Unlnnity o r Obaka

Fir~• Yt:tr 11.S. 4Huuoun) :'\Jinor 1~,.. miuation lOHI

Subject: Mal bcn1•lltt
Cour.-c :-:o.: :'-ITM 1113 C:ounc.· Ti1i: ,\n•lytlc and \'cctur
G1:omrtf}
Credits: 2 l'o1al Marl-, · 70 ·1,me: l.5 bc.un

.f,u'lil·r, on.r fl VI::. quouo•u Ft,-:r-,r, In th, r(i;ht ,.,:,');en ,,,•.J.cutr :JJ< m.;..•l., Qf ti~ rr•~'--r,w
qutJllon.,.

J. (•) Trn..·uforrn 1hc cqc :.1bn l h : • 2-by ,- 4J•1 - 20 • - .:oy- S • 0 t,) rc~~~t..1.u a,..c,
.'
1h:c.1Jgh the fX)in: (2. - 1) or.d ~ nc,"" :1..u , 11rt ir.:-:l!lC'.:13: w, ,.:,etc W1 '( - j) to

th: on a 1~.11tU,C\
(hi f inJ lhc >:Cd <)( th, 1ri:.n~:C rvrm,J b) 1h: llnci ttprc.cO:cd by 7
.1.x .. :!h.cy• by 1 .. t, ~md h -mJ "- I
1

l. (1) It the c:qiJ.1,1100 .1.\ J " '.!.hey ♦ by 1 "'"2J:t -2 fy .. 1.· :1 C, ~ prc~r.t.s rw., .unig..~: 7
iinc>. rr1..l• C1h:11 l!it' ~u:uc of the di.t..ir,,;:(' t'J f their r-,:,i.nt Cr in!..'7)Cd1::on frurn t.'1t-
1
. . . _ c(u•h ) - f,--,-
' _- .,
;:_
ongin , \ - - -.
,,} - h·
(b) i'f->' c tl-2: m o r-r lines rt'J)(c.\C:1:(J by t~.c cqiJ.Jtion 1

0...\
1
- b :' •• •('.1:>J • d r.)' ' • Cl)'• .. o
, .. i!I t,11<,;1 :rngk b<t\,ccn Ui C 00'.cr IWO if(" .. 6.J - 0. t, . J. 0 .
} HcJl:C< lhtt-qU.\IIQn J., ' •8.:y- Jy'-40.:r-20) .,o;i,; Q toltf.UJ.:"IJ.udf.;,rm 1•
2nd ukntily the con'.:. FlnJ ,:., pn,pc-n ic, uid <lr•" 11. ro•Jgh ,l.ctih
, . fa) II the .c..:tc.•, o ( ~ n:ct.mirut•r r.11Jlldcpirc-J ~c !l. b. z. tti:n JJ:o ,., 11-..11 th-c angle, '

NI'<\ cc-n the fc. w c!u31Jc-. .!h :trt' gi,rn b) Co, ' ( !:a' !: b' -:. c' )
..,1,b: .,1

(h) ~00,:t.1" , • __.,_ _ 1

2- e,.ntl
(;) J~nnif) lh< pO:.U equation
(Ii) FinJ the '-C:rtM.;c-1 .1nd cc:11n
fi,~) f i!::J the lcn.;th, o( m:.jor 111d r:, i.·xH 11\c.).
5.(,) Find the CG~ioo ofth: pt:i.r..c r.1.uina ll,.rov,h l""-O ,iHn r,o:n1, {..- 1 • J'" : 1) a.nJ
(.1·,. Y1 , : 1 ) an:i pcrr.coJ lcula, 10 • &i.,,n pl:1-"lc ,n • by • c: • (I • O·
(b) f ir.d the cq1U!,<n1 o( Lh~ pt.1r.c puJ.lnt: ;~co u1,,J: the poir.u {], ). - ,i) and (1. _ I , )) 7
.l,"IJ r,uo1lld 10 the ., .nu.
j- (•) Sh"l...,, ~.t: the lino ) , • 'l > • :- ~ • O• 1 • )' - : 1 - } and 7
2' - ... - : - IU • 0 • 7 r • toy - a: - 15 41c mu1.u.:.I:> pc-t'J)(r.1.fa. uu,
(b) fir:J
I inc
th !c;,wth
· .uni the ~'-o'lll..>:i ,
• or the ' H dl\l.&:KC (S()) bc1, " cc n h:-;
,hoftt "- two
1

1.(, )

(b)
1
J

(b)
J.5

J.5
6. (a) Dcfiac s11a.11ni11g SC't of \,'«tors. Dctem1inc \'thcthcr or not l-'9 :;; r1, 1~2). ll;i ~ (l _0. 1) 7
and v 1 = {2., 1 ~ 3) Sp.\n the \ ·ci.:tor 5p.:t,c R 1 •
(b) l.er 5 and T be daf r01lo in~ subsrnce of R":
1
.-. 7

S .-;;; ({x. y, 1 , t): y - 2z + t ~ O}

r-=- ((x. y,zli l);.r ..... r = O~y -- 2z =: O

f" inJ ll hJ.Sis Wl d dimcnJal)n of ll) s. (fa ) 111 and (iu} s n r .
7.. C.o) Dc:finc linear mli,.)form.ruiom. Consider O"~ b~ is S -= °(t•! ~v2 • v 3 }foc R). \\'h~.re L' 1 = 7
( 1. 2, l )., t1:z = (2, 9. O) rind i ~l = (3, 3~ It) m d h:1 T: gJ ...... R.J be r'hi! lini:.1:
trn.nsfonn11tions ~uch 1h.:.\ 'f {11,~,) :;;: { 1_OJ- T( l'J) ~ (- t 1) . T(v 1 ) ==- (O, 1) . Find :t
f ormut~ for T (.r, y"' z) tu1d U!JC 1h:u hnn:tUICl to t1nd T ( 7. t 3, 7).
(bJ Let T~ RJ -+ R 1 bf! a h ncar tran:sfonn3LiDn dc!int-.1 b)' . T(x.. y . z) === (x - y,fy - :t., x - 7
!). Find lhi: m:uri.--: or ·r in 'l ht bl.Sb 5, {/ 1. /'1., l \\'here 'J fi = (1. 0. 1). /1 ~
( 0, l i 1) anti / 3 = ( t l r 0). \ 'erify lnll iTJ,lt•J, : : . ~T(v) ) , .
H. fa > S1:o \\ Ii iat th~ roI! O\\ 1ng t rJ t1.:s.fa nnJ.ti on. de fines a 1~ne.),r OJ"C r.1to r on.
R1 : T(x. _;·, z'} = (z + Y~--x - ) 'i :}.
'■

i· b) St;1u: Caylcy~Hanl thon theorem L•sing C~) 1c;-Ham1ltoo ·1 hco~~ fi nd ,he in,.,c-N: of 9
21
rh~ mn1ri:-.
l
ll = ~
l 2
~ ~
 •,f I :,I 111 I
t•i'''' ~ 7 . U' ,,,, .._.
,,,,,.,,,,,,,
I n f -"' I , J/J , '_,L,L-J I
,,;11,1/ul ;I I,

, hJ

ti, I
l
-i
I ,r,l 111 '1tl1 I A ) r.:vl ' Ill , or,:y CJ•1J (cdJ,'.) "' !At I.
/()
I"' l 1M '°>ifil ••.Llf , ,.~I I. I (I Ft I Cl 3. !:.-l!n !:: A r~e ' &t .1J ,t

I , f ■J

7
· , • of
\J.' hJ.t 1\ t:"...: u,:, ! 1H!,n i nt ,:~a:c....,,: tn tr•• CT:.C
.
~ "'1
•:...:•n::.r-•
• •·
"11·.JA" ' (, [c , :-uof
'"' 1>v. w~,i,.

A • ( ~
-J
to!wlAa""hlluJ Q, - y a• 1,.,.t.n,;J< • ( 4, i .• 1.- )J =-~Jy 7
,1. '•J " Con.ld<T rho y:,ir.l, PO, a, -2) :&:Id Q(S, 3. 4 ) L~ R • f',~ " :.o :.= PQ " • 1
c (3. -1,6,-2 )

,,,d,,,gr,rul ,., 1ht ,t<.1JA (~ . -3.2).

