. . . . . . . . . . . . . . . . . . . . . . . . . . . . .>400 C (imide)
49,542-5 99.99+% 5g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.04 g/mL (lit.)
liquid 25 g R: 45-65
mp . . . . . . . . . . . . . . . . . . . . 15.7 C (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.25 g/mL (lit.) 57,580-1 (Pyre-M.L. RC-5019) 250 mL
15 wt. % in NMP 1L
Forms insoluble, inert polyimide upon 4L
Sodium mercury amalgam baking.
Viscous liquid
CAS No. 11110-52-4 Concentration. . . . . . . . . . . . . . . . 15.0-16.0 wt. % in NMP
Packaged under argon in ampules nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.507
800.558.9196 (USA)
R: 11-14/15-23/24/25-33-34-42/43 S: 16-26-36/37/39-45 Viscosity. . . . . . . . . . . . . . . . . . . . . . . . . . . 50-70 poise
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 F
45,189-4 beads, 99.9+% 10 g Density. . . . . . . . . . . . . . . . . . . . . . . . 1.166 g/mL 25 C
Magnetic characteristics were studied of 50 g R: 36/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
organometallic oxo-vanadium cluster
59,305-2 11 wt. % in NMP/aromatic 250 mL
compounds, such as [C5Me5V]4(m-O)6, which is formed by
hydrocarbons 1L
reduction with sodium mercury amalgam. Abernethy,
C.D. et al. Organometallics 1999, 18, 870.
baking.
Na 10% Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 F
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 C (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.066 g/mL
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Ordering/Pricing: www.sigma-aldrich.com
R: 45-65
45,190-8 beads, 99.9+% 10 g . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Magnetic characteristics were studied of 50 g 57,582-8 (Pyre-M.L. RC-5057) 250 mL
organometallic oxo-vanadium cluster 15.0 wt. %–5 wt. % in NMP/ 1L
compounds, such as [C5Me5V]4(m-O)6, which is formed by aromatic hydrocarbons (80%/20% 4L
reduction with sodiummercury amalgam. Abernethy, C.D. solvent ratio)
et al. Organometallics 1999, 18, 870. Forms insoluble, inert polyimide upon baking.
Na 5% Viscous liquid
Solubility
water. . . . . . . . . . . . . . . . . . . . . . . . . . . 65-71 wt. %
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.5120
Viscosity. . . . . . . . . . . . . . . . . . . . . . . . . . . 50-70 poise
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.090 g/mL
R: 45-65
348
Polyamic Acids for High k Dielectrics
(Continuation of) Cadmium sulfide

Poly(pyromellitic dianhydride-co-4,4¢-oxydianiline), amic
acid CAS No. 1306-23-6
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CdS FW 144.5
57,579-8 (Pyre-M.L. RC-5069) 250 mL Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.82 g/mL (lit.)
13 wt. % in NMP/aromatic 1L R: 22-40-48/23/25-53 S: 22-36/37-45-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
hydrocarbons 4L
21,792-1 powder, 99.995% 20 g
Forms insoluble, inert polyimide upon
100 g
baking . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Viscous liquid 20,818-3 powder 100 g
Solubility 500 g
water. . . . . . . . . . . . . . . . . . . . . . 65-71 wt. %, soluble
Concentration. . . . 12.3-13.3 wt. % (80% NMP/20% aromatic Cadmium telluride Coating quality Balzers
hydrocarbon)
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.5050
25,654-4 CAS No. 1306-25-8 10 g
Viscosity. . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-12 poise
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 F
CdTe FW 240.0 50 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.085 g/mL powder, 5 mm, 99.99+%
R: 45-65 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 6.2 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 20/21/22-50/53 S: 60-61
57,577-1 (Pyre-M.L. RK-692) 250 mL
12 wt. % in NMP/xylene 1L Gallium arsenide
baking. 32,901-0 CAS No. 1303-00-0 1g
Viscous liquid GaAs FW 144.6 5g
Solubility pieces, 99.999%
water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . miscible Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.31 g/mL (lit.)
Concentration. . 12.0 wt. %–0.5 wt. % (80% NMP/20% xylene) R: 23/25-50/53 S: 20/21-28-45-60-61
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.5052
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 F Gallium nitride
Microelectronics
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.095 g/mL

R: 10-20/21-36/38 S: 26-36 48,176-9 CAS No. 25617-97-4 10 g
Poly(trimellitic anhydride chloride-co-4,4¢-methylenedianiline) GaN FW 83.73 50 g
See: Polyimides Page 463 99.99+%
solid
Polyelectrolytes for SAMS See: Material for Lithography/ mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 800 C (lit.)
Nanopatterning Page 190 S: 22-24/25
Gallium phosphide
52,157-4 CAS No. 12063-98-8 2g
Semiconductors GaP FW 100.7 10 g
99.99%
Aluminum arsenide solid
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
40,122-6 CAS No. 22831-42-1 5g R: 15/29-28 S: 28-36/37-45
AlAs FW 101.9 25 g
-60 mesh Germanium(II) selenide
R: 23/25-50/53 S: 20/21-28-45-60-61
Aluminum nitride nanopowder See: Ceramic Nanopowders Page 48,455-5 CAS No. 12065-10-0 1g
376 GeSe FW 151.6 5g
99.999%
Aluminum nitride solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 670 C (lit.)
24,190-3 CAS No. 24304-00-5 50 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 5.6 g/mL (lit.)
R: 23/24/25-33-36/37/38 S: 26-28-36/37/39-45
AlN FW 40.99 250 g
powder, 10 mm, 98+%
Density. . . . . . . . . . . . . . . . . . . . . . 3.26 g/mL 25 C (lit.) Germanium(II) telluride
R: 36/37/38 S: 26-37/39
48,457-1 CAS No. 12025-39-7 5g
Cadmium selenide GeTe FW 200.2
99.999%
24,460-0 CAS No. 1306-24-7 10 g solid
CdSe FW 191.4 50 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 725 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.14 g/mL (lit.)
10 mm, 99.99%, electronic grade
Dispersions with CdS (Aldrich products 20,818-3, 21,792-
1) deposited on glass or Si substrates results in tunable
Indium(III) nitride
red, yellow, or green florescent material. 49,062-8 CAS No. 25617-98-5 1g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.81 g/mL (lit.)
References
InN FW 128.8 5g
Wang, Y. et al., J. Amer. Chem. Soc. 125, 2830 (2003) 99.9%
R: 20/21/22-50/53 S: 60-61 solid
349
Semiconductors
Indium(III) phosphide Zinc selenide Coating Quality Balzers

36,687-0 CAS No. 22398-80-7 1g CAS No. 1315-09-9
InP FW 145.8 ZnSe FW 144.4
pieces, 3-20 mesh, 99.998% Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.42 g/mL (lit.)
R: 23/25-33-50/53 S: 20/21-28-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Indium-tin oxide 24,461-9 powder, 5 mm, 99.99% 10 g
50 g
49,468-2 CAS No. 50926-11-9 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
55,301-8 random pieces, optical grade 25 g
In2O3SnO2 FW 428.3 100 g
-325 mesh, 99.99+%
Zinc telluride Coating Quality Balzers
solid
contains 10% tin oxide as dopant 25,432-0 CAS No. 1315-11-3 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 1.2 g/mL (lit.)
ZnTe FW 193.0 25 g
-100 mesh, 99.99%
Niobium nitride

Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.34 g/mL (lit.)
40,266-4 CAS No. 24621-21-4 25 g

NNb FW 106.9 100 g Zirconium nitride
-325 mesh
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 8.4 g/mL (lit.) 39,943-4 CAS No. 25658-42-8 25 g
ZrN FW 105.2 100 g
Silicon nitride -325 mesh
CAS No. 12033-89-5 For Cyclopentadienyl Lanthanide Dopants see section on Metal
Si3N4 FW 140.3 Organic Precursors See: Metal-Organic Precursors Page 303
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.44 g/mL (lit.)
R: 37 S: 22-24/25
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
33,410-3 powder, 99.9+% 25 g
100 g Sol-Gel Precursors
. . . . . . . . . . . . . . . . . . . . . . . . . . . . For a complete listing of silicon, germanium, tin, and lead products
32,517-1 -325 mesh, predominantly a-phase 50 g please request your copy of the Group 14 Compounds from Aldrich
250 g brochure.
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
24,862-2 -325 mesh, predominantly b-phase 5g
100 g Ammonium acetate
500 g
37,233-1 CAS No. 631-61-8 10 g
CH3COONH4 FW 77.08 100 g
Tantalum nitride
99.999%
33,320-4 CAS No. 12033-62-4 10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . 110-112 C (D) (lit.)
800.558.9196 (USA)
NTa FW 195.0 50 g
5 mm, 99.5% Acetylacetonates See: Metal b-dikenonates Page 295
For Nitrates See: Anhydrous Metal Nitrates Page 290
Titanium carbonitride
51,891-3 CAS No. 12654-86-3 250 g Aluminum
Ti2CN FW 121.8
powder, 1-2 mm, 99.8% Alumatrane tetramer
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >350 C (lit.)
47,739-7 (triethanolamine-aluminum complex) 10 g
Titanium nitride
CAS No. 94118-26-0 50 g
C24H48Al4N4O12 FW 692.6
33,324-7 CAS No. 25583-20-4 50 g ethylene glycol. . . . . . . . . . . . . . . . . . . . . . . . . . . <15%
TiN FW 61.87 250 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 270 C (D) (lit.)
10 mm, 99% Licensed under U.S. Patent 5 216 155
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 5.24 g/mL (lit.) R: 22-34-62-63 S: 53-26-36/37/39-45
O O O O
Vanadium nitride N Al N Al N Al N Al
O O O O
O O O O
33,633-5 CAS No. 24646-85-3 10 g
VN FW 64.95
-325 mesh, 99%
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 6.13 g/mL (lit.)
R: 20/21/22 S: 36
350
Sol-Gel Precursors
Aluminum
Aluminum acetate, basic Aluminum ethoxide

23,585-7 (Aluminum triethoxide) 5g
CAS No. 555-75-9 25 g
28,982-5 Aluminum acetate, basic 100 g
Al(OC2H5)3 FW 162.2 100 g
(hydroxyaluminum diacetate; Aluminum 500 g
97%
hydroxide acetate; Aluminum diacetate mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 157-160 C (lit.)
hydroxide) R: 11-14-37 S: 8-16-26-43
CAS No. 142-03-0 OCH CH
2 3
Insoluble form CH CH O
3 2
Al
No stabilizers added. OCH CH

2 3
S: 22-24/25
29,485-3 Aluminum acetate, basic 250 g

(dihydroxyaluminum acetate; 1 kg Aluminum isopropoxide
Dihydroxyaluminum acetate)
CAS No. 7360-44-3 (AIP; Aluminum isopropylate; Aluminum triisopropoxide)
contains boric acid as stabilizer CAS No. 555-31-7
Al 19% Al[OCH(CH3)2]3 FW 204.2
R: 20/21/22-36/37/38-40 S: 22-26-36 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138-142 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.035 g/mL (lit.)
Aluminum sec-butoxide R: 11 S: 8-16
CH
3
(Aluminum-tri-sec-butoxide) CH
3 O CH CH
3
CAS No. 2269-22-9 CH CH O Al
3
Al(OCH[CH3]C2H5)3 FW 246.3 O CH CH
3
Has been utilized in making high-surface-area alumina using CH
3
2,4-pentanedione (Aldrich product P775-4) as a chelating
agent.
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Microelectronics
bp. . . . . . . . . . . . . . . . . . . . . . . . . 200-206 C/30 mm Hg (lit.)

Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .82 F 22,940-7 99.99+% 10 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.967 g/mL (lit.) 50 g
References 250 g
Ji, L. et al., Chem. Mater. 12, 931 (2000) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 10-21/22 S: 16-26-36/37/39-43-45 22,041-8 98+% 5g
CH 100 g
3
O CH CH CH
2 3
1 kg
CH
3 Al
CH CH CH O O CH CH CH
3 2 2 3 Aluminum phenoxide
CH
3
49,513-1 CAS No. 15086-27-8 5g
Al(OC6H5)3 FW 306.3 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 99.9+%
51,160-9 99.99% 5g solid
liquid mp . . . . . . . . . . . . . . . . . . . . . . . . . . 156 C (dec.) (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 34 S: 26-36/37/39-45
20,107-3 97% 5g
Used in the preparation of photosensitive 100 g O
alumina gel films,1 microporous crystalline 500 g O Al
aluminophosphate AlPO-41,2 and pure O
alumina mesoporous material.3 (1) Zhao, G. Tohge, N.
Kobunshi Ronbunshu 1996, 53, 253 Chem. Abstr. 1996,
124, 328279f. (2) Clark, H.W. et al. Microporous Mater.
1996, 6, 115. (3) Vaudry, F. et al. Chem. Mater. 1996, 8,
1451.
Aluminum silicate See: Silicon Page 362
Aluminum tert-butoxide
Aluminum tributoxide
23,584-9 (Aluminum-tri-tert-butoxide) 10 g
CAS No. 556-91-2 50 g 40,335-0 (Aluminum butoxide) 5g
Al[OC(CH3)3]3 FW 246.3 CAS No. 3085-30-1 25 g
Technical Grade Al(OC(CH3)3)3 FW 246.3
R: 11-34 S: 8-16-26-36/37/39-45 95%
CH
3 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 103-110 C (lit.)
CH
3
C CH
3
R: 36/37/38 S: 26-36
O
CH CH OCH CH CH CH
3 Al 3 2 2 2 3
CH C O O C CH Al
3 3 CH CH CH CH O OCH CH CH CH
3 2 2 2 2 2 2 3
CH CH
3 3
351
Sol-Gel Precursors
Aluminum
Aluminum tri-sec-butoxide solution Antimony

55,890-7 Al(OC4H9)3 FW 246.3 500 mL Antimony(III) acetate
Concentration. . 1.0 M in methylene chloride 1L
bp. . . . . . . . . . . . . . . . . . . . . . .40 C 48,326-5 CAS No. 6923-52-0 100 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >221 F
C6H9O6Sb FW 298.9 500 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.237 g/mL
99.99%
R: 45-20/22-36/37/38-63 S: 53-23-36/37/39-45
CH
solid
3 mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 126-131 C (lit.)
O CH CH CH
CH
3 Al
2 3 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.22 g/mL (lit.)
CH CH CH O O CH CH CH R: 20/22-36/37/38 S: 22-26-36
3 2 2 3
CH
3
Antimony(III) butoxide solution
37,692-2 CAS No. 2155-74-0 50 mL
Cesium aluminum orthosilicate See: Silicon Page 362 Sb(OC4H9)3 FW 341.1 250 mL
65 wt. % in toluene

Cesium aluminum silicate See: Silicon Page 362
Reagent used in formation studies of poly(ethylene
Diethylaluminum ethoxide terephthalate).
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 F
Vapor pressure. . . . . . . . . . . . . . . . . 1.1 mm Hg ( 54.4 C)
CAS No. 1586-92-1
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.48 (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . . . . . . . 5 mm Hg ( 94 C)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.225 g/mL (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .-1 F
R: 10-23/24/25-36/37/38 S: 16-26-28-36/37/39-45
25,674-9 Diethylaluminum ethoxide 100 g OCH CH CH CH
2 2 2 3
(C2H5)2AlOC2H5 FW 130.2 CH CH CH CH O
Sb
OCH CH CH CH
3 2 2 2 2 2 2 3
97%
Packaged under nitrogen in Sure/Pac metal cylinders
bp. . . . . . . . . . . . . . . . . . . . . 108-109 C/10 mm Hg (lit.)
Microelectronics
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.5-4.5 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 0.85 g/mL (lit.) Antimony(III) ethoxide
R: 14/15-17-34 S: 16-26-27-36/37/39-45
21,331-4 CAS No. 10433-06-4 5g
19,278-3 Diethylaluminum ethoxide solution 100 g
Sb(OC2H5)3 FW 256.9 25 g
(C2H5)2AlOC2H5 FW 130.2 700 g n20
D . . . . . . . . . . . . . . . . . . . . . 1.495 (lit.)
25 wt. % in toluene Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 F
Packaged under nitrogen in Sure/Seal bottles Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.513 g/mL (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.862 g/mL (lit.) R: 36/37/38 S: 26-36/37/39
R: 11-14-17-23/24/25-34 S: 16-26-36/37/39-45
OCH CH
2 3
Lithium aluminate See: Salts Page 50 Sb
CH CH O OCH CH
3 2 2 3
Lithium tetrakis(dimethylamino)aluminate
800.558.9196 (USA)
47,068-6 CAS No. 114236-99-6 1g
LiAl(N(CH3)2)4 FW 210.2 5g Antimony(III) isopropoxide
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >255 C (lit.) 47,073-2 CAS No. 18770-47-3 5 mL
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 F Sb(OCH(CH3)2)3 FW 299.0 25 mL
R: 34 S: 26-27-36/37/39-45
98%
CH
3
CH
3 liquid
N
CH
3
CH
3 bp. . . . . . . . . . . . . . . . . . . . . .53-54 C/0.25 mm Hg (lit.)
N Al N Li
CH CH Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 F Ordering/Pricing: www.sigma-aldrich.com
3 N 3
CH CH
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.307 g/mL (lit.)
3 3
R: 36/37/38 S: 26-36/37/39
CH
3
CH O CHCH
3 3
CH CH O Sb
3
O CHCH
3
Triethanolamine aluminate barium salt CH
3
47,745-1 C18H37Al2BaN3O9 FW 630.8 5g

R: 20/22 S: 28 25 g
Antimony(III) methoxide
53,834-5 Sb(OCH3)3 FW 214.9 5g
solid 25 g
mp . . . . . . . . . . . . . . . . . 123-127 C (lit.)
R: 20/22-36/37/38-51/53 S: 26-36-61
OCH
3
Sb
CH O OCH
3 3
352
Sol-Gel Precursors
Antimony
Antimony(III) propoxide Barium tetrahydrofurfuryloxide solution

47,072-4 CAS No. 4292-34-6 5 mL 51,704-6 CAS No. 134358-56-8 100 mL
Sb(OC3H7)3 FW 299.0 25 mL C10H18BaO4 FW 339.6
98% 40 wt. % in tetrahydrofurfuryl alcohol and ethyl
R: 36/37/38 S: 26-36/37/39 alcohol
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.445 (lit.)
Barium bp. . . . . . . . . . . . . . . . . . . . . . 96-97 C/760 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 F
Barium acetate Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.14 g/mL (lit.)
R: 11-22-36/37/38 S: 16-26-36
25,591-2 CAS No. 543-80-6 10 g
(CH3COO)2Ba FW 255.4 50 g
2
99.999% O CH O
2
Ba
2
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.47 g/mL (lit.)
R: 20/22 S: 28
Barium aluminate Barium titanium(IV) tetrahydrofuryloxide solution See: Titanium

Page 367
43,401-9 (Barium aluminum oxide) 50 g
CAS No. 12004-04-5 250 g
Al2BaO4 FW 255.3 Bismuth
R: 20/22 S: 28
Bismuth(III) acetate
Barium 2-ethylhexanoate
40,158-7 (acetic acid bismuth(III) salt) 10 g
36,170-4 CAS No. 2457-01-4 5g
CAS No. 22306-37-2 50 g
C8H18BaO2 FW 283.6
C2H7BiO2 FW 272.1
Microelectronics
98%
99.99+%
Used in the preparation of thin-film superconductors.
Aldrichimica Acta 1990, 23, 54. Bismuth aluminate hydrate
R: 20/22 S: 28
51,028-9 CAS No. 308796-32-9 500 g
Barium isopropoxide Bi2(Al2O4)3 xH2O FW 771.8
99.9+%
CAS No. 24363-37-9
Ba(OCH(CH3)2)2 FW 255.5
R: 20/22 S: 28
Bismuth neodecanoate
CH CH O Ba O CHCH
3 3 54,413-2 CAS No. 34364-26-6 250 g
CH CH
3 3 C30H57BiO6 FW 722.8 1 kg
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.479 (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . bp. . . . . . . . . . . . . . . . . . . . . . . 300 C/760 mm Hg (lit.)
44,967-9 powder, 99.9% 2g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
For preparation of bimetallic Ba-Nb and Ba- 10 g Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.145 g/mL (lit.)
Zr alkoxides.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 200 C (dec.) (lit.) Boron
References
1. Turevskaya, E.P. et al., Polyhedron 14, 1531 (1995) Butyldiisopropoxyborane
2. Yamada, Y.M.A. Shibasaki, M., Tetrahedron Lett. 39, 5561
(1998) 27,797-5 (diisopropyl butylboronate) 10 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
CAS No. 86595-32-6
33,914-8 Technical Grade 5g
C10H23BO2 FW 186.1
25 g
98%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.395 (lit.)
Barium metasilicate bp. . . . . . . . . . . . . . . . . . . . 145-147 C/746 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 F
51,791-7 CAS No. 13255-26-0 100 g Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.794 g/mL (lit.)
BaO3Si FW 213.4 R: 10-36/37/38 S: 16-26-36/37/39
solid
Loss on ignition. . . . . . . . . . . . . . . . . . . . . . . . . . £10% Diethylmethoxyborane
R: 20/22 S: 28
CAS No. 7397-46-8
34,720-5 Diethylmethoxyborane 10 g
C5H13BO FW 99.97 50 g
97%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.387 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.761 g/mL (lit.)
R: 11-36/37/38 S: 16-26-27-36/37/39
353
Sol-Gel Precursors
Boron
32,883-9 Diethylmethoxyborane solution 100 mL Triisopropyl borate

(methyl diethylborinate) 500 mL
C5H13BO FW 99.97 19,733-5 (Triisopropoxyborane; Boric acid 80 g
1.0 M in tetrahydrofuran triisopropyl ester; Boron isopropoxide) 750 g
Packaged under nitrogen in Sure/Seal bottles CAS No. 5419-55-6
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -1 F [(CH3)2CHO]3B FW 188.1
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.868 g/mL (lit.) 98+%
R: 11-19-22-36/37/38 S: 16-26-27-36/37/39
Diisopropoxymethylborane isopropanol. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.376 (lit.)
28,368-1 CAS No. 86595-27-9 5g bp. . . . . . . . . . . . . . . . . . . . 139-141 C/760 mm Hg (lit.)
C7H17BO2 FW 144.0 Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.815 g/mL (lit.)
97% Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62.6 F
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.376 (lit.) R: 11 S: 7-16-23-24/25-33
bp. . . . . . . . . . . . . . . . . . . . 105-107 C/751 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 F Tripropyl borate

Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.781 g/mL (lit.)
R: 11-36/37/38 S: 16-26-36/37/39 22,492-8 (Boron propoxide) 80 g
CAS No. 688-71-1
2,2¢,2¢¢-Nitrilotriethyl borate C9H21BO3 FW 188.1
98%
T5,840-8 (Triethanolamine borate; Boratrane) 5g n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.395 (lit.)
CAS No. 283-56-7 100 g bp. . . . . . . . . . . . . . . . . . . . 175-177 C/760 mm Hg (lit.)
C6H12BNO3 FW 157.0 500 g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 F
97% Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.857 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235-237 (lit.) R: 10 S: 16-33
R: 36/37/38 S: 26-37/39
Cadmium
Microelectronics
O
N
B
Cadmium acetate
O O
28,915-9 Cadmium acetate dihydrate 5g

CAS No. 5743-04-4 100 g
Tri-tert-butyl borate Cd(CH3COO)2 2H2O FW 266.5 500 g
98%
23,660-8 (tri-tert-butoxyborane; Boron tert-butoxide) 50 g R: 20/21/22-50/53 S: 60-61
CAS No. 7397-43-5
C12H27BO3 FW 230.2 22,949-0 Cadmium acetate hydrate 25 g
98% CAS No. 89759-80-8 125 g
800.558.9196 (USA)
Packaged under nitrogen in Sure/Seal bottles 99.99+%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.389 (lit.)
Degree of hydration ~1-2
bp. . . . . . . . . . . . . . . . . . . . . . . . 101 C/74 mm Hg (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.01 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18-19 C (lit.) R: 45 S: 53-26-28-36/37/39-45
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.811 g/mL (lit.)
R: 10 S: 16-33 Calcium
Triethoxyarsine Calcium acetate
27,274-4 CAS No. 3141-12-6 250 mg Ordering/Pricing: www.sigma-aldrich.com
C6H15AsO3 FW 210.1 1g
97% 40,285-0 Calcium acetate monohydrate 100 g
R: 23/25-50/53 S: 20/21-28-45-60-61 CAS No. 5743-26-0 500 g
Ca(C2H3O2)2 H2O FW 176.2
Triethyl borate 99+%, ACS reagent
‡99.0%
T5,930-7 (Triethoxyborane; Boric acid triethyl 100 mL Titr. Acid. . . . . . . . . . . . . . . . . . . . . . . . . £0.035 meq/g
ester; Boron ethoxide) 500 mL insolubles. . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
CAS No. 150-46-9 Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
(C2H5O)3B FW 146.0
Ba. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
99% Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
Packaged under nitrogen in Sure/Seal bottles Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . 5.04 (vs air) K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.374 (lit.) Mg. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.05%
bp. . . . . . . . . . . . . . . . . . . . 117-118 C/760 mm Hg (lit.) Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.02%
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 F Sr. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.05%
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.858 g/mL (lit.)
R: 11 S: 7-16-23
354
Sol-Gel Precursors
Calcium
(Continuation of) Cesium

