wer CHEMISTRY SPEED ‘TEST jet IT JEE (Main & Ach CST-57, Time:120 Marks:120 Type:IIT Advanced 2420 9) — 9m lo -s eget es following figures represent I correctly the structure of transition st conecty the transition state in 9 of 3 ni toalker (a Fre A y, Br a be © O co © (car a. ehen jer (A) or (B) depending upon situation BBE) en ay d Acad lems Ay ae. for preparation el! alos Pg tohean ll yy williamson’s etl th the following pairs select the at will react faster with sodium bu, synthesis is M CH; F (A) CHO CH, — ¢ = Br T, (b)-1 (B) (a)-1, (b)-I bay (b)-T (O) (a)-I1, (b)-I (8) CH = CH = Ps cH; - GH er Cert, Ye - H- Hs Hy 1 Eee 64 # tre eee a Which of the following compound will be most. 5 ions Sparkwiz Academyys Target IIT JEE (Main & Adi Inced) (ee oe Oa ami vance: Neé~ & oh Me a on inthe acid catalyzed oe of alcohols toalkenes, the intermediate species formediis (a) Free radical Carbocation (C)Carbanion (0) Carbene Br / 10. a. + 2nbr, Br This reaction is a case of (A) o-elimination elimination, _prenension (Q.6 to 9) (C)yelimination _“(D) none of these arlay ‘The major products obtained. when this E substrate is subjected to E2 reaction will be ‘Most reactive towards SN, reaction ? oO 5 wai? th (A) and (B) (D) none of these OH Most reactive towards E, reaction ? t . Hh) eye rey ae Which of following cannot undergo an E2 reaction ? Most reactive towards E, reaction ? 125 ~All Right Reserved Page No-285paar Wiz, ct upon t in t-butyl alcohol ‘BMP Al QUAD CAMERA Sieeaysevels ge Target IIT JEE (Main & Advanced Total number of SN, products of given: compound are i 3 (B)4 (os (06 CH, The major product obtained when this sub is subjected to E2eaction will be Galley alow LU Tiany to be an UH Ties If the following £2 reaction proceeds throu an anti-periplaner transition state, products are expected CH uctis t-methylcycloher cts is 1-methylcyclohe, luct is 3-methyl cyclohe: 2021/01/03 09:57be yy SPEED_TEST SAD AD eet advance 5 of give er H He cH =e Ge aoe cis prods its |S: = nC H ee ( “The mator product obtained nents sibsake je subjected to Et reaction will be H cH cH. 3 cM, H,C. ? : “CA cH, chy cH) sRoderonetese 7 (9 €¥ AOS HH fians to | BEKO, Consider the given reaction 1 Major cH. Br ie H—-¢- OTs NaCN, cy,ch,cH-CN etoNa, y Le 1 — major 2 Cts cH. NMe, hich of following statement are correct for above reaction. place due to the (A) Product formation takes breaking of O- Ts e reaction S,2 {-butene, cis s-2-butene, 1-butene re) 2 1 (C) The reaction is St Frens-2-putene, 1 bulene wf ce pone of products (R) 4 Sol. uct (X) and (Y) respectively is 2-butene10H MP. Al QUAD CAMERA ot by Sayak Target IIT JEE (Main & Advanced ° ph — 0 — cH, Fs product are (B) Ph — CH — CH, cl cl a fon acta cA (D) Ph — CH, (p) —2hadust ‘compound (p) is CH, H—}—Br H Br CH, 2021/01/03 09:57prep TEST " Target UT JEE (Main & Advanced) er w) a" (A) Major Zn—dust Br ZN (p). The product (p) / 4 He> i g Ww 3437 5 hee 5+ - oH = ie Ww => BF 34222 of” | \ ed o: = 10 ‘otal number of Tous InA+B4Cls (A) 23 (c)37 14 to 13 (3 questions) yr >, ye! Ny in acid catalyst to up of the alcohol y ip. Loss of =) 2% ), given the s most reactive towards 28, Which alcohol | ols In acids catayzed dehydration of alcoh reaction. on OH Mechanism — fo CD) OH + H,50, x, = cH Brg F 4 10:7 oH d CH)-CH=CH) + Hy So ( improve the yield of above reaction which (c) (0) of following is correct. ) High, temperature esi B) Distillation Addition of H,0 Both (A) and (B)1° But wou C no. chp. mubttedt ATONE - Column IT Ethanolysis relative (P10 ilimination — substitution 48MP Al QUAD CAMERA Shot by Sayak 2021/01/03 09:57spt SPBED Reaction Hom R— CHT — @ oO () HO% R—CH,—F—> On sre WAY } column I Alkyl-bromide HOS R— CH, — Br—> HO% R—CH,— Ch» Reaction rate of reaction at 200 R) 10,000 ) 30,000 LG wb a 5, Column It Relative rate of SN* R) 1,200,000 column Column 11 _ Solvent Relative rate of SN* (A) 100% water. (P) 1200 (B) 80% water + 20% ethanol 19) 400 (C) 50% water + 50% ethanoL___—_——®) 60 — (D) 20% water + 80% ethanol 8) 10 yt (E) 100% ethanol ethanol pate gu pt Sl, Eltemol = poor pac a cael gueny osidie7 Target UT JEE (Main & ance with List: IStHforgiven 5. reaction & select the correct answer rom the codes given below —CH.Br + CHO? —, 2-cH,ocH, + 8 lative reactivity) ‘and select the correct answer from codes given below. List II (P) CH, — CH, — PH, (Q) CH, — 0 — GH, (R) CH,— 0 — CH, (S) CH= C—CH,— CH, entries each. Entries of column I are to be matched wit entries of column I may have the matching with tr ‘I may have one or more than one matching with e. ic 48MP Al QUAD CAMERA Sires ireNola 2021/01/03 09:57OME, menu + Ts0® | where nucleophile attack Me—OTs in the rate determining step to give the his reaction increases with concentration as well as nucieophilicity of the nucleophile lumn II for the above reaction. Column It (Relative rate) (P)3.25 (Q 6.25 (R10 (S) 7.75 |isomers produced in B-E, elimination) and select the correct List IT (i) Three i) Zero (iiiy One (iv) wo an myo) NC : bcm) ead OO mei) Ay MCDM caiycing)juct is Ph — OH CHO oduct is 2° alcohol [s 48MP Al QUAD CAMERA Shot by Sayak PONTE)