emmbd ayo / Higher Secondary Second Year Geugluusd - Chemistry (aysiBonid wind guip / English & Ta srovid ajo) : 15 (PuALoiesstt + 3.00 wei Time Allowed : 15 minutes + 3.00 hrs epansesr: 1. amasg Aemdsopb sfumat ugewna actos sioiissnen sifiuninsas aeaLUAasd GoMuIGuiict sips seteroniumenfiLip Brsdplenso il Version) Cuong wBLICLsHNeEeh » 7 Maximum Marks : 1) - i j ong oflennggsrott I / Model question paper I GQasncitenoyt. a _Lompunas Gpfalésay. 2. Good (Sedvog!) SHU snwulensr wi GW THHMASHGw oMdsCaryGuspGw LUGHLGSS CouoriGid. uLmussi orsngoase CusiAled wwiuGssoyid. . Check the question paper for fairness of printing. If there is any lack of faimess, inform the Hall supervisor immediately. 2. Use Blue (or) Black ink to write and underline use pencil to draw diagrams. SHLY: Csmauon Q_sHod urtd songisgi sweiunGsenon orapsoytd. Note : Draw diagrams and write equations wherever necessary ugh — I/ Part-I 1Sx1=15 SHLY : 1, SeoanHg1 Sond HeardEid oilomrwuofdesoyid 2. GarGSsiu prog —oflenaaficd aap gbtysn_us allan anus CHIOZGSH GHuLGLon aienrulensmupd Cstsss vapsis. . Answer all the questions 2. Choose the most suitable answer from the given four alternatives and write the Instructions : Note : option code and the corresponding answer 1. AGsCa_Gaoilat Sughusm sugsumwoiny 216v@, 2 [SiOs* as, [SiO] @. [Sioy ® [SiO.]* The basic structural unit of silicates is a) [SiOs]” b) [SiO,]” c) [Sioy d) [SiO* 2. GoparsAsoma usuGid elas, Ggpivnasiurd Guneiny _ ssesfworiessir (angus GmismoLUuGSSOUGSHainpen. St. Cori AL SSH ed GarcuscsUGHHSod QA MTs - Ayjreod pony 9. voi ad Hesfiiy F DleiteammpBLug se59b Elements like silicon and Germanium to be used as a semiconductor is purified by a) heating under vaccum b) Van Arkel method c) Zone refining d) Electrolysis 3. sor oulermasir shonin Hwsit aula 21. HOX > HXO} > HXO; > HXO,4 2, HXO4 > HXO3 > HXO2 > HOX ®. HXO3 > HXO, > HXO, > HOX . HOX > HXO4 > HXO; > HXO, The oxidising power of oxo acids follows the order : a) HOX > HXO, > HXO; > HXO; b) HXO, > HXO; > HXO> > HOX c) HXO3 > HXO, > HXO, > HOX d) HOX > HXO, > HXO3 > HXO. ML E@Bwr (C07) Suwiefuiled 2 sien 2. 4 Cr-O Wenominysct aif wid & 6 Cr-O Uenomiiysst sf sw QB. Simei Cr—-O Usoominjsenid of sib F. Sinenda Cr—O Wersmiijeonid sift SION! In the dichromate anion (Cr,0,) a) 4 Cr—O bonds are equivalent b) 6 Cr—O bonds are equivalent ¢) All Cr—O bonds are equivalent 4) All Cr—O bonds are non-equivalent . LQELYO Liramiysipsi ouflensuig (Glpionee CausHeuflans) Usagi refsensi ofa uye YyooilenLuiienes IDUGS Sug o1g51? ou Fo 2. CO @. H:0 #. Cl” According spectrochemical series which of the following ligand produces strongest field and cause maximum splitting? a)F" b) CO c) 2,0 acl - 9G YS aims sHononds, clemenGous wre 6.909 min! staicd 75% sioner Panna up Sserenumten sme (GLeussit) 3 2 3).0(3 2 Veo 4 at. {= flog2 = |og2 . {= Hog) = &. |= flog] = a ae ee a) For a first order reaction, the rate constant is 6.909 min"! the time taken for 75% conversion in minutes is po Ge HE) GE) Yast OWU SEEEET SWGSeatysir (foc) CurBays Sos ot. 74% AL 68% @. 52.38% FF. 48% The packing efficiency of a face centered cubic structure is a) 74% b) 68% ©) 52.38% d) 48% . Gat Bailie sovenan WeiiGeniypid (charging) Geuuyd Gung) 21 GpIVerupmanicd PbSO. yaw Phas gbbser Angi 24, Gpisirapsnenuisd PbSO, 24sg1 PbOr 21 ayoriiegBonirmwoer sings Q. agiciaporenuiicd PbSO, ayongi Pb as gbbavmsingi F. a@lienapsnenutod PbSO, agora! Pb as Qbmdggoniowsr dps While charging the lead storage battery a) PbSO, on anode is reduced to Pb b) PbSO, on anode is oxidized to Be ©) PbSO, on cathode is reduced to Pb 4) PbSO, on cathode is oxidized to PI Usiougocnoydgen 1g) sfusras GLne@bSuysitongs? ©). uTedwoib = Gules. 8% iw snp samyasy - tod ®. pny = pranyesed afl = GaussiansWhich one of the following correctly matched? a) Emulsion - Paint b) Liquid Aerosol - Milk c) Foam - Pumice stone d) Gel - Butter 10. Govt. SCunercigst sony Bs Guyda w7siy 3.2 x 10" sted wxser sang Sys w/ALy ot. 18x 105M a 1.6.x 10°M @. 2x 10°M m 4x 107M The solubility product of lead iodide is 3.2x 10°, its solubility will be a) 1.8.x 10°M b) 1.6.x 10°M c)2x 10°M d)4x10"M Ll, sniusnens Gsiwrusater agdaot Coitéens alenanuiet Cungiauton aeons sit auflene @, HCHO > RCHO > CoHsCHO > RCO > (CoHs)2 9, HCHO > CHyCHO > CoHsCHO > CHyCOCH; > CoHsCOCHs @. CoHsCOCsHs > CHsCOCH; > C.HsCHO > CHsCHO > HCHO #, HCHO > CH3COCH; > CylsCOCsHs > CHsCHO > CHsCHO The general order of reactivity of carbonyl compounds towards nucleophilic addition reaction is a) HCHO > RCHO > CsHsCHO > R3CO > (CoHs)2 b) HCHO > CH3CHO > C,HsCHO > CH;COCH; > CsHsCOCHs c) Co6HsCOC¢Hs > CHsCOCH; > CoHsCHO > CH;CHO > HCHO d) HCHO > CH3COCHs > CcHsCOCHs > CHsCHO > CsHsCHO 12. app : Haima gdonpiadrasr said eres gleam sysrsapictacnenasl ashes mBUBAMB! Gilera aysdnanror aft. qpailmam aydroamreract auaeme Senpbs eget ublevid. o. ahp wip siyomd BysiGbd sf Cogud sryomorog apidsron sffwmen aflondbasioT tb. 2. oH wppwbd sijobd ByoiGd sf Cogud saysmorog apS sro ofwnen allondsasavenev. D. ani ef eysnned anyombd Gaul F. SoHo wipud sngemb ByaiGbd sug Assertion : Tertiary alcohols undergo dehydration more readily than primary alcohol. Reason : Tertiary alcohols are less acidic than primary alcohol. a) Both assertion and reason are true and reason is the correct explanation of assertion b) Both assertion and reason are true but reason is not the correct explanation of assertion c) Assertion is true but reason is false d) Both assertion and reason are false 13, Veiagb senerouflnouies stmaGunqer X gg aovinpies. C,H,OCI— C,H,ON "5 CH,CHJCH,NH, (xy). BeNTBGLY wpanguiied SGopsed Sy . Sp Camevggenaonen att iggntb Lyoyfist 2 . afpuigenen antpind sonyeore womppieugs Ot oh Laas pe i 2), CHy;CH,CH(OH)CHC! 9. 7 sCHaCHa Ci . CICH)CH,CH,CHO Identify X in the following sequence of reaction, a a ¢,H1,0CI > C,H,ON "8" CH,CH,CH,NH, @ a) eis b) CHyCH)CH(OH)CH,CI c) CH3CH2CH,COC! d) CICH;CH;CH;CHO in nLonpt GynGusider 2Leit (NH,)S, alone fips: GenGsew qpasiieno oflensnGstepi agi? No? We) He . | ay, HN on On Hoe, ‘The major product of the reaction between m — dinitrobenzene with (NH4)2Sx is No No, we Ni Ga cued On and . UpsbBet Gyo Awl siomoiunengs sons GpbsApE? OL UTESALULICLG wpsGegudiier Plonscuston ous SismwisL} 2 Bi Gaupsetd Bon ulGastt Oo — SUACont sertiserior onflens a. O — Batt (paGiantdy The secondary structure of a protein refers a) fixed configuration of the polypeptide backbone b) hydrophobic interaction c) sequence of 0. - aminoacids d) ot - helical backbone ugé - I1/Part- 1 6x2=12 steed agi siomrboersS Heo wotiss. emt stot 24 &G BLL MULTE clan wierisesoyld. ‘Answer any six questions. Question No. 24 is compulsory. adlact UMELGSEass SiuFwid usr? ath floatation process? He conor Apepinwel. gsi? What is the role of depressing agent in fro Why fluorine is mote reactive than other halogens? . ser Amen GuGésld ousnjuia Define solubility product of a compound. are eipowrdd GridetuGsng. Baier AG sgsEt Gon ioTdSs Peptising agent is added to convert precipitate into colloidal solution. Illustrate with an example.20. 