Calcium acetate
Cesium acetate
37,996-4 Calcium acetate hydrate 5g
CAS No. 62-54-4 25 g CAS No. 3396-11-0
(CH3COO)2Ca aq FW 158.2 CH3COOCs FW 192.0
99.99% S: 22-24/25
acetic acid. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . <1% . . . . . . . . . . . . . . . . . . . . . . . . . . . .
S: 22-24/25 45,015-4 99.99+% 25 g
mp . . . . . . . . . . . . . . . . . . . 194 C (lit.) 100 g
O . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CH C O Ca xH2O
3 2 32,982-7 99.9% (Purity determined on metals 25 g
basis) 100 g
Chromium
Calcium 2-ethylhexanoate
Chromium(II) acetate,dimer monohydrate
36,296-4 CAS No. 136-51-6 5g
C8H18CaO2 FW 186.3 25 g 23,801-5 CAS No. 14976-80-8 10 g
98% 50 g
R: 36/37/38 S: 26-37/39
Chromium(III) acetate hydroxide
Calcium isopropoxide
31,810-8 CAS No. 39430-51-8 5g
49,739-8 CAS No. 15571-51-4 2g
C14H23Cr3O16 FW 603.3 250 g
Ca(OCH(CH3)2)2 FW 158.3 10 g
Cr 24% 1 kg
powder, 99.9+% R: 20/21/22-36/37/38 S: 26-37/39
R: 34 S: 26-27-36/37/39-45
CH CH O Ca O CHCH
3 3
Microelectronics
CH
3
CH
3 Cobalt
Cobalt(II) acetate
Calcium methoxide R: 22-36/37/38-40-43-53 S: 22-26-36/37/39-45
39,997-3 Cobalt(II) acetate 1g

44,556-8 CAS No. 2556-53-8 10 g
CAS No. 71-48-7 10 g
Ca(OCH3)3 FW 102.1 50 g
C4H6CoO4 FW 177.0
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >385 C (lit.) 99.995%
R: 20/22-36/38-41 S: 24-26-36-45 water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 298 C (D) (lit.)
Calcium silicate See: Silicon Page 362
43,787-5 Cobalt(II) acetate tetrahydrate 1g

Cerium (Cobaltous acetate tetrahydrate) 10 g
CAS No. 6147-53-1
Cerium(III) acetate hydrate (CH3COO)2Co 4H2O FW 249.1
99.999%
CAS No. 206996-60-3 Used to prepare complexes for examination of the
properties of metals with unusual coordination
. . . . . . . . . . . . . . . . . . . . . . . . . . . . geometries. Jaynes, B.S. et al. Inorg. Chem. 1995, 34,
52,955-9 99.999% 10 g
5735.
solid 50 g Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.71 g/mL (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
36,775-3 99.9% 50 g
Degree of hydration ~1-3 250 g
acetic acid. . . . . . . . . . . . . . . . . . . .£1% Cobalt(II) 2-ethylhexanoate solution
44,454-5 CAS No. 136-52-7 100 mL
Cerium(III) 2-ethylhexanoate
C16H30CoO4 FW 345.3 500 mL
44,557-6 CAS No. 56797-01-4 5g 65 wt. % in mineral spirits
C24H45CeO6 FW 569.7 25 g Polymerization accelerator
mp . . . . . . . . . . . . . . . . . . . >300 C (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 F
R: 20/21/22-36/37/38 S: 26-36 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.002 g/mL (lit.)
R: 45-10-36/37/38 S: 53-16-23-36/37/39-45
355
Sol-Gel Precursors
Copper
Copper(I) acetate Erbium

40,334-2 CAS No. 598-54-9 1g Erbium(III) acetate hydrate
C2H3CuO2 FW 122.6 10 g
97% 32,557-0 CAS No. 304675-52-3 10 g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250 C (D) (lit.) 99.9% 50 g
R: 36/37/38 S: 26-37/39 Degree of hydration £4
Copper(II) acetate Erbium(III) isopropoxide

47,884-9 CAS No. 14814-07-4 1g
Er(OCH(CH3)2)3 FW 344.5
Copper(II) acetate
99%
(Cupric acetate)
Precursor for aluminum-erbium complexes for active
CAS No. 142-71-2
optical fibers.,
(CH3CO2)2Cu FW 181.6
solid
R: 22-36/37/38 S: 26-36

. . . . . . . . . . . . . . . . . . . . . . . . . . . . mp . . . . . . . . . . . . . . . . . . . . . . . . . . 325 C (dec.) (lit.)
51,745-3 99.999% 5g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 F
References
solid 25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Zverev, Yu.B. et al., Vysokochist, Veshchestva 79 (1996)
32,675-5 98% 25 g R: 34 S: 26-27-28-36/37/39-45
Vapor density. . . . . . . . . . . . . . 6.9 (vs air) 100 g CH
3
CH O CHCH
3 3
22,960-1 Copper(II) acetate monohydrate 10 g CH CH O
3
Er
O CHCH
(Cupric acetate monohydrate) 50 g 3
CH
CAS No. 6046-93-1 3
(CH3COO)2Cu H2O FW 199.7

99.99+%
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . 6.8 (vs air)
Microelectronics
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.882 g/mL (lit.)
R: 22-36/37/38 S: 36/37/39 Gadolinium
34,174-6 Copper(II) acetate hydrate 5g Gadolinium(III) acetate hydrate
CAS No. 66923-66-8 100 g
98% 500 g 32,567-8 CAS No. 100587-93-7 25 g
Degree of hydration ~1 2.5 kg 99.9% 100 g
Vapor density. . . . . . . . . . . . . . 6.9 (vs air) R: 36/37/38 S: 26-37/39
R: 20-36/37/38 S: 22-26-36/37/39-38
Gadolinium(III) octanoate
Copper(II) 2-ethylhexanoate
41,326-7 CAS No. 29911-73-7 1g
33,732-3 CAS No. 149-11-1 5g C8H16GdO2 FW 301.5 5g
800.558.9196 (USA)
C8H16CuO2 FW 207.8 25 g 97%
mp . . . . . . . . . . . . . . . . . . 252 C (D) (lit.) R: 36/37/38 S: 26-36
R: 36/37/38 S: 26-37/39
Copper(II) methoxide Germanium

33,266-6 CAS No. 1184-54-9 5g Germanium(IV) ethoxide
C4(OCH3)2 FW 125.6 25 g
97% 33,918-0 (Tetraethoxygermanium) 1g
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 206 C (dec.) (lit.) CAS No. 14165-55-0 5g
R: 36/37/38 S: 26-27-36/37/39 Ge(OC2H5)4 FW 252.9 25 g Ordering/Pricing: www.sigma-aldrich.com
99.95+%
Copper(II) trifluoroacetate hydrate Sol-gel intermediate for optical fibers1 and photosensitive
SiO2-BeO2 glasses.2 (1) Mat. Res. Symp. Proc. 1986, 73,
31,118-9 CAS No. 123333-88-0 1g
443. (2) Non-Cryst. Solids 1994, 168, 195.
R: 36/37/38 S: 26-37/39 5g toluene. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . contains
Si. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .£0.01%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.407 (lit.)
Dysprosium Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.14 g/mL (lit.)
Dysprosium(III) acetate hydrate R: 10-23/24/25 S: 16-26-27-36/37/39-45
32,553-8 CAS No. 304675-49-8 25 g

99.9%
Degree of hydration £4
R: 36/37/38 S: 26-37/39
356
Sol-Gel Precursors
Germanium
Germanium(IV) isopropoxide Tetrakis(1-methoxy-2-methyl-propoxy)hafnium

44,764-1 (tetraisopropoxygermanium) 1g 56,817-1 CAS No. 309915-48-8 10 g
CAS No. 21154-48-3 5g Hf(OC(CH3)2CH2OCH3)4 FW 591.0 25 g
Ge(OCH(CH3)2)3 FW 309.0 99.99%, electronic grade
97% bp. . . . . . . . . . . . . . . . . . . . . . . . . . . . 135 C/0.01 atm
bp. . . . . . . . . . . . . . . . . . . . . . . 167 C/760 mm Hg (lit.) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 F
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 F Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.303 g/mL
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.033 g/mL (lit.) CH
CH 3
R: 34 S: 26-27-28-36/37/39-45 3 O
OCH(CH )
32 O Hf
(CH ) CHO Ge OCH(CH )
32 32 CH
3
OCH(CH )
32 4
Germanium(IV) methoxide
39,636-2 (tetramethoxygermanium) 1g
CAS No. 992-91-6 5g
Ge(OCH3)4 FW 196.8
97%
Sol-gel intermediate in the formation of GeS2 and IR-
transparent optics. Ceram. Bull. 1984, 63, 1427. J. Am.
Chem. Soc. 1990, 112, 5636.
methyl alcohol. . . . . . . . . . . . . . . . . . . . . . . . . . . . £5%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.399 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . 66-67 C/36 mm Hg (lit.)

mp . . . . . . . . . . . . . . . . . . . . . . . . . . -18 C (dec.) (lit.)
Microelectronics
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 F
1
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.325 g/mL (lit.) H NMR spectrum of Aldrich product 56,817-1, lot 92217AA
R: 10-23/24/25-36/37/38 S: 16-26-36/37/39-45
Holmium
Hafnium
Holmium(III) acetate hydrate
Hafnium tert-butoxide
46,733-2 CAS No. 312619-49-1 2g
44,554-1 CAS No. 2172-02-3 1g 99.99% 10 g
C16H36HfO4 FW 470.9 5g
99.99% (Purity excludes ~2000 ppm
zirconium.) Indium
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.424 (lit.)
Indium(III) acetate
bp. . . . . . . . . . . . . . . . . . . . . . . . . .90 C/5 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.166 g/mL (lit.)
R: 10 S: 16-26-36 51,027-0 Indium(III) acetate 10 g
CAS No. 25114-58-3 50 g
C6H9InO6 FW 292.0
99.99%
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 270 C (D) (lit.)
34,237-8 Indium(III) acetate hydrate 5g

CAS No. 304671-64-5 25 g
99.99%
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357
Sol-Gel Precursors
Indium
Indium(III) tert-butoxide solution Lanthanum

47,972-1 CAS No. 62763-52-4 25 mL Lanthanum acetate hydrate
In(OC(CH3)3)3 FW 334.2 100 mL
5 % (w/v) in tert-butanol, 99.9+% CAS No. 917-70-4
liquid (CH3COO)3La aq FW 316.0
bp. . . . . . . . . . . . . . . . . . . . . . . . 84 C/760 mm Hg (lit.) . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 F 54,208-3 99.99+% 5g
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.806 g/mL (lit.) solid 25 g
R: 60-11-20-34 S: 53-16-36/37/39-45 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CH
30,633-9 99.9% 5g
3
CH C CH Used in the synthesis of a novel 100 g
3 3
O phenolate-bridged dilanthanum(III) 500 g
CH CH
3 In 3 complex which has potential as a model
CH C O O C CH
3 3 for metalloproteins as well as in basic and applied
CH CH
3 3 chemistry. Wang, Z. et al. Inorg. Chem. 1997, 36, 629.