Ddinc \>('.($(, ( ~r...-:..c v.:11 e .......T.p 1C"1 Let U 1 " ( - L 3. 2. 0). t. ,: = (2. o. 4. -1 ).
f "' (7. l. I. 4 J o.,J v, ,. (/,, 3. I. 2J. l·m.h,~11,s u,.a 1• a ,,::-~ a• .....:!: t!-..>: a, u, + a,u,
u, : :
~
u,u,,.. u.u. • ( f), 5, 1.,, -3)

~.,., ,cc tun

b

( 1), u.,. v, v ... w.~-u

(ii/. u + v,u - v,u - 2v ,. w
Mc • Ir.a lm~.uly iodc-;,c~"kn1
(b) I.et V be the • cctm ,pxc uf 2 ,,. Z m~lll<o cr, ct L'>c rc.,J fit:<,: R f 1~..J • baJil 41\d
dimcrulo,i ()f lhc ,u!.,:p:,u W u( V , p.,..'lcl !,y th: m.JU>c.n

A~ I! :i].r,"' [~! !J,c .. l!s -;41 :,~..JD e 1..:1:, -;71

(<J V~nf) th;u lh< C.wcn,,!>Ch·~•n incqu.alU)' hold,i for folk,w,n 1-.-,, ~i,,n
6
5.
11 =
(-1.2, l). v c (8. -4. -2).
r 1r.J b;eX'j. for ru"'"' tp..ce, c.olwnn ,p.,,,..c ;z."1d uulh~ 0 r Lhc m.i:n,.,

,.r: 'J
I
-2 0
-5 -3
5 15
6 la
_,
10
0

~
J)

~ I•
6)
fmJ rw ;ar,J nu lh!j
11umber o( column, o( A "' th~ n--:J.!Ja, A \ t"Tl(} t.\.,1 nr.k(A) .,. nuli1 ty(A)
=
 Grou.p u~[M·t 1ul Cilu1hu

C}!i.. ~·•) h) E._~il lu.:s·t~ f: f (2r)t1_x 1f ( ms. cont im.J,ous .:ind JiJt / (-x)d;r ~ 10.
~ I

r' lii) Lei .A be lhc: ~1f¢J of 1he regio,n ·crut 1.•c1 unJcr I.he: iifiiph o.f y == l 1 bet~crn .r = 0
and ::c = L Usin~ right. end point!.. fimJ 1u1 c:..pc:~~•oo for A ,c..,; a limit Show lhot the
liml~ ~ri~~bci
,, !~
l • .

tb) Ftndi a f'TCJJuction fcmn ul.:. fo.t l;,. = J,~ 12 c:oi'"' :c· dx .
Qt,,. (::a) ]~'· •nti lhc tou! ~f\C'.l rutd n~t sig.r1 ~ do ::tf\e:~ or f 21 (2.t - 8) d%.

·(b) f 'ind the OJTiel. of ~ gton bourHkd dn ~ ri~t b-)· ihe l~ ne y = x ~ 2. on L~c lcn b;t x ==
y 1 ~d be IO Vo' by lh ~ ;r -.1..\. t'.!i.

(i) Sant~ Fucidur1en.I.nl 1hrorcmi of l.nt~grol Cmlculu.:s.

(ii) Th~ vclcx:try of a ¢:1r On f-c:-cUSC'Cnt:1d) t: s.,ec after :o.tm'ting from rcU is Sl'--Cn lby 1he
frunc~ion v(t) = 2,/i. (0 S r S 30),, Find lhe car•, ro~hicmj .s(,.), nt =ny time C,. An-umc
thal.s(O) = O. Find ~ht' ,.Hiuncc tra.,·ckd from £ ·= 9 '5,C'(; to r = 16 sc-c.

Find the ~c:n gth ,or Ihe pc-rime~fdu: urdio'[d r = a ( I. + ro~ O}.
(b) Fin-ti Lhc ~"'ta on.tic region c: 11dmcd b)-· z = y1 m-.d y ~ :r - 2 in.ctgnting Yt lth m,r~ct
1.0 '/·

)1:.) Find the \\hale~,..::· lrnglh of the C-)doid .- = a (r -t 1in ,)_ y ~ a( J - cos t}.
,~ t•) F-.nJ. L~c ,iu-c.i oflhc: iurf~c itut h g,c:ncr.a.11.':d b)· m ·oh ing the portion ofL~ ct.iri■"l! y = 7
.x J bciw~n x ... 0 a_nd x :::: 1mibout 1.hc X•U ~
,I
'7
tb) Find tht .lrl:'!l ~,( the ,1.1 rf4':c or lhc ~Hd fom-ic-.d by I h~ re \'olut ~o~ of I he =.,1cruhl xi -+-
, JI
y'i = a1 JbotU lhe. x·,u,i:5-.
 Unlvtnlty ur Dhaku
First Year 8.S. (Hu11oun) l\linor £1amlna1ion 2018
Subject: l\lnlhc:mallrs
Course No.: MTM 102 CoutlC 1i1k: C1k11lu I
Crcdiu: 2 Total Man;s; 7O Timc: l.~ liouo

N. B.: Annrtr an,v J (firtt) quot/on, oftht following a,~/ tal/11g al /,rut} (t••t>) qu.:.llion, from tad,
group, Fi>.,"llrt1 gi,~n in tht rigl1t """!:In iralicat, th.e nw,l.s o/tlu: roptrt/,-, I/~·"'"'"·
Crou11 A: DIITrr,ndal C1lculu,
QI. (o) Skc1ch lhc G,Dph of/ and find its dOllllin and n.1;;c:
1
(i) /(x) = - , (ii) /(x) = slnx + lsln1-I,
• •l

(b) Define c:,ustcncc of limil of a fonclionfix) al x = a, Using c - odefinition pro,·c thll 4

lr•ll••
I1m
J...,l 1-t
= 6.
(<) I.ct /(x) = 3x 5 - Sx 1 i11ld g(x) = x' - 2.r 1 . lx1cm1inc "hich function is c,·cn, odd,
or ncith<r e,cn no; odJ. Tcsl the symmctl)' of !heir gnph.l.
4
Wh:u is lhc rule for Um~ where p(x) ;nd q(x) an: pol)nomials7 Gh-.: e.umplc to
.r--a q(.r)
justify rour results.
5
(b) Sulc SMidwich lheon:m. Pru-. th,t llm.r 1 cos(!) = 0.
J"-0 1
4.r .xS-1
(<) Find values of c :,n~ d so •h•I L~c function /(r) = ex+ d, -I < x < 2 is continuous 5
{
-Sx .x~Z
for all re•I x.
QJ. (•) Show lhot /(x) = {iY:~ ~; i, nol JiITen:n1iablc 01 x = 2. ftnd 3 fonnula for f'(x) 6
and dom(j') . Ev.luate {'(3) and -.hot oocs it represent?
(b) Appl) ini ch•in rule cva!U>1c

(i) F'(x) if F(x) = f(g(x)), given 1hn1 {'(x) = ...!-;

lu
ond 9(x) = ,JJ:r - I

-= ..
(ii) ~_(/(x)) if .!.(/(3.r)) = 6r.

(e) If y cos(a sin-• .r), then ,how 1ha1 (I - x 1 )y• ., - (2n + l)xy•• 1 + (a 1 - 4
n')y0 = 0.
"' /ca) St.>le Mean value theorem (MVT) and hence deduce Rol!c's lhcomn. Verify the 6
~ ' hypothesis ofRolle's lhcon:m for /(x) = x 1 + r - 4 on (-1. 2).
(b) Consider the function /(x) = .r' - 6.r 1 + 2. S
(i) Whot ore lhc crillcal points of fl,)?
(ii) Find the inlcrvals un whichftrJ is increasing. dten:asing, ,or.co,·c up and concovc
down.
(iii) Find the inflec1ion points.
(iv) Find the relative ma.dmum and minimum ,oluc$ of /(r).

P>ge I cl 2
 A :-.\'.\°1.'~ l\H}' fo ur I:\ fr.,m th1.• !01111\, h~· q ,•....,t ~,,:)~ lti.';:, # .~ 'e: :i:>~
··- - -
l (nJ rrnu •,h•.·" ·, • . ._,,
t\l.v unii \'1-..:tc•:~ p ,,suHt•I h • t it(.' H.:!Ul~n1 ,•. ·..,·[ t l.,·," .,"'"' i ,••H<.I _!1-t
•1: . l;, 0

(h)

(c) Show tb,t. ,I ~ (G, ;, r : 1 )i •r (3,' - :;j

thr.l A = (re,_

~l,\lc Stokt .~' th\.'Ort·m nml verify 1t for . f " (2r - !l)i - y:~j- ~1:k, wJJt:re the undt•dyir.b ~111 i.u:c S
" the upper hnlf ,urfacv CJ[ th•: ,ph,,c , 1 +~ 1 .,. :• = I •nd C ,t·s bouudruy !~·r2.7~l
the- dffcr~cucc theo rem to t·.:iku!otc tl:c ~u: fo.cc lr.~("~o.J ff, ,.~• rJ§ i'i.: rc,~ tl1c t1urfoct: S, wlu-11•
l!_!J('
F(:c, y. :) = (r.o,: + .r11 1 )i..,. {.rt"')j •• (,in I}- r 2 : )i: 01,.J Si, the ,u, foc• of the •olid l,,,u:1tkd L:,·
the pnrolx:>lohl : = r ' + 112 nn.J tb: 1, J,.,:c : ~ •I !,]
1
A 2 k& objl'1.:l i.; , til>Jt~·t1.·.. t 1c, thr1,: fo:c-,.5 thn.t blVC 1t ~cl'lt'ullo11 ii '-! - (8m , - ); + lG rns-J)j . ti
two of the fo rce; ,uc lrnown P, ~ (JO ,Y)i + ( IG,\')j .lr,tl f;
= - (I:! :\'); ..- (S N)j, fi:,d tla- ti.ml
lo n.:t;. • ( 1. 7&]

m wlth sp1:t"l t: up;,rond1ts n st,,t1u:1;1r:.,· nu .. .1 ,\ I . Th•-- rn ti..~c-s Uo•.1111:.- ol t'3':h c.tb:t rh... rn.·a.ll~.
:\ t11i~
\Vlmt cue the fi:1r1.I ·.-clc-citw:; of tl.e parttd1.~? jh ,ullH.· th\.' n.oa 0?1 tak1.•.; p!tl.C\· m -0:v: dim,:m;o:1 (•lj
\\11;it is ~imple I Hu mome motlo:1(SIl~t f' E1tn.bl.!h tbl' t!d!•:runt l!\l c•qun.ttttll of I\ ;11yo;!em t-n.,·1wg SH~ l
.)'{•1 Sho"· that, the gen<rnl 50lutlon uf ,urh <liffrreuti~I <"lt:ltlCO <3:> l,., writtu. "" , (I) = )(~•l'-'c: - ¢) ,
,.dh:t\.· the: ~;·ml>ol, h ,1.-. ttlt'lr 11.:o:unl inttn.nin>:..• \ \-\ -21