21. 22. 23. 24. 25. 26. 27. 28. 90 Wore gers sordigyion AyaiG VomLgor Perwpmasess Bower gap 15 G58. qeiGaire, eiupmrenisr GDS upliyid 456.0516 stoi. OSN Weiugsfés smTENsS eraodns wuweiGdss sori pGwOULL ers way 15Q srefied, smpecler Huw SL sgwsSoor wglieou arose. ‘A conductivity cell has two platinum electrodes separated by a distance 1.5 cm and the cross sectional area of each electrode is 4.5sq cm. Using this cell, the resistance of 0.5N electrolytic solution was measured 15Q. Find the specific conductance of the solution. t- GyLersd adrsamronn oWlorrd sos or@EsrBocor UWI} smivisnensd Caiwors yboigQ@onppd oKoLwWs Csi Qwgnon? Is it possible to oxidise t — butyl alcohol using acidified dichromate to form a carbonyl compound? GusrsrdQmaDQAGSS! wroemat. uss smuid stovourgy swmilumls? How will you prepare Malachite green dye from benzaldehyde? Usiougasnaypenp ouflensuGsere. @ pKs waXtuyassrie Byres sulle : CoHsNH2, CoHsN(CHs)2, (C2Hs)2NH, CH3NH2 Gi) sry ausSemouist gyyeuflms : CoHsNH2, CoHsN(CHs)2, (CoHs)2NH, CH3NH2 Arrange the following. (i) In decreasing order of the pKy values : CyHsNHp, CeHsN(CHs)2, (CoHs)2NH, CHsNH2 (ii) Increasing order of basic strength : CsHsNH>, CsHsN(CHs)2, (C2Hs)2NH, CHsNH2 Byori_md ouflns any 2 Conasgier omawcesGe (X) sams (Y) stop Guunprefion Brivsgron ainonyfipar (Z) sop OGG siyonfulonsr soswsi. X,Y, wppud Z ow sori ge. ‘A hydride of 2 period alkali metal (X) on reaction with compound of Boron (Y) to give a reducing agent (Z). Identify X, Y and Z. | usd — W/Part— 11 6x3=18 ssqbd gg Aemdsense eorwciés. Slam car 33@ oc murs aHen_wsfiéasoytd. Answer any six questions. Question No. 33 is compulsory | sous sind 96 Sifseb ane sdusme sebH aGheberGacner | ond ea. Show that sulphuric acid is a dehydrating agent, by giving suitable examples. QorsGsGas Coiwwisst signed srsinon? sis gyrus 2 Conagssor uomiysoMdGbs! aisiourgs wonpuGApe? What are interstitial compounds? How they differ from the properties of its pure metals? Lipstyo PlansiwUuGs56d Ayhyod svsipned oriron? What is crystal field stabilisation energy? Lys Faiwwsna Uys agouwgpy HSemoisAdesa CupuGsass. Differentiate crystalline solids and amorphous solids. 429, uaugsster SerorBosonip sferenuled upiny sautseet Unive, etcion? ‘What is the role of adsorption in the heterogeneous catalysis? 30. aymrarade. BiSSod AGorw so swerumord seal. State and derive Ostwald dilution law. 31 Usagi GMBUILG Cpmiiasnon 2 GambSeid omen Worsefer Quustasner TH QBIS. (i) Gusdeorépit Gi) Guieuf Name the vitamins whose deficiency cause (i Pellagra (ii) Beri - Beri Night blindness 32, was UOOLUQESH sioikDTEd coker? TRS EET Gast BroiG som. What are bio degradable polymers? Give two examples, 33. snsiateGsr afonsmich enero upaypenu sone. Explain the mechanism of cannizaro reaction, ugg — IV/Part-1V 5x5=25 Shssraprd Hamssepbs oercussissoyb: Answer the following questions, Gi) wrennéGoo 8) Smamays Cotviisstieh Goons onomLy Gasrchersuor Can unGasnat sas. (eisoang) b) i) safto auflns sLeiemamuieo OTFFMG wpb xydyensnGaciicr Ge seong BUIMULUG se, i) XeOF,— ob sreminGd Qerssovin wns? oss eporbemg sinioiieu 56s. 8) Mention the main assumption of valence bond theory of coordination compounds. (or) b) 4) Justify the position of Lanthanoids and Actinoids in the periodic table. ii) What is the hybridisation in XeOF;? Give its structure: 3.8) i) afin Queidet camiuGares wines? S16) TSIATB. SumASsUUGHmgN? ii) Dera Cpapuied s~efund MSOSGS S006 Ayreon. seniiGesc gen UUSILGSSUGADS? (oiede0g) i) @G seme allenanaione WHB aporsengy sto sya CagunGssit wineneu? ii) sited asenyeoden Qoamsseit een? PAGAG MSG esnyomd goes, ') Which is known as Inorganic benzene? How it is prepared? ii) What is the role of graphite rods in the electro metallurgy of Aluminium? ) wou DIE Bor Gunster (or) > i). Write any three differences between order and molecularity, % i) What are the two types of buffer solution? Give example for each type. 1) snsveuraiids Weieavds SAulLgst wyysensn cragguss. Hi) eng sedge (intercalation) srsiqgréy steiten?(106053) b) i) unsrwoTéa60 WppIb unde Asay suengugy. ii) 96 obo - oon Qmendy Weugsaeesron sou - pubs wim xpsirenast FwsiuTLgenan aipEIE. i) What are the conventions used in Galvanic cell notation. ii) What is intercalation? a) (or) i) Define Emulsification and Deemulsification. ii) Write Debye ~ Huckel and Onsager equation for a uni-univalent electrolyte © 37. a) Esai wnpprismsr soangy BHoipsssyeut (i) BL Est Buster —>N - Llononsdrengmnt gnascloviBsit (i) uptiisr690G§ —> stu - 1 - snBein (iii) srsifeSer —> p— onpLGyn siaihasen (S1dovg)) b) i) Gprsast orsiprsd stsiton? GGT! Gswsdumeigsr aflenen culupsymeru endes. ii) “ipé@Lranm Comguid - ungysd aoraai dpsiafimauie uGSuoia geld Gums! sisson Blaqptb? a) How the following conversions are effected? (i) Nitro benzene. N — phenyl hydroxyl amine (ii) Propanamide > Propan — 1 — amine (iii) Aniline — p - nitroaniline (or) b) i) What are enzymes? Explain the mechanism of enzyme action. ii) What happens when fructose is partially reduced with sodium amalgam and water? 38. a) i) X wim Y adw smpsact BCC ups simoidiensr 2_Gandgdcnpan. sassgysHor gpmauicd X sjamssenb sige smwusHed Y oemiayd Quod GupAng!. SEBeiosgon oumisliinG steiton? ii) CsHjoO siaptd apmrdongy oiminimG Game’. (A) sig smtuemensd Gotwoworeng Comguid suscdrenul Get Ups afpma soins. Cogud igi srGumGLmumitd Aonee otuGAnE. Cand (A) syengy “Guddmisenssns |Geqarslevone arofisy Gain (A) snor aoxin gas. (o16d60g3) CHO sep gpmdag amiumGer.u Ast (A), seme out HI o.et GouiuuGSord Cura QIsIG sds CamnaGana GanGsémg.. Gwgud Qsenst BIMGUSSS, Exist (B) wind (C) eqandog. B gy aysdegConapw Geil (D) sisi oul | gaming). Cogud (C) m qbAegCenbp Grim éGuner (E) 2 gardpg. A,B,C, D wii E a sxiGuigég) slonarsenon aupgie. b)a) i) Atoms X and Y form BCC crystalline structure. Atom X is present at the corners of the cube and Y is at the centre of the cube. What is the formula of the compound? i) A carbonyl compound A having molecular formula CsHjO forms crystalline precipitate with sodium bisulphite and gives positive iodoform test. A does not reduce fehlings solution. Identify ‘A’. (or) b) A ether (A) CsHi20 when heated with excess of hot concentrated HI, produced two alkyl halides, which on hydrolysis forms compound (B) and,(C). Oxidation of (B) gives an acid (D) where as oxidation of (C) gives ketone (E). Identify A, B, C, D and E and write the chemical equation.tongifl ellemgsgrot IL / Model question paper II Crsrplensy Qyoin_mbd syoG§ / Higher Secondary Second Year Broo gyeray : Time Allowed : OBaysoyasit : j@muy : Note : @moy + Note : 15 