Indium(III) isopropoxide solution Lead
47,971-3 CAS No. 38218-24-5 25 mL Lead(II) acetate trihydrate
In(OCH(CH3)2)3 FW 292.1 100 mL
5 % (w/v) in 2-propanol, 99.9+% CAS No. 6080-56-4
Precursor for thin In2O3 conductive layers which improve Pb(CH3COO)2 3H2O FW 379.3
the luminance and aging characteristics of the R: 61-33-48/22-50/53-62 S: 53-45-60-61
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
cathodoluminescence of phosphors used in cathode ray
31,651-2 99.999% 5g
tubes.,
25 g
liquid
100 g
Microelectronics
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 F . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.808 g/mL (lit.) 46,786-3 99.99+%, ReagentPlus, 99.0-103.0% 50 g
References total metallic impurities. . . . . . . . <100 ppm 250 g
1. Kominami, H. et al., Jpn. J. Appl. Phys., Part 2 35, L1600 (1996) insolubles. . . . . . . . . . . . . . . . . . £0.01%
2. Kominami, H. et al., Appl. Surf. Sci. 113/114, 519 (1997) mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . .75 C (D) (lit.)
R: 11-36/37/38-41 S: 16-26-33-36 Density. . . . . . . . . . . . . . . . . . . . . . . . . . 2.55 g/mL (lit.)
CH
3 Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
3
CH O CHCH
3 NO3- and NO2-. . . . . . . . . . . . . . . . . . . . . . . . £0.005%
CH CH O In Ca. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
3
O CHCH
3 Cu. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
CH
3 Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
Trademark of Sigma-Aldrich Co.
800.558.9196 (USA)
Iridium Lead(IV) acetate
Iridium(II,III) m-oxoacetate trihydrate 39,884-5 (lead tetraacetate) 5g

CAS No. 546-67-8 25 g
51,110-2 CAS No. 308847-83-8 1g Pb(CH3COO)4 FW 443.4
solid 99.99+%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317 C (D) (lit.) R: 61-8-20/22-33-50/53-62 S: 53-17-36/37-45-60-61
R: 36/37/38 S: 26-36 lead tetraacetate See: Lead(IV) acetate Page 357
Iron Lead(II) trifluoroacetate
Iron(II) acetate 40,483-7 CAS No. 4146-73-0 5g

R: 20/21/22-33 S: 36 25 g
CAS No. 3094-87-9 For Lithium Containing Precursors See: Lithium Alkoxides Page 158
C4H6FeO4 FW 173.9
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190-200 C (D) (lit.)
R: 36/37/38 S: 26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Lutetium
51,793-3 99.995% 5g
solid 25 g Lutetium(III) acetate hydrate
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,919-9 95% 10 g 32,578-3 CAS No. 304675-59-0 1g
50 g 99.9% 5g
358
Sol-Gel Precursors
Magnesium
Magnesium acetate tetrahydrate 23,717-5 99%, ACS reagent 100 g

98.0-102.0% 500 g
22,976-8 (Acetic acid magnesium salt) 10 g Vapor density. . . . . . . . . . . . . . .6 (vs air) 2.5 kg
CAS No. 16674-78-5 100 g insolubles. . . . . . . . . . . . . . . . .£0.005%
pH range. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5.0-8.2
(CH3COO)2Mg 4H2O FW 214.5
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 C (lit.)
99.999% Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.636 g/mL (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 C (lit.) Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.454 g/mL (lit.) PO43-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
S: 22-24/25 SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
Ba. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
Magnesium ethoxide Ca. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01%
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
29,184-6 (Magnesium ethylate) 5g
Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm

CAS No. 2414-98-4 100 g K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
Mg(OC2H5)2 FW 114.4 Mn. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
98% NH4+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.003%
R: 11-14-36 S: 26-36-43 Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
CH CH O Mg OCH CH Sr. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
3 2 2 3
Manganese
Magnesium methoxide solution Manganese(II) acetate
33,565-7 CAS No. 109-88-6 500 mL
Mg(OCH3)2 FW 58.36 2L
6-10 wt. % in methanol 33,082-5 Manganese(II) acetate 5g
Employed in a sol-gel preparation of nanocrystalline MgO CAS No. 638-38-0 25 g
with 1.8-35 nm particle sizes. Chadwick, A.V. et al. Chem. C2H4MnO2 FW 115.0 100 g
Mater. 1998, 10, 864. 98%
Microelectronics
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3381 (lit.) R: 20/21/22-36/37/38-40 S: 26-27-36/37/39
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.816 g/mL (lit.) Manganese(II) acetate tetrahydrate
R: 23/24/25-39/23/24/25 S: 36/37-45 (Manganous acetate)
CAS No. 6156-78-1
Magnesium nitrate hexahydrate (CH3COO)2Mn 4H2O FW 245.1
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.589 g/mL (lit.)
CAS No. 13446-18-9 R: 36/37/38 S: 26-36
Mg(NO3)2 6H2O FW 256.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R: 8-36/37/38 S: 17-26-36 22,977-6 99.99% 50 g
Mg(NO ) 6H O 500 g
32 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
22,100-7 99+% 25 g
mp . . . . . . . . . . . . . . . . . . >300 C (lit.) 500 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 kg
52,936-2 99.999+% 5g
solid 25 g Manganese(III) acetate dihydrate
mp . . . . . . . . . . . . . . . . . . . . . 89 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.64 g/mL (lit.) 21,588-0 CAS No. 19513-05-4 5g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . (CH3COO)3Mn 2H2O FW 268.1 25 g
20,369-6 99.995+% 10 g
97% 100 g
Vapor density. . . . . . . . . . . . . . . . 6 (vs air) 50 g
R: 36/37/38 S: 26-36
mp . . . . . . . . . . . . . . . . . . . . . 89 C (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.636 g/mL (lit.) Manganous acetate See: Manganese(II) acetate Page 358
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
46,789-8 ReagentPlus, 99.99+% 50 g
98.0-102.0% 250 g Molybdenum
total metallic impurities. . . . . . . . <100 ppm
insolubles. . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
pH range. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5.0-8.2
2,6-Diisopropylphenylimidoneophylidenebis1,1,1,3,3,3-
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 C (dec.) (lit.) hexafluoro-tert-butoxy)molybdenum(VI)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.636 g/mL (lit.)
Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001% 57,654-9 C30H35F12MoNO2 FW 765.5 100 mg
PO43-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm CH
3 500 mg
SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005% CH CF
CH CH
3 2g
3 3
Ba. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005% C
Ca. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.01% CF
3 O N
CHCH
Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm Mo 3
CF O CH CH
K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005% 3 3
C CH C CH
Mn. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm CH CF
3 3
3 3
NH4+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.003%
Na. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
Sr. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
359
Sol-Gel Precursors
Molybdenum
2,6-Diisopropylphenylimidoneophylidenebis(tert-butox- Nickel(II) 2-ethylhexanoate

y)molybdenum(VI)
33,818-4 (2-ethylhexanoic acid nickel(II) salt) 25 mL
57,653-0 CAS No. 126949-65-3 100 mg CAS No. 4454-16-4
C30H47MoNO2 FW 549.6 500 mg C8H16NiO2 FW 202.9
CH
3 2g liquid (Highly viscous)
CH
3
CH
3
CH
3
CH Ni 15%
C Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
CH
3 O N Density. . . . . . . . . . . . . . . . . . . . . . . . . . 0.96 g/mL (lit.)
Mo CHCH
3 R: 45-20/21/22-36/37/38 S: 53-26-36/37/39-45
CH O CH CH
3 3
C CH C CH
CH
3
CH
3
3 3
Nickel(II) octanoate hydrate
30,999-0 (octanoic acid nickel(II) salt hydrate) 5g
CAS No. 304656-41-5 25 g
98%
R: 45-46-20/21/22 S: 53-36/37/39-45

Molybdenum(II) acetate dimer Octanoic acid nickel(II) salt hydrate See: Nickel(II) octanoate Page
359
23,207-6 (Di-molybdenum tetraacetate) 1g
CAS No. 14221-06-8 5g
Mo2(OCOCH3)4 FW 428.1 Niobium
98%
S: 22-24/25 Niobium(V) ethoxide
33,920-2 CAS No. 3236-82-6 5g
Neodymium Nb(OCH2CH3)5 FW 318.2 50 g
99.95%
Neodymium(III) acetate hydrate n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.516 (lit.)
Microelectronics
bp. . . . . . . . . . . . . . . . . . . . . 140-142 C/0.1 mm Hg (lit.)
32,580-5 CAS No. 16648-22-9 50 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 C (lit.)
99.9% 250 g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97 F
R: 36/37/38 S: 26-37/39 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.268 g/mL (lit.)
R: 10-34 S: 26-36/37/39-45
Neodymium(III) isopropoxide (CH CH O) Nb
3 2 5
41,010-1 CAS No. 19236-15-8 1g

Nd(OCH(CH3)2)3 FW 204.3
99.8%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) Palladium
R: 11-34 S: 16-26-33-36/37/39-45
CH
3 Palladium(II) acetate
800.558.9196 (USA)
CH
3 O CHCH
3
CH CH O Nd
3
O CHCH
CAS No. 3375-31-3
3
CH (CH3COO)2Pd FW 224.5
3
R: 41 S: 26-39
O
CH C O
3 2Pd
Nickel
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Acetic acid nickel(II) salt See: Nickel(II) acetate Page 359
37,987-5 99.98% 1g
2-ethylhexanoic acid nickel(II) salt See: Nickel(II) 2-ethylhexanoate
5g
Page 359 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Nickel(II) acetate tetrahydrate solid 5g
25 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
(Acetic acid nickel(II) salt)
20,586-9 98% 1g
CAS No. 6018-89-9
2g
Ni(OCOCH3)2 4H2O FW 248.8
10 g
Used in synthesis of polynuclear-nickel polyoxotungstate cluster
250 g
compounds that are ideal for the design of molecular magnets.
1 kg
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.798 g/mL (lit.)
R: 45-22-43 S: 53-36/37-45
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Palladium(II) trifluoroacetate
37,988-3 99.998% 10 g
50 g 29,968-5 (Trifluoroacetic acid palladium(II) salt) 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CAS No. 42196-31-6 5g
24,406-6 98% 5g (CF3COO)2Pd FW 332.5
100 g R: 36/37/38 S: 26-37/39
500 g
360
Sol-Gel Precursors
Palladium
Tetraamminepalladium(II) acetate 51,505-1 Potassium ethoxide solution 250 mL

KOC2H5 FW 84.16 1L
43,638-0 CAS No. 61495-96-3 1g 24 wt. % in ethyl alcohol
C4H22N4O6Pd FW 328.7 liquid
R: 36/37/38 S: 26-36 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.39 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.894 g/mL (lit.)
Potassium
Potassium acetate Potassium isobutoxide
25,578-5 (acetic acid potassium salt) 5g CAS No. 14764-60-4
CAS No. 127-08-2 25 g
CH3COOK FW 98.14 100 g 53,008-5 Potassium isobutoxide 1g

99.98% KOCH2CH(CH3)2 FW 112.2 10 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.57 g/mL (lit.) solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 F
R: 11-14-34 S: 8-16-26-43-45
Potassium tert-butoxide
CH
3
CH CH CH OK
CAS No. 865-47-4 3 2
15,667-1 Potassium tert-butoxide 5g

KOC(CH3)3 FW 112.2 100 g 53,009-3 Potassium isobutoxide solution 100 mL
95% 500 g KOCH2CH(CH3)2 FW 112.2
Vapor pressure. . . . . . . . 1 mm Hg ( 220 C) 1.0 M in 2-methyl-1-propanol
mp . . . . . . . . . . . . . . . . . . . . . . . 256-258 C (dec.) (lit.) liquid
R: 11-14-35 S: 16-26-36/37/39-43-45-7/9 bp. . . . . . . . . . . . . . . . . . . . . . . 108 C/760 mm Hg (lit.)

CH Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 F
Microelectronics
3
CH
3
C OK Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.845 g/mL (lit.)
CH
3
R: 10-20/21/22-36/37/38 S: 16-26-28-36/37/39
CH
3
CH CH CH OK
3 2
Potassium tert-butoxide solution

KOC(CH3)3 FW 112.2
Packaged under nitrogen in Sure/Seal bottles Potassium methoxide
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,134-1 1.0 M in 2-methyl-2-propanol 100 mL 29,278-8 (Potassium methylate) 5g
Fp. . . . . . . . . . . . . . . . . . . . . . . 54 F 800 mL
CAS No. 865-33-8 250 g
Density. . . . . . . . . . . . . . 0.82 g/mL (lit.)
R: 11-14-20-34 S: 16-26-36/37/39-43-45-7/9
KOCH3 FW 70.13
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 95%
32,865-0 1.0 M in tetrahydrofuran 50 mL R: 11-14-34 S: 8-16-26-43-45
Fp. . . . . . . . . . . . . . . . . . . . . . -3 F 500 mL
Density. . . . . . . . . . . . .0.902 g/mL (lit.) 2L Potassium tert-pentoxide solution
R: 11-19-22-34 S: 16-26-27-36/37/39-45 20 L
100 L 60435 (Potassium tert-pentylate; Potassium (2- 250 mL
200 L methyl-2-butoxide)) 1L
CAS No. 41233-93-6
Potassium dichloroacetate CH3CH2C(CH3)2OK FW 126.2
techn., ~25% in toluene (~1.7 M) (T)
34,808-2 (dichloroacetic acid potassium salt) 10 g may crystallize; can be redissolved on heating to approx. 30C
CAS No. 19559-59-2 Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .0.90 g/mL
C2H3Cl2KO2 FW 169.0 R: 11-14-20-34 S: 26-36/37/39-43-45
98%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 C (D) (lit.)
R: 23/24/25-36/37/38 S: 26-28-36/37/39-45
Praseodymium
Potassium ethoxide Praseodymium(III) acetate hydrate
CAS No. 917-58-8 32,582-1 CAS No. 17829-83-3 25 g

R: 14-20/21/22-34 S: 16-26-27-36/37/39 99.9% 100 g
33,337-9 Potassium ethoxide 5g

KOC2H5 FW 84.16 100 g
95% 500 g
361
Sol-Gel Precursors
Praseodymium
Praseodymium(III) isopropoxide Rhodium(II) trimethylacetate,dimer