(l,) ;\ l>ody of m&.,;s m undergoes o.\CHJ,, tory mouon ma \ 1.:,vu, Uu1d . th~ l ";."'!t~th,: iorce by t h~ n~1d on
Lill' ""'"'' l< -bv ~,·tup the Jollcrcnw,J ,-qu•l'" " o'. ,uch mut,c:i. I! :r\r\ >(..:;· t:: co,(w.,r + ¢) 1, tho =
solut100 of !ouch mvt10:1. ~how t!il\' rn u:1i- cyd t (dun r.~ a t ~r:H: pcdt>t\ T ) th•.: d urn&t: 1n n:1.·ch.,mca\
•oucrio· (dE) is,

di:: ; - ~(I; -l: /.lm )r~(I - ,.,.,r ) He:r" = 1•/ ~m .

.
[2-2 1:.1

J {t,) D\·rivc th•: Wu\"t.' l'tt t1.t.l1on (or n io11~itud1ttill W l\'.1· prop,,t~t\!i1:h t:"I ~ ~l.'I. IGJ

(b) Calculate t he an·:att! kinctk cm·r)ty c1\!'t11.,-.i ot:t L;: t ?1:.• w,wt· in b•'' ·
!J.751
6.(u) Stat e Ncwto1i's ><.'CO~•I l•w o! ,u,t:on fe r .1 rot,tm,; n ,41<l l•o<ly
l~l
(b) A solid cyli nder of 111~,s ,\/ nml rtldllL• f'. roll, w,:l:out shpprni; down nu u:duwJ plan• ti! i<•nf.th /.
"nd height h . Find tl11, ~pc'l.-<l of ,t; ccnt,•r <lf noa.'.> wlttri tl,e t;,liw.!,,r r.-~rl:r, the l>vttota j:1,5I
(c) Yo u ru e gi \\•n n u:liform ~olid r,:t.:tc111g11li1r p1f'\t,· o : h·r:;;th ~ 1\;'.ll\ w11lth t, t l1'\t ti '-"' uub, .\( C-skulntt•
1ls rotationol mc.:tlA t\hout 11n <1.-<i., pt!r?'(1~Ctcula: 10 tht! pl!\t~ ~rn•l thrv·..1.oh n s n·ntt:r . ...,,.v l
·3
 (iii) Cakuh:tc tl:c electric field ~trcnsth '." 11:c t:bp.
\iv) Cl\kulatc the e!eclrk field str~ngth tn th,, t!li'lr.<tttc. f5J
(\') C:i!culnte the poto•ntial di!To:n:ncc btlW\!Cn tho p!J1tcs
j'{a) A lun&th I, of wir~ c.u1iL-;< 3 current 1. Sltvw Ila,\ if the " 'l!C L' fo1111<'J 11,to n circul.u coil, lbt•
, m.uimum torqcc h1 l' given mo.gu-:t h: fidd is d1:"vdop1:d ,d1en the coll hn.a one turn only Md chc
to,quc h>.< the \':lluc. T ~ .!.,I,
4~
1
D. IJf
(b ) S1,,1, nnd ..xpl!\ln Furodny'1 ln1,· of elt'<:trorr.•g11clic i:1d"ct,on. G1>c ,·xnmp~e. wl:c,e Forad~y'• I""'' I,
CS<.'<i
[2.7~1
(c) A cltcu.lo.: l:x,p m•do of., otrctd:t'<I conducting el11.St:c m,:crial hos a 1.23111 radius. It is p!ac«l w11!t
its p""1c at 11ght o.nglc,. to• uniform 76, mT coagnelic f.e!d. \\'hcu rtlc:,.<,)d, the rndiiu of the loop
,tiuts to <11'<:rca.sc at !I.II inste.ntnnt'OUS r,,tc of 7 (,O on/.• C11lculntc the tmf anduc~ :o the loop at
th,1t i1s,tl\llt. 13I
5.(n) Show thllt, the "'Ori< done m pulling the loop tl1rough the m,b-nctk field ap;,c.us ..,, thermAI cnoq;y
in th,· loop, !·:\
( l,} Drfine self m<luctaucc onJ mut uni rncluctll..llce. \\lu,t rue I he dr awht\Ck!I o( mut u.a.l indcct tul.C<"7 [ l .751

(c) The lo:ig ,clcnoid S shO\\'O (m cro,s ot'Ction) in Figure hM 2'20 tut'ns/cm ruid carries 11, C".1."t,nt I.~
A: its din.mttcr iJ 3 2 cm. ,\t il:l center we! place;), 130-turn cloi,,Jly p&el<.cd cui\ C uf <lia..·1lt:tcr 2.1 cm.
The currt11t lo the solenoid is re<lurc-<l to zero at a stendy rate In 25 ms. \Vhl>l Is the magnitude o!
till' l'Hlf that i:J induu:J in roil C whill· the cuncnt in lhc !-.CJh.: noitl i'\ rhau~iug·! rJJ
,e '
,
r
- . ...
. .. .• . ' e:r\, ..
.-..• ---· - ·-·

G (i\) \',,1 ,ot ,; "" olttrnatin,; cuncut'! /!)

{t,) Dt•ri,-e au l'.:q,r~ io11 for the potent1nl 1:1 o circuit cor1t iu11 1:JK l\ copac1t ut C o.nJ II rt)btar.« Fl m
~en~ when :m nll-.·rnntiug t'tnf i~ npph1..·d tu tlm rm.; uit JJ.i~I
(c) Pro"\! tha:, the average power Ill an lltcrnat111&current <'1rc11 it Is P., = \.' lco.,o. lh·nce drfine Power
fncto: 13.,. 1l
 Dcpnrt111c11t
F y nf l'hyaka, lln h·t•n>il., _, "f
..., 1) 1l olPl.o\
t. ,

• •al '-'{.\f U.S 1~1mor) Fia..r.J Exrunuut1ou, '.:tJIS

Si..lJ;i ..:t : Pln·i a,:~. \our""· f"~.f-12'.! f tl ..-ctr H'lt) .L"ld ~ll'L-lo\tteti\:1q
l·uh :O.! t:;.:. , 'J.;j, f u;1,c: : :! :, hu·J :•

/ ,\ n.\ ~·..-r 1\!I)' four (4) Crom the fullowm~; ,;w·•tJvm (I;;:,, •1 • J:i)

J !,P,r t 1
::,:. _1.11 .\Jl r!«tric tp ;nrlruJl(l'.,:'! Obll\!!l I.HJ l"XVH">llo:J h•r l he ~:«:tuc 1,>vt,.,n,ru {\/) n.t n ,h._t ,,ur•· f
rom U~C'.\.Cl l~rt: of t ht: quMtrupo!,, nlt' I•~ 1~ ~ ru. 1, :,.;oN ,·,Jt11p .u•• )'UIU It ., 1,1t \.\llh O PQut\ \'.'h:i.r.:e nuJ
,u1ch..'('trtc- •hpvl,: I" J,
(ll' A ;>.'H t tc h: or
d1:u ;~c Q b "-'-"'l!lnt,,:, t t o l. l'\ \t ' h ti..,:tJ JH)Ht 1u11 1\1 1-0m1 p A M"t'IJUd put1d,· UIJv:"'1 '" ,.1
tu :d d1-ugc - q 1110\t") l\l l\ <.oti."itnut :1.p,:1.·d 111 ta curl~· t•i : t,thu, r 1 u :1.t~a..J nt ,, Di!fl\u nu r-t i,it,ut.11
fo: the 9.--0rk doue I\' that mw•: be J ou~ Lr ,rn r-xh·rnc.J !\6•: 11t 0 11 th1.: ~ cmd (H\rtide 1n uni" to
rn<rc!LW th,, rnJou.i of the Corde of mutiOJ3 to r 2. j2j