BwWLrivssir + 3.00 wonf Gaugfuiussd - Chemistry (aytewd woquud gidip / English & Tamil Version) Guns wPUCLEE : 79 15 minutes + 3.00 hrs Maximum Marks : 70) ty 2. simasg) Hemdsenbd sfurst upon voitongr ctoiugssnon sMuninses Csreimapd. sesLUGeled GopulGuisr sjonyd sevieenonicwsmenfietd DLomgQuirad Opflalasoyo. . Bob (oKedmg) sGly amon wiGo sEINIBEID SWUACETGAGISH UWAUGSS CasiGid. ums suengousive, Gusiréiod LUsUBS Bap. Check the question paper for fairness of printing. If there is any lack of fairness, inform the Hall supervisor immediately. Use Blue (or) Black ink to write and underline use pencil to draw diagrams. Csmauitor QrsSed utd aonyisgs swsinmGsensn sagged. Draw diagrams and write equations wherever necessary 1 Me ugg — 1/ Part-I 15x1=15 SinsiG) Memrsserseid en_woflésssayd . OSIGSSUULL prSIG Terraced Dood gbyrLw aorous CotbOsoss1 SHU GL sfenruionanuyd Csinsss supe. . Answer all the questions . Choose the most suitable answer from the given four alternatives and write the option code and the corresponding answer 1. Ustagacrouppict seupren soy og? 21. [Ni(CO),] — sreiapa, unjrambs setemoujso_wigs 4. [Ni(CN)4° — senegmd, muna, sohemoUe9LWE [Ni(CO),] - Bretgpd, mLuranbs Sairomwoujs_wsg) &. [Ni(C),)—preiapeal, unpre ssiomoujsoL.wigs Which statement is incorrect? a) [Ni(CO),] - Tetrahedral, Paramagnetic b) [Ni(CN),}* - Square planar, diamagnetic ¢) [Ni(CO),] - Tetrahedral, diamagnetic) [Ni(C).]* - Tetrahedral, paramagnetic 2. @amiGun unsdues sudeosaAsir smygdssioub a1 a 2 m4 The basicity of hypophosphorus acid is a)1 b)2 °)3 4 3. Seip : Gunna Ups Sei Pissed ouWlesgsheno amirb—gs. Siyamb : sigWofuid sul gSymbuetusoaugsned O FH whgwd syed QyewiGd sf Cogn SIoMVOTEAG FAH 5e sifusren silences.2 FOGG wg snyesmd sig sf Gogyd snyemorongi sD erflusren allendasiosdev. 3. rm SPH Ff gyuned soyamd soupy SPD! GHW sijambd QyoxiGb sup Assertion : Aqueous solution of potash Alum is acidic. Reason : Aluminium sulphate undergo hydrolysis. a) Both assertion and reason are true and reason is the correct explanation of assertion b) Both assertion and reason are true but reason is not the correct explanation of assertion ©) Assertion is true but reason is false d) Both assertion and reason are false |. HdyosGsalen Curgiouran sysAgg@enip lenovo. . oe) +2 he 13 #. +6 The most common oxidation state of Actinoids is a) +2 b) +3 o) +4 d) +6 DALIT FIG GassiohussdrsoiOG ba USCS WO St 2 GSGHO 2h anppsdraor Gpaded aBIss> QB. apidsed F. Worambs UAL Epp Wolframite ore is separated from tinstone by the process of a) Smelting b) Calcination c) Roasting 4) Electromagnetic separation Usitougoumonigiet orgs Souptong!? OL Gprpsaiicr GeusduTLe SoSH BFKUGSS wplquo ay Biman GprAaaiensd GprBastict aieneuswonbs GouedurS SmpspEs! @. GprA cnaGas wmiporeng obs CHibB Gswaonord gstemveu ubpiotronss =. anwinier pH wAllenul GuTEge Gre sfienenBaisionsyy eilenanc — iom08DB Which of the following is incorrect? a) Enzymes can be inhibited (poisoned) b) Catalytic activity of enzymes is decreased by coenzymes. c) Enzyme catalysis is highly specific in nature d) The rate of enzyme catalysed reactions varies with the pH of the system Gunsgsw0TH 965 gogymibasit WaitgDMLL SS Guippisiton stovds greiesafiot —stevtesebons ‘B, 6.022x10% — 6.022 10° 6.022x 10% 6.022 x 107" ‘The number of electrons that have a total charge of 965 colombs is a) 6.022 x 10% b) 6.022 x 10° ©) 6.022 x 10 ) 6.022 x 107 om 2 Gooresggion pail IP) se GIT DIG Flot (FCC) afleffubry Bomb 8v2 pm asic, 2 Gore orapisit ast =k 8x 107 R 21. 0.04 2 0.02 SleIn FCC unit cell of the edge length is 82 pm. The radius of the metal.atom is_A° 8 a) 0.04 b) 0.0: 10? de ) 0.02 o) 8x YG OG aMenonuist sHenenGouss ronpfeduSen wsAluy 2.3 x 107 lit mol's', sistefenenuten sflenensuans Sh YER ous Be YS ams QB. Qyoinmd aims * apsigmbd mene The rate constant of a reaction is 2.3 x 107 lit mols". The order of the reaction is a) Zero order b) First order c)Second order _—_d) Third order UdiuGamappist Gonpons songurdsagu Pepoyyrs oy sengecd sil? Bi Ssh CUGéGI > sengApar GUGHHID (Key) BA Swe GuGbob < sengSmor GuGsad (Key) 8. ous Gugésb = sonyAps Qugsab (Ko) (2) wild (Q) ByosiGwo In which of the following cases, the sparingly soluble salt solution is unsaturated? a) lonic product > solubility product (Ks,) _b) Ionic product < solubility product (Ksp) c) Ionic product = solubility product (Ks,) _d) Both (a) and (b) Ustugacroubpist 1g) sure Gungigaileoone i Bucur = Te ? 2h. sports — 6 - — -LNH- Ch,),-NHCO- CH, - ° B. @Lfassn - focn,-cr,-0-c-g- U4, I 0 F. UTeaéMGeor smptenysd — +-CH,-CH, wy Which of the following not correctly matched — — forenoon © b) Nylon - 6 = fret catty nttco-(ory- Eh o c) Terylene - poet, cth-0-c OL, ane ° d) Poly acrylonitrile — Lor-cH, 4, iy # Usieugid aubpssited sigs sfusmongs? oh GujsolCutsG + unevumflé onder + Huy soi@usren_gG 2), GusaNCutnsG + snp > GuysafiGunanG Q. sidaeoy + argd > BuyseflGutonsG Bn GudoGuroneG > unadpGuyessriGuroorGWhich of the following statement is incorrect? a) Nucleoside + Phosphate —> Nucleotide _b) Nucleoside + Base —> Nucleotide c) Sugar + Base + Nucleoside 4d) n Nucleotide > Polynucleotide Ulitougid aAlenemuieir SHlenen@ungGencnds Bevirpha. CH,C/ SS, Aho, Bh Joa yp 4 CH3CH2NH2 24, CHCN @. HCONH, #. CHsCONH2 The product ‘D’ of the reaction CH,CI 2% 5 A090 yp) C8 yp a) CHsCH2NH2 b) CH3CN c) HCONH2 d) CH;CONH2 ° AX OH ei TUPAC Gust St) UL - 3 - remmuléoueod ay uy - 1 = mon - 4 ayuiarbloowd + @. Gul - 2 - wet - 1 - quis sudo mr ug - 3 - Rot - 1 - Quldsoufevid oO The TUPAC name of 770M a) But - 3 - enoic acid b) But - 1 - en-4 oic acid b) But-2- en- 1 - oie acid d) But -3- en-1- oic acid Usiugausroupgict ag suse Wis ousorie? OL 2 - ep Gymifonted 2 4 - @GontGyrifonmed 4. = angi GymSoned 3 apt Gymfanred Which of the following is the strongest acid? a)2-nitrophenol _b)4~chlorophenol_¢)4-nitrophenol__ d) 3 - nitrophenol ug — I/ Part-II 6x2=12 stogwd oi cfandsenss sSoiuiés cla cat 24 de a1 muons lan wiethseaaylD. ‘Answer any six questions. Question No. 24 is compulsory. [Fe(CN)o]" win [Fe(H:0)6]"* aySucufyier Gidsogscracr GeusiBoyp sSypupsr uss! sit? [Fe(CN)6J* and [Fe(H20)«)* are of different colours in dilute solutions. Why? Lu(OH)s wisp La(OH)s as SISSoowW OoLwug) s1g1? got? Which is more basic among Lu(OH)s and La(OH)s? Why? Ayiimagshod si6iowr Dl @Gonnfisr gsusmficwmis? How will you prepare chlorine in the laboratory? Loy sortase Apiudussdyssit steno? What are the characteristics of adsorption? gress sresit (B) stein Tod austen? ‘What is Buffer index (6)?21. 22. 23. 24. 25. 26. 27. 28. 29. 