Safety Data Sheet

according to 1907/2006/EC, Article 31 Revision No: 1

Version 1 Revision: 06-11-2019

Section 1: Identification of substance/mixture and of the company/undertaking

1.1 Trade Name Prima Autowash FX WM

1.2 Application of Blanket and Roller Wash for auto cleaning systems
Product

1.3 Company Ultrachem

Identification

Section 2: Hazards Identification

2.1 Classification of the substance or mixture

- Classification according to Regulation (EC) No 1272/2008

GHS08

Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.

- Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xn - Harmful

R20, R21, R22, R20/21, R20/22, R21/22, R20/21/22, R48/20, R48/21, R48/22, R48/20/21, R48/20/22, R48/21/22,
R48/20/21/22, R68/20, R68/21, R68/22, R68/20/21, R68/20/22, R68/21/22, R68/20/21/22, R65.

- Information concerning particular hazards for human and environment

The product has to be labeled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.

- Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature
and by information furnished by supplier companies

2.2 Label elements

Labeling according to Regulation (EC) No 1272/2008
The product is classified and labeled according to the CLP regulation.

- Hazard pictograms

GHS08

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 Safety Data Sheet
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- Signal word: Danger

Hazard determining components of labelling:

Naphtha (petroleum), hydro treated heavy

Hazard statements
H317 May cause an allergic skin reaction.

- Precautionary statements
P280 Wear protective gloves / eye protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/ international
regulations.

2.3 Other hazards

- Results of PBT and vPvB assessment
- PBT: Not applicable.
- vPvB: Not applicable.

Section 3: Composition/Information on ingredients

Dangerous Components:
CAS: 64742-48-9 Naphtha(Petroleum) Heavy
EINECS: 265-150-3 Xn; R65. R66, Asp. Tox. 1, H304 60 - 100%
Long-term (chronic) aquatic hazard, Category 4, H413

Section 4: First Aid Measures

4.1 Description of First Aid Measures

- General Information
Instantly remove any clothing soiled by the product
Personal protection for first aider

- After inhalation If inhalation of this material occurs and adverse effects result, move person to fresh air
and keep comfortable for breathing. If breathing stops, administer artificial respiration
and seek medical aid promptly.
- After skin contact Immediately brush off excess chemical and flush contaminated areas with plenty of
water. Immediately remove all contaminated clothing, jewelry, and shoes. Rinse skin with
large amounts of water/shower. Discard any contaminated leather goods.

- After eye contact If in eyes, immediately rinse eyes cautiously with water for up to 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical attention
immediately.

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- After indigestion Caution if victim vomits. Risk of aspiration! Keep airways free. Call a physician
immediately. Pulmonary failure possible after aspiration of vomit.

4.2 Most important symptoms and effects, both acute and delayed
Depending on the concentration, duration and nature of exposure may result in cyanosis, drowsiness, agitation,
cardiovascular disorders, headache, somnolence, CNS disorders. Repeated exposure may cause skin dryness or
cracking.

4.3 Indication of any immediate medical attention and special treatment needed
Subsequently administer: activated charcoal (20 - 40 g in 10% slurry).

Section 5: Firefighting measures

5.1 Extinguishing media

· Suitable extinguishing agents
CO2, extinguishing powder or foam. Fight larger fires with water jet or alcohol-resistant foam. Use firefighting
measures that suit the environment.

5.2 Special hazards arising from the substance or mixture

Combustible. Vapors are heavier than air and may spread along floors. Development of hazardous combustion
gases or vapors possible in the event of fire. Forms explosive mixtures with air on intense heating.

5.3 Advice for firefighters

· Protective equipment:
Do not inhale explosion gases or combustion gases.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Section 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure
adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency
procedures, and consult an expert.

6.2 Environmental precautions

Do not allow to enter drainage system, surface or ground water. In case of discharge environmental agencies
should be IMMEDIATELY notified.

6.3 Methods and material for containment and cleaning up

Absorb with inert, damp, non-combustible material, and then flush area with water. Dispose of contaminated
material as waste according to item 13.

6.4 Reference to other sections

See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

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Version 1 Revision: 06-11-2019

Section 7: Handling and Storage

7.1 Precautions for safe handling

Keep containers tightly sealed
Keep away from heat and direct sunlight
Information about protection against fire and explosions: Keep away from heat, sparks and open flame.
Eliminate all sources of ignition. Provide good ventilation. Take precautionary measures against static discharge.

7.2 Condition for safe storage, including any incompatibilities

- Storage
- Requirements to be met by storerooms and containers
Keep container tightly closed in a cool and well ventilated workplace. Keep away from heat, sparks and open
flame. Eliminate all sources of ignition. Provide good ventilation. Take precautionary measures against static
discharge.