(c) A decade b.:fore Em, tcm publis!,,-o l,:5 t heory or rcl11:i\'il}', J J Tr.orr.'!On propo,i«J t h•t t ho , :rctrori
rnntJc up of :,t:uill part~ tltl<l it'r1 mt'\., , k"\ 1..kc to t lu.1 t·!i-t:B i• a1 ma·mctmn u' th•· J,i'l.rt" Furttu-rrnott!, hl·
or
::uggl~tt"U that thr energy \'(p.ol, to mt.1 ~1,,kr a CO'Jhh e~:llltlllc t h~ electron ID!J.Sll b tlm fvlbwmg
WO)" Asslllllc that the ek-ctro 11 is N mpo,;,,<I or tl1:t•s i•lc:ilk,J P.'-'1• t hot "'" tirougbt fror:i infinity
Mel pl11o:,-d nt the vcrtic~ of au .-1u11atcr.i1 mang!c !iav1ns ~id,~ tqu,u to the c1 ....,.,ca l r,uhm of tll"
electron, 2.62 x II)• I> rn
(iJ 1:"ind thr totn.l clt"Ctr1<: p<ttcntiltl t·ner&.>· 1J( tllb 111ra.11;t"mtri:
(11) O"·id,n~ by c', compMc your rcru!t t,, the occ,,ptcJ l'i,-ctron "'"'"' (9. 11 x IU""k.9) [21
ld) Ii £ ,:qu.J, to t<ro • t • Riwn p oint , dot·s \' rr,·.ut r.,1utJ t o zt ro ,,t thot pome Give cxamplt, to
p:U\i: )'UIJr l\ll.~V.t:t fl.7!,]

)t•l F1bwi: showi; 11 G1W!.; lan surfocc tht• form of n. rylmdcr ,,,r r11dnu H i:nmctM"tl rn a uniform dt.<tne
in
fidJ , with tho <ylindcr a.~i., po.r:illd to tlio f:dd. \\1,.t h t he flux¢, of the ckctric field t hw ui;h thl,
cl<r.1<.'<1 ,urf,u-,,·, l•l]

(l,) F:gurc sh<..rw~ no el•.-ctrn: qu1u.Jrup,vl,· It 1,.1-.11',;jt ~ of , .., o dtpo!,·, w1t?1 d1pv!1· 11:ouu·nt:-i thnt ,uc t-qu .'1
m magmtudc hut opp,r>..<ltt! 111 d1rt,:tl1m Sit<.•" 11:t.t tiR· , alt;,• <., f E 0:1 t h i: 11., 1, o f the quntlrupole for I\
3(.l
point Pat "d1s,nncr : from tli n:nt,·r (".:,au mc : ;..> <!) u; gh•·r1 IJy, I::...:; ---,.
•l'l"I' I ~ ;
1n wh1cb Q = ~J~•
1-s known 11-'\ t hr <t'rndrupoh: morw:nl uf t l1t: ~1ru&e <.i:~t11Lut w1: {" .-;"5}

1'100,., ~ Que,t:u11 2( b)

/4) Show t h>t, the «:t~SY ,frruity u,: 1n.,:d,· • pnullel-pb: -, cnp,.et'.or » 1,,E' wh"r" E "ti.< d,'<tt.t
iidd ber..·c~n the plat<-.. 'J .7j j

(bl A dlch.'(tric !->bl, of t h1ckn~s:s ~ 1rnd d1c!c-c1nr cvr.:.t :\!1~ J: p!Mt<l IJ1Jt·Ar,!tl tbc phtts o( a para:.kl•plAt 1!
c.ipa.dtor o! plott' a:ctt A Md 6('p!\rnt:o:i cl A r,otr:it in.1 dlF.'H •!nr.e Vi) is applii."Ct •,1,•ith nr, <l:d l'Ctr;t i..
p re5ertt Tht! l,a~t.cr}' ).i thtn d l$C0:111rct,-d n.;iJ tbt! tl1dl'C't rk ! L,l, 11:St•rt n:i A~\"it!lf.t' that _.t :..: ) n n', .rn
a=I ~cm. b~ 0.70=.k = 7.0 arid\ ; = !~0 t·olt!
(i) Ca!cula:e the c1,p..·u.·i t~r.t:l' Ci; L..f'-'rt' t ~ .. i-lrib i, 1!:..n l L"\J
fii) Ca!cu!,tc t~~ h t-.: cbirge q.
 Ucp.utJr)(11l lll lhcmnt:\
l ' :ii \C'U,1 )' ,,(l)hJiJ .
•
l'1r•,1 YcJJ [I S fll r,n, \ 1 '...t1:11n,1t1vn ~01 ~.
CotJhc I Ille hmi!.,,mrntJt, <i i Ar-~:) !Il l? O ,cr.m:r
Full ,\hr~ J~ 1 ( , OUl>< l'iu. (.'JI 161 \~ (':cJol.>)
T 1rur. 1!iho•,Ja

fA.nn,,r (}ut:11ion nu mlnr I gr,J .,,~ lhrtt (:H H It.( r:m~:rat1b Ouc.,1101ul
L, ptu;1 ,~r ~l~C i.bon Qn\'.\('J o! th: ro:hm,110 ttue1lil"l1' I~ a .. k
(ilJ \\ !wt h .sr..:i)):ic.:.I chcma tr)'?
1b) Wlu1 Jo ) .>•J 1ai:.1:1 Ii) lhc lcnm lt'.J]Or. rnmor ar.J H:a.:c cuni:11ucrm·•
(c) l:.xpl>Jn 1hc <l1lfcrcn:c bcl\\ttn lhe GtOIJp of p«:od,: 1,blc .ir.J Grou;,, ~r .ro-r
><p;ira1:on 1,hl: u,cd in qu.,Jiutilc lnori;Jnte ■tw)m
CJ ~ ~ fenl!(ln lUIJ lm~n..u,,t Ad,M.USc-t o( wir.a O'a-All:.C r:c,.:1p1t,lf11.) In ~U\ilJICtm;
30Al~sii.
(c) E>rloin thJt in u ml\lUr< of nicl d •11J 1>1il.1J1ur.1 ,cni, Ii' 4,,J 011' cw o.::: >< >
nuul ing Q.otnl .Junntt irl\'lmctm: dr:crminn!i<Jil
IO Diitingoi,h !,,:1\\ccn nccurxy ar.d rrc.:l\ion o( M J'l.il)tlc.tl tr.ca,urcmc~I.
(.;) Ill.)\\ d0<:, 11 mclJ!lC'C tuomk mdicatm [r.dic.it<"' 1hc end point (J( J complexon:ctr1c
111r,11tor.?
\h) 11·1,•c J ~.-n lhc n.1mc, of~., lr;:hl ww<n of li\' JnJ ""~I<
, pcrnopho!omct

(l) \\ 'ntc the ,1c-;,, those a:c tlC'CCtW) ,,t1rn ,onfwntN "tlh ~11 unf.umluu qc..mtit.11nc
Jctcrrr~inJtion
lb) Wh,10.-. a:i<l b.uc in~i.,1~07 far,IJ.in ,.,~, or.c c,..unplc hov. th<) inJ,cott the enc
or
r""'in1 .1 ncu:ruli1~t1on n·.:iction
(c ) Wlut .uc 1bc Ji~:11,ha:1t.Jbf('> of CJIT)'ing c.;u111:nHon, 1n J.q'JC'tl'U1 mcdlurn? H\,w the.~
r:r1blcn:i c:in ~ O\'l.:rcornc 1 1Vi
) lt) Wtu1 l.."C tht .:ntcil:\ t.> l:\: J rrir.1.1.r, tUr.d:uJ )U!--1lJ.t);;c f~>r u,i:1e it1 qw..l"ftiLJll\t'
.J 1.k1i:mun.J11vn..' ~• ·.
...
(t,) (k.)Cn}x lhc o.inJ,J.nlil.111011 of 1'.MnO. s"luhor. u ith 1:wol~cd ,~oichiomc1rn:
chcml~ f\".\Ctlon.s a~lni1 • pmnvy 1unc!ud i.otv.ion of I rc,facing agrnt a.nd Jho,v.·
i!'lc t\utl o( urcn~th c:ikub1ion
(CJ Dis.:u.u ltll the slcp, irwohc~ in the dctcr.nirution of Fe:• :tnJ Fe> io:u ir. 3 supr,hcJ
S<..\lu!lN1 "11h .:.tJJh.l.i:J Cr;O:·· M:llutil'n "'ilh stoic.h.iontc-uh. chcffik11:J r~tio.i.s She\-.
thC' prvo:c-ss o( O:.lkolltion ,.,f L'lc .m:cunl o( 1ror. ~pcdc-s ;,rc,cr.i m Ll-ic s.upp!tciJ
101ution. Whr )t.indJrJ ~Mno. $.Olu:io:1 CJJ\ 't be u~I l\lr l~C d(IC::rrun.Jl1on1 .
•
-l (:1>Elt.i!:iliih the n-lJt1omh1p t\:t,,ccn "disuihut1l"n .:odfiticnt (Ka) 3.r.J ··J~sin~tJoo J
t"Jlio \Of.
(b) E..~pl:Un th..11 \\ h1:h one ,,, mo:c cffic1rnt md "h> ~Cl\~t"':"n b.m:h ~rnJ c"ntir.uow.
t\trxtioru. .
(c) 20 ml. of :m 11-qt;CNi )tilut:on of 0 . IO ~t bu:~ n~ :iciJ h..u ~ s.h.U.cn "1th 10 rr.L of
ether. l\ftcr lhc 1.a~crs .'ltc S..--plrJ.ted, il 11 dc-tem1bcJ b) ti:rat:on tbt O ~ nun\ll of
but~-:ic aciJ rtmJir:.s in the :..tueou.s solut:on fmd <1.:1 the di.stntn111on tJhO :r.1J
pc-runt c,L~tcJ ofb:.ll)rk u;1d. ;
(d) \\~>ut can be s:i.iJ .1boU1 1~c ..:h.:uijc o! :i srcdcs OOITT..111~ c~tt.:CIC'l.t inti.> :s:, ors-ir.ic
sohc-r.l''

