Fiansa| Corporacién Ferreyros aus FABRICACION DE ESTRUCTURAS METALICAS — PLANTA MOLY-COP SAN MARTIN C.G.S.A, INSUMOSCallington TA A Scotter oe RA Raia SALE Ula) jay-2014 CHEK D-100 Developer Aerosol 400m jereby at this material meets the requirements, and conforms to AMS 2 is materi st m1 (or listing on QPL-AMS-2644. Results of the required quality conformance tests, a ted ragraph 4 3.2, are listed below, > further certify that this material has been tested and meets the requireme Boiler and ssel Code Section V, MIL-| 35E, ASTM E1417. AS 2062 \d on the bottom of aerosol cans or labels of bulk containers ed hereon have beon in: Patrick Fernandes Quality Manager Callington Haven Pty Ltd Sern Pe OR)D-100 AEROSOL DEVELOPER Chemwatch Independent Material Safety Data Sheet Issue Date: 2-Oct-2012 CHEMWATCH 22-4972 A317LP Version No:3.1.1.1 CD 2012/4 Page 1 of 16 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME 100 AEROSOL. DEVELOPER PROPER SHIPPING NAME PRODUCT USE = Application is by spray atomisation from a hand held aerosol pack. ised in NDT testing as a developer. SUPPLIER Sompany’ Callington Haven Pty Company: Callington Haven Pty Lid Address Address 30 South Street PO Box 144 Rydalmere Rydalmere V 244 NSW, 2116 alia Australia phone: +61 2 9898 2788 nergency Tel 1800 039 008 (24 hours) nergency Tel-+81 3 9573 3112 ‘ax +61 2 9684 4215 mail: sales@calhaven.com.au Website: www.callingtonhaven.com Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. CHEMWATCH HAZARD RATINGS Flammability ERS \ | rs Reactivity iL (;,-§ CALE: MiniNil=0 Low=1 Moderate=2 -High=3.«—‘Extreme=4 continued.D-100 AEROSOL DEVELOPER Chemwatch Independent Material Safoty Data Shoot Issue Date: 2-Oct-2012 CHEMWATCH 22-4972 AS17LP Version No:3.1.1.1 CD 2012/4 Page 2 of 16 Section 2 - HAZARDS IDENTIFICATION RISK SAFETY = Extremely flammable + Keep away from sources of ignition. No smoking, « Iritating to eyes. + Avoid contact with eyes 1 Risk of explosion iTheated + Wear eyerface protection under confinement + To clean the floor and all objects contaminated by this material, use water, + In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons information Centre, + If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label). + This material and its container must be disposed of as hazardous waste Section 3 - COMPOSITION | INFORMATION ON INGREDIENTS. NAME CAS RN % 'sopropano! 67-63.0 NotSpec hydrocarbon propellant 68476-85-7. _NotSpec Section 4 - FIRST AID MEASURES ‘SWALLOWED + Not considered a normal route of entry. + If swallowed do NOT induce vomiting, + If vomiting occurs, lean patient forward or place an left side (head-down position, if possible) to maintain open airway and prevent aspiration, + Observe the patient carefully + Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious, + Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. + Seek medical advice. EYE 2 If this product comes in contact with the eyes + Immediately hold eyelids apart and flush the eye continuously with running water. + Ensure complete irigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by ‘occasionally liting the upper and lower lids, + Continue flushing until advised to stop by the Poisons information Centre or a doctor, or for at least 15 minutes, + Transport to hospital or doctor without delay. + Removal of contact lenses after an eye injury should only be undertaken by skilled personnel SKIN 1 If skin contact occurs: + Immediately remove all contaminated clothing, including footwear. + Flush skin and hair with running water (and soap if available). + Seek medical attention in event of irritation continued,D-100 AEROSOL DEVELOPER Chemwatch independent Material Safety Data Sheet Issue Date: 2-Oct-2012 CHEMWATCH 22-4972 A317LP Version No:3.1.1.1 CD 2012/4 Page 3 of 16 Section 4 - FIRST AID MEASURES INHALED + Iffumes or combustion products are inhaled remove from contaminated area + Lay patient down. 70%. Environmental Fate: IPA is expected to partition primarily to the aquatic compartment (77.7%) with the femainder to the air (22.3%). Overall, IPA presents a low potential hazard to aquatic or terrestrial biota Aqualic Fate’ IPA has been shown to biodegrade rapidly in aerobic, aqueous biodegradation tests and therefore, would not be expected to persist in aquatic nabitats. IPA is expected to volatilize slowly from water. The calculated nalfife for the volatilization from surface water (1 meter depth) is predicted to range from 4 days (‘rom a river) to 31 days (from a lake). Hydrolysis is not considered a significant degradation process {or IPA, however. aerobic biodegradation of IPA has been shown to occur rapidly under non-acclimated conditions. IPA is readily biodegradable in both freshwater and saltwater (72 to 78% biodegradation in 20 days). Terrestrial Fate: Soil - IPA is also not expected to persist in surface soils due to rapid evaporation to the air. IPA will evaporate quickly from soll and is not expected to partition to the soil however; IPA has the Potential to leach through the soil due to its low soil adsorption. Plants - Toxicity of IPA to plants is expected to be low. Atmospheric Fate: IPA is subject to oxidation predominantly by hydroxy radical attack. The atmospheric half- life is expected to be 10 to 25 hours. Direct photolysis is not expected to be an important transformation process for the degradation of IPA. Ecotoxicity: IPA has been shown to have a low order of acute aquatic toxicity and is not acutely toxic to fish and invertebrates, Chronic aquatic toxicity has also been shown to be of low concern and bioconcentration in aquatic organisms is not expected to occur. HYDROCARBON PROPELLANT: = For Petroleum Hydrocarbon Gases: Environmental Fate: Petroleum hydrocarbon gases are primarily produced in petroleum refineries, or in gas plants that separate natural gas and natural gas liquids. This category contains 99 petroleum hydrocarbon gas Substances, the majority of which never reach the consumer. Petroleum hydracarbon gases do not contain inorganic compounds, (e.g. hydrogen sutfide, ammonia, and carbon monoxide), other than asphyxiant gases; the low molecular weight hydrocarbon molecules are primarily responsible for the hazard associated with these gases. ‘Atmospheric Fate: All components of these gases will evaporate to the air where interaction with hydroxyl radicals is an important fate process. Substances in refinery gases that evaporate to air may undergo indirect, gas-phase oxidation reaction with hydroxyl radicals and this is an important fate process for these substances, Halt-lives for refinery gases range from 960 days, (methane), to 0.16 days, (butadiene). The constituents of the C5- C6 hydrocarbon gases have light breakdown half-lives of approximately two days, The inorganic gases are chemically stable and may be lost to the atmosphere or simply become involved in the environmental recycling of their atoms. Terrestrial Fate: Biological breakdown of these organisms is not expected to be an important fate process since they tend to evaporate to the air, however; some of the higher weight components may become available for microbial attack. Naphtha gases are also considered to be inherently biodegradable. Aquatic Fate: The solubilities of these substances in water