B>C. In reverse-phase chromatography the order,of elution will be A>Boc (2) C>B>a (8) B>oc>a SA B>A>c (312) 3 PTO)13P/206/4 14. Which statement(s) are true? (A) Cation-exchange resins have primary amine groups (B) Cation-exchange resins have sulfonic acid groups (C) Anion-exchange resins have tertiary amine groups at {D) Anion-exchange resins have carboxylic acid groups wis we Answer codes (1) (A) and (D) (2) (B) and (C) (3) (A) and (C) (4) B) and (C) ——_— 15. Which statement is correct? } Aon-exchange and ion-exclusion chromatography are same techniques ) Ion-exchange and ion-chromatography are same techniques (3) Adsorption and partition chromatography as same techniques (4) Ion-paired and ion-exclusion chromatography are same techniques 16, Identify the structure of oxine OH 0 CD CKD OH @ (of9) ‘“ y OH NH, 1H 17. Oxigie forms complexes with metal ions in he dcprotonated state (2) protonated state (3) neutral state (4} zwitterionic state (312) 41a, 19, 21. 22. (312) 13P/206/4 One mole of potassitim bromate in bromate-bromide reaction produces (1) one mole Bry (2) two moles Brz US three moles Bry (4) four moles Br, Which one is redox indicator? (Qj Methyl red (2) Fluorescein 199 Fecin (4) Phenolphthaiein Which Ce(lV) solution is stable enough for a year or at 100 °C cemperature? (1) Basie CejIV) solution el none Ce(IV) solution (3) Neutral Ce(IV) selution (4) Complex form of CejI¥) solution Asill) oxide is used in standardizing oxidizing reagent as a primary standard. The best method to prepare a standard solution of As(III) oxide is {l) dissolving weighed amount of As,0, in water 2) dissolving weighed amount of As;03 in acidic water dissolving weighed amount of As,0, in a basic water followed by neutralisation with an acid (4) dissolving weighed amount of As,0, in acid followed by neutr: tion with a base if you do not have Eriochrome Black-T for complexometric titration, can you perform this titration? (1) Not at all | Yes. with the use of an alternative indicator like phenolphthalein {3} Yes, with the use of an alternative indicator like ferroin (4) Wait untit a suitable metallochromic indicator is procured 8 PTO}13P/206/4 23. EDTAoften combines with metal ion (regardless the charge on the cation) in the ratio of Gy 4 (2) 1:3 (3) 1:2 UG in 24. Metal ions through oxinate precipitation can be estimated by { bromate titration (2) direct titration (Q) back titration (4) colourimetric titration 25. EDTA titrations require a buffer of pH / Qy 12 A210 @ 4 1 6 26. in the titration of iron(II) with cerium{V}, the equivalence point potential (Bqq] is "OE, + Bet joeh 2 -E, - 0) Beg = Epa pe + Boat jee UB Hag = ‘cet pce (3) Beg = 2B per pe + Boe po () Beg =F, ret yr? 27. In the following potentiometric titration curve for the determination of chloride with silver nitrate . th OA egos : : $10 18 20 V, mL. 0-1 M AgNO AE/AV, V/mL the equivalence point is Q) 10 mL (2) 20 mL (3) 15 mL (4) 22 mL (312) 613P/206/4 28. The equivalence point pH in the titration of acetic aefd with standard sodium hydroxide is (1) in acidic range f} in basic range (3) in mild acidic range (4) neutral 29. The pH values at 0, 10, 90 and 100% titration of S00 mL of 0-100 M HCI with 0:100 M NaQH are 10, 1-09, 2:28, 7:00 (2) 11, 1-20, 2:50, 7-50 (3) 0-1, 0-11, 0-23, 0-70 (4) 1-09, 1-00, 7-00, 2:28 30. The conductometric graph given below 8 2 3 3 8 ‘end point Volume of alkali ee a titration involving (1) strong acid against strong base (2)__strong acid against weak base (3) strong base against weak acid (4) weak base against weak acid 31. Phenolphthalein (Kj, = 1x10") is used as an indicator when transition pH is in the range of ay 14 2) 46 us 6-10 (4) 10-12 32. Which of the following relationships is correct one? a tog %7 «2.4100 (2) A=2.0-log %T x fo I oF (3) og %T = 2 «100 (4) log %T =2-G-A 4 ow 2 Tee Sanne (312) 7 (PTO)13P/206/4 33. The unit of ‘molar absorptivity’ is (1) L mot em? Q) 2 mol em fo tt mot! em"! L mol! cm’? 