30. O- D+) GensCarenuyBemraer oisniwieu sions. Write the structure of ct - D(+) Glucopyranose. MHoleh Senondsrons uisCunpd ondorsorsn ysoegoriy allereronur oapsves Write the chemical equation for oxidation of ethylene glycol with perlodic acid. WacIMOnGFUUGsAasit Lode arom Gerussd1 yNeAleingss? How the transquilizers work in body? Wosevssghed0 Zn(s) + Co = Co(s) + Zn?" arsiny ailensa Dapamgy. erase SL emf somdHGa, GarGéstuiig Eo. =+0.76V, E., =+0.28V Znlen* ‘ColCo** The reaction Zn(s) + Co™* = Co(s) + Zn** occurs in a cell. Compute the standard emf of the cell. Given that E? . .. =+0.76V and E° = +0.28V “Zl Zn ‘ColCo* ugg — HT / Part - 6x3=18 TOW Ag AamssHSG loruciis. lem cost 33 SG sLMUNOTS Heorwoiesssayd. Answer any six questions. Question No. 33 is compulsory. Utagasmapey Fes 2 siyammiseHLor oondoe. 2 BaD wwTE a soflln 535 Explain the following terms with suitable example. a) Gangue b) Slag HCuTsot. Gaot uso GPLy sveopes. Write note on Zeolites. afi wip syrsrafer unsissnonds sips. Mention the uses of Helium and Argon. Gurgs) sow saboEy SomviLIe CUBaSAns spoissSoends sonsAGs. Calculate the percentage efficiency of packing in body centered cubic system. siBarg sulens arsine setex? Asiouflons croton “ssfuoremd sien upd sSipenen sori Gu LUssGADBI? What are electrochemical series? How is it useful to predict corrosion? Sichiarned vec Gey ABEL, Be tir 4 C A,B,C aaucuiany sori. Coan ofrentenar wis Asura, Anisole—-woriorte , 4 SWI, ptr yc Complete the above reaction and Find ABC. oe (A) send sflos Cai gGdsnempe Bai (B) GanGbAng. ‘B’ syengi CHCh LopmWD eysrsawmIe Goss KOH e161 Geib (C) my GsnGedpg. Coad (C) SHlonenGous ni dpsiaficnavuicd gba Gow N-— Gwsger syafieden Horr sang sisi) A,B wiipid C gg soriGilig — aflenansanen supgie~32. 33. 34, 35. 36. An organic com, pound 5 a a alcoholic KOH give ia on reduction gives compound (B). (B) on treatment with CHC/s and S _ oh a i pone a ). (C) on catalytic reduction gives N - methyl aniline. Identify A, B, f i) CLrgwulahode iss at ii Sriarecaa es oe as ondeoid gumfcnimis? / . ; MGHbEror goed QyoiG & : i) How will you prepare benzoie acid fiom seach ri be om sale two tests to identify carboxylic acid. Silt lwerd i " cea a LUIUGSD, Ty wigud Tz Gaxtuyplensseticd oSlananGoves ae ear, Wk: wow ky qswcroupiier wvALysoteSebs! Sento syed E, ae 17 i Bib SahMLQeend uGalis. / ive Arhenius equation to calculate activation energy from the rate constant ky and k, at temperature T; and T; respectively. ; ugg - IV/Part-IV Spsoremwd alomssepse, ofl usiissayd: Answer the following questions. / 5x5=25 a) i) CamCourgeafioré Criiisaier usinyscit wanes? ii) sf wp CO ydus Gyaiygsi Z1O ai QGSs, Finds OGSGH srgou? ag? gi? (a1) b) Gurcinfud mr @eyr@ot sums sna aondes. a) i) Mention the characteristics of interhalogen compounds. ii) Out of Coke and CO, which is the better reducing agent for the reductio (or) 7 b) Describe the preparation of Potassium dichromate, a) i) AICH age Bansoiysstoniouyen. wis ayansd TIC: Aenwtiygsscromowuiog! gsi? ii) © Goons eniuenarsaficd stomlLGD oamiuds setomouionen Aen es- (2196) a 1s Lond ceypTed ctoton? |S TTOMD FHS. guLsgicen ‘“f smi oustiessnsn aonb ee. here as TICI is highly unstable. Why? mn. of ZnO? Why? b) i) prGenr aslenant ii) Qgeffeuran cus a) i) AICh is more stable w ii) Explain the bonding nature in metal carbonyls. (or) a) i) What is Nano catalysis? Give example. «f centers with a neat diagram. quanes sfeoarberon OpTOSLUGSEUUCL Floste. asi. OL. SADE. (oso) wo pOH &6 Beorulooron Omens agai. LAUISGss sogspe GuGss wALY — stsveury i) Explain a) i) 9G we i ii) ystot GoopuTGsafia svensum b) i) pH wba : ii) Goreomt sor poe piremusebe5GSDE?a) i) Derive integrated rate law for a first order reaction. ii) Outline the classification of point defects. (or) b) i) Derive the relationship between pH and pOH. ii) How solubility product is determined from molar solubility? 37. a) i) sree aybARConimd wipnd ovantLot Guemosi ailenen ups SAL senga. i) DLS MoOsSAG bs sMLQs sory wow sere |BanronyG cso! SUMMA UGHog!? (SIs) b)i) SNIGsAMer auf WdAUABIEOMSS soOIB. ii) Qo1ss Gasreptuona (TFM) wSiy UGH GLY ousnyes. a) i) Write note on Swern oxidation and Schotten - Baumann reaction. it) How will you prepare acetic anhydride and acetyl chloride from CH;COOH? (or) b) i) Mention the biological importance of Lipids. ii) Write a note on TFM value. 38. a) i) @Guwuisr (monomer) Gspameng 0.05 mol L* sys asin Bouy (dimer) LGamsb Dyswimbd sums eSlenswuet alemenGarstbd 7.5 x 10° mol L's". eSlenenGars wongfleSuilensnds earings. ii) Usted aHenonenu YidA Gout. : Mg- H, () CH-CH= ow oe? () CH;COCH, =o 2 Hy - (o19g)) b) C3Ha(A) arsine Boi Hg” / H:SO, S8yimweigg) Csi (B) GanGsane. (B) S@ummutind CongeensG 2 LuGib. Csi (B) syeng) NH — NHp / CoHsONa Dot aflnon YAbg! sopmlCsraninusy (C) ad swag. 61g NOH apeieansouded (B) aysg) HCHO 2 Lei aflnomi@ Goi (D) gs sEXps. A,B,C wim D wp SoRIGUig. alenousensn stapes. a) i) The rate of formation of dimer in a second order reaction is 7.5 x 10° mol L" s" at 0.05 mol L"' monomer concentration. Calculate the rate constant. ii) Complete the reaction 0. Mg- Hg @ CH,-CH=C-cH,; OS 2 wy CH,COCH; Fg du (ii) 20/0. 5 ? b) An organic compound C3H,(A) on hydration with Hg”* / H;SOy gives compound (B) which gives positive iodoform test. Compound (B) heated with NH; — NH; / (C2HsONa to give hydrocarbon (C). (B) also treated with HCHO in the presence of dil NaOH gives compound (D). Identify A, B, C and D. Write the chemical reactions involved.wonghifi slemggsrot LIL / Model question paper II Coadrgienn Qyainmbd sy6i6 / Higher Secondary Second Year Gaufuiwsd - Chemistry (qyiiBootd wipud sup / English & Tamil Version) sro Sion8| : 15 PisLetiesstt + 3,00 wonll Guo wAIGussiresstt : 70 Time Allowed : 15 minutes + 3.00 hrs Maximum Marks : 70 opansss : 1. Sores a1 Soméseni sumac uBewnA 2 ciongsn sienigancn afuningbe Gansionoid. — @iestUuGad Ganpudgcniir HBrHCI>HF 9) HF>HCI>HBr>HI ) HCl>HF>HBr>HI #) HI>HCI>HF>HBr The correct order of thermal stability of hydrogen halides is a) HI>HBr>HCI>HF b) HF>HCI>HBr>HI ©) HC>HF>HBPHI d) HISHCI>HF>HBr 2 [Ni(C20,)3]* - acy oimamays BsinosBHed Nici ssw xi a) 3 ah) 6 9) 4 w) 2 Co-ordination number of Ni in [Ni (C20,)3]* - is a)3 b)6 °) 4 a2 CH 3. HsC-CH-CH-CH-CHy-OH - asin Gainoger affumen IUPAC — Guuit cl CHs O) 4-GGontGyn-2,3-m_GwsHPHled Giusincit-l-aysd 2) 2,3-coL.GwssHed-4-GGonnByr Guusiteoit-1-zysd D) 23,4-LenjOwdgHed-4-eGonnGyr TuyLeit-l-xyed *) 4 @ConnByn-2,3,4C engGuogsgAed Guisisi-l-apsdx The correct IUPAC name of the compound , CBs HyC-CH-CH-CH-CHy-OH ClCH a) 4-Chloro-2,3-di methylpentan-1-01 __b) 2,3-di methyl-4-chloropentan-1-o1 ©) 2,3,4- tri methyl-4-chlorobutan-I-o1 __d) 4-chloro-2,3,4-tri methyl pentan-I-ol . 2202 ——> 2H20+0) stony lenemuded gq GUHUILL Corder, DOL Seis 486 Oz LGardpgH asied os CoysHod Gt eGargeb Caw Cored Gori" sivdler) =) 1 a2 Q)3 a) 4 During the decomposition of H:O2 (2H202 ——» 2H30 + 02). 