y (>) On"' lhc hlo,:j. Jllgr.1.m vf a doi.:l>le bc.Jtn !jX'~Uorhot.J.n.c!c-r pomtiat= different
com~n~nts of the initrumcnt
(b) Sutc lkcr-L&rt,b<rt'" I.aw ::i.:ld dc\CWi If• \ 'J.flO'J~ limU.:tllcn.s..
(<) Oridl) dC'ioCnbc t~ prcp.intio:1 :t!"J 3;>p!ic~:hm o( .s ~·.1ht-:-.i:..iC1n cur.c for tt:C'
qu.i..,tjtJti,c Jr1rr.11in.11:on of; r.1et.\J 10n by U\'•\ nitil:: :•p("l.'1:C'lpht\tn,'t\Ct:-r.
.., .'
✓Write >l-A'rl M!e1 o:, an \· thrtt iJfthc fo!tO\\ins j •) C \)
(J} Scpl.":J.tlon of f b·· 11.,:J cu=
1
· ion" ;)CtSCll1 1:, .t.1 ~CC'•Y.:J ~lu1io11 .mJ thtir
confirr.u1!on,
tbl lmp:O\'Cffl(:r.l ofthr <clc.:ti,u~ of .m u.'t)dccu,c :-clc!C't:I EUT·\
(c) WUWcrdcu.nnir..:tir,n "( d!i!ohc-J o.x~scn m ,, J;cr.
(d> Sj"(\:tr..>?hclllrr.c!ri; 1:cterr.11r.,11iC1n o( co~rosi1:on cf :i :nc~l-lit,;J.r.d co:nr,>=~
l e) Sot:r.:c, of '°nor'i .1:1J !heir r·unur.11:i:.o:, 1:-i 11).!t r:'l<m.: tll: J:11.)rJ.
 (dj \\'hai is surface tension'! o~tlinc the c:msc of its origin. How is it c!L111i;e with
temp.:ralurc?

5. (a) Deline pH of;, solution, drow an nppro:-;imate pH titration curve when 20.0 mL of
0.10 ~I propJnoic ucid ( KJ c 1.3, Io·S) is titrated with 0.20 1...1 NaOl 1, the totnl volume
of NaOI! ~.!ded is 20.0 ml. I low can you use ii to detcmiinc the K., \'Jluc of the 4t·2
ocid? ~
(b) Wh:u is meant by a buffer solu1ion? A buOcr solution is prepared by dissol\'ing 4.0 g I+3
NuNOz (!\-Ir - 69) in I00 ml. 0 .39:VI HN01 (K., ~ 4.7>< I 0 4 ) solution. Calcul~t. the pl! ..-2
of the buffrr .iml discuss th~ mechanism of the resuhing buffer solution. =6
tc) \Vhu1 is common ion cllcct'! t-lcntion two of its applications in inorganic qu.ilil.Jlivc
analysis. ,

6. (11 ) Expl:iin kinetic energy om) potcntiol energy. Energy of atoms or molecules are
qu:u11i1.cd, explain. 3
(b) Discu!(.~ about Jifl~ren1 types of motion possible in g:i.~ molecules. E.~pbin di!Tcrcnl
types o f \'ibmtional motion possible in 11 wntcr molecule in the vapour stat.:. 3
(c) Deline with c~amplcs i) cxtcnsi\'c nnd intensive properties ii) microscopic and 3
macroscopic propcnies and iii) ph)'sical and chemical prop.:nics of matter.
(J) Explnin the maf!Jtetic propert)' of molecular oxygen u., ing molecular orbiul diagr:im. 2
(.:) Sketch the distribution of speeds of g.i..s molecules in a container according to
~1axwdl and discuss the figures. 3

) · (a) Define electrode and electrode potential.

\b) Sk.:tch an elcctrochemicnl cell. IJbcl ils difli::rent pans nnd mention their functions. 3
(c) \Vrite the half reactio~ occurring in n Denial cell. \\/hat physjQJ ch.inses occur
when a Danie! cdl works?
Nan,c Jiffc,cch ~ypc:~ of ~h.'\..tn•di.:s \\titJ1 ~xamplc,.
Wdtc u nutc 011 cell notution used 10 de~ribc an clc.:trochemic.il cell. 3

II. (a) Explain the terms. rate ar.d r.itc law of a chemical reaction. Name the factors which
,,
affcc1 1hc reaction mtc.
(b) Explain how we can mcnsurc the instantaneous rate of n chcmic11J reaction nt any 2
time.
(c) For a first order reaction derive the rate equation in lhc intcgmtc<l form and show the 3 ''.!
plot (i) (A} vs I and In/A} \ 'S t when: (A] is the concentration of rcac:ant nttirnc t. ~s
(d) Half-life of a l" order reaction is independent of initial conc~ntration, cxplcin. 3
 l>c,.mmcnt o f Ch<mi>lt)
Un1vcr>ity of l)h..ut,a

h n t Y= US. (110 :>1.) Eumi:wi.,n, ~018

Counc Thie: l'h)>iul Chcmim)" I
Counc :"io• . CII I0 I ( 4 Crcdlu o
.-u ll :'>b rl;: 70
Tl-. ~ ha .:,~

(Anv,••c:r AD)' n,e Qu.u.tion1.)

I. (a) \\'I..: do )ou unden.u:,J by .,n ide.il ~J 3 r<>I vu·•
(b) \\"rite do-.n the t:;'(rrc-.}., 1on lh..tt ,ho..-.-, the rc1.1huruhi;,- t-d'""«n, .aro•J.t ftc.uu:~, o f ~
hquid \\ith tcmpel'J lW< n:rntiuuini; mc:.nin;; uf cw, iam thcmn .
\c) Wh.lt .uc the m o lc-cub: critcrfa of a comr,., unJ ,,. h•'< h)dt~£~ lx,:-.J :.s :>.~
intrm-.olc,:ul;tr t\Jr~c?
Id) lli·:lro~cn diffu,c, tJ, lcr r~.>n met.'i:,n,,, cspl:un
tel Ex:,bin IM t SO~ os a J)l)IOI m ~k,u!c ~ul SO, 1>n'1
(f1 Dbtinsui1h t-.:mcn, equilibrium ccmu.,111r.d :c.101,on quotirnt of r<-'-tio~
(g) Gr.iphtc.l!ly ,1..,w the ch.L,~c nf cunccn1::ition of re;i.;:unt. I,\), .,.., th t1:nc for L',:
rcJc1ion A - t P. \,hen t.hc rc.ir.::tion i1 (i) zcru. (iit fir,t .u.d (111 ) i.c..:cnd l":-,kr A1:b 0

rc>.,«t u, ,\ .
,.
(h) \\'h:,1 3r< 11:c fo,t11 r; 111.11 i11tl•Jen<:e the buffer c.ip.,city of a bu!fc:''
(I) - solul>11i1y of Co(OII): o! ""''" 1cmpcr.it1.:1e is I I• 10·' ~-1. c.i!cub:e ,u solu:-,l.~
rroouct
\i I \\'Jut tue the rc.1S01ti o f ir.t rc>$C of rc.1.ii.,n r.:1< Y.i :h tl:c in.ruse of tc:::ipc:;,ru.-c'?
(I:) Etlun-.,111 Jws fa,tc: 1h.sn i:J)ccnn wuui;h a i:l.t\\ tube, "h> '
(11 Wh.l: .uc the cro:eri, -,f ,,n 1do.!I !'o<llutoon'
{m) \\1,:n i~ c•,mosis .1nJ o,mo:ic pr-:-~nuc?
{n) \\'ritic the: Eins.tdn CtlUJtion "f n:la1h·c , 1xosity .1.r.J c,pll11n L~c terr.:, in i!.