34. Beer's law is obeyed for a complex when it is formed by taking me in large excess ) ligand in large excess (3) metal : ligand mole ratio 1-0 (4) metal : ligand mole ratio greater than 1-0 35, Bgkr’s law is obeyed in the case of an aqueous solution of a weak acid, if My solution is made acidic (2) solution is made basic {3) solution is made neutral (4) solution is made dilute 36. A7-25x10° MKMnO, solution has transmittance 10%, when measured in a 2-10 cm cell at a ae nm. The absorbance of this solution is (2-00 100 3) 0:20 (4) 0:10 37. The distribution constant (K) for iodine between an organic solvent and water is 85. What is the concentration of Ip remaining in the aqueous layer after extraction of 50-0 mL of 1-00x10~ M ly with the 50-0 mL of the organic. solvent? ce eitn (2) 5-28x10°7 M ,[Colg|*,[AeFot »|Agl2!” (2) [CoFg |", [Colg|*- (2) [Colg]?”, [AgF2” (3) [AgF2]. (Aglal” (4) [CoP], [Agta] Molecular formula of Geraniol is (1) CioHieO (2) CigHjgO (3) Cots (4) Cio ,0 Acetaldehyde is the presence of few drops of HxSQ, at 0 ‘C gives () aldol (2) paraldehyde (3) metaldehyde —(4)_crotonaldehyde Molecular formula piperine is (1H Cy7HygNOy (2) Cy7HygNO2 (8). CyzHgNO3 (4). None of these ‘The reagent that differentiates an aldose and a ketose is (1) Febling solution (2) Tollen’s reagent (3) Molish test (4) bromine water Bubbling of chlorine gas in boiling acetaldehyde gives (1) CH,Coc! (2) CH3CH,Cl (3) CCt,CHO (4) CICH, CHCl ‘The reaction of phenylacetylene with sodamide in liquid ammonia gives (1). styrene (2) 2,5-dihydrophenylacetylene 1 dihydrophenylacetylene (4) sodium phenylacetylide 15 PTO)13P/206/4 83. 84, 85. 86. (312) In the following reactions () CHy—N=N—CH, (1) CHyN, 5 (IM) (CHy)3C—OH +H* ——> (iV) (CHg)3C—Cl + AIC]; —> the reaction intermediates formed will be 1 " I Vv () CH, :CHz —— (CHg)3@— (CH) 3” (2) “CHs CHz ——[CHg)3C* —(CH)3C7 (3) -CHy CH, (CHy)sC*(CHg}5C" 4) CHy CHz — (CHy)gC(CHg bs Oxidation is associated with (Q) change in molecular weight (2) gain in electron (3) evolution of gas (4) loss of electron Which one is the reversible reaction in the following? (1) Sulfonation of benzene (2) Nitration of benzene (3) Halogenation of benzene (4) Alylation of benzene ‘The electrophile in oleum in the sulfonation reaction of benzene is (1) S02 2) 805 (3) $03, (4) 80, 1687. 90. 91. 92, (312) 13P/206 /4 Vulcanisation of rubber is (1) cross-linking of hydrocarbon chain in crude rubber by sulphur (2) heating of rubber to mould in the desired shape (3) decreasing its tensile strength (4) decreasing its elasticity Polyester is condensation polymer of (1) phenol—formaldehyde (2) terphthalic acid—ethylene glycol (3) terphthalic acid~-hexamethylene diamine (4) urea—formaldehyde Which one of the phenol derivatives is more steam volatile? (1) oNitrophenol (2) m-Nitrophenol (3) Hydroquinone (4) _p-Nitrophenol The compound readily reacts with Lucas reagent at room temperature is (1) 2-methyl propanol (2) 2-methyl propane-2-ol (3) 2-butanol (4) 1-butanol The compound which does not reduce Febling’s solution is (1) formic acid (2) acetaldehyde (3) benzaldehyde (4) fructose ‘The acidity in decreasing order of different acids is {1} formic acid > chloroacetic acid > acetic acid > propanoic acid (2) formic acid > propanoic acid > clloraacetic acid > acetic acid (3) chloroacetic acid > acetic acid > formic acid > propanoic acid (4) chloroacetic acid > formic acid > acetic acid > propanoic acid 7 PTO}13P/206/4 93, 94. 95. 96. 97. 