41,014-4 CAS No. 19236-14-7 1g 51,109-9 CAS No. 62728-88-5 1g
Pr(OCH(CH3)2)3 FW 318.2 C20H36O8Rh2 FW 610.3
Packaged in ampules 99.9+%
R: 11-34 S: 16-26-33-36/37/39-45 solid
CH R: 36/37/38 S: 26-36
3
CH
3 O CHCH
3
CH CH O Pr
3
O CHCH
3
CH
3
Rubidium
Acetic acid rubidium salt See: Rubidium acetate Page 361
Rubidium acetate
Rhenium (acetic acid rubidium salt)
CAS No. 563-67-7

trans-Dioxotetrakis(pyridine)rhenium(V) perchlorate C2H5O2Rb FW 146.5
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
57,583-6 CAS No. 83311-31-3 1g 28,930-2 99.8+% 10 g
C20H20ClN4O6Re FW 634.1 50 g
R: 36/37/38 S: 26-36 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,613-0 98% 25 g
100 g
Rhodium
Rhodium(II) acetate dimer dihydrate Ruthenium
(Tetrakis(acetato)dirhodium(II); Dirhodium tetraacetate) Ruthenium(II,III) m-oxoacetate trihydrate
CAS No. 15956-28-2
Microelectronics
[Rh(CH3COO)2]2 2H2O FW 478.0 51,111-0 CAS No. 308847-84-9 1g
solid
O
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 290 C (D) (lit.)
R: 36/37/38 S: 26-36
CH C O 2 Rh
3
2
Samarium
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
48,228-5 99.99+% 250 mg Samarium(III) acetate hydrate
solid 1g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32,587-2 CAS No. 100587-91-5 25 g
20,905-8 powder 50 mg 99.9% 100 g
250 mg
800.558.9196 (USA)
1g Samarium(III) isopropoxide
Rhodium(II) hexanoate,dimer 41,013-6 CAS No. 3504-40-3 1g

Sm(OCH(CH3)3)3 FW 327.6
48,117-3 CAS No. 62728-89-6 1g 99.9%
C24H44O8Rh2 FW 666.4 5g R: 11-34 S: 16-26-33-36/37/39-45
97% CH
CH
3
3 O CHCH
solid CH CH O Sm
3
3
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 130-136 C (lit.) O CHCH
3
R: 36/37/38 S: 26-36 CH
3 Ordering/Pricing: www.sigma-aldrich.com
Rhodium(II) octanoate,dimer
44,210-0 CAS No. 73482-96-9 500 mg
C32H60O8Rh2 FW 778.6 2.5 g Scandium
R: 36/37/38 S: 26-36
Scandium acetate hydrate
Rhodium(II) trifluoroacetate dimer
32,589-9 CAS No. 304675-64-7 1g
39,919-1 (Trifluoroacetic acid rhodium(II) salt 50 mg
99.9% 5g
dimer) 250 mg
CAS No. 31126-95-1 1g
[(CF3COO)2Rh]2 FW 657.9
Recently used in the preparation of isomerically pure a,b-
unsaturated carbonyl compounds1 and the preparation of
building blocks for one-, two-, and three-dimensional
molecular solids.2 (1) J. Org. Chem. 1996, 61, 2908. (2)
Inorg. Chem. 1996, 35, 3183.
rhodium acetate. . . . . . . . . . . . . . . . . . . . . trace amount
R: 36/37/38 S: 26-36
362
Sol-Gel Precursors
Scandium
Scandium isopropoxide Mullite (lattice spacing, other parameters)

41,012-8 CAS No. 60406-93-1 1g 52,017-9 CAS No. 1302-93-8 250 g
Sc(OCH(CH3)2)3 FW 222.2 Al6O13Si2 FW 426.1
R: 11-34 S: 16-26-33-36/37/39-45 powder
CH S: 22-24/25
3
CH
3 O CHCH
3
CH CH O Sc
3
O CHCH
3
Sodium metasilicate
CH
3
30,781-5 CAS No. 6834-92-0 25 g
Na2SiO3 FW 122.1 1 kg
SiO2 44-47%
R: 34-37 S: 13-36/37/39-45
Silicon
Sodium silicate solution
1,2-Bis(triethoxysilyl)ethane See: Tri-Alkoxy & Greater Silanes Page
228
33,844-3 (Water glass; Sodium trisilicate solution) 25 mL
CAS No. 1344-09-8 1L
Calcium silicate Na2Si3O7 FW 242.2 3L
Employed in preparation of NaZnSiO3OH,
37,266-8 CAS No. 1344-95-2 50 g a novel chiral framework material which has potential
CaO3Si FW 116.2 250 g application in ion exchange, adsorption and catalysis.
-200 mesh, 99% Healey, A.M. et al. Inorg. Chem. 1999, 38, 455.
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 2.9 g/mL (lit.)
SiO2 27%
R: 36/37 S: 22-26-37/39
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.39 g/mL (lit.)
R: 35 S: 26-37/39-45
Cesium aluminum orthosilicate
Tetrabutyl orthosilicate
49,554-9 CAS No. 12003-48-4 25 g

Microelectronics
AlCsO4Si FW 252.0 T570-2 (Tetrabutoxysilane) 25 g

-100 mm, 98% CAS No. 4766-57-8 100 g
(CH3CH2CH2CH2O)4Si FW 320.5
Cesium aluminum silicate 97%
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . >1 (vs air)
49,553-0 CAS No. 12251-36-4 25 g n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.413 (lit.)
AlCsO6Si2 FW 312.1 bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 275 C/760 mm Hg (lit.)
powder, -100 mm Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.899 g/mL (lit.)
Dipotassium tris(1,2-benzenediolato-O,O¢)silicate R: 36/37/38 S: 26-36/37/39
OCH CH CH CH
2 2 2 3
46,845-2 CAS No. 101519-13-5 10 g CH CH CH CH O Si OCH CH CH CH
3 2 2 2 2 2 2 3
K2Si(O2C6H4)3 FW 430.6 50 g OCH CH CH CH
2 2 2 3
97%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 360 C (lit.)
R: 34 S: 26-27-36/37/39-45
2
Tetraethyl orthosilicate
O
Si 2K
O (Tetraethoxysilane; Orthosilicic acid tetraethyl ester)
3 CAS No. 78-10-4
Si(OC2H5)4 FW 208.3
Will interact with dodecylamine in the formation of
intercalation compounds of H+-magadiite and used in a study
of mixed-metal bioactive glasses.
Disodium tris(1,2-benzenediolato-O,O¢)silicate Vapor pressure. . . . . . . . . . . . . . . . . . . . . . <1 mm Hg ( 20 C)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.382 (lit.)
46,216-0 CAS No. 101519-12-4 10 g bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 168 C/760 mm Hg (lit.)
Na2Si(O2C6H4)3 FW 398.3 50 g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 F
90% Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.934 g/mL (lit.)
R: 34 S: 26-27-36/37/39-45 References
1. Pérez-Pariente, J. et al., ibid. 12, 750 (2000)
Lithium (1,2-ethanediolato-O)bis[1,2-ethanediolato(2-)- 2. Kwon, O-Y. et al., Chem. Mater. 12, 1273 (2000)
O,O’]silicate R: 10-20-36/37
OCH CH
2 3
48,463-6 CAS No. 155740-37-7 10 g CH CH O Si OCH CH
3 2 2 3
C6H13LiO6Si FW 216.2 50 g OCH CH
2 3
Lithium orthosilicate
49,536-0 CAS No. 13453-84-4 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
33,385-9 99.999% (Purity based on metals 25 mL
Li4O4Si FW 119.8 500 g
analysis) 100 mL
solid
Vapor density. . . . . . . . . . . . . 7.2 (vs air)
363
Sol-Gel Precursors
Silicon
23,620-9 99+% 50 mL Tetrapropyl orthosilicate

Vapor density. . . . . . . . . . . . . . 7.2 (vs air)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
13,190-3 98% 25 mL 23,574-1 (Tetrapropoxysilane) 25 g
Vapor density. . . . . . . . . . . . . >1 (vs air) 500 mL CAS No. 682-01-9 100 g
1L (CH3CH2CH2O)4Si FW 264.4
4L 95%
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . >1 (vs air)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4 (lit.)
Tetrakis(2-hydroxyethyl) orthosilicate solution bp. . . . . . . . . . . . . . . . . . . . . . . . . .94 C/5 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 F
47,738-9 CAS No. 17622-94-5 25 g Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.916 g/mL (lit.)
C8H20O8Si FW 272.3 100 g R: 36/37/38 S: 26-36
in solution in ethylene glycol
R: 22-36/37/38-62-63 S: 53-26-36/37/39-45 OCH CH CH
2 2 3
CH CH CH O Si OCH CH CH
3 2 2 2 2 3
OCH CH CH
Tetramethylammonium silicate solution 2 2 3

43,866-9 CAS No. 53116-81-7 100 mL
(CH3)4N(OH) 2SiO2 FW 211.3 500 mL
15-20 wt. % in water, 99.99+% 3-(Trimethoxysilyl)propyl acrylate See: Tri-Alkoxy & Greater Silanes
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.072 g/mL (lit.) Page 216
R: 34 S: 26-36/37/39-45
CH
3 OH
Tris(tert-butoxy)silanol
CH N CH
3 3 2SiO2
CH
3 55,346-8 CAS No. 18166-43-3 5g
((CH3)3CO)3SiOH FW 264.4 25 g
99.999%
bp. . . . . . . . . . . . . . . . . . . . . . . . . 205-210/760 mm Hg
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .63-65 C
Tetramethyl orthosilicate S: 22-24/25
Microelectronics
CH
(Tetramethoxysilane) 3
CH C CH
CAS No. 681-84-5 3 3
CH O
3
Si(CH3)4 FW 152.2 CH C O Si OH
3
Used in the sol-gel synthesis of chromium-doped silicates and in CH O
3
the formation of hexagonal mesoporous silica layers. CH C CH
3 3
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.368 (lit.) CH
3
bp. . . . . . . . . . . . . . . . . . . . . . . . 121-122 C/760 mm Hg (lit.)
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -4 C (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .84 F
References
1. Klotz, M. et al., J. Mater. Chem. 10, 663 (2000)
2. Devi, P.S. et al., CHem. Mater. 12, 1378 (2000)
R: 10-26-37/38-41 S: 16-26-36/37/39-45
800.558.9196 (USA)
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
34,143-6 99+% 25 g
100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
21,847-2 98% 5g
Easily hydrolyzed. May cause blindness! 100 g
Vapor density. . . . . . . . . . . . . 5.25 (vs air) 500 g
Vapor pressure. . . . . . . . . .3.35 psi ( 20 C)
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.023 g/mL (lit.)
Tetramethyl-d12 orthosilicate
39,339-8 CAS No. 80396-70-9 1g
Si(OCD3)4 FW 164.3 5g
99 atom % D
Easily hydrolyzed.
May cause blindness!
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.366 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.114 g/mL (lit.)
R: 10-23-34 S: 16-26-36/37/39-45
OCD
3 1
CD O Si OCD H-NMR spectrum of Aldrich product 55,346-8 lot 92720HA
3 3
OCD
3
364
Sol-Gel Precursors
Silicon
Tris(tert-pentoxy)silanol Sodium acetate

55,344-1 CAS No. 17906-35-3 5g (Acetic acid sodium salt)
(CH3CH2C(CH3)2O)3SiOH FW 306.5 10 g
‡99.99% 25 g
bp. . . . . . . . . . . . . . . 96-99 C/2-3 mm Hg Sodium acetate
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 F CAS No. 127-09-3
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.944 g/mL C2H3NaO2 FW 82.03
CH CH
2 3
S: 22-24/25
CH C CH
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
3 3
CH O 22,987-3 99.995% 10 g
3
CH CH C O Si OH 100 g
3 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CH O
3 47,089-9 ReagentPlus, ‡99.0%, 99.99% 50 g

CH C CH
3 3 insolubles. . . . . . . . . . . . . . . . . . £0.01% 250 g
CH CH
2 3 total metallic impurities. . . . . . . . <100 ppm
Loss on drying. . . . . . . . . . . . . . . . . . . . . . . . . . . £1.0%
pH range. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7.0-9.2
Zirconium silicate See: Zirocnium Page 372
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324 C (D) (lit.)
Other Silanes See: Silanes Page 208 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.528 g/mL (lit.)
Silane Coupling Agents/Adhesion Promoters Page 227 Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
PO43-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.003%
Ca, Mg and R2O3 precipitate. . . . . . . . . . . . . . . . . £0.01%
Silver Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
Acetic acid silver salt See: Silver acetate Page 364 Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
Silver acetate 43,143-5 Sodium acetate trihydrate 50 g
CAS No. 6131-90-4 250 g
(Acetic acid silver salt) CH3COONa 3H2O FW 136.1