vary. ranging from approximately 22 parts per continued.D-100 AEROSOL DEVELOPER Chemwatch Indopendent Material Safety Data Sheet Issue Date: 2-Oct-2012 CHEMWATCH 22-4972 AB17LP Version No:3.1.1.1 CD 2012/4 Page 13 of 16 Section 12 - ECOLOGICAL INFORMATION millon to several hundred parts per milion. Some of these gasses have substantial water solubility, but they will eventually evaporate to the atmosphere. Refinery gases are not broken down by water but, they will be broken down by microbes. Gaseous tiydrocarvons are widespread in nature and numerous types of microbes have evolved whic are capable of oxidizing these substances as their sole energy source. Ecotoxicily: These substances vary in their toxicties to aquatic organisms from slightly toxic to moderately toxic. They are not expected to persist long enough in the environment to elicit toxicity. Emissions of petroleum hydrocaroon gases to the atmosphere would not likely result in acutely toxic concentrations in adjacent water bodies because such emissions will tend to remain in the atmosphere. Several of the constituents in refinery gases were shown to be highly hazardous to aquatic organisms in laboratory toxicity tests where exposure concentrations can be maintained over time. Hydrogen sulfide was shown to be the most toxic constituent to fish, and invertebrates. For Isobutene (Refrigerant Gas): Koc: 35, (estimated): Henry's Law Constant: 4.08 atm-cu mimole; Vapor Pressure: 2611 mm Hg @ 25 deg C; CF: 74, (estimated) ‘Atmospheric Fate: Isobutane is a gas at ordinary temperatures. The substance is highly flammable and ‘explosive. It is degraded in the atmosphere by reactions with hydroxy! radicals; the half-life for this reaction in air is 6.9 days. The loss of these substances via wet/dry deposition is thought to be of minor importance. It is thought that the substance will evaporate upon leaving the atmosphere in precipitation then Feemitted to the atmosphere after deposition to the land. Isobutane is a contributor to the production of PAN {peroxyacy| nitrates), under photochemical smog conditions. Terrestrial Fate: Isobutane will have very high mobilty in soil and low adsorption potential. Evaporation ‘rom dry/moist soil surfaces is an important fate process for this substance. Isobutane is biodegradable, especially under acclimated conditions, and may biodegrade in soil. The substance is not expected to contaminate the soil Aquatic Fate. Isobutane is not expected to not adsorb to sedimentiparticulate matter in the water column Isobutane will readily evaporate from water with an estimated half-life of 2.2 hours, for a model river and 3.0 days. If the gas is introduced to water, it wil float and boil, producing a flammable, and visible, \vapor cloud. Isobutane will not concentrate in aquatic organisms and will be broken down by microorganisms in water, however; the substance will not contaminate the water Ecotoxicity: Isobutane has slight acute toxicity to aquatic life, Short-term effects include death of animals, fish, and birds and low growth rate in plants. Long term, (chronic), effects include shortened life-spans, reproductive problems, lowered fertility, and appearancerbehavioral changes in animals For Propane: Koc 460. log Kow 2.36, Henry's Law constant of 7.07x10-1 atm-cu mimole, derived from its vapour pressure, 7150 mm Hg, and water solubility, 62.4 mgiL. Estimated BCF: 13.1 Terrestrial Fate: Propane is expected to have moderate mobility in soil, Volailization from moist soll surfaces is expected to be an important fate process, Volatiization from dry soil surfaces is based vapor pressure. Biodegradation may be an important fate process in soil and sediment Aquatic Fate: Propane is expected to adsorb to suspended solids and sediment, Volatiization from water surfaces is expected and half-lives for a model river and model lake are estimated to be 41 minutes and 2.6 days, respectively. Biodegradation may not be an important fate process in water. Ecotoxicity: The potential for bioconcentration in aquatic organisms is low. Atmospheric Fate: Propane is expected 10 exist solely as a gas in the ambient atmosphere. Gas-phase propane 's degraded in the atmosphere by reaction with photocherically-produced hydroxyl radicals; the half-life for this reaction in airs estimated to be 14 days and is not expected to be susceptible to direct photolysis by sunlight, Ecotoxicity Ingredient Persistence: Persistence: Air Bioaccumulation Mobility WateriSoil isopropanol Low MED Low HIGH hydrocarbon propellant No Data No Data No Data No Data Available Available Available Available continued,D-100 AEROSOL DEVELOPER Chemwatch Independent Material Safety Data Sheet Issue Date: 2-Oct-2012 CHEMWATCH 22-4972 A317LP. Version No:3.1.1.1 CD 2012/4 Page 14 of 16 Section 13 - DISPOSAL CONSIDERATIONS + Consult State Land Waste Management Authority for disposal. + Discharge contents of damaged aerosol cans at an approved site. + Allow small quantities to evaporate +100 NOT incinerate or puncture aerosol cans. + Bury residues and emptied aerosol cans at an approved site. Section 14 - TRANSPORTATION INFORMATION Labels Required: FLAMMABLE GAS HAZCHEM: 2YE (ADG7) ana7: Class or Division 24 Subsidiary Risk None UN No 1950 Packing Group None Special Provision 63 190277 327, Limited Quantity, See SP 277 Portable Tanks & Buk None Portable Tanks & Buk None Containers Containers - Special instruction: Provision: Packagings & IBCs P003 LPo2 Packagings & IBCs PP17 PP87 L2 Packing Instruction: Special Packing Provision: Name and Description: AEROSOLS Land Transport UNDG: Class or division 24 Subsidiary risk None UN No 1950 UN packing group None Shipping Name:AEROSOLS Air Transport IATA: ICAOMATA Class 24 ICAOMATA Subrisk None UNMID Number “1950 Packing Group Special provisions: A145 Shipping name:AEROSOLS Maritime Transport IMDG: IMDG Class 2A IMDG Subrisk P63 UN Number ‘1950 Packing Group None EMS Numbe F-D,S-U Special provisions: 63 190 277 327 344 959 Limited Quantities, See SP277 Shipping name:AEROSOLS continued.D-100 AEROSOL DEVELOPER Chemwatch independent Material Safty Data Sheot CHEMWATCH 22-4972 Version No:3.1.1.1 CD 2012/4 Page 15 of 16 Section 15 - REGULATORY INFORMATION Indications of Dange Fe Extremely flammable Xi Irritant POISONS SCHEDULE None REGULATIONS Regulations for ingredients isopropanol (CAS: 67-63-0) is found on the following regulatory lists; “Atala faaosue StandarsAuaaia Hazardous Suotar ay Ausvala igh Volant Grams! Lot HVICL"“Auarata entry of Chemical ‘Shstanaes (cS). Aum Nora liar verte “eval Gumarie and epacion Serves ao chemea cengexids tse ses cy {or use a esatesnars eps opreneenex ana rested Me purpose ore Exper Cont Ac "862 “SeGANtre vs Compost st ESA Var Bares "10 ic Code Crap 7 Sunvary ot mrimum fequromarts" MISC Cace Capo 2 Lit of rogue ta wah te Cosa Soa at ap °NO MARPOL T276 Anne I) st of Oe Lisa Subaareer’“1MO Provsral Cabepoizabon of Lua Sutsaroas “Lei 2. Pott el res coiaing st least 99% by nog 3 conpenents asi assesea oy IMO’ "eratonal Agency fer Rereten on Canc (AR) Agents Revwed bythe FC Wonotanne Intaraterlopanes Asocaton (FRA) Survey Tanaparony Ut “OECD a igh Mecucion Voine (PY) Chemseal0SPAR Natal at Candas hydrocarbon propellant (CAS: 68476-85-7,68476-86-8) is found on the following regulatory