98. (342) Which one is an example of azo dye? (1) Malachite (2) Methyl orange (3) Indigo [4) Fluorescein ‘The reaction of benzaldehyde with ethyl a-bromopropionate in the presence of zine is known as (1) Perkin reaction (2) Knoevenagel reaction (3) Claisen-Schmidt reaction (4) Reformatsky reaction The reaction of acetaldehyde with concentrated NaOH gives (2) yellow resin (2) aldol {3) metaldehyde (4) paraldehyde ‘Anthracene on oxidation with chromic acid gives (1) anthranilic acid (2) anthraquinone (3) phthalic acid (4) terphthalic acid ‘The order of each of hydrogenations is (1) anthracene > naphthalene > benzene (2) benzene > anthracene > naphthalene (3) benzene > naphthalene > anthracene (4) naphthalene > anthracene > benzene ‘The intermediate in the reaction of m-bromoanisole with sodamide in liquid ammonia is CH; CHa Q) i (2) Ze OCHy OCHs 2 3) 4) Br “Br 1899, 100, 101. 102. 103. 104, 108. (312) 13P/206/4 a-Naphthol couples with benzenediazonium salt at position ay 2 4 3) 5 4 6 Conversion of aliphatic ketones to esters is known as (1) Wolf rearrangement 2) Beckmann rearrangement (3) Bacyer-Villiger oxidation (4) Clemmensen reduction Isoquinoline on reduction with tin and hydrochloric acid gives (1) octahydroisoquinoline 2) 1,2,3,4-dihydroisoquinoline (3) 1,4-dihydroisoquinoline (4) 1,2-dihydroisoquinoline ‘The reaction of pyridine with acyl chloride in the cold gives (1) L-acylpyridinium chloride (2) 3-acylpyridine (3) 4-acylpyridine (4) None of the above Which one is least stable carbanion? (1) Cys CH, (2) (CHg}3°C 8) “CCly (4) “CHs Which of the alkyl halides undergoes most readily for nucleophilic substitution reaction? (1) CHZCH,Br 2) CH,CH,F (3) CHjCH,I (4) CH,CH,CI The reaction of ethanolic KOH on 1,1-dichioropropane gives (1} propanaldehyde (2) propyne (3) propan-i,1-diol (4) propanone 19 (PTO)13P/206/4 106. 107. 108. (312) An axial methyl at position 1 in methylcyclohexane is closer to (1) 2a, 4e hydrogens (2) 2¢ 6¢ hydrogens (3) 16 3a hydrogens (4) 3a Sa hydrogens Predict the product of the following reaction Oo if Pa/O, Hp R—C—C—O—H + NH; ————> I ll (i) R+CH,-C—O—H (2) R-GH-C-O-H NH, (3) ROC=NH (4) R-CH—COH OoH —H Predict the product of the following reaction CN Ro Ke (1) NH PN cute (2) HNOz (3) CgHsO—H (4) HCL ZN CN (1) RCH (2) rot CO2H NHCO,Cols CN (3) RACH (4) R-CH—CO,H con, a NH, 20109. 110, 1. 112, (312) 13P/206/4 A dilute solution of D(+tglucose in presence of sodium hydroxide is converted into an almost optically inactive mixture which contains (1) Dé+glucose, D(}erabinose and D(+}mannose (2) D+} glucose and D(+}-mannose (3) D(+}-glucose, D(i-mannose and D(-Hructose (4) D(}mannose and D¢-}-fructose Predict the product of the following reaction “a (2) PhP 2 STEN > (2) CatigONa “Some (3) PaCHO (4H CH, (1) PhgP=CHOMe (2) Ph—-CH,CHO (3) Ph—CH=CHOMe (4) Ph—-CH,—CH,—On Which aldoses and ketoses form same osazone when treated with excess of phenyl- hydrazine? (1) Dist-ghucose, D(+}+mannose, Dir}-ribose (2) D(s+glucose, D(+}mannose, D(4-fructose (3) Dis} glucose, L(sparabinose (4) D(s+glucose, D(-}arabinose Predict the product of the following reaction CHO I (1) NH,OH (GHOR), (2) Ac, oe CH,OH (3) CH,ONa, CHCl, D (+) glucose (Q) D-}arabinose (2) Gluconic acid (3) Glucose penta acetate (4) Di}ribose 21 (PTO)13P/206/4 113. Which pair of the following pair of sugars is epimers? (1) Dirglucose, Di-Hiructose {2) D(s)-glucose, D(-}arabinose (3) DG}glucose, D(4-mannose (4) Di-Hructose, D(}-mannose 114. The orbital angular momentum for a 3p electron is « - ns a 28 @ 6? a) 7 mo Qn Qn Qn Qn Which one of the following atomic spectral transitions is forbidden? (1) 3d af (2) 2p-> 3s (3) 3p» 3d AGA 5F 16,' According to quantum mechanics, the energy levels of a free particle are 4 AU continuous (2) discrete and equally distant (3) discrete but not equally distant (4) Energy is always zero 117, The quantum number which is not derived from the solution of the Schrédinger wave equation for hydrogen atom is (1) azimuthal