Microelectronics
CAS No. 563-63-3 ReagentPlus, 99.99+%

CH3COOAg FW 166.9 Meets A.C.S. reagent specifications.
Used in a novel preparation of highly reflective, conductive MnO4- reducers. . . . . . . . . . . . . . . . . . . . . . . passes test
silvered polymer films. Also effectively catalyzes cycloaddition insolubles. . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
reactions of isocyanoacetates with a variety of olefins. total metallic impurities. . . . . . . . . . . . . . . . . . . <100 ppm
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.259 g/mL (lit.) pH range. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7.5-9.2
R: 36/37/38 S: 26-36 Cl-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.001%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . PO43-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
20,437-4 99.999% 10 g SO42-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.002%
50 g Ca, Mg and R2O3 precipitate. . . . . . . . . . . . . . . . . £0.01%
. . . . . . . . . . . . . . . . . . . . . . . . . . . . Fe. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
21,667-4 99% 5g Heavy metals. . . . . . . . . . . . . . . . . . . . . . . . . . £5 ppm
25 g K. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . £0.005%
100 g Trademark of Sigma-Aldrich Co.
Silver benzoate
Sodium tert-butoxide
22,727-7 CAS No. 532-31-0 10 g
C7H6AgO2 FW 230.0 50 g 35,927-0 CAS No. 865-48-5 5g
99% NaO(CH3)3 FW 96.10 100 g
97% 500 g
Silver trifluoroacetate R: 11-14-34-37 S: 26-36/37/39-43-45-7/8
(Trifluoroacetic acid silver salt) Sodium dichloroacetate

CAS No. 2966-50-9
CF3COOAg FW 220.9 34,779-5 (dichloroacetic acid sodium salt) 10 g
R: 36/38 S: 26-36 CAS No. 2156-56-1 50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . C2H3Cl2NaO2 FW 152.9
48,230-7 99.99+% 1g 98%
solid 2.5 g ethyl alcohol. . . . . . . . . . . . . . . . . . . . . . . . . . . . . <2%
mp . . . . . . . . . . . . . . .257-260 C (D) (lit.) 10 g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198 C (D) (lit.)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . R: 36/37/38 S: 26-37/39
T6,240-5 98% 5g
mp . . . . . . . . . . . . . . . . . 257-260 (D) (lit.) 25 g
Sodium ethoxide
Trifluoroacetic acid silver salt See: Silver trifluoroacetate Page 364
(Sodium ethylate)
CAS No. 141-52-6
Sodium
15,624-8 Sodium ethoxide 5g
Ethyl acetoacetate sodium salt CH3CH2ONa FW 68.05 100 g
16,410-0 CAS No. 20412-62-8 50 g 95% 500 g
Vapor density. . . . . . . . . . . . . . 1.6 (vs air)
C6H10O3 FW 130.1 250 g Vapor pressure. . . . . . . . . . . . . . . . . <0.1 mm Hg ( 20 C)
95% R: 11-14-34 S: 8-16-26-43-45
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 C (D) (lit.)
365
Sol-Gel Precursors
Sodium
23,055-3 Sodium ethoxide solution 5 mL 40,306-7 0.5 M in methanol, A.C.S. reagent, 100 mL
NaOC2H5 FW 68.05 100 mL 0.48-0.52 M (25.9-28.1 g/L) 800 mL
21 wt. % in denatured ethyl alcohol 500 mL Packaged under nitrogen in Sure/Seal
Chemical darkens on storage without bottles
change in quality A novel high-spin hexanuclear Mn(III) cluster,
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.385 (lit.) [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 F oxidation with simultaneous NaOMe promoted
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.868 g/mL (lit.) aggregation. This cluster has an unprecedented cyclic
R: 11-14-34 S: 16-26-36/37/39-43-45
CH CH ONa
structure and 24 unpaired electrons in its ground state.
3 2
Abbati, G.L. et al. Inorg. Chem. 1998, 37, 1430.
ACS reagent
clarity of soln. . . . . . . . . . . . . . . . . . . . . . . . . . . to pass
bp. . . . . . . . . . . . . . . . . . . . . . . 64.6 C/760 mm Hg (lit.)
Sodium 2-ethylhexanoate Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.809 g/mL (lit.)
51,169-2 CAS No. 19766-89-3 1 kg R: 11-14-23/24/25-34-39/23/24/25 S: 7-16-36/37-45
C8H15NaO2 FW 166.2

97% Sodium tert-pentoxide
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >300 C (lit.) 28,070-4 CAS No. 14593-46-5 5g
R: 36/37/38 S: 26-36 NaOC(CH3)2CH2CH3 FW 110.1 100 g
95% 500 g
Sodium Isopropoxide R: 11-14/15-35 S: 6-22-33-36/37/39-7/8
CH
3
40,018-1 (Sodium 1-methylethoxide) 5g CH CH C ONa
3 2
CAS No. 683-60-3 25 g CH
3
NaOCH(CH3)2 FW 82.08
R: 34 S: 26-27-28-36/37/39
Microelectronics
Sodium methanethiolate
Sodium phenoxide trihydrate
28,101-8 (Methanethiol sodium salt) 1g
31,819-1 (sodium phenolate) 5g
CAS No. 5188-07-8 5g
CAS No. 156150-40-2 100 g
CH3SNa FW 70.09 25 g
NaOC6H5 3H2O FW 170.1 500 g
95%
R: 29-34 S: 26-36/37/39-45
99%
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61-64 C (lit.)
R: 34 S: 26-27-28-36/37/39-45
Sodium methoxide
ONa
3H O
2
(Sodium methylate)
CAS No. 124-41-4
16,499-2 Sodium methoxide 5g
800.558.9196 (USA)
NaOCH3 FW 54.02 100 g
95%, powder 500 g
A novel high-spin hexanuclear Mn(III) 2 kg
Strontium
cluster, [NaMn6(OMe)12(dbm)6]+, was
Strontium acetate hydrate
synthesized via MnCl2 oxidation with simultaneous
NaOMe promoted aggregation. This cluster has an CAS No. 543-94-2
unprecedented cyclic structure and 24 unpaired electrons (CH3COO)2Sr aq FW 205.7
in its ground state. Abbati, G.L. et al. Inorg. Chem. 1998,
37, 1430. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vapor density. . . . . . . . . . . . . . . . . . . . . . . . . 1.1 (vs air) 43,788-3 99.995% 1g Ordering/Pricing: www.sigma-aldrich.com
Vapor pressure. . . . . . . . . . . . . . . . . . .50 mm Hg ( 20 C) Precursor to promising candidate materials 5g
Vapor pressure. . . . . . . . . . . . . . . . . . .96 mm Hg ( 25 C) for superconductor wire. Lee, B.I. et al.
R: 11-14-34 S: 8-16-26-43-45 Physica C 1994, 226, 377.
water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~4%
Sodium methoxide solution . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CH3ONa FW 54.02 38,854-8 water. . . . . . . . . . . . . . . . . . . . . . ~3% 100 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 500 g
15,625-6 25 wt. % in methanol 25 mL
Vapor density. . . . . . . . . . . . . . 1.1 (vs air) 1 L Strontium isopropoxide
Vapor pressure. . . . . . . .50 mm Hg ( 20 C) 2 L
Vapor pressure. . . . . . . .96 mm Hg ( 25 C) 18 L 44,069-8 CAS No. 88863-33-6 5g
n20
D . . . . . . . . . . . . . . . . . . . . . 1.37 (lit.)
Sr(OCH(CH3)2)2 FW 205.8 25 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 F 99.9%
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.945 g/mL (lit.) R: 34 S: 16-26-36/37/39
R: 11-14-23/24/25-34-39/23/24/25 S: 16-26-36/37/39-43-45-7/ CH CH O
3
Sr O CHCH
3
8 CH
3
CH
3
366
Sol-Gel Precursors
Tantalum
Tantalum(V) butoxide Thallium(I) ethoxide

38,333-3 CAS No. 51094-78-1 1g 14,984-5 (Thallous ethoxide) 5g
Ta(OCH2CH2CH2CH3)5 FW 546.5 10 g CAS No. 20398-06-5 25 g
98% TlOC2H5 FW 249.4 100 g
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.483 (lit.) 98%
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 F Darkens on exposure to air. Vacuum-filter dark solids!
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.31 g/mL (lit.) n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.676 (lit.)
R: 10-36/37/38 S: 16-26-36 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Ta(OCH CH CH CH ) Density. . . . . . . . . . . . . . . . . . . . . . . . . 3.522 g/mL (lit.)
2 2 2 35
R: 26/28-33-51/53 S: 13-28-45-61
Thallium(III) trifluoroacetate
Tantalum(V) ethoxide 15,053-3 (Trifluoroacetic acid thallium(III) salt; Thallic 5 g

trifluoroacetate) 10 g
33,911-3 CAS No. 6074-84-6 10 g CAS No. 23586-53-0 50 g
Ta(OC2H5)5 FW 406.3 100 g (CF3COO)3Tl FW 543.4
99.98% Technical Grade
bp. . . . . . . . . . . . . . . . . . . . . . . . . .155 C/0.01 mm Hg mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213 C (D) (lit.)
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.4880 R: 26/28-33-51/53 S: 13-28-45-61
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21 C
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.566 g/mL
toluene. . . . . . . . . . . . . . . . . . . . . . . . . . . . . <2 wt. % Tin
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.488 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 F
Tin(II) acetate
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.566 g/mL (lit.)
R: 10-36/37/38 S: 16-26-36/37
34,516-4 CAS No. 638-39-1 5g
Sn(CH3CO2)2 FW 236.8 25 g
Tantalum(V) methoxide
Microelectronics
Used to prepare tin(IV) oxide thin films by

38,324-4 CAS No. 865-35-0 1g photochemical vapor deposition.
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 180-182 C (lit.)
Ta(OCH3)5 FW 336.1 5g
References
R: 11-36/37/38 S: 16-26-36
1. Thin Solid Films 251, 19 (1994)
2. J. Org. Chem. 59, 7521 (1994)
R: 20/21/22 S: 36
Terbium
O
Terbium(III) acetate hydrate CH

3
C O 2 Sn
32,592-9 CAS No. 100587-92-6 5g

99.9% 25 g
Tin(IV) acetate
Thallium
34,517-2 CAS No. 2800-96-6 2g
Thallium(I) acetate Sn(CH3CO2)4 FW 354.9 10 g
mp . . . . . . . . . . . . . . . . . 232-233 C (lit.)
22,995-4 (Acetic acid thallium(I) salt) 5g R: 20/21/22 S: 36
CAS No. 563-68-8 25 g
CH3COOTl FW 263.4 100 g Tin(IV) tert-butoxide
99.99%
49,413-5 CAS No. 36809-75-3 5g
R: 26/28-33-51/53 S: 13-28-45-61
Sn(OC(CH3)3)4 FW 411.2 25 g
Thallium(III) acetate 99.99+%
Precursor for OMCVD. Precursor for Sn-Al oxy alkoxide
CAS No. 2570-63-0 which may be heat-treated resulting in a zerovalent metal
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 C (D) (lit.) film. (Lu, G. et al., Langmuir, 14, 1532, (1998)) Ester
elimination reactions lead to the rational synthesis of
metal oxide materials. (Caruso, J., J. Chem. Soc., Chem.
15,116-5 Thallium(III) acetate 5g Commun., 157, (1995).; Caruso, J. et al., Inorg. Chem.,
Tl(OCOCH3)3 FW 381.5 25 g 34, 449, (1995).)
R: 26/28-33-51/53 S: 13-28-45-61
solid
40,010-6 Thallium(III) acetate sesquihydrate 5g mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40-44 C (lit.)
(Thallic acetate; Acetic acid) 25 g
(CH3COO)3Tl 1.5H2O
Hydration may vary slightly
R: 26/27/28-33 S: 22-36/37/39-45
367
Sol-Gel Precursors
Tin
References
Tributyltin methoxide
1. Caruso, J. et al., Inorg. Chem. 34, 449 (1995)
2. Lu, G. et al., Langmuir 14, 1532 (1998)
22,924-5 CAS No. 1067-52-3 25 g
3. Caruso, J., J. Chem. Soc., Chem. Commun. 157 (1995)
R: 20/21/22-36/37/38 S: 26-36 (C4H9)3SnOCH3 FW 321.1 100 g
CH
97%
3
CH C CH 100g units packaged under nitrogen in Sure/Seal
3 3
CH
3
O CH
3
bottles.
CH
3
C O Sn O C CH
3
For a review on tin reagents in organic synthesis, see
CH
3
O CH
3
Aldrichimica Acta 1984, 17, 75.
CH
3
C CH
3
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.472 (lit.)
CH
3
bp. . . . . . . . . . . . . . . . . . . . 97-97.5 C/0.06 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.115 g/mL (lit.)
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61
CH CH CH CH
3 2 2 2
Tin(II) 2-ethylhexanoate CH CH CH CH Sn OCH
3 2 2 2 3