lists; ‘Natal Exoaue tds“ abe Marrs Subsares“Auavoa-4gh Vouneeutal Gerscal (HCL) musa veto of Cre Susans AICS? Auata Wor oa ant Seay Rogers 2011 = Marae Stamens oar aces nthe eae ay rate Counc of Chemea Aasogubons (CON gh Proucion Voume lst "SECO Ust of ah roducen Vou (PV) Gnomeas No data for D-100 Aerosol Developer (CW: 22-4972) Section 16 - OTHER INFORMATION INGREDIENTS WITH MULTIPLE CAS NUMBERS Ingredient Name cas hydrocarbon propellant 68476- 85- 7, 68476- 86-8 «= Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references A\list of reference resources used to assist the committee may be found at vwew. chemwatch.netireferences, = The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or ather settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or citicism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 2-Oct-2012 Print Date: 26-Feb-2013 continued,D-100 AEROSOL DEVELOPER Chemwatch Independent Material Safety Data Sheet Issue Date: 2-Oct-2012 CHEMWATCH 22.4972 AS17LP Version No:3.1.1.1 CD 2012/4 Page 16 of 16 Section 16 - OTHER INFORMATION This is the end of the MSDS.Callin fon BA re CR) eeu ter May-2014 esday years from Date of : hat this material m n QPL-AMS-2644, Results ‘aph 4.3.2, are listed below he require RIPTION fe furt at this material has nV, MIL-l f 1 following results w E1417, MIL-STD- obtained DESCRIPTION e bottom of ak oF labels of bulk c ve been d, tested a Patrick Fernandes Quality Manager Callington Haven Pty Ltd Lael eeeDP-40 DYE PENETRAN i Chemwatch Independent Material Safety Data Sheet Issue Dato: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 1 of 14 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME DP-40 DYE PENETRAN PROPER SHIPPING NAME AEROSOLS PRODUCT USE = Application is by spray atomisation from a hand held aerosol pack. Used in NDT testing as a dye penetrant. ‘SUPPLIER ompany: Callington Haven Pty Lid Company: Callington Haven Pty Lid Address Address PO Box 144 30 South Street Rydalmere Rydalmere NSW, 2116 NSW. 2116 AUS AUS Telephone: +61 2 9898 2788 Emergency Tel: 1800 039 008 (24 hours) Emergency Tel: +61 3.9573 3 Fax: +61 29684 4215 Email: sales@calhaven.com.au Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE NON-HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG ode. CHEMWATCH HAZARD RATINGS Fanneb\y Ase aa = — xiv | AA ALE MinNiI=O —Low=1-—Moderate=2—High=3.-=—«Extreme=4 POISONS SCHEDULE None RISK Risk Codes Risk Phrases RI2 = Extremely flammable Raa + Risk of explosion if heated under confinement R67 = Vapours may cause drowsiness and dizziness SAFETY Safely Codes Safety Phrases si6 = Keep away from sources of ignition. No smokingDP-40 DYé weie RANT Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0, CD 2009/3 Page 2 of 14 Section 2 - HAZARDS IDENTIFICATION = Do not breathe gas/ fumes/ vapour! spray = Avoid contact with skin = Wear eye! face protection. = Use oniy in well ventilated areas, = Keep container in a well ventilated place = Keep container tightly closed. 1 In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre s60 s This material and its container must be disposed of as hazardous waste Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS AME CAS RN % distillates, petroleum, middle, hydrotreated 64742-46-7. NotSpec hydrocarbon propellant 68476-85-7 NotSpec. Section 4 - FIRST AID MEASURES SWALLOWED = - Not considered a normal route of entry - If swallowed do NOT induce vomiting - If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration, - Observe the patient carefully, ~ Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. ~ Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. - Seek medical advice YE 1 If aerosols come in contact with the eyes: - Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water - Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. - Transport to hospital or doctor without delay. - Removal of contact lenses after an eye injury should only be undertaken by skilled personnel SKIN If skin contact occurs: - Immediately remove all contaminated clothing, including footwear. ~ Flush skin and hair with running water (and soap if available) - Seek medical attention in event of irritation, INHALED = If aerosols, fumes or combustion products are inhaled - Remove to fresh air - Lay patient down, Keep warm and rested Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. if breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demang valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary, Transport to hospital, or doctor.DP-4u SYE PENETRANT Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 3 of 14 Section 4 - FIRST AID MEASURES NOTES TO PHYSICIAN = Treat symptomatically For acute or short term repeated exposures to petroleum distilates or related hydrocarbons: ~ Primary threat to life, from pure petroleum distillate ingestion andior inhalation, is respiratory failure - Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (p02 50 mm Ha) should be intubated - Arthythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported: intravenous lines and cardiac monitors should be established in ‘obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax. - Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the ‘eferred agents, with aminophylline a second choice. - Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology] Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA = SMALL FIRE: - Water spray, dry chemical or CO2 LARGE FIRE: Water spray or fog, FIRE FIGHTING = - Alert Fire Brigade and tell them location and nature of hazard - May be violently or explosively reactive - Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. If safe, switch off electrical equipment until vapour fire hazard removed. - Use water delivered as a fine spray to control fire and cool adjacent area - DO NOT approach containers suspected to be hot. - Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. - Equipment should be thoroughly decontaminated after use ‘When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 100.” metres in all directions. FIREJEXPLOSION HAZARD = - Liquid and vapour are highly flammable Severe fire hazard when exposed to heat or flame. - Vapour forms an explosive mixture with air ~ Severe explosion hazard, in the form of vapour, when exposed to flame or spark. \Vapour may travel a considerable distance to source of ignition. ~ Heating may cause expansion or decomposition with violent container rupture - Aerosol cans may explode on exposure to naked flames. Rupturing containers may rocket and scatter burning materials. Hazards may not be restricted to pressure effects. - May emit acrid, poisonous or corrosive fumes. On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon dioxide (C02), other pyrolysis products typical of buming organic materialDP-40 DYE PENETRAN : Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22.4973, NC317ECP Version No:2.0 CD 2009/3 Page 4 of 14 Section 5 - FIRE FIGHTING MEASURES FIRE INCOMPATIBILITY ‘= - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, poo! chlorine etc. as ignition may result HAZCHEM: 2YE Personal Protective Equipment Gas tight chemical resistant sui Section 6 - ACCIDENTAL RELEASE MEASURES. MINOR SPILLS = - Clean up all spills immediately. void breathing vapours and contact with skin and eyes. - Wear