(•) Stale the &ycr, llY., Or,w r u 1· ;ind I' u /II' gr.ip!n for an i<kA ;.u :u t-,.o
diffcnnt [Cfflpr-r.llW'C)~
(t-) Draw lh< Am;sgat' > CUl"\'<1 for iJe.11, h)dzoi;cn on,J c.::l,on diox,..'c i ; =. \\'h) ...~
how did ,._,,, dcr W.ul moJify the idc:,J g.u cqll-'li\ln for tcd i;:u" ; j
(c) f_,pl.tin che Am"o;u', Cll1''e l'f c.ub.,n Jioxide with the un dcr Wu!', cqu.>t:o n.
(d) Cakublc "ith the ,·:in
de: w,_.1, t:q1Ulion, the i,r:-;nir, of l mol o f CO: .1: 273 . I K
"!:en cur.tin.'<! in u volume of~-~➔ L ,.,~ Iler w.,_,1, ,.,n<1.i.:iu for CO,. a• 3.6 10
>Im L'mor 2 :ind b • 4.21)x 10-: L mor' .
•
3. (•) Odine >)otem, ,urround1ni; .nil >I.lie function.
✓ (b) Dcn,c: the c,preuion\. for v.ork. done in 3n ikHh:nr.;11 rc:,cn1f'!le .i."')J ,n·c,--cntl-lc:
csp.,n.sion C'I on :deal S" Sho" th.it the ""'I.
o f the re·.enit.-lo Fnxess , i i;,c,tcr lb .,
rlu: c t inc.cr>iblc proc-:.u .
(CJ Or.,·, . :>n:1 l•bcl 8om ••lla~<r cy.:k for Mi;CI: P.ie l,in,.;e er.er~ of ~li:("1:
d<tcnnifl<'<l by using thi, q ·d c i• rusher th,,n 1!u1 of 1h,'<)1<1k~ll ) c::!oul.ltc.l , ..Jue. :-1
e~plairy.
(d) Calcula: t the ston<br<l er.~1.t!p) ch.u,ge, .1.11~ uf1he rc.>et i.,n,
4Slli(SI - SO;(~> - ~S01;:l • <>11;0(1)
Gh-cn. the st.::nda1J cntlulpic, uf foim~lion of SIi,, :-,;o onJ 11:O o.:-e -15 .9. t),) J .t:>J
-141.S kJ mol' 1 , rc,rc.:1i,d)

_¼' (:a) \\,Ut :u-c Ulc colht.3th c rruric:rucs.., Wiut is mc.un b) ,:ipv.u .,rts(:.cc t,f a li~1.ud~
llow da<s 11 du.,~c " ith tcmr<rJturc?
(b) SL,te R:l,,u!l's laws nf c!<\Jtlon ,,r
t--,ilin£ roint ui ., ! Olul!On er. ,d!,:,an 01 c.o n,
\'ol.1hl: :uiJ r.on-<lt'\:truhtc- M:•hm: h) it. Dcdu..:e ll from U'.t: '-'?uUt prenurc , i
t:mpcr.i~m: ;tlo: c-! j >''h,:nt :..-.d its S\)Jlltion,
(c) .-\ s,,lution of urc,3 1s rr.:p>r<J b:, Ji~suh L~; t, 0 ~ u i II i n 60 '., ~ of "•:er fK,• 1) 5:,
C.,ku!J:< 1:1.: bo1lir.1; p,•int 1,f the s..,ktir•r. :.t n~r:r.:.i.l Jtr.'l~!rhrri : pr:uc.:r

Pose I of2
 (c) Define cr,st:1\linc and amurphl,)US solids. How d1.1 you distini;ui~h b.:l1\ccn
3
them'> 2
(d) Draw and dcscribc the suuchuc of NaCl.
2
(c) Discuss band theory of mctnllic bonding.

. / (a) Explain the following on the b~:.ilfilp,1olt:cular orbital theory;

(i) Bond length of 0 2• ion is ~tcr than that o~ 02 molecule.
(ii) 8 2 molecule is ~table whereas Dc2 molecule is unstable.
(b) Explain your um!crs!.lllding about conjugJIC ocid Md base v.i 1h suitable
cxu111plcs.
(cl \Vhich arc of the followini; sp1..-cics Lc1\iS ucids and Lewis bases? Explain your
reasoning of choice.
SO, . Pl!,, DF1 and so/·.
(d) Deline stoichil'mctric crystll defects. Dis.:uss the different types of
stoichiometric Cf)'Sial defects. 3

(a) \Vhnt do we mean b}' polnrizin&nbility? \Vh;it is Fojun's rule of polnri1.nlion'1 1+11/,
(b) Colc ulotc the bond order for an ion with the following confii;u.ration:
2
(oi,) (o • :,):(01.,i( 112,,. .t1.,)'(n • 10.., 11• ii,yi>
(c) Esplain \\h:11 "" incjn b~ hurd nn<I ,ofi ncids and buses. using specific
c~;implcs. 3
(d) Discus~ the opplic,uion of HASS (Hnrd Soft Acid Base) principle. 3
(c) Describe, lh: following:
(i) Sut-stitution rc.iction. (ii) Condensation rc~ction and (iii) lsomcri7.:ition I 1/,x3
rcac1io11 =4½
- (a) h1c,uion the foc111rs on "hich nucleor stability depends. How the nuclear
stability docs ,·:1f)' on neuthln l\l proton ratio?
ll-) Calculate both the 1otat bindin~ energy (~tcV) and the binding energy per
nucleon (lv1cV) for 'le. {Given that mlSs of proton = 1.00728 .unu, mn.~s of
ncu1ron "' 1.00!!67 umu, and atomic weight of 1ic is 12.00000 nmu. and I nniu
= 93 t.5 ~leVJ
(c) \Vhot is the Q value of a nucknr rc;1ction? Cakulnte the Q va lue for the rcac1io11
1
;N + 1Ue-- 1io • !II
Is the reaction cxothcnnic or cndo1hcrmic'/ (G iven thnt masses of ';N 1-r2
= 14.003074 ai11u. ~lie = 4.002604 nmu, 1 ;0 = 16.999 133 amu and of :11 ..3
= 1.007825 wnu]
(d) Balance the following rcdox rcJctions using hal f reaction method:
(i) CriO/'(aq) •· l'(nq) - - cr3·(aq) + Ii (g) in acid ic m~-dia
(ii) ~lnO,'(aq) ~ Br'(~q)-- ~lnO1 (s) + Br0f (nq) in basic media.
 lk~tmcr.t 01 Chcrn:">J)
Cm\ c-:.>11y of l>h.1).1

(°o un~ T il lt. rr:.r.Clj}le, or lnorµnic t.:hcrmi:r.· Count :"rio CU1-'l ( J <.:,cell\.)>
Full Mark 70 , 1'1mc· 4 hou:,

JJ\tn\\U Q u,--,tioo nuo1bcr I anJ e nv '"'!.! fwm th~ 1cm11:tm~ Ql..e,1ium,)

1. Upl.:ain or ~,1 vc 3-hort .an:mcr oflhe follm,ins quc,1:ua, l ~ 1-1
(.1) \Vhk~ o:,; lu., 1hc lont:!''t ,,.1\'dtflt;lh. btix or rcJ h ght'1
(b) What is Compton el fre t'/
(e) \Vh>1 " me.ult by O ruJ L,.1 'h)><lc'! llo" rrur.1 roJi:u rr.od« :,,re there for ld
orbiu l,7
(d) ()i\CuU the r:w,,l prob,b1ht) Ji.iribuiion cur.e, fu r ~p or.d ;p orbitah.
(e) E,pt•L~ th>t 11itro~cn !us higher \'aluc ofio11i1.1:1on cn<ri:) L~.:n OX)S<tl.
( f) Om, tl:c slupc .,f na-!ccub, orbitoh oblllincu by Ille o,c,i,p of P,·P, otom:c
orbita~.
(Fl Defir.: unit c dl 11,,w o the u~it cell ch313,:tcri1t<J' It"
(hl Ctu .. f) the foll<•"'"S,, ocid,e, b>.>ic onJ 'nc.Er.'r.iITaer:
co. 1',0 ,. Sr.0 and
Fc,O,
(i) Dm, the ske:chcs oi J-,11bit>b sho"rn~ the dmxtior..tl ch.1rnc1cri11io.
\j) £.,rllin that LiCI h cov1knl "hik N1CI i., ionic
(k) Ix fine bonJi:is and antibunJing molccul31 orbit.ib .
(II ln< JiJ)<>lc ronmcnt of 11:S I, 0.?7 D. h the m~lcctdc linc.v or b<ni? &p!>Jn
your 1tl$onini;.
(rn) ~.imc the i m;"()rt~nl fund.:1mcnt.1J p;irt1dc1 of;m a:om
(nl Wr,tc J o" n the name, of MnO, occoriling to to.>1h IUl'AC !IJ1d AS !:
rC'C'onuncnJ.llion.

Dcn\c Uc Dro);l1c •s \\-::s ,·c: cqu.1hon l'r d ll,11 nJtu:c of r.ut:cr.

