DISTRIBUTION LAW
Dr. Parjanya Shukla
Dr. M.P. Singh Clases
whaB is Distiaukon kad-
(NaTngts Dismhuhion Lauo)
whEn a salus t added to two immisuiblt biqics
(In bot d which soluts is Aolubla
Re ouks disbibute itaf b/w tR two
uqwdls I'n Auch a way
hat tR xakio o ih tonun hraton
in two qw'd phoss i COnstant
au a quwwn tempAraburA .
By-Dy Mahendha PraBab Sing
plonoton
x 4 0 Aolue x diaibuted taalf bJw tooimmi»ikl
Aouents Aand a constant temp. and X
Insam molu l o r Condihon in boh soluants,
on Comunrahon x inA
Com on hroiom o X in B
KD
4f C C Con cenhahion d soluto in soluent A and
and
CC2 Cwnentraton abolus în &akuont 8
4 Can bo xprad a
CL KD
C Diahbubom (ouhiuurt or
uh Kp Or aimplyK t callud forhlicn caulfiuent or
Dishibuwhcn xato
T i an equilibmum Ja-
Dr. Parjanya Shukla
pluhe
Dr. M.P. Singh Claeks
$olvent A C
Solunt 3
O C2
O
hun ob'atoibuhon ad soluk X uachud dy ramit
qwibum
h aks (R,) af uhich moluauls x þaus trom
rom
Aaluant A to B is propahanal t rit Comunrahcn
Cin A
R, d C
RI K C1.
wheu K o comstant.
T ale (R) af uhich mal cales qX paus om
AoJuenf 8 to A b propohional to ita lon cenhahan
Cn
By-Dr Makundro Prala Sin
Ro C2
R Ka C2
uhn K9 o ConaBont
Sinu a equil bnum
K C Ka C2
C KD
C2 K
CL
C
KD NMnats Dixmbuhion Jad.
eguabion
Aplicatons oDiaibuton Luo
Dr. Parjanya Shukla
() SolunB Exhachion Dr. M.P. Singh lassus
Dshibuhon Jaw is wadfOT gporaHon oorganic. albstonus
Tom qunous Aalutions.
A So.luhon shakan wih
quauss immi^ublu organic
on
Aolunt u ch as ethan or hemn
m stparabingunnd)
Bubstanu
ehevaal layen Aapovatad orqanicAehttnt þams into
by dishlafon orual JaykY
orqanic Aubsanu is fh bahind
(8)
(8) Partition Chromoatoqrabhy y-Dy.mahurdra Praob Sing
A asta mixtua i appbied al top otR column
Ab'ca Aoakod in water
immisuikb Aolunt (Rexonu) ts allowad
to Mow down th coumn
Each (ompament omixtura
pho L
orHiond b/w
btaianany auid, uoatay and mabil quid
phosA huxont
(3) Danilvarizaton q Laad (lorkes rous)-
when molten 2i'nc is added to moltn lsad
Contauning Ail vY
Zinc and Jsad om immiubls layevs
ond i l r disihutsd bataen m .
xTh dismbuton Haho i l e r 300 Im tavo
nc a 800° (mox iJur i in zinc) Dr. Parjanya Shuhla
Dr. M.P. Stngh Clasus
On (ooling zinc Jyer alloy of Al'urY and
inc baparatas
2in alloy i dishlud and
8ilueY is 30p0rakad
Lad layar shU contains Ailuer is traatsd oi ash
quantitids molfen zinc.
to ucouT moat of K Bllver
(4) ConiTmaony Tst for Bromide and Iodid
k Th sal solui'on is traaked wi chlon'n wator
Amall quanhity of bromint or iod'nu
Rus bbaraled
ndra
Mahe th Aoluhion tRen haken wik chlorofom
TK u bromune or iodine mors Aolublu
n thlorofom
making it ud or bromin
violut OT od'na
5) Detorminaíon Aouahon'-
ien ub slanu ik asouakad
i'n a &0olunt A and oxis 0 Ampl moluul in soluent 8.
Disibuhion lao is modited as
Lhaus
n
CalCb = K
n i numbov mol aules which fom an avMouabd molh tuls
6) Determinakton o Diksociakion'-
Dr. Parjanya Shuhla
Suppose Subatonu X i di«ouialadin Dr. M. P. Singh ClassMs
aqurous ayer and exibhh as Aingl moltuuls.
f% s Re dag7e o dimo uaion Cov inisahon)
R distrihukon Jauo t modiid a -
C kd
C2 (1-c)
h C Conunhai om dX in ether
Ca
Ca onuntraHon x in wotay
tK can be datorminud rom com duthivity masunmunts.
By-Dr Mahandro Rratab Singb
7) DakzY minaHon o Solubtiy
Smppor K solubi'Luty iodin I'n ban 3enu to ba
datuminud
odint is shakan oik waBer and benzen
a pquubbnum od/'nt in bement (Cb)
and waeY ( Co)
Cb Kd
Co
Sh = kd
Sw
lih Sh =salubikity in ben 3eht.
Sw Aalubiiy in water.
5
'mitakima of Diati bulion Lauo-
Dr.Parjanya Shukla
Drlute doluion , Tk comc. s0uto muut
b Jo Dr. M. P. Sinqh Classes
in tuo boJ usntr..
Constant temperatura Temperalurs shold bs kaph
Comston througaut k x
pTimunt.
dam molu culoY Atate Sohuto mus ho in Aam
malu uloY state in boh Aaluunt.
equulibium COnunaHion Ts ls achizuud by
Ahaking
TK mixturA for Jom
Hme
Non- miscibiby od Solunh- Soluunt should hi non
misubu AoHat con h
&aporad
By-D1. Mohundho Praklb Sing