protective clothing, impervious gloves and safety glasses, - Shut off all possible sources of ignition and increase ventilation. - Wipe up. - If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated = Undamaged cans should be gathered and stowed safely. MAJOR SPILLS = - Clear area of personnel and move upwind. - Alert Fire Brigade and tell them location and nature of hazard, - May be violently or explosively reactive - Wear breathing apparatus plus protective gloves. ~ Prevent, by any means available, spillage from entering drains or water courses = No smoking, naked lights or ignition sources. - Increase ventilation - Stop leak if sate to do so - Water spray or fog may be used to disperse / absorb vapour. - Absorb or cover spill with sand, earth, inert materials or vermiculite If safe, damaged cans should be placed in a container outdoors, away from ignition sources, until pressure nas dissipated - Undamaged cans should be gathered and stowed safely. ‘ollect residues and seal in labelled drums for disposal Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING = - Avoid all personal contact, including inhalation ~ Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. - Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked Avoid smoking, naked lights or ignition sources, - Avoid contact with incompatible materials - When handling, DO NOT eat, drink or smoke. - DO NOT incinerate or puncture aerosol cans DO NOT spray directly on humans, exposed food or food utensils. ~ Avoid physical damage to containers - Always wash hands with soap and water after handlingGP-40 DYE PENETRANT ‘Chemwatch independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 5 of 14 ‘Section 7 - HANDLING AND STORAGE - Work clothes should be laundered separately, Use good occupational work practice - Observe manufacturer's storing and handling recommendations. - Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained SUITABLE CONTAINER = - Aerosol dispenser heck that containers are clearly labelled STORAGE INCOMPATIBILITY = - Avoid reaction with oxidising agents STORAGE REQUIREMENTS 1 - Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure Jay eject contents of can - Store in original containers in approved flammable liquid storage area -D0 NOT store in pits, depressions, basements or areas where vapours may be trapped ~ No smoking, naked lights, heat or ignition sources. - Keep containers securely sealed. Contents under pressure. - Store away from incompatible materials - Store in a cool, dry, well ventilated area. Avoid storage at temperatures higher than 40 deg C. - Store in an upright position - Protect containers against physical damage. - Check regulary for spills and leaks. - Observe manufacturers storing and handling recommendations. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS. Source Material TWA ppm TWAmgm? Australia Exposure Standards distilates, petroleum, middle, 5 hydrotreated (Oil mist, refined mineral) Australia Exposure Standards distilates, petroleum, middle, 5 hydrotreated (Oil mist, refined mineral) Australia Exposure Standards hydrocarbon propellant (LPG 1000 1800 (liquified petroleum gas)) EMERGENCY EXPOSURE LIMITS Material Revised IDLH Value (mgim3) Revised IDLH Value (ppm) hydrocarbon propellant 2, 000 [LEL] NOTES Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit for safety considerations even though the relevant toxicological data indicated that irreversible health effects or impairment of escape existed only at higher concentrations ODOUR SAFETY FACTOR (OSF) OSF=0.16 (hydrocarbon propellant) = Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded.DP-40 DYE PENETRANT ‘Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22.4973, NC317ECP Version No:2.0 CD 2009/3 Page 6 of 14 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Odour Safety Factor (OSF) is determined to fall into either Class C. 0 or E. The Odour Safety Factor (OSF) is defined as: OSF= Exposure Standard (TWA) ppm! Odour Threshold Value (OTV) ppm Classification into classes follows: Class OsF Description A 550 Over 90% of exposed individuals are aware by smell that the Exposure Standard (TLV- TWA for example) is being reached, even when distracted by working activities 8 26-550 As" A" for 50- 90% of persons being distracted 1-26 As "A" for less than 50% of persons being distracted b 0.181 10- 50% of persons aware of being tested perceive by smell that the Exposure Standard is being reached E <0.18 As" D" for less than 10% of persons aware of being tested MATERIAL DATA DP-40 DYE PENETRANT: = None assigned. Refer to individual constituents, DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED: = Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for these irritants have been based on observation of ‘workers’ responses to various airbome concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effect- vvels (NOEL) are used to determine these limits where human results are unavailable. An additional approach \ypically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, hhas been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on intensive odour, local iritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA OSHA (USA) concluded that exposure to sensory iritants can ‘cause inflammation cause increased susceptibility to other irritants and infectious agents lead to permanent injury or dysfunction permit greater absorption of hazardous substances and acclimate the worker to the irritant waming properties of these substances thus increasing the risk of overexposure Toxicity and Irritation data for petroleum-based mineral oils are related to chemical components and vary ‘as does the composition and source of the original crude. A small but definite risk of occupational skin cancer occurs in workers exposed to persistent skin contamination by oils over a period of years. This risk has been attributed to the presence of certain polycyclic aromatic hydrocarbons (PAH) (typified by oenz[alpyrene) Petroleum oils which are solvent refined/extracted or severely hydrotreated, contain very low concentrations of both Human exposure to oil mist alone has not been demonstrated to cause health effects except at levels above 5 mgim3 (this applies to particulates sampled by a methad that does not collect vapour). Itis not advisable to apply this standard to oils containing unknown concentrations and types of additiveDP-40 Gr = “ENETRANT Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 7 of 14 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTION EYE = No special equipment for minor exposure i.e. when handling small quantities, DTHERWISE: For potentially moderate or heavy exposures: -_ Safety glasses with side shields. - NOTE: Contact lenses pose a special hazard; soft lenses may absorb iritants and ALL lenses concentrate them. HANDS/FEET = - No special equipment needed when handling small quantities, OTHERWISE: - _ For potentially moderate exposures: Wear general protective gloves, eg. light weight rubber gloves For potentially heavy exposures: - Wear chemical protective gloves, eg. PVC. and safety footwear. OTHER = No special equipment needed when handling small quantities. OTHERWISE - Overalls. - Skin cleansing cream yewash unit Do not spray on hot surfaces. RESPIRATOR = Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important. Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator ppm (volume) Factor 1000 10 AX- AUS P 1000 50 AX- AUS P 5000 50 Aline * 5000 100 AX-2P. 10000 100 AX-3P 100+ Airline * Continuous Flow **- Continuous-flow or positive pressure demand. The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required, For further information consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor. ENGINEERING CONTROLS = General exhaust is adequate under normal conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fits essential to obtain adequate protectionbP.4d DYE PENETRANT Chemwatch independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973, NC317ECP Version No:2.0 CD 2008/3 Pago 8 of 14 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Provide adequate ventilation in warehouse or closed storage areas. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable hydrocarbon propellant. Red liquid with 3 typical petroleum spirit odour; does not mix with water. PHYSICAL PROPERTIES Liquid, as oes not mix with water. Molecular Weight: Not Boiling Range (€): Not available Mel ting Range (‘C): Not applicable available. Specific Gravity (water=1): Not ‘Solubility in water (g/L) pH (as supplied): Not available immiscible applicable pH (1% solution): Not Vapour Pressure (kPa): 345 @ 21C Volatile Component (%vol): Not applicable. available Evaporation Rate: Not available Relative Vapour Density (air=1) Flash Point (0): Not Not available. Available Lower Explosive Limit (%): 1.8 Upper Explosive Limit (%): 9.5 Autoignition Temp (C): 460 approx Decomposition Temp (C): Not State: Liquid Viscosity: Not A vailable Available Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY = - Presence of incompatible materials, - Product is considered stable. - Hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED ‘= Not normally a hazard due to physical form of product. Ingestion may result in nausea, pain, voriting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis. EYE = There is some evidence to suggest that this material can cause eye irritation and damage in some persons.ve 40 DYE PENETRANT ‘Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 9 of 14 Section 11 - TOXICOLOGICAL INFORMATION SKIN = Skin contact with the material may damage the health of the individual; systemic effects may result following absorption There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons. The material may accentuate any pre-existing skin condition INHALED 1 Inhalation of high concentrations of gas/vapour causes lung imitation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination WARNING: Intentional misuse by concentrating/inhaling contents may be lethal CHRONIC HEALTH EFFECTS = Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS] JARNING: Aerosol containers may present pressure relates hazards. TOXICITY AND IRRITATION = Not available CARCINOGEN Petroleum solvents International Agency Group 3 for Research on Cancer (IARC) Carcinogens Section 12 - ECOLOGICAL INFORMATION Refer to data for ingredients, which follows: DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED: HYDROCARBON PROPELLANT: For hydrocarbons: Environmental fate: The lower molecular weight hydrocarbons are expected to form a “slick” on the surface of waters after release in calm sea conditions. This is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals. Some hydrocarbon will become associated with benthic sediments, and itis likely to be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or anaerobic. The material, in probability, is biodegradable, under aerobic conditions (isomerised olefins and alkenes show variable results). Evidence also suggests that the hydrocarbons may be degradable under anaerobic conditions although such degradation in benthic sediments may be a relatively slow process. Under aerobic conditions hydrocarbons degrade to water and carbon dioxide, while under anaerobic processes they produce water, methane and carbon dioxide. Alkenes have low log octanoliwater partition coefficients (kow) of about 1 and estimated bioconcentration factors (BCF) of about 10; aromatics have intermediate values (log Kow values of 2-3 and BCF values of 20 200), while C5 and greater alkanes have fairly high values (log Kow values of about 3-4.5 and BCF values of 100-1,500 The estimated volatilisation half-lives for alkanes and benzene, toluene, ethylbenzene, xylene (8TEX) components were predicted as 7 days in ponds, 1.5 days in rivers, and 6 days in lakes. The volatiisation rate of naphthalene and its substituted derivatives were estimated to be slower Indigenous microbes found in many natural settings (e.g., soils, groundwater, ponds) have been shown to be capable of degrading organic compounds. Unlike other fate processes that disperse contaminants in the environment, biodegradation can eliminate the contaminants without transferring them across media The final products of microbial degradation are carbon dioxide, water, and microbial biomass. The rate of hyarocarbon degradation depends on the chemical composition of the product released to the environment as well as site-specific environmental factors. Generally the straight chain hydrocarbons and the aromatics areDP-40 DYE PENETRANT Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 10 of 14 Section 12 - ECOLOGICAL INFORMATION degraded more readily than the highly branched aliphatic compounds. The n-alkanes, n-alkyl aromatics, and the aromatics in the C10-C22 range are the most readily biodegradable; n-alkanes, n-alkyl aromatics, and aromatics in the C5-C9 range are biodegradable at low concentrations by some microorganisms, but are generally preferentially removed by volatlisation and thus are unavailable in most environments, n-alkanes in the C1-C4 ranges are biodegradable only by a narrow range of specialised hydrocarbon degraders; and n. alkanes, n-alkyl aromatics, and aromatics above C22 are generally not available to degrading microorganisms Hydrocarbons with condensed ring structures, such as PAHs with four or more rings. have been shown to be relatively resistant to biodegradation. PAHs with only 2 or 3 rings (@.g., naphthalene, anthracene) are more easily biodegraded. In almost all cases, the presence of oxygen is essential for effective biodegradation of oll, The ideal pH range to promote biodegradation is close to neutral (6-8). For most species, the optimal pH is slightly alkaline, that is, greater than 7. All biological transformations are affected by temperature. Generally, as the temperature increases, biological activity tends to increase up to a temperature where enzyme denaturation occurs. Atmospheric fate: Alkanes, isoalkanes, and cycloalkanes have haif-ives on the order of 1-10 days, whereas alkenes, cycloalkenes, and substituted benzenes have half-lives of 1 day or less. Photochemical oxidation “oducts include aldehydes, hydroxy compounds, nitro compounds, and peroxyacy! nitrates. Alkenes, certain substituted aromatics, and naphthalene are potentially susceptible to direct photolysis. Ecotoxicity Based on test results, as well as theoretical considerations, the potential for bioaccumulation may be high. Toxic effects are often observed in species such as blue