48g of O2 is formed per Minute at particular instant. The rate of formation of water at this instant in mol min” is a)1 b)2 3 4 MungBL wighedbaror aiongwogpuTengy 2) 9G srs grat GubAGs Gb Kensisno 2) 6.2210" sors pretest CUDHGSSb Weirsenw B) 96 Gwred Coiodongs ugusOsi CSeraumer GeireenD F) 9G Cored ss grees GuBHGsSwb Woraenw Faradays Constant is defined as a) Charge carried by one electron b) Charge carried by 6.2210" electrons c) Charge required to deposit one mole of substance 4d) Charge carried by one mole of electrons. . Nat owe wigid Cl oueiscic: owe aymasit (popu 95 pm wignb 181pm. safc) Na* sweifuiet sjenemey stort o) 4 a) 6 @)8 #3 u The radius of Na* ion is 95pm and CI ion 181 pm. The co-ordination number of Na’ is a4 b) 6 8 d) 3 . OpLErIUEETed CSTE 2CUGb Bsiowbd CHs t 2) CéHsCHO &) CHy¢-NO; CHs @) CoHsCH2NO F) Bona sinensgubd Nef carbonyl synthesis given by CH; a) CéHgCHO b) CHs-¢-NO, . a c) CeHsCHNOz d) All of these . Geteugid os Swefluler © ty Garston Pmapen.uigh? 2) Ca a) Cr @) Co* ». ) v* Which of the following ions of salt is white in colour? * j a) Cd* b) Cu* °c) Co* dvsroucpouonouiyed 1g erinBsieiomoujerus aaypuoir? ir lai e “ \ 2) aytdiaiés eedooug 28) Guiles mame groo5G Q) axiBiore onion ®) ey smut Which one of the following is negatively charged colloid? a) arsenic sulphide ' b) Ferric hydroxi ¢) Haemoglobin I betas 4) Basic dyes PD : LITT SACLONE wind sysdiiflen syHuena ag Blorngonessit sagem + UNIT SWALLions> wood aysiiich xyuena1 smows ppld4 wainLeojong gree SLOUGSSUUCL wp Welt Carwsdrypenpuisd 2_omiroipseassGaiseiynen, 2s) Sib! ‘ogpopulb Srjombd QroiGwb sf siyombd apmdaron shuren MendswTeo. B) FAHD Wp Smyamid BysiGwb sf snysmd supprsssnon eifusron aflanéssosooo 9) Hbo sf sons enyemd soup F) soH Upp sryomb OyoiGibd sau. Assertion : Paracetamol and aspirin are both antipyretics. Reason: Both paracetamol and aspirin are controlled and reversible loss of concionsness by affecting central nervous system a) Both assertion and reason are true and Reason is correct explanation for Assertion b) Both assertion and reason are true and Reason is not correct explanation for Assertion c) Assertion is tue but reason is false. d) Both Assertion and Reason are false. WdEaTUEdLQ SBS Parodi soi Gsroi ssriuaisr yeaydpIErL sugoutd 21) speugtb 24) aysdoot snessit DEOL. a) ppr@omr Gipmitiesit Thermodymanically the most stable allotropic form of carbon is pate a) Diamond b) Fullerenes c) graphite d) Nano tubes £0p GarGssucLoasensr abs osm GOSHrE sibsns? 2) GOSCarord Qh) KSEpTad wredG_ierd F) eoré&@Lirerd Which one given below is a non reducing sugar? a) glucose b) sucrose c) maltose d) lactose Gar auqavenoniyfied org -afusres GuuTeybesaisvono ©) Liroosit esnyeni - ° AgNO3 + NH,OH : ‘24 Gusdess songs - CUSO«+ GynGesrBor 2M Q) Quafigs sengscd — ~ “CuSO, + Gemguid ALG + NaOH fF) Guus anyon ~ gitHCl+ sop ZnCh Which one of the following is incorrectly matched? a) Tollen’s Reagent = “AgNO; + NH,OH b) Fehlings solution = , CuSO4+ Rochelle salt ©) Benedict’s solution - CuSO, + Sodium citrate + NaOH d) Baeyer’s Reagent -:, Con HCl+ anhydrous ZnCl curginires econ Brevis pions (6K youd SLNissinGsins. oiselordsres Scio args seiolB TEs GOXBlsCGAI5-> Yyapuld SLiiéstuGspe? ‘op witGegeinit §—-Q) SeSan @) salut snusopt ) ad@Levent.20. 21 22. 23. 24, Sulphide ores of metals are usually concentrated by froath floatation process. Which one of the following sulphide ore offers an exception and is concentrated by chemical leaching. a) Argentite b) galena ©) Copper pyrites d) Sphalerite Ag(CrO,) stain Bsns Aoi sony Sinsn CugsosSinow (Ksp) Cronsorir sony Amst | (S) Ber Cuter Qgreiny 2) Ksp=s? 23) Ksp=S? @) Ksp=4s? ®) Ksp=3S? The relationship between the solubility product (Ksp) and molar solubility (S) for Ags (CrO,) is, a) Ksp=s? b) Ksp=s? c) Ksp=4s* d) Ksp=3S? uggs — I/ Part-II 6x2=] Se5abd AO AemsHHSG eoruciss. flea cio 24 SG wLmuoTs aAan_wafiasayd. UTELITEsD BuTE smBLFeQe GusiLT CamonaGasnan 2 GemdGeusedroner oes? Nitrogen does not form any penta halides like phosphorus. why? BorHinng scfhowssr wrpUudir denon Poasmwu GuisiGuusseh? Why transition elements shows variable Oxidation state? [Co(NHs)sCI]SOs wp [COCNHs)sSOs]Cl-eg CapuGsiuiuyd 90 Cansensnenus e195 16. Give one test to differentiate [Co(NHs)sCI]SO4 and [Co(NHs)sSO,]Cl Gurg) Suef senso sisipred acter? Go egIFEMbd Cong What is common ion effect? Give an example ! Answer any six questions. Question No. 24 is compulsory. Soi srs AIG mbit s6dBuLan GanGéatulrgy. Fane, = 0.34V wig E°, dys. Soraied CrOSE onords ug? 0.44V FEF, Is it possible to store copper sulphate in an iron vessel for a long time? Given E,,.,.=0.34V and B°,..,, =-0.44V YEU cine clonsmiar sienyopa| radars sombsGa Calculate the half-life period of zero order reaction, oo aged agsMet uussiassh proiBene sales, Give four uses of diethyl ether. Simaiichc soNLLit Sue (QGupsnss SwWahl) Semwleu HHB. Write the Zwitter ion structure of alanine, 2 oma User) GuuTELasir eteiLienAY witeneu? What are food preservatives?2%. BY 2». a 34, UGH ~ UW) Part — 10 gem AM Momsen, atonrwatan, aa_wahaayto. Shemt seri 33 ie) at.LmuTE Answer any six questions, Question No is compulsory, As) UNI (i) ommidsassd Gi) aNDeFsdaoT apIAdsd nme Define the followin (i) Roasting (i) Caleinatios Lagi CHTSHGO doopmu urs FrsPiny onze. Write a note on Fisher Tropsch synthesis [Ti(H20)6}"* -89 CpsmLuss! ayers [Sc(H:O)6]* Bonnar aan. [Ti(H:0)q]** -is coloured while [Sc¢t DoJ" is colourless. Explain Spas. GenwurLigsnsn ofiondysa Explain Frenkel defect. Cagsrwtapniad Ws ByCar xiBsa, sasiyyrsd orion’ What do you mean by Helmholtz electrical double layer? simon Cangsionen Snort GO uly asiusyanan DHUSHIDHL oT oases. Explain the rate determining step with an example WOwAAH AVG aMsFsi1-2-4sd stsiogy AfdertG® srypentuir How will you prepare copa Surname? d reagent? ethyl hexan-2-01 form g SMUny sings: oni siinon. Write note on Etard reaction. CNC] apn oumiutGeow wfwsGrneid (A) Cw Fo GwisiFumd yByrarie simenyibsy Grit B— (CN) QS sotina Bays: oioraan iorghurd gas wapar Geis C — (CiHsN) @ saspar C-nrtanus asics Gain A.B wpm C-sud soit yibar aonssomm stupa An Organic compound (A) ~ CNCI react with methyl magnesium Bromide to give compot B —(CsHyN), B-upon catalytic reduction to give compound C ~ ( test. Identify compound A. B and C and write the reactions. oh afenasg a CUGayD nl “sH-N). C gives carbylamine ug IV / Partly 5x5=25 Apsangpid RenrsaHapse oMoncworlesaeyo: Answer the following, questions. A) ampssrniihsonmup nsgarisGamanay glntGa Caos ay) 2b) i) Arya uussirassir Hyssingons aysiu Be. ii) Bowby woud oniust 9 Cyst wr oubBwnr a) Compare lanthanoids and Actionoids. (OR) uinaAsit aoe usta? a) i) Mention any two uses of Zine ii) What is the reaction of Ammonia with [ron and copper salts?35. 8) i) bs Stmemeys Csitomash tsi? ii) GumLnad ugesnyid atcieurgy SuMASsUUGApgHi ' (oreds0gi) Bi) Gubius upiy sorsA, Couuiusd ugiy sass Capos ii) O51 cimatas wnins Sie BG esnsomd 565 a) i) Whatare inert and labile complexes? ii) How is potash Alum prepared? bord Bemus sismas Caines areigprey (OR) , a) i) Differentiate physisorption and chemisorption. ii) Give two examples for enzyme catalysis. 