- Information about storage in one common storage facility:

Keep away from beverages, food stuff and food.

- Further information about storage conditions: Store in a cool place.

- Recommended storage temperature: 5 - 25⁰ C
- Storage class: Flammable liquid storage.

7.3 Specific End use

No further relevant information available

Section 8: Exposure controls/personal protection

- Additional information about design of technical systems: No further data; see section 7.

8.1 Control parameters

- Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.

- Engineering Control: Provide local exhaust ventilation (>10 air cycles/hour) where dust or mist may be
generated. Ensure compliance with applicable exposure limits. Ensure that eyewash station and safety shower is
proximal to the work-station location. Technical measures and appropriate working operations should be given
priority over the use of personal protective equipment.

8.2 Exposure controls

- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals. Keep away from
foodstuffs, beverages and food.
Take off immediately all contaminated clothing.
Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin.

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Do not eat, drink or smoke while working.

Breathing equipment: If ventilation is insufficient, suitable respiratory protection must be provided when
vapors/aerosols are generated.
Recommended Filter type: Filter A (acc. to DIN 3181) for vapors of organic compounds.

Protection of hands:
The protective gloves to be used must comply with the specifications of the EC directive 89/686/ EEC and the
resultant standard EN 374.
This recommendation applies only to the product stated in the Safety Data Sheet and supplied by us as well as to
the purpose specified by us.
Only use chemical-protective gloves with CE-labeling of category III.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Protective Material Types: Nitrile Rubber (full contact) and Butyl-Rubber (splash contact)

Eye protection: Safety glasses recommended during refilling.

Body protection: Wear rubber apron. Wear rubber footwear.

Section 9: Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

- General Information
Appearance:
Form Liquid

Color Clear
Odor Mild

pH-value at 20° C Not determined

Change in condition
Melting point/Melting range < -50 ⁰C
Boiling point/Boiling range 180 - 196 ⁰C

Flash Point 62⁰C

Inflammability (solid, gaseous) No information available

Ignition temperature Not determined

Decomposition temperature No information available
Self-inflammability 247 ⁰C
Explosive property Not classified as explosive.

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Critical values for explosion

Lower 0,6 %(V)
Upper 7 %(V)

Vapor pressure: < 1 kPa @ 20 ⁰C

Density 0.78
Solubility in / Miscibility with Water Miscible
Partition coefficient (n-octane/water) Not determined

9.2 Other information

No further relevant information available

Section 10: Stability and Reactivity

10.1 Reactivity
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be
rated as critical.

10.2 Chemical Stability

Stable at normal temperatures and pressures
- Thermal Decomposition: Not determined

10.3 Possibility of Hazardous Reaction

Violent reactions possible with: Strong oxidizing agents, Strong acids

10.4 Conditions to avoid

Avoid excessive heat for prolonged periods of time. Avoid heat, flames and other sources of ignition.

10.5 Incompatible materials

Rubber, various plastics

10.6 Hazardous decomposition products

No relevant data available

Section 11: Toxicological Information

11.1 Information on toxicological effect

- Acute toxicity
CAS: 64742-48-9 Naphtha(Petroleum) Heavy
LD50 > 5.000 mg/kg (Rat) OECD Test Guideline 401
LC50 > 5 mg/l; dust/mist (Rat) OECD Test Guideline 403
LD50 > 5.000 mg/kg (Rabbit) OECD Test Guideline 402

Skin irritation Repeated exposure may cause skin dryness or cracking.

Eye irritation No data available

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Sensitisation No data available

Germ cell mutagenicity No data available
Carcinogenicity No data available
Reproductive toxicity No data available
Teratogenicity No data available
STOT - single exposure No data available
STOT - repeated exposure No data available
Aspiration hazard Aspiration hazard, Aspiration may cause pulmonary oedema and pneumonitis

11.2 Further Information

- Systemic effects
After absorption Cardiovascular disorders, Cyanosis, agitation
After uptake of large quantities Somnolence, CNS disorders

Other dangerous properties cannot be excluded.

Handle in accordance with good industrial hygiene and safety practice.