mussel, daphnia, freshwater green algae, marine copepods and amphipods. Tne values of log Kow for individual hydrocarbons increase with increasing carbon number within homologous series of generic types. Quantitative structure activity relationships (QSAR), relating log Kow values of single hydrocarbons to toxicity, show that water solubility decreases more rapidly with increasing Kow than does the concentration causing effects, This relationship varies somewhat with species of hydrocarbon, but it follows that there is a log Kow limit for hydrocarbons, above which, they will not exhibit acute toxicity this limit is at a log Kow value of about 4 to 5. it has been confirmed experimentally that for fish and invertebrates, paraffinic hydrocarbons with a carbon number of 10 or higher (log Kow >5) show no acute toxicity and that alkylbenzenes with a carbon number of 14 or greater (log Kow >5) similarly show no acute toxicity. QSAR equations for chronic toxicity also suggest that there should be a point where hydrocarbons with high log Kow values become so insoluble in water that they will not cause chronic toxicity, that is, that there is also a solubility cut-off for chronic toxicity. Thus, paraffinic hydrocarbons with carbon numbers of greater than 14 (log Kow >7.3) should show no measurable chronic toxicity ‘ISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED: HYDROCARBON PROPELLANT: = Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.) OP-40 DYE PENETRANT: HYDROCARBON PROPELLANT: DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED. = DO NOT discharge into sewer or waterways. DP-40 DYE PENETRANT: DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED = for gas oils and distillate fuels: The gas olls category includes both finished products (distilate fuels) and the refinery streams (gas oils) from which they are blended. The materials in this category, together with those in the Jet Fuel/Kerosene category, constitute a generic class of petroleum substances commonly known as middle distillates, The distilate fuels covered in this category are used in diesel engines and for both industrial and domestic heating. While within the refinery the gas oil streams exist primarily as intermediates in closed systems. Selected gas oil streams may ultimately be blended into distillate fuels, marine bunker fuels and occasionally into lubricants. At ambient temperatures, all the substances in this category are liquids. Gas oll streams and distillate fuels are complex petroleum mixtures, composed primarily of saturated (paraffinic and naphthenic) or aromatic hydrocarbons with carbon numbers ranging from C9 to C30. Gas Oils are similar from both a process and physical-chemical perspective, being differentiated from each other primarily by their aromatic and saturated hydrocarbon content. The compositions of the gas oil streams range from those that are predominantly saturated hydrocarbons to those that are predominantly aromaticQ DP.43 DYE PENETRANT ‘Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Pago 11 of 14 Section 12 - ECOLOGICAL INFORMATION hydrocarbons. Consequently, the category can be considered a continuum, bounded by materials that are compositionally either high in saturated hydrocarbons or aromatic hydrocarbons. While the ratio of the saturated and aromatic hydrocarbons may vary between category members the saturated and aromatic hydrocarbons species that make up the category members are similar. Based on the available data, the physical-chemical properties of an individual category member depend on its compositional makeup, vis a vis saturated and aromatic hydrocarbons, Therefore, gas oil streams that are predominantly saturated hydrocarbons will have similar physical-chemical properties, while those that are composed predominantly of aromatic hydrocarbons will have Somewhat diferent properties. As products that are blended from the gas oil streams, the compositions of the distillate fuels fall within the range of the compositions shown by the gas oil streams and reflect the characteristics of the gas oils streams from which they are blended. Boiling Poin Gas oils do not have a single numerical value for boiling point, but rather a boiling or distillation range that reflects the individual components in the hydrocarbon mixture. Distillation ranges for a variety of gas oils have been reported for a number of blended gas oil products and individual production streams . Typical distillation ranges for blended fuels are 160 to 390 C for an automotive gas oil (diesel fuel), 160 to 400 C for a heating oil, and 170 to 420 C for a distillate marine fuel Typical low end rd high end distillation temperatures for gas oil production streams were 172 and 344 C for a nydrodesulfurised middle distillate (65.6% -79.4% saturated hydrocarbons), 185 and 391 C for a straight-run middle distillate (78,8 saturated hydrocarbons), and 185 and 372C for a light catalytic cracked distillate (60.8% -79.8% aromatic hydrocarbons). No substantial differences in boiling range were apparent for gas oils, with high concentrations of either aromatic or saturated hydrocarbons \Vapor Pressure : For mixtures such as petroleum products, the vapor pressure of the mixture is the sum of the partial pressures of the individual components (Dalton’s Law of Partial Pressures). Gas oils are expected to have low vapor pressure due to their boiling range (150 to 450 C) and molecular weights of the constituent hydrocarbons (C9 ~ 30 carbon atoms). Because the physical-chemical characteristics of distilate fuels, reflect the gas oil streams from which they were produced, these vapor pressure measurements are expected to approximate the vapor pressures of individual gas oils. Vapour pressure estimates of low molecular weight hydrocarbons of varying isomeric structures fell within a range of 0.01-1.6 kPa, with higher molecular weight hydrocarbons showing very low vapour pressures (@.g., 10-8 to 10-10 kPa). Partition Coefficient The percent distribution of the hydrocarbon groups (i... paraffins, olefins. naphthenes, and aromatics) and the carbon chain lengths of hydrocarbon constituents in gas cils largely determines the partitioning characteristics of the mixture. Generally, hydrocarbon chains with fewer carbon atoms tend to have lower partition coefficients than those with higher carbon numbers. Because gas complex mixtures, it is not possible to determine their log Kow values. Rather, partition coefficients have been calculated for individual component hydrocarbons from known hydrocarbon composition. Those calculated ‘ow values ranged from 3.9 to >6.0 for a hydrodesulfurised middle distillate ((65.6% -79.4% saturated nydrocarbons), straight-run middle distillate (78.8% saturated hydrocarbons), and a light cat-cracked distillate (60.8% -79.8% aromatic hydrocarbons). There are no apparent differences in the range of Kow values determined for gas oils with high concentrations of either aromatic or saturated hydrocarbons. A similar range of partition coefficients would be expected for component hydrocarbons in distillate fuels Environmental fate Photodegradation : The direct aqueous photolysis of an organic molecule occurs when it absorbs sufficient light energy to result in a structural transformation. Only