36. 8) i) Bun a seSmst wig Gwrott s.soSnre umgjwpids. sino sions Qgm_iny GasrooirGsirnen? ii) Srevemnahé Mereovmiseried RUYywiToPsSHeHt ue stein? (a16d0g)) 2%) i) SwafiugariscMer ussnysot wens? ii) gm slots Bsrstansonus Lip GALL avsnges a) i) Define molar conductance and specific conductance How they are related? ii) What is the role of salt bridge in Galvanic cell? : (OR) b) i) What are the characteristics of Ionic solids? une ii) Write note on Lewis concepts of Acids and Bases. : 37. 8) i) adsontaeng) oe ceoaas womiyh cpsiainsoule Sraewy Meneses 2 ule RSSaer FGI olensmist afloner aiGupsomenu spss. ii) Usieugi ofensmuded alonar Gurwsit X wip A-smu worn ge. CH3MgBr Suse SILO ECenrej§ ———>+ X——+A 130° K2Cr,07 (a1s060g5)) ) i) Bopupswest wip Como womans Gor Guus CouurGsci usmenau? ii) vobsrés stot omTuUp. Asi wobser uTgEniL seireniow|n steven Osr_MyUGSSUUGAS!? a) i) Write the mechanism of acid catalysed dehydration of ethanol to give'ethane. ii) What will be the product (X and A) for the following reaction? CHyMgBr _ acidic Acetyl chloride ————+ X ——_+A 30° K2Cr07 (OR) a) i) What is the difference between fibrous protein and globular protein? ii) Define the term therapeutic index. How is it related to the safety of the drug?38. 2) i) A,Buosmb C-ow sane 941 2) i) 29C-sd Dimatoor Fr s9860 Corot a a) a) HO OH Y SOCh, , Nik, gp Lidl ¢ °o ° if) SALCLasr qsesonw yersYEReyT GuTTéS DIL sUerbd GaroriG RbACapM Osigred sisiion Paw? (arsoovgy) AAAs vg uyssta Bobs OALigd Suess A °CH;COOH-ms somsdGa denies NaCi_[HCI__| CHsCOONa A (Som? mot) | 126.5 | 426.2 91.0 ii) eflwsGefin CzHO (A) — Lrevetod wpgid usin senyror BansenonsG PLuUGAS? Camowb (A) ussarre wip HClect ailensr fle Cain (B) CaHO2 -22 soaps. Bs (A) Cwdsenau_or Gis NaOH cpsiarflensvused silnsmyfibas Gono (C) — CsH,0. —mai GanGsdpa. soils) Gries A, B wobpwd C-w soon ibs Lonsnsensn sigs. i) Identity A,B and'C HQ OH Swe soch, 4, NH, p Lidl ¢ ° ° ii) What happens when acetoncoxime on oxidation with triflouroperoxy acetic acid? (OR) i) Calculate» A° CHyCOOH using appropriate molar conductance of the electrolytes listed below at infinite dilution at 25% Electrolyte [NaCl [HCI | CHsCOONa ° (Sem? mol") 126.5 426.2 ae ii) An Organic Compound (A)-C2H,0 reduces Tollen’s and febling’s solution, A-react with methanol and HCI to give compound (B) ~ CsH1qO2. A-on reaction with Methanal in the presence of dilute NaOH to give compound (C) ~ C3H¢O2. Identify Compounds A, Band C with necessary reactions.tongéifl silemzsgnett V / Model question paper V BwsrpHens Oyeinmd song / Higher Secondary Second Year SID Sierra} : Time Allowed : OuBmyeoyast : Instructions : @miy : Note : @gmoy : Note : GougSuuisd - Chemistry (ayiiBloo widgnb gH) / English & Tamil Version) 15 PiALmesit + 3.00 won QwIss wHUCueHas : 79 15 minutes + 3.00 hrs Maximum Marks : 79 |, Simao Memdsenb shunt ulema o sions stehugenss sfuninsgds Ganctonyb. —» SF aLUBeied GoplGuier sieonps serivsnenhwmeniAid SLemgumag Asifledsoyb. 2. Bevid (16d60g)) eGuy emouienen tot Gio AYBIAUBDED SMHACSMGABHGI LsiiGss CossiGib. urmssit ovsogousye used UWSUBSSAd. + Check the question paper for faimess of printing. If there is any lack of fairness, inform the Hall supervisor immediately. 2. Use Blue (or) Black ink to write and underline use pencil to draw diagrams. SSemouiTor DSBs uvwd sings swsiunGsadar stapsayd. Draw diagrams and write equations wherever necessary ugg - 1/Part-1 15x1=15 1. Sines) cemdcepdeid oenrwetiéeseyid . OSIGSGIUCL BISIG ooraaiisr Vsoyd ghYLW HoLous CsTASoAE: SMU Gret clemulonsmuyd Cstday sways. . Answer all the questions . Choose the most suitable answer from the given four alternatives and write the Ne option code and the corresponding answer 1. GanGseuuLL elenswuded [Y] orinsgy H2SO4 (NaOH 2 Ges CoHsOH 9=——> x) —_—— ™ 10°C (passin di) H Alanon Guunpsit OH OH OH OH “QO 207% 9) °& In the given equation HySO4 (i) NaOH fasion CoHsOH ——> [X] ———> vis OH : Q 110°C Major Product ~— (ii) H OH OH OH on ») cy ae ° C d) Cr ft2. srg cfensraciied aed yur snus — anus - oi) Basnovis oilenen BS) Lidija chen MM @Gauresatedenes? 8) QdLTed Gossow ®) UfLS) pn. te ‘ D ' mf In which of ‘the following Teactions new carbon — carbo bond i fc 1? a) Kolbe’s reaction b) Wolf kishner reduction eS c) Aldol condensation ¢) Friedel craft reaction 3 Usagi Crnomasficd ois Qeig cue Beis snd? oN S Ha Hy l a 2) l % Ni 8) Q ®) G Which one of the following compound is a strong base? q ae b) °) ( CHy NH, 1CHy 4) Os 4. oappr : DNA apmdaniiicr engifler Gonam, signers 9 1 gb mst Onder Qarom Garronsrsn 2L gpd Benomiaysirongy. eri DyaiG sy Aeopsewsdon Cu o sion mame gegen Venwwiny sryomuomes So) HD wg snyamd OysiGbd sf Cogud sryamb, swiVieron sifusnon allonSeuor@1b. a) apg wpprd aenyomd QyoiGd sf, syne snyembd sapPibane susan ailendbestnads0. B) sq Ff ayes enyomd soupy. ) SD GH spam ByoiGid soup, Assertion : Thymine pairs with Adenine wheareas Cytosine pairs with Guanine in DNA molecule. Reason : The hydrogen bonding between bases of two strands is highly specific. a) Both assertion and reason are true and reason is the correct explanation of assertion. b) Both assertion and reason are true but reason is not the correct explanation of assertion. c) Assertion is true and reason is false. d) Both assertion and reason are false. 5. Usragacopgusit abs QerD wSEid UU 8) PGA 24) | DBSVTBHT-6 @) PVC #) HDPE Which one of the following is a bio-degradable polymer? a) PGA b) Nylon-6 ,c) PVC d) HDPE 6 200K-s> @@ aflenenuicr ailensnBous wrgeduien we tiumengi, 400 Kb siren ailsnsalBeaes wghoSuies w~iie oH. 10 WLI GMa, stale yy afonenudo onitoy [OH] b) [H30°])<[OH] ©) [Hs0"] = [OH] @ [H:0°] < [0] Buijosuied anand foore QowUpHs, srgemnb 2) snlpwosgiscisoriet Weiapmans soured i 24) UGgenafwis alenanay ' @) wormed aenotey FR) uTewedengo} The blue colour of the sky in nature is due to : a) Electrophoresis of sol particles b) Brownian movement c) Tyndall effect 4) Deemulsification . 