\\1,.11 i; dsrn ,,-;we func1i0117 Write Jown the chlnctcri.stia of an ctgcn '"•' c
func:•lon
(<) \\'hAJ osc qu.;utu.un numbcn? Uptain I.he ~1&nifi conc.c. o r c::ach qu.unum number.
1low Ate rhcv rdol<.-J ro c~ h othff,>
(u) \\"hy an o rb(l!II c,1.n nccommod.1tc o nly rwo c:l«uo n.,'?
( C) faplrun "ith c~nmplc, Hum.I', rule or m:i.,imum muhJplici1y l!o" d on thu
rule help w in dt:tc:nnirjng ;he electronic: configl!l"3tjon of clement,'? )

Write do•,n t~e, arious menu of Bohr's :uo :nic ml-..dd. )

3. ./ \l)
/ . (bl Tbc h~d.'Ut;ca ::it t1m con.si~b of a single cl«t:'On IIO\\ C.l!l ) ' OU cxpt:Uo the
:i~;i.,-;ince o!" $0 mln)' lin\' .S i o lhc :'>f'CCtrum of .!tomic hydrogen"?
(<) . \l,:l,a~CIL.□C1P b:· ·]' " OlWll-llWllt-'i~ -.;...,,.,..J;ff,1wt · l)ptt-Of-<t'-" """m
r.u.-n~.llltlL.lll,'.lliftc= pl<>~'$ .\ \ , ~ ct-t· ~/~ .
(d) St:uc lhc un,auinl)' principle :md cxp!Jin ., situ.:,tion in " hich it becorn<:<
iruignific.int.
(c) Comrncr.t <Jn the fol!o,,·ins ~round su~c c!cc.trC\nic configuntioru:
K , (Arl4st . Cr: [,\r}3d'4s 1
Ni: (Ar)JJ'-1,' Cu: (,\t)Jd 104s 1

4. (o) Expb.in the ,t.n;eturc 30d l.)yout of the moJcrn pcnoJic tabk o f clement\ 6
(bl E.,pl.lin wh~
\i) Elccuun nl1initk, of tuloacru :i,c \Cf)' hip,
( i i) lhc ~onJ ckctrun .iffinity ofu,)icn .itom h po1ith·c
(c) Wb t infonr.ii,.,n cant,: obwincd b)' knowius the clceuuncg:,th11y .!itfr:cncc,
h<t~c-:"n m u c lements,,
(J) fap!.tin "hr c.i,tioa, ore l!n>llcr .md onion, llri;cr in r.id,i
:ltnms~
~°'"" lhci, ~ •
.i

/4 (>l Wb t " h; ,!rotcn ':-vnJmg'? Give • btf , cco"nt of t;Jrogcn t:,mding in

tnorS,:ttllC .:.:~:tlf)OlL'id
lh) Odinc limcc c.-n:,.;i ..! r, w.1:.: ~o r:i;,ound. Cokuhtc the l:c,1 o f fomution oi
.lJ !, c:· ,I) ,111linc :-,L • ,•m~ 11:c fo!lll\\1",; d,u ,cconiins l.l ncm-lfa~r C\'Ck
(Gh cn 1b1 S • : 6 kcal. 1/,D • •~9 ~.:>!. l ~ · I !~ kc.,.J . E • -!13 i:c:,!, u - ·.1s:; l •~
lc~ I

P>;el ofl p:.e-uc t-:..:-:i OH"

 (c) C,ampo-i.mdt, A ar.J n ha\t ltM:' ~ C' molccul~ formul:i IC,ll,10~ Bo~h t~.1nn~
dur:il c.) ~b)drini.· v.·H.h HCN ~:id o·n reduction ii\ c-, ~1,ni :11,.~e. (Ci1U11J
J
~du-.;;c tl~c ~t..~ttltt of A .ml D.

6. (.1) Cl:usify thi; folJowi11s tompo~nJ.1 u a.ronl;1itk 3l1J non••::arcimLllic ifflJ ju1tiry
/
o~ o o .co
,( b ) E-~pl:uu tt.h.11 ''benzene u more ,rr~.:-li"-c th..ln niuo~n,-"rnt lo"·J.rJt dcclro~tl l. f.
1ub~il Lnii."'n rcctlon....
J
{(; ) I IO\'I." '\.\U!L:i]d you c,b~.nn 1he r,.,HO\o\in.g r,um,bcn1tn~?
{! ) Hcntfl u.~ acid, (H). I.,.11pro flt)' I b<nz.c11 e a:¾1 ('i ~ i) Phcno~
i

(Jl H-illid~}"~ u. ~ L1 Cl('lnJ ~~ur 1n Frill!'d.d CtJfi·, 2-11.)!.llU)n •t-3 cUOr.i but p.1!)·t.;_:.~.1t~on i1
1

nol 1:uunJ Ln !~ritd,;I C raft''1, D',:)'l..l~,on ff.Xlhnf" c.1rbmJ1

J. (a) DiKUM ilie (.Onf..:irnt.11hm of n-huum.e ....; ,h qlcre} prulal.c:: J~.,....un. J

l 1, ,,... I I~'-\' uo.uJJ )OU Jctcmdne the conrigmitlon .,.r rh,,.,.,a.,u ~1-0tflC"ri~ilr{I J
(cl [ )~iti n ~ui '1.h, thr foll p v., i l'lii!=, ·
l i) En:;..nt i"'"'rncan a r.)J d •~~ te."'1=om ~f-,,_
(Ii) ~,~ Ct'l-fflJ"<l'UlJJ .1n•l r~cm,r:. mh,11,. ur
s...,~ re·'KI i0 11 pi-."lC'Ccd"" \Uth Lru-'C'n •Qn n r (,t: nfi gw-~= ion ...., hi ,e S ..,,! 11'....;yy, I
r;:a;crn i:r:.:ni11n c-,; p ~.ra.• n , he f-lCl 1 J

X, (~) l[o..,..- ~~'l .r.tl \h,c !our h)'dto~cn··1 of mcth:.~, •·t c:qu•·,-,1l~ll
) C' U csublid1 th.,t
(b) OtSl!ri'bc the uorna1ic i1~· of P)Ti1dlne.
(c.J Wri tc 1hol1 RQlC1; en un,~'lrn'c:c of tM folk,"' in~;
(i) Croi n rcx1i.,o
(ii) ~\~d ol co niktu;;1! ion
(iii1 Pc-rlin tc.;s.:tuin
(ix} Confo,rm:i~io.n• <.~r ~tdcbnane
, , ·) k.ci.:.i it~n of~"' 111 Uj.11 eJ d ~ene-1.
 l)q,~nmcnl ur ("hcmhtr)
Uni>·cniry or Dh.1kn

"'"' )'cur II.!> (II~,;., l hxom,11.11io1121Jlfi

Count l"illr: 0:.-,ui, Chcnn,u·,· I Counr Su. : C:11121 (4 Cmliu)

l'ull Mark· 70 · 1"imr: ~ htn:r,

(An t¾~r Qunliun nun1htr I an:!'"" fuur r,omlh(' rcm.unint,t Quc-.tic.>n)I

bpl•in 111 the ,hon oruwcr vfrhc (ollu"ln• quc,11oru. I • 14
(o) \\11ar h :i c>1boc~tiun'/ !lo" c:i.n )OU ~,cute It'/
(b) flr.1w lhc 111biul pkturr of Cll 1' onJ Cllf.
(c) Define clc<:trophi!c, nnJ uudcophilc.s with examples
(d) \\"h,t is cna;.y of acth:itiou? ~l<nlion iu imporuncc
(c) Who: is• r.iccrnic rn i,.1urc7 Gi,·c nn cwnplc.
(1) Whlt as an illdol7 Wmc iu ~tructurc.
(i;)llo" .:nn you differentiate u, unJp,xylcr.c~chcmi.:Jlly'/
(h) lln" mru1) s1 s,i1J onJ pi bomls '«i,t in 1hc molecule C,11 ,Cl!:-CK
(i) \\'hat :Ire h JnJ Z oot.1uo1u'!
(j) Wnt: tlu\\ n r"h.: ,iructu~I fom1ub ofCH1Cll(Oll)C(Cl li);C l!:Cll0 cotnpoun.J.
,,r
(k) Wh>· the 1~,1hng 1.:m, 11-pcnl:mc ii higher lhAn that of ncop<numc?
(I) Wnlc do\\n the hcmi:>eclol ~,ruciwc of &lucosc.
(m) Wha1ore 1hc duracteris1k s or pol)nUclc:aI 11toma1ic hydrocatbon'/
(n) \\'hu; types of 111olteulc1 nrc IR-.ctivc'!

