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It is very important to determine the explosibility of the mixture gas in the coal mine sealed area after a gas explosion
occurred. If the combustible mixture gas has high explosive tendency, the potential re-occurring explosion would
cause rescue workers’ death when they proceed with their rescue operations in the accident mine. Therefore, no one
is allowed to go down to the underground until the mixture gas is not explosive. Lots of methods have been developed
to determine the explosibility of the mixture gas in the sealed area for a long time. One of these methods is the Coward
explosive triangle method which was published by Coward in 1952. Because of its easiness and high efficiency to
determine the explosibility of the mixture gas, it gradually becomes a very popular tool for mining engineers and
rescue team members in the mining industry. However, although the Coward explosive triangle method has extensive
applications, there are still a few drawbacks in this model. Consequently, errors may be introduced when applying.
In this paper, a brief introduction of the Coward explosive triangle is described firstly. Then based on analyzing its
drawbacks, some improvements with different aspects to calibrate the Coward explosive triangle are proposed and
discussed. Finally, case demonstrations and comparisons with the old model are also shown. The results indicate
that the improved Coward explosive triangles have better accuracy and reliability and could make more accurate
judgments.
© 2010 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
Keywords: Coward explosive triangle; Gas explosion; Explosibility of the mixture gas
∗
Corresponding author.
E-mail address: jchengwvu@gmail.com (J.-w. Cheng).
Received 20 July 2010; Received in revised form 29 November 2010; Accepted 1 December 2010
0957-5820/$ – see front matter © 2010 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
doi:10.1016/j.psep.2010.12.001
90 Process Safety and Environmental Protection 8 9 ( 2 0 1 1 ) 89–94
the laws of gas flammable limits under various influence fac- sive zone COD, thus the explosion may be triggered. Below the
tors, such as temperature, pressure, oxygen concentration, line AE is the non-explosive zone, also known as the absolute
other combustible gases and the inert gas. Based on exper- safety zone. This diagram just provides the explosive trian-
imental results, they proposed a new method to plot the gle with only one individual single combustible gas existing.
explosive triangle for determining the explosibility of the mix- If the mixture gas consists of two or three combustible gases,
ture gas in the mine fire area (Zhou and Wang, 2008). Ray and the procedure of generating the resultant Coward triangle can
Singh introduced the USBM explosive triangle which is widely be described as follows (McPherson, 1993):
used in the U.S. mining industry. The explosibility diagram uti-
lizes the concept of converting the methane, hydrogen, and
1. Determine the total combustibles percentage.
carbon monoxide in the atmosphere into an effective com-
Using subscripts 1, 2 and 3 for the three combustible gases
bustible content and the carbon dioxide and nitrogen into an
and their volume percentage are P1 , P2 and P3 , respectively.
effective inert content (Ray et al., 2004). Therefore, it is a sim-
The total combustibles’ percentage is:
ple method to determine the explosibility of the mixture gas
but not a precise model.
PT = P1 + P2 + P3 (1)
Oxygen (calibrated)
3.1. Redefining the shape of the Coward explosive
triangle
12.64
8.47
8.00
9.47
11.53
9.69
9.75
8.52
Nose limits (CO2 as inert gas)
and the alkane (Cn H2n+2 ), alkene (Cn H2n ), and alkyne (Cn H2n−2 )
series of hydrocarbon gases, and carbon dioxide produced by
mine fires (Timko and Derick, 2006).
Under the condition of the high temperature in the sealed
5.96
5.20
15.67
3.53
3.82
2.50
2.61
3.27
Gas
2.89
3.12
2.09
2.21
2.67
Gas
13.8
Upper
Table 3 – Vertices of explosive triangles (%).
5.00
4.00
12.50
2.75
3.00
2.00
2.12
2.50
Propane (C3 H8 )
Propene (C3 H6 )
Methane (CH4 )
Hydrogen (H2 )
Ethane (C2 H6 )
g 0.054 0.321
h 71.77 44.23 Fig. 3 – Redefined triangles under different dilute gases.
Process Safety and Environmental Protection 8 9 ( 2 0 1 1 ) 89–94 93
ai bi ci di ei fi c i d i e i fi
PCO2 − 0.03
˛= (7)
PCO2 + PN2 − 3.778 × PO2
situation is. Therefore, the early warning index (EW) could be References
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