2 Care Gopuystion GOpPUTG sromuuGid wget : &) NaCl @) KCl @) ZnO ft) FeO The crystal with a metal deficiency defect is : a) NaCl b) KCl ©) ZnO d) FeO Usrargasneuigisn sg gion Woitssvb o) GordaomesGa sirsarsit 2) HS Sund - owe WeiBedUuydsaorsi @) ungss ULLet WetBeliyssovsit %) (#) ip @) ByowiGw af Which of the following is Secondary Cell? a) Laclanche cell b) Lithium ion battery ©) Mercury button cell 4) both (a) and (c) ; picts GAG Gor poms saiwwsais (Cr, Mn, Fe & Co) +2 asFegGonip Bansouien Blonavcnygs ssivonw auflns [kapisrest: Cr (24), Mn (25), Fe(26) wibipub, Co (27)] 9) Fe>Mn>Co>Cr 24) Co>Mn>Fe>Cr fe @) Cr>Mn>Co>Fe ®) Mn>Fe>Cr>Co For the four successive transition elements (Cr,Mn, Fe & Co) the stability of +2 oxidation state will be there in which of the following order? x a) Fe>Mn>Co>Cr b) Co>Mn>Fe>Cr ec) Cr>Mn>Co>Fe_d). Mn>Fe>Cr>Co stargamarpen og) unst anid sehen Cupsrongy? ) [Zn (NH3)4}* £4) [CO (NH:)I* — @) [Ni(H20)]**_m), [Ni (CN)* Which of the following paramagnetic in nature? i a) [Zn (NH3)4J** b) [CO (NHs)e]* —c) [Ni (H20)6]** d) [Ni(CN)* Usiegid H3BO3 upp sapped seuprongy ogi? 2) BS! 9G asdow JG Wonder oudorid 2%) BSI Gungrdoie Frdsojsmn QUlUGs) sunfldstugaper:, B) BB BOs smgasI Mancyensr eraiians UrondstiulG 6&6 SimwwUienud CesrosiGsirongy. *) Bai YOITLLiso apiigagses users samt greberded Doe esos lan Col amd suewre AswsuGdlngy. are eT ae oesWhich of the following statement about H3BOs is not correct? a)Itisastrongtribasicacid. =, 5 b) It is prepared by acidifying an aqueous solution of borax. c) Itis a layer structure in which planer BOs units are joined by hydrogen bonds. d) It does not act as proton donor but acts as a Lewis acid by accepting hydroxyl ion. UstaGacrayppst Cxpod sew agi? 2) Ha 8203 Q)) Hz S2 O7 ®) H:SOs_— #) HySO3 Which of the following is caro’s acid? a) Hz S:0g b) Hy S207 c) HySOs d) HySO3 SMIOWUTSGSOO GPUIGH olenemunongs ous apsp? Ti Gmbowuysps) +21, SOK, Til, 1800K, Ti (gw) + 21, 8) YLUGSsd 2) Wowie asHefioy aunsit - syrecdapay 8)’ wrain_apanp Which method of purification represented by the equation? Ti (impure) + 2h SSOK, Til, 1800K Ti (Pure) + 2 a) Cupellation b) Zone refining c) Van ~ Arkel method 4) Mond’s process. uggs - Il/ Part-I _ OX2=12 Stem ao Hemése5d6 couche. lem ask 24 se LL muons aen_wotsaay. Answer any six questions. Question No. 24 is compulsory. Crouse siolenso crsinptsd cisiten? What is water gas equilibrium? @Bsret (Os) GG adonnuter qdFeGonbmnd anyone gait? Ozone (03) act as a powerful oxidizing agent why? Usiagid silnonsenon iss Gaus. i) 2MnO; +4KOH+O2 ——> 4i)"Cr OF + 14H" + 6 > 20. 2. 22. Complete the following reactions. i) 2MnO2+4KOH+O._ ——> ii) Cr, O° + 14H" + OF — Bier SwchiCuGesb suemjwg Define ionic product of water. emomtsegs! FdOUGB aun Missi sbomwG sonyosd ouflurs CsadsudCurg aise Baugh? Bad) apmguion Cuusfinsn GALIGS. What happens when hydrogen sulphide gas is passed through a solution of arsenic oxide? ‘Name the chemical method. Lysmiscter Guodpsssd uixh GLY ouonpes, Write a note on denaturation of proteins. Cues choy SUT sUGAng? How is terylene prepared?Gorangh Crnows ai IUPAC Guuitaona supa. (i) CoHs-O-CHs-CH-CHy (ii) Cy =CH-CHy-CH;OH cus (ii) BEuT Groitsm.cd sysd-npy1a iv) ahaflayast Write the IUPAC name of the following compounds. (i) Cobls-O-CH-CH-CH (i) Clly = B. Plot of concentration of A V. 4 s time is given in the graph below, Answer the following questions on the by xIsis of this graph, 1Alt (1) What is the order of the reaction? oe (1) What is the stope of the curve? 7 tS (ii) What is the unit of rate constant?35. CH;NO. amniumyne ByjaiG wii i i nD wea GaguGsaveunts? Buriat There are two isomers with the formul Dsitimar Qeralyasnruy — stoiounBl la CHsNO How will zl i as you distinguish between them? aspame opp Umndamm Camus omy Cxnpenanash ware? What are the tests to differentiate ethanol and phenols? oe (A) stapitd ciel Gaiwid —(CaHsBr) gg matt eayfled stoniye Me oe MaatuGdeurGurgs Coton (By Som bs 5 gs os 8 aaa ° : Hom bs Dv. BICainwsang ae 5 DUAeOLUGH UGG! Cxiwid (C) Bomdngy assed vd (By COz ateit sfionoasG is Amato TUPI. Loud (C) ab sor Obs! An organi¢ Compound CsHgBr (A) on treatment with Mg in dry ether gives (B) which on treatment with CO; followed by acidification gives (C). Identify (A), (B) & (C) and write possible equations. i : . uggs -IV / Part-1V 5*5=25 Assad AoamrssoGSG Me_wuciisaoyd: : Answer the following questions. a) i) anti DUMILY GH! SILO UNOSSSSw wmpau sions ii) Aadamy DetaniussHsd apsnpullsd gmllmwurdssno saul : : (21600085) b) i) aub-wiGunedsst arsinynsd asian? a_gazomid: Gas ii) Ustagbd Catomaatcd sotcunons Qordsvtry por Gupéiper? 2) BrFs @y) IFy a) i) Explain extraction of copper from copper pyrites. ii) Explain electrolytic refining of silver. (OR) a) i) What are amphiboles? Give example. ii) What type of hybridization occurs in the following compounds a) BrFs b) IF> a)i) Cr? aSempusrar QGbBAuine 2stionBungs Mn** avSenn.uro aydbFlegBonifusmes a.stangy gar? aloes ii) Bansotiybgsciton0, wngod ASG! WTB? ABs PSBUSHUMS AOI (.Q1ed50HI) jongeumpasraiid — sisofusp. —Upssdasna anand Stensounp b) i) 9@ — aflananuiiat gaos GsGonal GLIGSS! slomoaugsdenso Bracorarg) alearuG GuTGatiait aauengd sm Gs. ji) a tater SomBUEb. a) i) Explain why Cr’ ii) What is stability constan 2) wri 6 xpFeuoy otoitenr? while Mn**is strongly oxidizi ignificance. (OR) jod of reaction, Show that for a first order rea Mention its tion half life period is b) i) Define half life p independent of initial concent ii) What do you mean by salt hydrolysis? a) i) BCL mawcyagdi Warypenar (SHE) uf aad DC ation. gh sa I. aiCani pws users AC ii) Manigetds ardardBusr srenell PeirGarn.Lib UWAIUGSAUUGS BS (21s0RH)) 551?b)i) Daiupmonds soréA up Gp avenge. ii) GurdiaysDmss sreingasd stcion? a) i) Write a note on standard hydrogen electrode (SHE)? ii) Why is AC current used instead.of DC in measuring the electrolytic conductance? (OR) 4 a) i) Write a note on electrophoresis. ii) What is packing efficiency? 37. a) i) pemiectficr Wpssdfeow, Byoimbpes wppnd cpspmdpms siemoiy ub sons Gs. i) Usagi nip sian HapPssiuGspg? Gawdad -4- retanpe flor— Camsad - 4- Rene. (crsboogs) aa b)i) Conijast wim grigain Gace supe PSS Aswerumcys uPupsmsow ailondvGa5. i) Using wnbpwssH sciong HapssiuGsog1? (&) Gusitésit —p Fi. CLt. Bourn (CY) GusienstigenG —» snanceyr Cusirsen0G a) i) Explain primary, secondary and tertiary structure of proteins. ii) How is the following conversion affected? hex — 4 ~ enitrile—> hex ~ 4 — enal (oR) a) i) Explain the mechanism of cleaning action of soaps and detergents. ii) How are the following conversions effected? (X) Benzene— acetophenone (Y) Benzaldehyde —> hydrobenzamide. 38.) i) HCN-st Ka win) 10? sraficy O.4M HCN aséngeoden pH weSiny sieién? (@isbovgy) »)i) eByrGocys smpLGyr Esto (A) SWHC] eich g@sswerfe Csi (B) CoN mb GanGéaipg. Grn (B) Gustemudoy @BorTengGLait Lifiged Gatohcronie sHereruGss Cswb (C) mb GanGsApg. Gs (B) eysras CHsBr ator simontuGss Cain (D) gun, sysereng Ggainbgs NaNOs/HCl Pts cheneniudss webssr Soup aaiGams Guneiny Pyaxypsoius Geno (E) wb Gans sally (A) upsed (E) ous sion Gsinorveenond Sori Bibs! oSlonsrssnon STIPE. a) i) The Ka value of HCN is 10°. What is the pH of 0.4M HCN solution? (OR) b) An aromatic nitro compound (A) on reduction with Sn/HCI gives compound (B) CsH;N. which on treatment with Benzoyl chloride in the presence of pyridine to give compound (C). Compound (B) on treatment with CHsBr to give compound (D) which further reacts with NaNO,/HCI to give compound (E) with yellow oil liquid. Identify (A) to (E) and write the reactions, :grou wlomoy : 15 pGUBLLeSH + 3.00 won Time Allowed : 15 minutes + 3.00 hrs worghifl alennggnct VI / Model question paper VI Coeds OQyoinmbd sys / Higher Secondary Second Year GougGulused.