quantum number (2) principal quantum number (3) magnetic quantum number (4) spin quantum number er as} ‘tal which has a maximum probability density lying along two axes is known. - 2 ( dp B) dy @) de (as Which one of the following molecules has the highest bond energy? Qn Fe ae (9) Bre (a (312) 2213P/206/4 420. ) The translational partition function has the unit of wv yw @P wh number 121. The fundamental relation in Helmholtz free energy (A) and molecular partition function gis (1) A= MET Ing (2) A=-NeTIng @) A= NKTE (-£ (4) Ax-NKTZ ex (-£) (3) Pl op (4) PEE (2) For an ideal monatomic gas, the particle partition function q is apa or 0) v he 2 2 @) (aa) v 2nmkT 123. If-vis the fundamental frequency, jis the reduced mass and k is the force constant, then for a harmonic oscillator ay kek ia (2) v= 4n%e2y @) v 4 vee Pon 24.) The Maxwell-Boltzmann distribution function of speed is s(t 2) a m (312) 23 TOS13P/206/4 125, The difference between the magnitudes of the magnetic fields at which ‘ree’ nuclei and molecular nuclei resonate is called () chemical shift (2) magnetic shift (3) screening constant (4) anisotropy in gvalue a 126.) When a transition between states of the same multiplicity occurs without emitting \__/ fight, the process is called (1) Guorescence ternal conversion (IC) (3) quenching (4) intersystem crossing (ISC) @ (ay, Rotational spectra are observed in the (1) neg? infrared region (2) visible region (3)Aar infrared region (4) UV region 128. Which one of the following is adopted as the primary reference electrode, assigned standard electrode potential equal to zero? (1) Hg/KCl soln. (aq) 2) Cu/Ccuso, soln. (3) Ag/Agcl/cl (4) Pt/Hy(g, 1 atm)/H* 129, The reverse of a photochemical reaction is called (1) chemituminescence (2) phosphorescence 3) fluorescence (4) photosensitization 130. A5-0x10° M solution of KCrO, has optical density of 1-5 at 680 mp using a 10 mm cell, Its extinction coefficient in the unit of L mol”' em‘! is a) 075 (2) 300-00 3) 750 {41 30:00 (312) 2413P/206/4 131. For reversible isothermal expansion of a perfect (ideal) gas, which particular set of the following statements is correct? () gy0,w>0, AU =0 and AH =0 (2) q>0,w<0, AU =0 and AH sO -BY/9>0,w<0, AU =0 and AH=0 (4) q>0,w<0,aU<0 and AH =0 &) “Fugacity of a gas in a mixture is equal to the product of its mole fraction in the mixigre and its fugacity in the pure state at a total pressure of the mixture” This is in apis with Lewis-Randall rule (2) Konovalov's first law (3) Konovalov's second Iaw (4) mathematical form of Duhem-Margules equation aN 138) Which one of the following is not true for real gases? (1) aG=nrr inf fe 2) tim {Loa ? nl) 3} P P. G=mRT In| 2 . (F) Ga) Jn osmotic pressure method, molecular mass of polymers can be obtained from the intercept of the graph of c Q) avs. 2) (z WC 8 Suse (4 Bvs. ve {Being osmotic pressure;C the mass concentration (mase/volume) of the polymer) The half-life of a given reaction was halved as the initial concentration was doubled What js the order of ihe reaction? () Zero order (2) Pseudo first order ~134/'Second order (4) Third order (812) 25 (PTO)13P/206/4 136. Which of the following ions has the highest ionic mobility in aqueous solution? ow Ww (2) Rbt (3) Nat (4 Ke oN j( 137. | which of the following isotherms was successfully explained by Langmuir’s \\_J unimolecular layer theory? a) wal / 2) (/m) Po } ap! m) ( (4) Geir J Po £Y Po (aa co (3) emt 139} According to Debye-Hickel theory of strong electrolytes, an ion while moving in a particular direction under the influence electric field experiences a drag due the presence of ionic atmosphere of excess oppositely charged ions around moving ion. Thisfeffect is known as Po \e_ ‘The oscillator strength of a spectral transition has he units of : (1) mol sm? 2) dim mol ‘cm imensionless quantity 1) fasymmetric effect (2) electrophoretic effect (3) Brownian effect (4) concentration effect Which one of the following statements is wrong? @ U1) BIC is a radioactive isotope of carbon (2) Sco is an unstable radio isotope of cobalt (2 Radioactive disintegration follows second-order kinetics "Tay Superconducting materials are diamagnetic (312) 26(0) 144, 145. 