~i (a) f)rJw the orhilll piclurc of on ollcnc. IVi

(b) Dci-cribc t\\O general methods of pr<p.11ation of ulkcn, with chcmic.ul rc.l<."'lion 2'/J
(c) Dcscnbc dectr0philic addition n:ac1ion.\ or :tlkcnc with mcdw1im1. ~½
(d) Wntc •II the procum ohuin when l-bu1cnc ,nd 2-butcne rc.u:l with IIBr.
rcsp«ti,cli Oct~t the chir.Jity of the product (s). J
Oc"ribc the follo\\ing reactions m th cXAmplcs.
(i) Oximcrcurnt1on-dcmm:ur.1tion
(ii) llydrob<-rJ1io11-o,id.11io11
(iii) llydruxyloiion

J. (a) \\'ri,c do"1i two gcncr.11 mc1hod, oi prci,=~on of nionoh)dric .,lcohol, "iih 3
f" c.\ilmplcs.
(b) \111y ·•ko~ols arc not llooJ suosltltc for S, reactions"! 11/,
(c) \l'ntc do"n 1hc possiMc rca.tivn productsor(Cll il,CCl l,UH "ith cooc. H:SO,. J
Est.,~lish your answ« " ith possible rcot,ion ruchmism.
(d) C<1mp.u-c the reactivity of the following p:,irs:
(i) ,\kohols anJ nll yl h•lidcs.
(ii) Alcohols anJ phenols. ''.
J ,t

(c) Comp,,u!ld A (C. ll11 Cl)on UcJtment " ith alcoholic KOii gives 8 (0~10). ll o n
oxid,1,on "ith K~inO, provtdcs C (C.ll1iO:) a.,d Cuc oxiJJtion t!lldcr dr..stic
conJuion provid<:s D (C,.11 100 ,). Deduce Ille ,..•,mures or,\, II. C u.d D wi1h
the .:hcmic,! rcae1ions

-1 . (a) O,scrit\: '"" meihoJ, l.lf p:cpamtion ofolipli.111c uldchidc.s :ind k<lon<s. ..
3, .
(b) Expbin why "prop.uial is more rcm1\'C tvwanls nuc!cur-hili, wldi1ivn rccction
1han :ha1 r;,f prop-.1nonc". 3
(c) S1n1)~$it c 1ho follo" ins comp,.,uniis:
(i) m r-Bur:mol from propJnol-1
\ii) 1-Phcn~lctlunol from cthyltn, uxidc
(iii) 11-Prop..i.1 0I from cth:!Jlol.
(i,·) But.mane from e:hyl b1,1midc. 5xl!'i
~ 71/:
(v) PhiCrC(Cll)l: from occt.1nc

5./ (3) or
~;,rib,: t I\\) gcncr.,J rr.cth,>Js of prcp.1ra11on aliphltic CJINX)"lic ncid} 3
/ (bl How o~ :011 , ~n\Crl a carhoX)il, ,,id into: (i i .Ill amide. (ii) an cstc:
Jr.d uiJJ .!II nc~ I h,liJe'? 3
(c l E1h:u:oi~ ac,J 311d cthwol bo1h contait\5 -OH gro'Jf faphin the reasons that
one oi 1hcm is ac:di.: a::d the other is :\01.
Ho" : ln yo:., prc~m I•. : '.!1', J :;• o.kvhols from crt...m) I cc,mpol.lilds? 3
(cl)

pk-3.\C turn rr, ct

P.igo I ofl
 Il<r.nm,.,..t ,,( 1 "h<m":"
l!n" ~'"'1 ,,r llh.a,.

C:e111rn Thi, Utfl\!lte <:hrnn,:" I Counr !'io C'lll)I (I Cml,u)

I· ull ~hrlo.· 70 •
11111, ~h....n
I \ru--n l)un tioa aamb«r I anc! ,a• [ygr h or, ti><' ,cn,.,,.n,ng ,~i..,mJ
hpla1n1,q;i,t'alto•M1111>>1n1•fthc'f,,t1-,,.U>4'1~'""" 1 • I~
t•l \\1..,1 ts a ,,.t-.x:.u,m·t 11-,,. '"" )"" rrna.ue n•
tb) D:-~w the 1llh1ul 111m,rc ('f<:lh' anJ nii·
1c) Define clC\1Nph1!n a:l.l nuJeorhlle1 ...1111 cuo;,1"
tJ) \\ Im 1, cnct,r) ul ~ u,111,m7 ~lrr.111.,a 11.> ,ml''lU."'-c
(c) \\ h4! IJ a r.,c,crn,, mi~tu,cJ Ul\c an c.,~m!'lc
II) \\'h.,: ".\n Ill.Joi '\\ IIIC II\ ,:r.xiurc.
(i;J Ito" ,.c: )•' U Jo.l: =nhalc IJ• ~/"\)I= cl;rm!.;.lllJ :
th) 11,, ., ,:un~ 1:i;ma a.:)J p, NnJ, C\hl in th< m.t!C\:ulc l·,111r t1:-<,:1'
It) \\11lt lt~ I J.nJ I Mul11>n,·1
IJ\ \\ n:: J ,," n 1h~ )lni,. 111nl r,,mu!J ,,( l'll,rl hllll){'t fl lil:rl 1:CIIO '"ml'•wi.l
\lt Wh~ •~c t-. ,,l,n~ ,, in• ,,t 11-1'<nt;a.-.., ,s h,i:lu-f thlln tlul 111 nC\•rrn1.cnc~
(II \\'r.1: J ,1\\ll \.'le l1e1111~1.CIA1 ~tni.twc of i;l~u,c.
(ml \\ h.L1.u.: the 1.hJ.1J.tai111.-, of l',l)nuclr.u :11t1 m,11,c hill:-oc.ut-.on'
tnl \\ lui tH"<• ~ I m,•lc-ulr, ,110 IR-a,·1,,c'.'

l
l>rJ" the ,•;t,11JI p1.:1111.- ol an ollcnc
•✓
l'lc-.."11t-c '"'' ~cnn;1l mctl1,,J, ,,r J'ICJ\11llll'll or ullcu \\llh ,:hem,ul IU.:h M
L>n.nt-c dc.:1n,rhth, 3JJ111,,n l'C.l lll!'n\ ..r 311..c.-i< .. ,:h m«h&nilnl
\\'m~ all the proJu,h ,•!>l• tn ""-<n l •Nlmc ,nJ :.t,utcn: 1..-..:1 ..,:~ I Ill:.
•~p,'\:ll•cl~ l).:1.-.:t lhc d111Jlt1~ oftl:c pr.i.lu.:t ())
t<) l.>,: ..,r,l'I: the loll,11,111~ rca.1ic•n1 \\llh cumrk,
(1 ) lh~;n~w•tl\•n.Jcm~rcun.11011
I II I II~ Jn,l-.'f'Jl1,>n-o,i,l.t11"~ II.•)
\1111 I l~Jru\.~ la11,1n .. .,11. ,

J Wn:c J.,,rn '"" ~rncr.il mcth,, h c,{ r:CJU=.!!:Cn ,,( mvn~!,~Juc 3l;.i!l.>h "Ill:
, e,.ur.plcs
(bl Wh~ ·.uc.i~uls arc"''' i;,-.>J )Ul:-~ua:c fo: S, :e.:-ho1u· ,
tc) \\'ntc 1.,\rnn the p,,uiNc rcJ.;liun proJuc:1 .,f !Cl Itl1CCll;l)II "'u, cun.: 11:SO.
bt.iNish ~••t.r .111.wcr \\llh l').ssiblc rc.i.::,on rr.«lunism
Cum;,.in- lhc rc.i.:1i>·i1~ uithc follo" ini; p:,irs·
(ti Ak.ih..,ls w iil~~ I tuliJ:s.
(ti) :\k('hvls JnJ rhcn<'ls .'
J I

IC) Com~i.."\J A (CJl11CI) 011 U'c:J;mcnt \\ith ;,!.:,.ih,1hc KOii £1'e> ll 18 ,11:•I IJ ""
""~:,in "ilh K~lnO, pro,·1Jc-5 C \C,11,:0.J a."'-' l' QC o,i.1.itivn i.:.-.Jci ~,::.:
conJ111on p1u1 iJc! D (C,11 1.0,). ~u, c 1!:c ,:.-Jctu:cs ,,f A. ll. r .ir.J O "nh
i..'ic .:hc:m:cl rc:ictions ..
..i . u) !x,-.;ri!-o: ,.,.,. m:th,.J. "f imr=:ion l'f ;ihp!uuc ~)Jeh~.!~ 2.•J lc::.ir.n J I
\bl £.'l'.pl.ii:1 wh~ ··rrop.lll.ll i, m..,r, 1cJ.:tt1e hl\\'Jl\ll nudr,•r!'.1lr.: •.!~:11..:: r.~ .•c
tn.1."11.l'..ll ,,( pr!'~onc".
(t ) s,ntl-.csizc tl:c folh.'" in; ,~m.,..,un,h·
(1) :rr:-0:Jund in' m p~.il-1
11i ) ~-Ph<:::t~ lc:tlun,,I ir'1m ctl:~l<r.: ,,,1Jc
(:11 t ,,.p,...,f'L,cl f:.ir.1 c1l-..1.i-1!.
(•• , 0;1.&!Nnc frum .-:hJI m,r:i,dc 5' 1:
1.J l'h:C' C1Cil1l: fro:r. >:tl~e

Il l lx~.::il--c '" 1) ~rne:-J.! rr.cth.,Js Of FXfJ.":lh0:1 C'I lhJ'l1lU, !:.: :i..iJ1 =~"~ ;
I ~) Ho" :2., ) <>U , ,, :l•,c:t :i .:Jr~,~l!.; ,:iJ 1r.:c \i t .,_, :uni.!,·. (ii\ ::1 n :r:
.ir.d lW) .!r. l,, , 1'..!ln:c-
E.1h::.ro:.: :i.:.,i Jn.! ctlunul Nti: .:lln~i:t~ -OH fr.J'..lr brbm the rt.1.l.l:I) tl'..i:
,·r.c C'f tJ-.c.-:i , . J.:: 1:c ur..! -.!:.:, t:t!-.cr :, ;'1,)1
ii,\',.\ :J.:: \ r"°":J r r::-,:.::- •• , ,.., . ::.r_I :•
.. .. . 1... ..... ,;_. -
J..:~.X'-1 ••• o H
~.. ~" I
• • ,
-,~~u.,:U'
•t
\.\. •
3