light energy at wavelengths between 290 and 750 nm can result in photochemical transformations in the environment, although absorption is not always sufficient for a chemical to undergo photochemical degradation. Saturated and one-ring aromatic hydrocarbons do not show absorbance in the 290 to 800 nm range and would not be expected to be directly photodegraded. Polyaromatic hydrocarbons, on the other hand. have shown absorbance of the 290 to 800 nm range of light energy and could potentially undergo photolysis reactions. The degree and rate at which these compounds photodegrade depends upon whether conditions allow penetration of light with sufficient energy to effect a change Components in gas oils that do not directly photodegrade (e.g., paraffins, naphthenes, and one-ring aromatic compounds) may be subject to indirect photodegradation. Indirect photodegradation is the reaction with photosensitised oxygen in the atmosphere in the form of hydroxyl radicals (OH ). ‘Atmospheric oxidation rates and half-lives were calculated for the low and high end of the range of molecular weight constituents of gas oils (e.g., C9 and 30 hydrocarbon structures). Half-life estimates for these compounds ranged from 0.1 (for various C9 to C30 olefinic structures and C30 2+ring aromatic compounds) to 1.5 days (for a C9 one-ring aromatic structure). Based on the calculated halt-life values calculated substantial differences in indirect photodegradation potential is expected between gas oils with high concentrations of either aromatic or saturated hydrocarbons. A similar range of water solubility values would be expected for component hydrocarbons in distillate fuelsDP-40 DYE PENETRANT Chemwatch Independent Material Safety Data Sheet Issue Date: §-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 12 of 14 Section 12 - ECOLOGICAL INFORMATION Water Solubility : When released to water, gas oils will float and spread at a rate that is viscosity- dependent. Component hydrocarbons in gas cils will partition to water according to their individual solubility values. For individual hydrocarbon constituents in gas oils, water solubility values vary by orders of magnitude. Molecular weight and chemical structure have a great influence on the ultimate degree of solubility. Calculated water solubility ranged from essentially insoluble (approximately 10-8 mg/L) for the higher molecular weight fractions (e.g., C30) within gas oil to approximately 52 mgil. for a C9 alkylbenzene, Hydrolysis The materials in the gas oils category do not contain chemical moieties that undergo hydrolysis. Transport and Distribution in the Environment (Fugacity) Models have been used to estimate the percent distribution in environmental media (.e.. air, water, soil, sediment, and fish) of various C9 to C30 compounds representing the different classes of hydrocarbons found in gas oils (e.g.. paraffins, olefins, naphthenes, and aromatics). Hydrocarbons having nine carbon atoms showed a tendency to partition to air (up to 98%). As molecular weight increases, partitioning shifts to soil, which accounts for 98% of the distribution of the C30 components. This trend was similar for saturate and aromatic structures alike. Therefore, gas oils with high concentrations of either aromatic or saturated hydrocarbons are expected to partition in the environment in a similar manner iodegradation : Much of what is known is based on information gained from testing hydrocarbon mixtures of other petroleum products. Under standard biodegradability tests, hydrocarbon compounds representative of those found in gas oils typically do not pass ready biodegradability test conditions. Although those compounds are not recognized as being reacily biodegradable, most hydrocarbon species present in gas oils are known to be ultimately degraded by aerobic microorganisms. lower molecular weight compounds may be expected to be degraded relatively quickly in aerobic conditions, while higher molecular weight compounds, Particularly polycyclic aromatics, will degrade slower. Much of this evidence is based on bioremediation studies of contaminated soils, which have shown that hydrocarbon components in gas oils are degraded in the presence of oxygen. Bioremediation of a diesel fuel spill has also been demonstrated under Arctic conditions Under anaerobic conditions, such as anoxic sediments, rates of biodegradation of gas oils components are negligible and the gas oils may persist under those conditions for some time. Degradation then will be dependent on bioturbation or resuspension to provide microbes with access to oxygen. Ecotoxicity: Muttipie ecotoxicological studies on heating and transportation fuels (e.g., no. 2 fuel oil and diesel fuel) have been conducted. in general, these commercial distillate fuels show moderate toxicity to aquatic life. LC50 values for fish ranged from 3.2 to 65 mg/L... while EC5O values for invertebrates ranged from 2.0 to 210 mail. HYDROCARBON PROPELLANT: ‘arine Pollutant Not Determined Ecotoxicity Ingredient Persistence’ Persistence: Air Bioaccumulation Mobility Water/Soil DP- 40 Dye No data Penetrant distilates, No data petroleum, middle, hydrotreated hydrocarbon No data propellant Section 13 - DISPOSAL CONSIDERATIONS Consult State Land Waste Management Authority for disposal - Discharge contents of damaged aerosol cans at an approved site Allow small quantities to evaporate - DO NOT incinerate or puncture aerosol cans. Bury residues and emptied aerosol cans at an approved site.a DP-40 DYE PEWETRANT Chemwatch Independent Material Safety Data Sheet Issue Date: 5-Nov-2009 CHEMWATCH 22-4973 NC317ECP Version No:2.0 CD 2009/3 Page 13 of 14 Section 14 - TRANSPORTATION INFORMATION Labels Required: FLAMMABLE GAS. HAZCHEM: 2YE (ADG7) ApG7: Class or division 2 Subsidiary risk: None N No 1950 UN packing group: None Special provisions: 63, 190, 27, 327 Packing Instructions: None Notes: None Limited quantities: See SP 277 Portable tanks and bulk None Portable tanks and bulk None containers, containers - Special Instructions provisions: Packagings and IBCs- _P003, LPO2 Packagings and IBCs- -PP17, PP87, L2. Packing instruction Special packing provisions: Shipping Name:AEROSOLS Land Transport UNDG: Class or division 2 Subsidiary risk None UN No. 1950 UN packing group None Shipping Name:AEROSOLS Maritime Transport IMDG: IMDG Class: 24 IMDG Subrisk SP63 UN Number: 1950 Packing Group: None MS Number: F-D,S-U Special provisions 63 190 277 327 959 Limited Quantities See SP277 Shipping Name: AEROSOLS. Section 15 - REGULATORY INFORMATION POISONS SCHEDULE: None REGULATIONS distillates, petroleum, middle, hydrotreated (CAS: 64742-46-7) is found on the following 20 asain igh Vaure SEC Represertatal ist of eh hydrocarbon propellant (CAS: 68476-85-7,68476-86-8) is found on the following regulatory lists; Asa xaasre Standards” Australia Mazardous Svostaces”"Ausvala Higa Vume ndutial Chemis it HVICLY" "OECD Repogontatve Lot ghDP-40 UE PENETRANT Chemwatch Independent Material Safety Data Sheet Issue Date: §-Nov-2009 CHEMWATCH 22.4973, NC317ECP Version No:2.0 CD 2009/3 Page 14 of 14 Section 15 - REGULATORY INFORMATION No data for DP-40 Dye Penetrant (CW: 22-4973) Section 16 - OTHER INFORMATION INGREDIENTS WITH MULTIPLE CAS NUMBERS, Ingredient