CH CH CH CH
3 2 2 2
28,717-2 (Stannous octoate; Stannous 2- 5g
ethylhexanoate; 2-ethylhexanoic acid 250 g
none)
CAS No. 301-10-0
C16H30O4Sn FW 405.1
n20
Titanium
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.493 (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . >230 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.251 g/mL (lit.) Barium titanium(IV) tetrahydrofurfuryloxide solution
R: 36/37/38 S: 26-36/37/39
O
51,705-4 CAS No. 308796-51-2 100 mL
CH CH CH CH CH C O Sn C30H54BaO12Ti FW 791.9
3 2 2 2
CH CH 2 in solution in tetrahydrofurfuryl alcohol and ethyl
2 3
alcohol
Microelectronics
liquid
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.47 (lit.)
bp. . . . . . . . . . . . . . . . . . . . 176-183 C/760 mm Hg (lit.)
Tin(II) oxalate Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.16 g/mL (lit.)
40,276-1 (Stannous oxalate; Oxalic acid tin salt) 100 g R: 20/22 S: 28
CAS No. 814-94-8 500 g
SnC2O4 FW 206.7 Chlorotriisopropoxytitanium
98%
R: 21/22 S: 24/25 CAS No. 20717-86-6
Tributyltin ethoxide
800.558.9196 (USA)
25,151-8 CAS No. 36253-76-6 25 g 25,062-7 Chlorotriisopropoxytitanium 100 g
(C4H9)3SnOC2H5 FW 335.1 100 g (Titanium chloride triisopropoxide; 800 g
97% Chlorotitanium triisopropoxide)
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.467 (lit.)
[(CH3)2CHO]3TiCl FW 260.6
bp. . . . . . . . . . . . . . . . . . . . . . . . 92 C/0.1 mm Hg (lit.) 95%
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 F Storage below 25 C may cause crystallization. Moving
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.098 g/mL (lit.) container to a warm location should remelt the solid (mp
R: 21-25-36/38-48/23/25-50/53 S: 35-36/37/39-45-60-61 ~35 C). Recrystallization occurs slowly. Thus, the liquid
CH CH CH CH
3 2 2 2 may be transferred using syringe techniques.
CH CH CH CH Sn OCH CH
3 2 2 2 2 3 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 F
CH CH CH CH Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.091 g/mL (lit.)
3 2 2 2
R: 34 S: 26-36/37/39-45
25,267-0 Chlorotriisopropoxytitanium 100 mL

solution 800 mL
C9H21ClO3Ti FW 260.6
1.0 M in hexanes
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -9 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.775 g/mL (lit.)
R: 11-23/24/25-34 S: 16-26-27-36/37/39-45
CH
3
CH OCHCH
3 3
CH CHO Ti Cl
3
OCHCH
3
CH
3
368
Sol-Gel Precursors
Titanium
Titanium(IV) butoxide Titanium(IV) ethoxide

24,411-2 (TNBT; TYZOR TBT organic titanate; 5g 24,475-9 (Tetraethyl orthotitanate; Tetraethyl 50 g
Tetrabutyl titanate; Tetrabutyl 100 g titanate) 250 g
orthotitanate; Orthotitanic acid 500 g CAS No. 3087-36-3
tetrabutylester) 2 kg Ti(OC2H5)4 FW 228.1
CAS No. 5593-70-4 Technical Grade
Ti(OCH2CH2CH2CH3)4 FW 340.3 contains ethanol (excess)
97% Ti 20%
Used to prepare nanosized titania in the anatase form and n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5043 (lit.)
ferroelectric Bi4Ti3O12 thin films. Used in the preperation bp. . . . . . . . . . . . . . . . . . . . . 150-152 C/10 mm Hg (lit.)
of nanocrystalline TiO2 powders at room temperature. Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 F
n20 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.088 g/mL (lit.)

D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.49 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . 206 C/10 mm Hg (lit.) R: 10-36/37/38 S: 26-36
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 F
DuPont product Titanium(IV) 2-ethylhexyloxide
References
1. Wang, Z. et al., Mater. Lett. 43, 87 (2000) 33,348-4 (Tetrakis(2-ethylhexyl) orthotitanate; 250 mL
2. Chen, J. et al., J. Mater. Sci. 31, 3497 (1996) TYZOR TOT organic titanate) 1L
3. Gu, H. et al., Rengong Jingti Xuebao 25, 54 (1996) CAS No. 1070-10-6
R: 10-36/38 S: 26-37/39 C32H68O4Ti FW 564.7
OCH CH CH CH
2 2 2 3 95%
CH CH CH CH O Ti OCH CH CH CH
3 2 2 2 2 2 2 3 n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.479 (lit.)
OCH CH CH CH
2 2 2 3 bp. . . . . . . . . . . . . . . . . . . . . 248-249 C/11 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.927 g/mL (lit.)
DuPont product
R: 36/37/38-43 S: 26-36
Titanium(IV) tert-butoxide
CH CH
2 3
Microelectronics
CH CH O CH CHCH CH CH CH
46,255-1 (Tetra-tert-butyl orthotitanate) 25 mL 2 3 2 2 2 2 3
CH CH CH CH CH CH O Ti O CH CHCH CH CH CH
CAS No. 3087-39-6 50 mL 3 2 2 2 2 2 2 2 2 3
CH CH CH CH CH CH O CH CH
Ti[OC(CH3)3]4 FW 340.3 3 2 2 2 2 2 3
CH CH
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 F 2 3
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.881 g/mL (lit.)
R: 10-36/37/38 S: 16-26-36
CH
3
CH
3
C CH
3 Titanium(IV) isopropoxide
CH O CH
3 3
CH
3
C O Ti O C CH
3 (TYZOR TPT organic titanate; Tetraisopropyl orthotitanate)
CH
3
O CH
3 CAS No. 546-68-9
CH C CH
3 3 Ti(OCH(CH3)2)4 FW 284.2
CH
3 Novel metal oxide/phosphonate hybrids were formed from
titanium(IV) isopropoxide in a two-step sol-gel process. Starting
material for barium-strontium-titanate thin films., Used to
make porous titanosilicates, potential ion-exchange materials
Titanium(IV) butoxide, polymer for cleanup of radioactive wastes. Applied in the formation of a
heterosupermolecule consisting of a TiO2 nanocrystallite-
51,071-8 CAS No. 9022-96-2 50 mL viologen electron acceptor complexwhose light-induced
Ti(OC4H9)4 FW 340.3 250 mL electron transfer has been demonstrated.
Used in the study of thermal properties n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.464 (lit.)
of siloxane coating KT-30 produced in varying methods., bp. . . . . . . . . . . . . . . . . . . . . . . . . . . 232 C/760 mm Hg (lit.)
liquid mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18-20 C (lit.)
Vapor pressure. . . . . . . . . . . . . . . . . <0.8 mm Hg ( 20 C) Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .72 F
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -39 C (lit.) References
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 F 1. Guerrero, G., Chem. Mater. 12, 1268 (2000)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.13 g/mL (lit.) 2. Behrens, E.A. et al., Chem. Mater. 8, 1236 (1996)
References 3. Guerrero, G. et al., Chem. Mater. 12, 1268 (2000)
Zin, I.M. et al., Fa-Khim. Mehk. Mater. 31, 136 (1995) 4. Jans, S-I. et al., Han’guk Chaelyo Hakhoechi 6, 449 (1996)
R: 10-22-37/38-41-67 S: 16-26-36/39 5. Cusak, L. et al., Chem Mater. 9, 1765 (1997)
R: 10-36 S: 16-26-36/37/39
OCH CH CH CH
2 2 2 3
CH
CH CH CH CH O Ti OCH CH CH CH 3
3 2 2 2 2 2 2 3
CH O CHCH
OCH CH CH CH 3 3
2 2 2 3
n CH C H O Ti O CHCH
3 3
CH CH O CH
3 3
CH
3
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
37,799-6 99.999% 5 mL
Density. . . . . . . . . . . . . 0.963 g/mL (lit.) 25 mL
100 mL
369
Sol-Gel Precursors
Titanium
20,527-3 97% 5 mL Titanium(IV) (triethanolaminato)isopropoxide solution

Density. . . . . . . . . . . . . 0.955 g/mL (lit.) 100 mL
DuPont product 500 mL 38,817-3 (TYZOR TE organic titanate) 100 mL
2L CAS No. 74665-17-1 500 mL
C9H19NO4Ti FW 253.1
Titanium(IV) methoxide 80 wt. % in 2-propanol
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 F
Ti(OCH3)4 FW 172.0 DuPont product
Used for the preparation of polyoxotitanates. R: 11-36/37/38-41 S: 16-26-36
References CH O CH CH
3 2 2
Clegg, W. et al., J. Chem. Soc., Dalton Trans. 681 (1996) CH CH O Ti O CH CH N
3 2 2
. . . . . . . . . . . . . . . . . . . . . . . . . . . . O CH CH
2 2
46,358-2 99.99+% 25 g
solid
mp . . . . . . . . . . . . . . . . . . . . . . . . . . . 200-210 C (lit.)

R: 11-41 S: 16-26-36
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
40,495-0 95% 10 g Vanadium
methanol. . . . . . . . . . . . . . . . . . . . . <5% 50 g
mp . . . . . . . . . . . . . . . . .210 C (dec.) (lit.) Vanadium(V) oxytriethoxide
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 F
R: 11-20/21-41 S: 16-22-36/37/39-45 47,077-5 CAS No. 1686-22-2 5 mL
OV(OC2H5)3 FW 202.1 25 mL
Titanium(IV) neopentoxide 95%
May darken in storage!
53,079-4 CAS No. 35061-92-8 Building block for a series of neutral oxovanadium
Ti(OCH2C(CH3)3)4 FW 396.4 complexes containing both ethoxide and acetylacetonate
99.99% ligands the complexes have potential biological relevance
Microelectronics
as well as uses in catalysis. Jiang, F. et al. Inorg. Chem.
Titanium(IV) propoxide 1998, 37, 5439.
liquid
25,308-1 (Tetrapropyl orthotitanate) 100 g bp. . . . . . . . . . . . . . . . . . . . 125-128 C/760 mm Hg (lit.)
CAS No. 3087-37-4 500 g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 F
Ti(OCH(CH3)2)4 FW 284.2 Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.139 g/mL (lit.)
98% R: 36/37/38 S: 26-36
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4986 (lit.)
O
bp. . . . . . . . . . . . . . . . . . . . . . . . . 170 C/3 mm Hg (lit.) CH CH O
3 2
V OCH CH
2 3
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 F OCH CH
2 3
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.033 g/mL (lit.)
R: 10-36/37/38 S: 26-36/37/39
OCH CH CH
2 2 3
800.558.9196 (USA)
CH CH CH O Ti OCH CH CH
3 2 2 2 2 3
OCH CH CH
Vanadium(V) oxytriisopropoxide
2 2 3
40,492-6 (triisopropoxyvanadium(V) oxide; 1g

Vanadium(V) trisisopropoxide oxide) 10 g
CAS No. 5588-84-1
Titanium(IV) tetrahydrofurfuryloxide solution OV(OCH(CH3)2)3 FW 244.2
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.479 (lit.)
51,703-8 CAS No. 22290-53-5 100 mL bp. . . . . . . . . . . . . . . . . . . . . . . 80-82 C/2 mm Hg (lit.)
C20H36O8Ti FW 452.4 Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 F
50 wt. % in tetrahydrofurfuryl alcohol and Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.035 g/mL (lit.)
R: 10-36/37/38 S: 16-26-27
isopropanol
liquid CH
3
O CH
3
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.493 (lit.)
CH CH O V O CHCH
3 3
bp. . . . . . . . . . . . . . . . . . . . . . . 178 C/760 mm Hg (lit.) O CHCH
3
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.14 g/mL (lit.) CH
3
R: 36/37/38-43 S: 26-36
4
O CH O Ti
2
4
370
Sol-Gel Precursors
Vanadium
Vanadium(V) oxytripropoxide Yttrium butoxide solution