Section 12: Ecological Information

12.1 Toxicity
- Aquatic Toxicity
CAS: 64742-48-9 Naphtha(Petroleum) Heavy
Toxicity to fish (Chronic Toxicity) 0.21 mg/l; 28 d [NOEC Oncorhynchus mykiss (rainbow trout)]
Toxicity to daphnia and other aquatic 0.02 mg/l; 21 d [NOEC Daphnia magna (Water flea)]
invertebrates (Chronic toxicity) OECD Test Guideline 211

12.2 Persistence and degradability: The product is not readily biodegradable

12.3 Bio accumulative potential: No further relevant information available
12.4 Mobility in soil and water: No information available

Ecological effects: No further relevant information available

Additional Ecological information: Material exhibits slight toxicity to terrestrial organisms

12.5 Results of PBT and vPvB assessment

- PBT: Not applicable
- vPvB: Not applicable

12.6 Other adverse effects

No further relevant information available

Section 13: Waste Disposal

13.1 Waste treatment methods

- Recommendations

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Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste
Disposal Authority. Do not puncture or incinerate even when empty. Rags and the like, moistened with flammable
liquids, must be discarded into designated fireproof bucket. Must not be disposed of together with household
garbage. Do not allow product to reach sewage system. Product must be specially treated under adherence to
official regulations.

Un-cleaned packaging
- Recommendations
Non contaminated packaging can be used for recycling.
Empty contaminated packaging thoroughly. They can be recycled after thorough and proper cleaning.

Recommended cleaning agent: Water, if necessary with cleaning agent.

Section 14: Transport Information

14.1 UN-Number
- ADR, ADN, IMDG, IATA Void

14.2 UN proper shipping name

- ADR, ADN, IMDG, IATA Void

14.3 Transport hazard class(es)

- ADR, ADN, IMDG, IATA
- Class 3: Flammable Liquid

14.4 Packing group

- ADR, IMDG, IATA III

14.5 Environmental hazards Not applicable

14.6 Special precautions for user Not applicable
14.7 Transport in bulk according to Annex II of Not applicable
MARPOL73/78 and the IBC Code

- Transport/Additional information Not dangerous according to above specifications

- UN "Model Regulation": -

Section 15: Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
- Designation according to EC guidelines:
The product has to be labeled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.

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- EU Legislation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing
mothers. Observe restrictions to employment for juveniles according to the Juvenile Work Protection Guideline
(94/33/EC). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006
concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a
European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93
and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission
Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 Chemical Safety Assessment: A chemical safety assessment has not been carried out

Section 16: Other Information

Abbreviations and acronyms

ADR Accord européen sur le transport des marchandises dangereuses par Route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
IMDG International Maritime Code for Dangerous Goods
IATA International Air Transport Association
GHS Globally Harmonised System of Classification and Labelling of Chemicals
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
CAS Chemical Abstracts Service (division of the American Chemical Society)
LC50 Lethal concentration, 50 percent
LD50 Lethal dose, 50 percent
H304 May be fatal if swallowed and enters airways
H317 May cause an allergic skin reaction.
H413 May cause long lasting harmful effects to aquatic life
P280 Wear protective gloves / eye protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/ international
regulations.
R20 Harmful by inhalation.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R20/21 Harmful by inhalation and in contact with skin.
R20/22 Harmful by inhalation and if swallowed.
R21/22 Harmful in contact with skin and if swallowed.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R48/21 Harmful: danger of serious damage to health by prolonged exposure in contact with skin.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R48/20/21 Harmful: danger of serious damage to health by prolonged exposure through inhalation
and in contact with skin.

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R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation
and if swallowed.
R48/21/22 Harmful: danger of serious damage to health by prolonged exposure in contact with skin
and if swallowed.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation,
in contact with skin and if swallowed.
R68/20 Harmful: possible risk of irreversible effects through inhalation.
R68/21 Harmful: possible risk of irreversible effects in contact with skin.
R68/22 Harmful: possible risk of irreversible effects if swallowed.
R68/20/21 Harmful: possible risk of irreversible effects through inhalation and in contact with skin.
R68/20/22 Harmful: possible risk of irreversible effects through inhalation and if swallowed.
R68/21/22 Harmful: possible risk of irreversible effects in contact with skin and if swallowed.
R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if
swallowed.
R65 Harmful: may cause lung damage if swallowed.

Important
The data presented herein, while not guaranteed, was prepared by technical persons and is accurate and factual
to the best of our knowledge. No guarantee of merchantability or of suitability for a particular purpose, or warranty
or guarantee of any other kind, expressed or implied, is made regarding safety, stability, performance, suitability or
otherwise. This information is not intended to be all-encompassing as to the manner and conditions of use,
storage, disposal, handling, and other factors which may involve other or additional environmental, legal,
performance or safety considerations. The company undertakes no liability whatsoever for the use of or reliance
upon this information. While our technical staffs will be happy to reply to questions, handling, use of the product
and all other responsibilities lies with the customer. No recommendations for use are intended as, and nothing
herein shall be interpreted as, a recommendation to infringe any prevailing patents or to violate any Federal, State,
local or foreign laws.

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