Name CAS hydrocarbon propellant 68476- 85-7, 68476- 86-8 1 Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references A list of reference resources used to assist the committee may be found at www.chemwatch netireferences. = The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or enticism, as permitted under the Copyright Act, no part may be reproduced by any process without vntten permission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 5-Nov-2009 Print Date: 5-Nov-2009 This is the end of the MSDS.CANTESCO CORPORATION WELDING PRODUCTS DIVISION ;AUGA, ONTARIO “BUFFALO, NEW YORK EMAL SAI CERTIFICADO DE ANALISIS - LIMPIADOR PENETRANTE NUMERO DE LOTE: 20120764 CERTIFICACION: Los resultados mencionados en lineas posteriores se han basado en los requerimientos de la Sociedad Americana de Ingenieros Mecanicos 2007 en la Seccién V, Articulo 6 Seccién T-641 ESPECIFICACIONES: PRUEBA hi | Fluoruro mig |, Ne-epiicabie Cloruro mig ‘ASTN D-808/D-512 | No apiicable legen Ye por peso [ASME L640 | ‘0.002 FECHA DE CADUCIDAD: El tiempo de duracién es de dos aflos desde la fecha de fabricacion. EI Numero de lote se lee de la siguiente forma (ANO/MESIDIA) y se encuentra impreso en la parte superior del frasco. COMPOSICION: No contiene jo siguiente como quimicos constituyentes principales: Aluminio, magnesio, arsénico, zinc, cobre, plomo, mercuro, cadmio. estat, antimonio, fosforo, bismuto, azufre, cloruro o flucrur. PROCEDENCIA: Este producto ha sido febricado en USA. Para soiiciter los certficados NAFTA, escriba a info@canteseo.com anleseo Corporations encuentra on 'SOH001 2000 corre compat repstade. AVISO: £1 modo de uso y as condiciones del producto se encuentra mas allé col control de CANTESCO CORPORATION. La garantia de os productos se encuantra limitade a los ‘esutados del rencimiento del pradcto como se datala ene certficado de calidad Lo nteroretacion de los resuitacos de prueba sor de respansabildad del usuario final. No existe otra garantia expresa o implicit [LEAK DETECTION COMPOUNDS - GAS LEAK DETEGTORS -ZINC RICH SPRAY GALVS [OYE PENETRANT INSPECTION - ANTLSPATTERS - NOZZLE TP OVP WIRE LUBE PADS ‘COOLING FLUIDS - STAINLESS STEEL PICKLING PASTE - ALUMINUM CLEANER CANTESCO CORPORATION 2000CANTESCO CORPORATION {EL FANG PRODLTS OVISION SERRE Ga Bara nas vom are BACB CERTIFICADO DE ANALISIS - LOTE 20120354 spur 10 CCANTESCO PENETRANTE -REVELADCR D101 -NO ACUOSO er ae 251 D0" a Un reveladoe 9 acucs9 oulvaizante Loa tvolacoroe (DIONG y D10186 26 can on un solver Sorina Tods. Iso dnansenes eumpen con aquermientat co contri det sono y halégene cea socciin 5 dea Sop" Amercane de Ingerieros Mirco. er ove ovelacer Danco suspendido er ir base solverte Los les) os Se musetan an el andl 9 "1 para! D101-A nv 442.000 STM O-1200815 (8) maa 9.510 *STMO-1200816 8) meg 252,090 ASTMD-1200816/8) | “shn3030%0 er pose 0 | sere Paar! / erpiaarss en el formato cise le on aias eM ‘eODiGe ARO ea es ow +0370 ‘lata sot 0378 . laws i 1d $1030 a_i} JaDr Os Sh Seyi sy scHstud la HOJA DE DATOS . = SEGURIDAD u JEL DUCTO se oreuerta dape) — Pararociby "as deal, srvase excntwmos * gence vs ‘eelmads del DICTA Anrose 104 Revelador >A RANA: coc @eomo usar las peeks inspection sla conrleta fe orady —olestenuesto Para mayer informe an seeartescacamPare copia dees métode: prt ASTH ara PENETRANTE -PIOIS Et) DOR SOLVENTE Lo Sun tos na clonades umple 2 Jos roueimntos ela Soccen V ae a Seetedae America se Ingerierce Penetanis basado en un slvenie dah cs po stbone ‘res epcosenia “is pico para PACUE sto Prov Pro P10 Pros Ars rato sex ur 9 1D. ARISTA Con 112.000 0.530 238 000 gona + peso 0 on o foxmata asp copie so0z0 10325, 1030p 10335 __¢ vas) HOUADE DATOS 9 enoventa der ory isda BDIS.A AT 8 coro usar ee products pa de ues ‘slow mala de produ eo eee TM 2.290516 12) ASIN D.8080-7:79 6) NM D.an854 eres ‘NO CANTIDAD | POR Ch Sy per pal EGURIOAD saree s@earescs Supe Paos NETRANTE ro! de usodole malades: sda ASTHL sora wtenas* Je chrurey nelegon’ autre fuoure Eb seas vemte oma (AND DUA) 30 2 ylas eoncicion oe! 2100s $e encuentra ms ak det contro 8 ORATION. L +e = productos se ‘alimtada a los nto el pro 25 ‘allaen el ceri 9's -caidac La sutades ev ponsabiidad co ano final. No ‘esa o imp ¢ COMPOUNDS. "AK DFTECTORS -ZINGRIC' “AY GALVS NSPECTION. /ATTERS- NOZZLETIPOP LUBE PADS: S- STAINLESS ich”) PASTE. ALUMY AMER. c 0G) ORATION 200‘CANTESCO CORPORATION WELDING PRODUCTS DIVISION INISSISGAUGA, ONTARIO™ BUFFALO, NEW YORK -aNTWER” BE. EMAL SALES@CANTES (PRODUCTO:Pio1s IPAGINATDET CERTIFICADO DE ANALISIS - LOTE 20120765 PRODUCTO. CANTESCO PENETRANTE -P101S REMOVEDOR SOLVENTE APLICAGION! Los sclventes no Cosinados cumplen con tos requeriienios «te a Secon V de te Socisdad Amarcana de Ingeriercs composicion. PPenetvan‘e tasado en un sovente de Naracarbono Los resucados posterior recresenta el andlisistpico para 2 P0153 Azule mga © 112.000 ASTM 0-1281D816 (8) Fuoro maig 9.830 ASTM 0-8080.1179 (a) ‘Coruro meg 258.000 ASTM O-808/0512 Tala % nalogeno por pes0 0, 935000 ASME T-681 EMPAQUE Liste pora omplaarae ene! frmaio dgponiale on lates aise Trew GODIGO __TAMARO CANTIDAD it POR CAJA Tatas de Protss 10023 16onz 2iaes lata de ProtsiG 10325 galon ota pailade Sgal er pala 1 basen HOJA DE DATOS DE ‘Sogur su salictud la HOA DE DATOS DE SEGURIDAD SEGURIDAD DEL PRODUCTO se encuentra dsponila Para recibir una copia de lo. stvase eecttimos a: mads@cantesco ‘com y soc el msds del PIOTS-A AEROSOL y/o P10! PENETRANTE CALIDAD YGARANTIA ——_ Con respecto& coma user los reducing - PENETRANTE CANTESCO spice una cop de nuestro manual de uso, ‘S desea una sta completa de productos, ealcte nusstro _atdloge Para mayor intermacién vate wivn.cantesco.comPra rec una copia de los malodas de prusba ASTI pera os cortondos do corre y halogenee (azutre,ioruro Yoleruro) we wasw 2s a Elote sa lee de 1s sgviene ‘rma (ANOMES®OIA) ¥ se enevertra moreso en ia pate superior dol AVISO: E| mode de use y las condiciones cel predusto se encuentra més alla del conti de CANTESCO CORPORATION, La garantia de los productos se encuentra limitada a ios ‘esultados del rendimiento del producto como se details en ol catiicado de calicad La interpretacion de los resultados de prueba son de responsabilidad del usuario final No CANTESCO CORPORATION 2000L | cernnica | | GUENTE/ CusTOMER eTERIL/ ATER [eames 2: (434) 935 863 629 fax: (+35) 935 917 234 et oar CONTROL DECALIDAD ret ‘Site ae QUALITY CONTROL a ANAL HAL CERTICAT FeoHN oars 6-50 coos ‘coor - 280714 carmoxoauwmry 74.000 Kg ]tuemaia sawn | RESULIADOOE A muESTRA METODD AMMUSIS| SOREN Size ate resrmesur rest eras 160 4497POMETON ESPANA, S.A. Pometan Dy. Begs, sn - E091 ROUT el: (+34) 935 863 629 fax: (434) 936 917 234 infogpometon.net “CONTROL DE CALIDAD QUALITY CONTROL CERTIFICADO ANALISIS (ANALYSIS CERTIFICATE 20/11/2014 GRANALLA HCS $280 copco/ cone 290914 cANTIOAD/ QUANTITY §— 24,000 Kg LUZ ALLA en nvm RESULTADODE LA MUESTRA FOL ANALISIS seRcen zt nm rear ness | reerwenicos FSPEciricacion | MUESTRASAMPLE | ANALSIS >4re0 | (0% 0 | ca GRANULOM 1,000 30% Max | 28.3 ISO 11125-2 | 20710 =| 90% Min 1UTION > 0,600 97 % Min 100.0 | GRAN SITE UREA Max | [ in | | 3so 11128-3 | | ; OK | HEHE ANALISIS OK | LECO pe ie NL-AROL | OK teanoa « < Faia LECO [| ae coe [| | CORRECTO / PASSED ERED MARTENSITE MARTENSITA REVENIDA / TEM!