47,078-3 (Vanadium(V) tripropoxide oxide) 5 mL 51,066-1 CAS No. 111941-71-0 25 mL
CAS No. 1686-23-3 25 mL Y(OC4H9)3 FW 308.2 100 mL
OV(OC3H7)3 FW 244.2 0.5 M in toluene, 99.9+%
98% Precursor to composite film electrode for solid oxide fuel
Precursor for composite film electrodes in solid oxide fuel cells.
cells. liquid
May darken in storage! n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.495 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . .82-83 C/0.25 mm Hg (lit.) bp. . . . . . . . . . . . . . . . . . . . . . . 109 C/760 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 F Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.076 g/mL (lit.) Density. . . . . . . . . . . . . . . . . . . . . . . . . . . 0.9 g/mL (lit.)
References References
Hayachi, K., Proc. Electrochem. Soc. 97, 700 (1998) Hayashi, K. et al., Proc. Electrochem. Soc. 97, 700 (1998)
R: 10-36/37/38 S: 16-26-36 R: 23/24/25 S: 16-26-28-36/37/39-45
O
OCH CH CH CH
2 2 2 3
CH CH CH O V OCH CH CH
3 2 2 2 2 3 Y
OCH CH CH CH CH CH CH O OCH CH CH CH
2 2 3 3 2 2 2 2 2 2 3
Yttrium 2-ethylhexanoate
Ytterbium
34,708-6 CAS No. 114012-65-6 10 g
Ytterbium(III) acetate tetrahydrate C8H16O2Y FW 233.1 50 g
99.9%
CAS No. 15280-58-7 R: 36/37/38 S: 26-37/39
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
32,601-1 99.9% 10 g
Yttrium(III) isopropoxide solution
Microelectronics
50 g
. . . . . . . . . . . . . . . . . . . . . . . . . . . .
54,497-3 solid 5g 38,029-6 CAS No. 2172-12-5 5 mL
25 g Y(OCH(CH3)2)3 FW 266.2 25 mL
25 wt. % in toluene
Ytterbium(III) isopropoxide bp. . . . . . . . . . . . . . . . . . . . . . . 106 C/760 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.955 g/mL (lit.)
51,406-3 CAS No. 6742-69-4 5g
R: 11-23/24/25-34 S: 16-26-36-36/37/39-45
C9H21O3Yb FW 350.3 CH
99.9% 3
OCHCH
Packaged in ampules 3
CH C H O Y O CHCH
mp . . . . . . . . . . . . . . . . . . . . . . . . . . 349 C (dec.) (lit.) 3 3
CH CH
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 F 3 3
R: 11-34 S: 16-26-36/37/39-45
CH
3
O CHCH
3
CH C H O Yb O CHCH Yttrium isopropoxide oxide
3 3
CH CH
3 3
37,942-5 CAS No. 118458-20-1 5g
OY(OCH(CH3)2)5 FW 1132 25 g
Fp. . . . . . . . . . . . . . . . . . . . . . . . . 54 F
R: 34 S: 26-27-36/37/39-45
Yttrium Yttrium trifluoroacetate hydrate
Yttrium acetate hydrate 39,536-6 CAS No. 304851-95-4 5g
99% 25 g
R: 36/37/38 S: 26-36
R: 36/37/38 S: 26-36
54,190-7 Yttrium acetate 5g
99.99+% 25 g
solid
Zirocnium
32,604-6 Yttrium acetate 50 g Tetrakis(1-methoxy-2-methyl-2-propoxy)zirconium

CAS No. 304675-69-2 250 g
99.9% 57,805-3 CAS No. 309915-47-7
Zr(OC(CH3)2CH2OCH3)4 FW 503.8
99.99%, electronic grade
R: 36/37/38 S: 16-26-36
CH
CH 3
3 O
Zr
O
CH
3
4
371
Sol-Gel Precursors
Zirocnium
Zirconium acetate solution Zirconium(IV) butoxide solution

41,380-1 CAS No. 7585-20-8 500 mL 33,394-8 (Tetrabutyl zirconate solution) 100 mL
C2H4O2Zr FW 151.3 2L CAS No. 1071-76-7 500 mL
in solution in dilute acetic acid Zr(OC4H9)4 FW 383.7 2L
Zr 15-16% 80 wt. % in 1-butanol
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.279 g/mL (lit.) Used in an unconventional method to prepare a gel of
R: 20/21/22-34 S: 26-27-36/37/39-45
CeO2-stabilized zirconia polycrystals that have promising
applications as protective coatings of steel and ferrous
Zirconium(IV) acetate hydroxide alloys.
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.466 (lit.)
46,460-0 R: 34 S: 26-27-36/37/39-45 100 g Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 F
500 g Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.049 g/mL (lit.)
R: 10-22-37/38-41-67 S: 16-26-36/39
Zirconium(IV) bis(diethyl citrato)dipropoxide OCH CH CH CH
2 2 2 3
CH CH CH CH O Zr
OCH CH CH CH
3 2 2 2 2 2 2 3
51,581-7 (TYZOR ZEC organic zirconate) 1L

OCH CH CH CH
2 2 2 3
CAS No. 308847-92-9 CH CH CH CH OH
3 2 2 2
C26H44O16Zr FW 703.8
liquid
ethanol and 1-propanol. . . . . . . . . . . . . . . . . . . . . . 12%
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.451 (lit.)
Density. . . . . . . . . . . . . . . . . . . . . . . . . . 1.14 g/mL (lit.) Zirconium(IV) ethoxide
R: 11-36/37/38 S: 16-26-36
O 33,912-1 CAS No. 18267-08-8 5g
O CH
2
OCH CH
2 3
C Zr(OC2H5)4 FW 271.5 25 g
C C CH
2
C OCH CH
2 3 97%
O OH O Convenient precursor for the synthesis of olefin-
CH CH CH O Zr OCH CH CH
3 2 2 2 2 3 functionalized zirconium-containing monomers, which
O OH O
Microelectronics
have potential for the generation of hybrid zirconium-
C C CH C OCH CH
2 2 3 containing polymers.
O CH C OCH CH
2 2 3 bp. . . . . . . . . . . . . . . . . . . . . . . . . 235 C/5 mm Hg (lit.)
O
R: 11-36/37/38 S: 16-26-33-36/37/39
OCH CH
2 3
CH CH O Zr OCH CH
3 2 2 3
OCH CH
2 3
Zirconium(IV) tert-butoxide
(Tetra-tert-butyl zirconate)
CAS No. 2081-12-1
Zr[OC(CH3)3]4 FW 335.7 Zirconium(IV) isopropoxide isopropanol complex
bp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 C/3 mm Hg
nD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.4240 33,923-7 CAS No. 14717-56-7 10 g
800.558.9196 (USA)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185 F Zr(OCH(CH3)2)4 (CH3)2CHOH FW 387.7 50 g
Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.985 g/mL 99.9%
R: 36/37/38 S: 26-36 Convenient precursor for the synthesis of olefin-
OC(CH )
33 functionalized zirconium-containing monomers, which
(CH ) CO Zr OC(CH )
33 33 have potential for the generation of hybrid zirconium-
OC(CH )
33 containing polymers.
R: 36/37/38 S: 26-37/39
CH
3
. . . . . . . . . . . . . . . . . . . . . . . . . . . . CH O CHCH
3
3
56,003-0 electronic grade, 99.999% 5g CH C H O Zr O CHCH
3 3
CH C H OH
3
25 g
CH C H O CH CH
3 3
. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
CH
3
33,708-0 98% 5g
May darken in storage! 25 g
Reagent for the preparation of
heterometallic tin(II) or lead(II) zirconium alkoxides. Teff,
D.J. et al. Inorg. Chem. 1996, 35, 2981. Zirconium(IV) propoxide solution
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.424 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . . . .81 C/3 mm Hg (lit.) 33,397-2 (Tetrapropyl zirconate) 100 mL
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185 F CAS No. 23519-77-9 500 mL
Density. . . . . . . . . . . . . . . . . . . . . . . . . 0.985 g/mL (lit.) Zr(OCH(CH3)2)4 FW 327.6
70 wt. % in 1-propanol
n20
D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.451 (lit.)
bp. . . . . . . . . . . . . . . . . . . . . . . .208 C/0.1 mm Hg (lit.)
Fp. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83 F
Density. . . . . . . . . . . . . . . . . . . . . . . . . 1.044 g/mL (lit.)
R: 10-41-67 S: 26-39
OCH CH CH
2 2 3
CH CH CH O Zr OCH CH CH
3 2 2 2 2 3
OCH CH CH
2 2 3
372
Sol-Gel Precursors
Zirocnium
Zirconium silicate
38,328-7 CAS No. 10101-52-7 250 g
ZrSiO4 FW 183.3 1 kg
-325 mesh
R: 36/37/38 S: 26-36
Aldrich is pleased to announce that we now offer

stainless steel bubblers designed for use in the pro-
duction of semiconductor and thin film materials.
These bubblers are used to deliver ultra high-purity
organometallic precursors in the vapor state to the
reaction zone during the process of chemical vapor

Microelectronics
deposition. To inquire about custom synthesis and

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please contact us at 1-800-336-9719.
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• Pneumatically tested to ensure leak-free service.
• Currently available in a 300 mL size for custom packaging.
Manufacturing Capabilities
• Modern precursors for CVD of metals, nonmetals, III-V, and II-VI semiconductors.
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• Purity up to 99.9999% (metals basis) by ICP/MS.
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Products
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The above is only a sample of our products available for CVD.

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VCR is a trademark of Swagelok Co.
ALDRICH ®
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253

Materials for Thin Films/

High k Dielectric Materials

Your local Sigma-Aldrich office: See Back Cover

Aluminum fluoride Antimony(V) chloride

Packaged under argon in ampules 5g R: 23/24/25-51/53 S: 7-26-45-61

H2O. . . . . . . . . . . . . . . . . . . . . <100 ppm 25 g

Antimony(III) bromide Antimony(V) fluoride

Antimony(III) iodide 44,963-6 anhydrous, beads, -10 mesh, 99.99% 5g

Your local Sigma-Aldrich office: See Back Cover

57,380-9 CAS No. 15513-75-4 1g

Materials for Thin Films/

Barium chloride Bismuth

CAS No. 10361-37-2 Bismuth(III) bromide

Bismuth(III) chloride 30,761-0 99% 50 g

Packaged under argon in ampules 25 g

R: 34 S: 26-36/37/39-45 bp. . . . . . . . . . . . . . . . . . . . . . . . 90 C/760 mm Hg (lit.)

40,152-8 99.99+% 5g Lube, M.S., Inorg. Chem. 35, 5007 (1996)

Cadmium bromide 22,231-3 Technical Grade 25 g

Your local Sigma-Aldrich office: See Back Cover

(Continuation of) Carbon-13C tetrachloride

Carbon-13C tetrabromide Tetraiodomethane

48,846-1 CAS No. 72802-79-0 500 mg 26,922-0 (Carbon tetraiodide) 5g

99 atom % 13C CI4 FW 519.6

mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88-90 C (lit.) mp . . . . . . . . . . . . . . . . . . . . . . . . . . 168 C (dec.) (lit.)

Cerium(III) chloride Cesium chloride

Your local Sigma-Aldrich office: See Back Cover

Cesium iodide Chromium(III) chloride

give unprecedented soluble rhenium-selenium or Packaged under argon in ampules 25 g

Cesium tribromide Chromium(II) fluoride

52,943-5 CAS No. 14023-00-8 5g 39,989-2 CAS No. 10049-10-2 1g

R: 36/37/38 S: 26-36 Chromium(III) fluoride

Cesium triiodide 44,976-8 CAS No. 7788-97-8 2g

AAPL specializes in a number of areas including:

AAPL advantage gives products with:

H2O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<100 ppm 23,050-2 (Cuprous bromide methylsulfide complex) 10 g

45,166-5 anhydrous, powder, 99.995+% 5g Dysprosium(III) iodide

Copper(II) fluoride Erbium

Your local Sigma-Aldrich office: See Back Cover

42,937-6 CAS No. 14456-48-5 1g

CAS No. 13569-80-7

Europium(III) chloride Gadolinium(III) iodide

Europium(III) fluoride Gallium(III) bromide

CAS No. 13765-25-8 CAS No. 13450-88-9

Solids 1996, 197, 8. Gallium(II) chloride

bp. . . . . . . . . . . . . . . . . . . . . . 2280 C/760 mm Hg (lit.)

Gadolinium Gallium(III) chloride

Gallium(III) fluoride Germanium(II) iodide

Your local Sigma-Aldrich office: See Back Cover

Germanium chloride dioxane complex (1:1)

Hafnium bromide Holmium(III) iodide

Hafnium(IV) chloride 46,060-5 CAS No. 14280-53-6 5g

zirconium. . . . . . . . . . . . . . . . . . . . . .1% 54,508-2 99.999% 5g

bp. . . . . . . . . . . . . 656 C/760 mm Hg (lit.)

CAS No. 10138-62-2 Indium(II) chloride

33,406-5 98% 10 g Iron

Your local Sigma-Aldrich office: See Back Cover

Iron(III) chloride Lanthanum fluoride

mp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304 C (lit.) S: 22-24/25

CAS No. 10031-22-8

28,865-9 (Ferric fluoride) 10 g PbBr2 FW 367.0

23,615-2 powder, 5 mm, 99+% 100 g 43,137-0 ReagentPlus, 99.99% 50 g

Your local Sigma-Aldrich office: See Back Cover