146, (342) 13P/206/4 ‘The violet colour of Naj,, 5 Cl crystal is due to (1) Frenkel defects (2) Schowtky defect (3)_ interstitials ‘centres ‘The difference between the potential of the electro, observed and the theoretical reversible potential v; when gas evolution is actually 1c for the same reaction is called (1) concentration polarization (3) Dorn effect (4) sedimentation potential Sulfur can exist in (1) one phase (2) two phases —(3)_ three phases four phases f fsstorder chemical reaction is 10% complete in 10 minutes. tts half-life is (gjven log 3-=0- 48) - (1) 50°50 minutes (2) 7-5 minutes (3) 956 minutes (4) 75-2 minutes The halflife of @ second-order chemical reaction 24> products whose initial concentration was 0-01 mol L’!, was found to be 300 minutes. Its rate constant is (1) 0-36 mol Lb’! min ! (2) 3:6 molL? min? (3) 0-63 mol L! min? (4) 0-036 mol L! min’! ky For a reversible chemical reaction A= X in which both the forward and reverse reactions are first order and the initial concentration of A is @ and the equilibrium eoncentration of X is x,, the value of k ; in terms of ky is given by (ky lay ~ 6) (2) ky a/x, (3) Ry (ay ~ xox, (4) ky x, May - a7 (P.F.0,)13P/206/4 |, consecutive chemical reaction, A—!-+ B—**-+ C is first order at both the stages (d kp. ‘The time required to attain the maximum with rate constants as Ky concentration of B is given/by 3 fink Ink, ink, +Ink, ny 2:93 no" 3 Inky} @ (nk, +Inka) (ey Ka) (ky #2) irgy of activation for the decomposition of NO} into NO and ¢ Og is negative which ¢ ene! may be due to one of the following Increase in entropy on decomposition of NO2 4 (2) Formation of stable intermediates (3). Formation of free radicals (4) Decrease in enthalpy on formation of NO and Op (we. sue activation energy of a unimolecular surface reaction is obtained by measuring the hemperature dependence of rate constants at one of the following (2) Loyw“temperatures (1) Low pressures (3) Constant volume (4/tHigh pressures The rate constants, k;,*.. and ky for the enzyme catalysed reaction »EtP are 0-1, U1 and 0.05 respectively. The Michaelis constant for the reaction is () % Q) 16 (3) 0-066 (4) 225, NY 28 D/3[312}—4800see afters ab wer sere ae aaa SE aC eae oe meth ae wa 10. a. 12. 13. 14, wafer & fry fer ae fers wer fret fir 1 fine ie oer ta SP ee A et ge ag Boh A ed ga wa 8) aimee Sage oR oe east gar Tame aa fea aT tae eee ser A qua yee ow a aL eon & silat fore 7a ug ate AA en ITA wre FB PFN secen orpotie aon Sire a ar apn stom rere ga) we fain tars om Fea paces & wera yy we A ser oe Fron we we fend ae aA Ag TH wee orto ores th omeh we-gferey wt wah am Be wT ora afer ard we fests she use me vert seperiae Hon, aH gfe then a A chon Cafe rh A) ye wes gene srgtties Yo aA his Wo atte TA) Ho Pea) nfs seta oat cope afaten A vind of aloxda war Pens am yrafora era RRA area ae eR gaa RT aI ur) ae | sense HL eas a a se Anis ee fe wt By rohan er & dew sere RT arrad oa sy at mati afew a ard RS TD ye a aay tar ye oe RIT fea srgae HB me aon er son ya esate fort ea we ae weg SE we A caw opt aL me eA Stee Se ee eum fie ee re Tato alin aa HY Eo oT BL AL oa Pneh e wT saT eF aot ee Bah aeahn ie a fe wa woh eh Sop 1 AR ae a Se FA ce veoh A fo sos gfe gap ore a ye wat steer gE aa a ait & air Hart siteqwosnes Fa wa Pia MA 4mm a 21 iy gam G2 AWA when oem A awe oR at gst ae erty afe aid api wien srgfaa areata var Ae & th am faeateererr gm Prafta ce 4 aneerit