--Chemistry (ayisBloo wind gidip. / English & Tamil Version) Quon wxALGLeciresctt : 70 opianyast : 1. Sincigg1 comdaenbd sfusrat ugleural |_songs siitLgsnon stunt aI Garston. —- HEGLUPaled GenpulGivier sions — seritesnoniiLursronfi te DLemgunsg Ogiflaldaop. 2. farbd (dog!) sGiLy mules VLG THBAGIGo oystangGuspSe UULSUGSS CousiGid. urmessir cumgoge Cuusidied uusssuGssou. Instructions : 1. Check the question paper for fairness of printing. If there is any lack of fairness, inform the Hall supervisor immediately. 2. Use Blue (or) Black ink to write and underline use pencil to draw diagrams. SPLY: Sserouner BSS urw susngisgi swotismGaonn stapsoyd. Note : Draw diagrams and write equations wherever necessary uggi — I/ Part-I 1sx1=15 SMU: 1. Sena Hors sensGi oeorwsisayd 2, Geis prs Bonraocd Wasoyd —sybysmtus leno CsIOSGSH! SHU Got cfeorulonomyd Case TUBE. Note : 1. Answer all the questions 2, Choose the most suitable answer from the given four alternatives and write the option code and the corresponding answer 1 Usiagasreyspisr ag oupror ono? ©) LaOH)s ayarg1 Lu(OH), mi amt ygd Gaparten angio 2eLwgi 24) eSNG aufinguie Ln quaiiscicr owe syoHiy Gopeips. @) La gongs onbsonniG pried ection sail sting ol arog, af. a) arpsamlG epsasder olmorars Zr who Hf gb sep yy wxsLvTenonts Guppgysitenes. Life soft Which one of the following is not correct? a) La(OH)s is less basic than Lu (OH); ) In Lanthanoid series ionic radius of Ln** ion decreases c) La is actually an element of transition metal series rather than lanthanoid series. 4) Atomic radii of Zr and Hf are same because of lanthanoid contraction. 2. Vsiagid sionals Csiowscied orbs goin YsAU LYSLIYO Penovdiyssiiencoom 1 (CFSE) ant. Geings? 2) [Mn(H,0);3]**" 28) [Fe(H20).*" — @) [Co(H0)<* ) [Co(H2O)}” Maximum Marks : 70Among the following complexes, which one shows Zero Crystal field stabilization energy (CFSE) is . a) [Mn(H,0)3}** b) [Fe(Hs0).]** ©) [Co(Hz0).]** d) [Co(H20)s]** HOD Siemens Coho sianentsvre wong ups, 2) aMsHd 2) 2 GbE GB) suQGsaId The process of converting hydrated aluminia into anhydrous alumina is called. a) Roasting b) Smelting c) Auto-reduction _d) Calcination BF; @ GMbUGSsH Gunhs olor Horadog. Toit yox@sr Gunfls snHeow0re LOMBBLUGHGS!. YABRyT Cum ones Hie 2sitononay o) H*,F & BF; 2) H &[BFy 2) (HBF]°& Fo) H*, BY &F On hydrolysis BF; gives Boric acid and converted to fluroboric acid. The fluoroboric acid ) @rpMedroors Gpedod oumidsssd contains the species. a) H’,F & BF; b) H &[BFy c) [HBRJ*&F od) HY, BY & UsioGbd ovlermsaied orbs oularjsSed O-O Genaminy 2 sitongy 2) H;SO3 24) H2S:0¢ B)H2S203 #) H2S4O¢ The acid having O-O bond in its structure a) H2SO3 b) H2S206 c) H2S203 — d) -HzSyOe OpGBaH GuIgbs Caromiasfist ciritenidens ‘n’ stofled pretupsél gioneneerflatr sissitemersbe sire DoHcwugs. o) n 2) 2n @) 2° ®) 3n The number of close packed spheres is ‘n’. The number of tetrahedral voids generated is equal to an b) 2n : ©) 2n? d) 3n 2A+2B ——> C+2D asin sHlenondse, aenaxGars afig6 aision? B-si Gaghenar woniyymosd A- s1 Bega} ByooiG wimg ewinbsuiGung1, osnsnicr Cousionengy preiie worms, Ciogud Ad Gaylnai wibpnosd Bot Gaxiey ByoiG woven © wirdsnd Cures aAemsmuist Corsi Qowr masnrsys. ©) Coretd =k[A][B]* 4) Gastd = kLA][B] @) Gasid =k{A] 4 [BP ®) Goad =k[A}[B] What is the rate law of the reaction 2A+2B—* C+2D If the concentration of A is doubled at Constant [B] the rate of the reaction increases by factor 4. If the concentration of B is doubled at constant [A], the rate is doubled, a) Rate =k{A][B?? b) Rate =k[A][B] c) Rate =k{A] “(By d) Rate = k[A?[B] W/O unsvwxgsang O/W unsbwniores wong Gsussd aperurangy 2S) AfbguTssd 2) UTeWIDTEcd B) Amsouemrgsoo ®) Benevenw Cpinorimd The change of W/O emulsion in to OvW emulsion is Called a) Coagulation b) Emulsification ©) Decomposition _d) Inversion of phase9. auras Wsiasvgena, Gung youre; SHUIGaay 2) SALUTES / espe / Wewsayat | LPeSUpENE | eyéFagonrdyh 2B) BbAConpH / Bsiyparen | VDsLIESN / eiapsnen / afoungst B) aMuMEst / estapsman / Deiniayat / Baiupanen / | Gao 5) QdAegGono / etapsrn / Bes OM / Wohapensn | opis The general representation ofa fuel cell is a) Fuel / Electrode / Electrolyte / Electrode / Oxi b) Oxidant / Electrode / Electrolyte / Electrode / ©) Fuel / Electrode / Electrolyte / Electrode / Reductant d) Oxidant / Electrode / Electrolyte / Electrod 10. Gsmgui siLeLL, fant Fuel le / Reductant SudGonsiiu — gBanrengG, Gsmgund empLyc. sGieaenyersdossin ? wonptu 2) HGH. suds. say 2) aude, aig, BEPoMAssIen0 9) sry, aude, Besser ) any, awed, wry The aqueous solution sodium acetate, amomonium chloride, sodium nitrate are respectively % a) Neutral, acidic, basic b) acidic, basic, neutral ) basic, acidic, neutral 4) basic, acidic, basic Ustagasioaybpish sg alonen Fd s50n9 GaIGSGwb? 1) CxHsONa + C2 Hs Br —> @LtH2SO, a) CH\CH;0H “413K HBF, @) CHs CH; OH + CH, N: ~A” : F) Ghai slenenggb + Which of the following reaction will give ether? a) CzHsONa + Cp Hs Br —> Con #80, b) CH;CH,OH = 413K HBFs — ©) CHs CH; OH + CHiN: “& 4) All of the above. une / eee Csidsende SITPUGLU cloncwuis lenomyfluyd gerenouler Sows auflin @uigasi (1) C6HsCOCI @)cHs¢_\-cocl a) 2>4>1>3 ee @) 1>2>3>4 id eaiedieesArrange the following compounds in decreasing order of reactivity for hydrolysis reaction. (1) CoHsCOCI Q) ow-¢\-coci oe @)chy-€Y-coa — @ onc-€_)-coc a) 2>4>1>3 b) 2>4>1>1 ce) 1>2>3>4 d) 4>3>2>1. hoz Y ‘A? ere) N=N-Cl ft 2!) H3PO2 wind H2O 24) H’/H20 B) HgSO4/HSOs ®) CuCl Ah : NO2 oe oO eis NeN-CL ie a) HsPO; and H;0 b) H'/H;,O —_—_c) HgSO4/H:SO, d) Cu Ch GEHbGsro> HCN ononGuresst Syncs) olononGungst MIA, Bein A aus 2) Gapiiemuls sie 4) 2-sCureLt GamdCacit @) GamisGLcit FR) Gaptiented Glucose HCN, Product hydrolysis, Product HIA, A, the compound ‘A’ is a) Heptanoic acid b) 2-iodohexane —_—c)_Heptane d) Heptanol SGD : OG Csrtuior sporeng oissir Cuonds Gawnagiusney (TFM wgitiy) sugtuemcuiisd @SUILOUGApg. i asnjemb: BIS sy PiomisAeiuy Css sy GCaninysst Genpbs ULsi 60% TFM sion Garosing ss CoussiiGib. 2) sip wbpd siyembd ByaiGb sf Cognd snyembd, sappdaren sfwmnen HlonéewoT gid : 2) abo wp syed ByorGd sf ayoncd snysmb, ~sabgebsron sflusnen esleriéSebu0sb60 . B) omby ofl ajonnod snyombd soup ) abo wpm anyon QysiGb soupy Assertion: The quality of soap is described in terms of total fatty matter (TFM value) Reason : As per BIS Standards, Grade-I soaps should have 60% minimum TFM value. a) Both assertion and reason are true and reason is correct explanation of assertion b) Both assertion and reason are true but reason is not the correct explanation of assertion c) Assertion is true but reason is false. d) Both assertion and reason are false.