Subject- Chemistry

Name -……………………………
Class Roll No……………Merit Position……
Put X marks beside the letter of correct answer

Consider the following reaction and answer the

question1-10: 2A+B→3C+D 1x12

Q.1 The rate of the reaction is given by

(A) d[A]/dt (B) -d[B]/2dt

(C) d[C]/3dt (D) -d[D]/dt

Q.2 The rate equation of the reaction is

(A) Rate = k [A]2[B] (B) Rate = k [A]nA[B] nB

(C) Rate = k [C]nC[D]nD (D) Rate = k [C]3[D]

Q.3 The unit of rate of a reaction is

(A) mol dm-3s-1 (B) mol dm-3

(C) mol dm-3s (D) none of these

Q.4 The order of a reaction can be

(A) 1, 2, 3 only (B) 0, 1, 2, 3 only

(C) 0, 1, 2, 3 and fractional (D) fractional only

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Q.5 If above reaction is 1st order with respect to A and
1st order with respect to B, the unit of the rate constant
will be

(A) mol dm-3s-1 (B) mol-1 dm3s-1

(C) mol-2 dm6s-1 (D) s-1

Q.6 If above reaction is 1st order with respect to A and

1st order with respect to B, the reaction will occur at
least in

(A) one step (B) two steps

(C) three steps (D) four steps

Q. 7 If the activation energy of the above reaction is

reaction is very high, the rate of the reaction will be

(A) very (B) fast

(C) very slow (D) unpredictable

Q.8 The rate of above reaction is doubled if

temperature of reaction mixture is increased by only
100 C, the reason behind this is

(A) The more fraction of reactant molecules gains Ea

(B) frequency of collision increases
(C)Activation energy is decreased
(D) both (A) and (B)
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Q.9 Above reaction is 1st order with respect to A and
1st order with respect to B, if the concentrations of A
and B are doubled, the rare of reaction will increase by

(A) 2 times (B) 4 times

(C) 6 times (D) 8 times

Q.10 If above reaction is 1st order with respect to A

and 2nd order with respect to B, the rate equation of
the reaction is

(A) Rate = k [A]2[B] (B) Rate = k [A]nA[B] nB

(C) Rate = k [A]2[C] 2 (D) Rate = k [A] [B]2

Q.11 The rate equation for the reaction NO2 + CO →

NO + CO2 is found to be, Rate = k[NO2]2. Which of
the following statement about this reaction is wrong?

(A) The reaction is second order.

(B) The reaction is bimolecular.
(C) The reaction is not elementary.
(D) The order of the reaction with respect to CO is zero.

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Q. 12 The rate equation for the acid catalyzed reaction
CH3COCH3+I2→CH3COCH2I+HI is found to be
Rate= k[CH3COCH3][H+].Which of the following
statement is incorrect?

(A) The order of the reaction with respect to I2 is zero.

(B) The rate of the reaction is doubled if [H+] is doubled.
(C) The rate determining step involves a collision
between a I2 molecule and an CH3COCH3 molecule.
(D)The rate of the reaction is proportional to
concentration of CH3COCH3.

Q. 13 The best way of freezing (or quenching) of a

chemical reaction is

(A) diluting the reaction mixture

(B) cooling the reaction mixture
(C) heating the reaction mixture
(D) simultaneous cooling and diluting the reaction mixture

Q. 14 A chemical reaction can quickly be completed by

(A) diluting the reaction mixture

(B) cooling the reaction mixture
(C) heating the reaction mixture.
(D) simultaneous heating and diluting the reaction mixture

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Q.15 The best method to study of kinetics of the acid
catalyzed reaction CH3COCH+I2→CH3COCH2I+HI is

(A) conductometric method

(B) titroimatric method
(C) spectrophotometric method
(D) mass loss measurement method

Q.16 The best method to study of kinetics of the

reaction CH3COOC2H5(aq)+NaOH(aq)→
CH3COONa(aq)+C2H5OH(aq) is

(A) conductometric method

(B) titroimatric method
(C) spectrophotometric method
(D) mass loss measurement method

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To answer the questions number from 13 and 14,
consider a reaction A → P
Q. 17 Draw a graph to show the change of
concentration of A with time if the reaction is (i)zero
order, (ii) 1st order and (iii) 2nd order with respect to A.
1.0

Zero order reaction

[Reactant] 0.5 1st order reaction

0.25

2nd order reaction

Time

Q.18 Draw a graph to show the change of rate of the

reaction with [A] if the reaction is (i) zero order, (ii) 1st
order and (iii) 2nd order with respect to A.

(iii) First order

Rate of
Reaction (i) Zero order

(ii) Second order

[Reactant]

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Q.19 In a set of experiments to determine the
rate of the reaction between persulphate ions
and iodide ions S2O2-8+21-→2SO2-4+I2,in
aqueous solution, following data were
obtained:
Initial rate /
Expt. [S2O82-]/ [I-]/ mol dm-3 mol dm-3s-1
No. mol dm-3
1 0.100 0.100 0.36
2 0.200 0.100 0.72
3 0.200 0.200 1.44
Deduce the order of reaction with respect to
each of the reagents and hence write the rate
equation for the reaction.
In expts. 1 and 2, [I-] is kept constant, and
[S2O82-] is doubled, the rate of rection is also
doubled indicating the reaction is 1st order
w.r.t S2O82-.

In expts. 1 and 2, [S2O82-]is kept constant, and

[I-] is doubled, the rate of rection is also
doubled indicating the reaction is 1st order
w.r.t I-.

In expts. 2 and 3, [I-] is kept constant, and

[S2O82-] is doubled, the rate of rection is also
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doubled indicating the reaction is 1st order
w.r.t S2O82-.
Q.20 Calculate the rate constant of above
reaction including unit. 1

Rate = k [S2O82-][I-] or, 0.36 = k(0.1)x(0.1)

k = 36 mol-1dm3s-1

Q.21 Calculate the activation energy of a the reaction

if rate constants of it at different temperatures are as
follows:
k/10-3s-1 2.46 10.6 45.1 160.4 576
Temp./oC 0 10 20 30 40