Page 1 of 6 Markscheme Unit 5 Mock Code: 5006 Marks: 90 1 [c [2 [a ]3 |p [4 [A |5(a)|c |()|B [6 JA |7 [B [8 [dD ]9 JA qo [0 [11 12/68 [13/8 [aa [Dd [as|c [a6|/a ja7|c [18/8 |19/8 20.(a)(i) Fe* > Fe* +e" =~ and %02 + 2H" + 2e > H20 OR 02+ 4H* + 4e > 2H.0. (a) (ii) 402+ 2H. + 2Fe** > 2Fe* + H.0 OR 02+ 4H" + 4Fe”* > 4Fe* + 2H20 (a) ALLOW — Multiples {b) (i) SFe® +MnOx~+8H* > 5Fe*+ Mn’ +4420 (1) (ii) (pale) pink a (iii) Amount of MnO« = 24.90 x 0.0195 x 10° = 4.8555 x 10~* * (mol) () Amount of Fe" in 25 cm? = 4.8555 x 10x 5 = 2.42775 x 10°? (mol) So in 250 cm? = 2.42775 x 107 (mol) (1) EITHER ROUTE 1 (via moles) Amount of Fe" used to prepare the solution = 6.90 / 277.9 = 2.4829 x 10 (mol) (1) Either % of Fe®* remaining = 100 x 2.42775 x 10°*/2.4829 x 10? = 97.7785 (%) (1) % Oxidized = 100 ~ 97.7785 = 2.221 (%) (a) oR ‘Amount oxidized = 2.4829 x 10? - 2.42775 x 10?=5.516x 10 (mol) (1) % Oxidized = 5.516 x 10-* x 100 / 2.4829 x 10° = 2.221 (%) () oR ROUTE 2 (via mass) mass from titration = 2.42775 x10?x 277.9 =6.7467(g) (1) % of Fe® remaining at titration = 100 x 6.7467 /6.9 = 97.7785 (%) (1) % Oxidized = 100 ~ 97.7785 = 2.221 (%) () (iv) 3 (significant figures) because all the data (except A. (H)) is given to 3 SF OR 2 (significant figures) because the least precise data (Ar (H)) is 2 SF(i) (ii) (ii) 21.(a) (i) (b) (i) Page 2 of 6 OR — 2 (significant figures) because the data is to three figures. After processing only two figures are certain. OR 1 (significant figure) because of the subtraction of two similar numbers. (1) Alkali neutralizes the acid shifting the equilibrium to the left OR Alkali neutralizes the acid so E value for half-cell becomes less than +2.20V (1) 4Fe* + 4H20 > 3Fe”* + FeOa” + 8H" Correct Species (1) Correct balancing (1) EITHER Required half-cell value is E° = (+) 0.77 (a E°cell = (0.77 - 2.20 = -1.43V (Ecell negative so disproportionation) not feasible (1) OR Fe* (aq) +e" = Fe2+ (aq) B=40.77V FeO,? (aq) + 8H* (aq) + 3e” = Fe**(aq) + 4H20(I) = +2.20V Equations in order of increasing E? value and arrows shown (1) Anti-clockwise rule shows top reaction moves left and bottom reaction moves right so disproportionation not feasible (a) (A transition metal) forms ions/oxidation states with partially filled/incomplete d orbital(s)/d sub-shell (1) W = chromate(VI) (ion) /CrO?* (1) X= chromium(III) hydroxide / Cr(OH)s / Cr(OH)3(H20)3 (1) Y= hexahydroxochromate(|tI) (ions) /{Cr(OH)s]*-/tetrahydroxochromate(It!)(ions)/[Cr(OH)s}-/ [Cr(H20)2(OH)a]- (1) Z= chromium(tt) (ions) / chromium(tI)sulfate / Cr°* / Cr°*(aq) / [Cr(H20)6]* (1) ‘A= ethanol / C:HsOH / ethanal /CHsCHO OR any primary or secondary alcohol or any aldehyde (a) B=zinc/Zn ALLOW magnesium / Mg (a) C= any acid (name or formula) a)(iv) () (c) i) (ii) 22. (a) (i) (i) (ii) (iv) Page 3 of 6 C0; + 20H” > 2CrO.?" + H20 (a) Allow Multiples (NHa)2Cr2O7 > Cra03 + No + 4H20 (1) Allow multiples Chromium is reduced from (+) 6 to (+) 3 () Nitrogen is oxidized from -3 to 0 (a) (Chromium (II) ions) oxidized by (oxygen in the) air (1) (A ligand is a) molecule or (negative) ion with a (lone) pair (of electrons) (1) ALLOW Species / Compound / group Which forms a dative covalent bond with a (central) metal ion or atom (to form a complex) () Cr(H20)s** + 6NHa > Cr(NHa)5** + 6H20 (2) ALLOW, Cr(H2O)s** + 4NH3 > Cr(NH3)a(H20)2 3° + 4H20_ HNOs + 2H2S04 > Hs0" + 2HSO«" + NOz" OR HNO3 + H2SOs > H20 + HSO«” + NO2* OR — 2-step version of these involving H2NO3* (2) (3) Benzene ring in phenol has higher electron density () ALLOW —_O/OH donates electron density to the benzene) ring Because lone pair of electrons on (phenol) oxygen is donated to/overlaps with / interacts with (r electrons of benzene) ring (a) Substitution may also occur at the 2 /6 ring positions / ortho position (1)(v) (vi) (b) (i) (iii) () i) (d) 23. (a) (i) Page 4 of 6 Tin /Sn & (conc.) hydrochloric acid /HCI (aq) (a) Yield = (100 x 0.25 x 0.74 x 0.85) = 15.725 /15.73/15.7/16(%) (1) Insoluble impurities are removed by the hot filtration (1) Soluble impurities are removed by the cold filtration (1) 5°C and 95°C (1) Because the lowest proportion (1) ALLOW ‘amount’ of paracetamol remains in solution (at the end) Measure melting temperature (1) Peak at m/e=151.clearlylabelledM (1) ALLOW _— Alternative labels + OR 43 = CH3CO* / C2H30* (1) Limit number of tablets sold OR Give (oral) advice at the point of sale OR Use packs with tablets individually wrapped (a) ethanol has hydrogen bonding (as well as London / dispersion (allow van der Waals) forces) (a) ethoxyethane has van der Waals forces only/London forces and dipole-dipole forces/mainly London forces (1) so more energy is needed to separate ethanol molecules than ethoxyethane (molecules) () ALLOW —_Hydrogen bonding is stronger Any three of (3) 1. 1 mcars sounds large but represents a small proportion of global cars 2. industrial / domestic power sources produce more man-made CO2 3. Side-effects of alternative anaesthetics 4. Unacceptable not to use anaesthetics 5. Possibility of capturing anaesthetics at point of use 6. Possibility of using a different type of anaestheticPage 5 of 6 C-F bonds much stronger (than C-H bonds) () Desflurane remains in the atmosphere for longer (and so act as a greenhouse gas, because itis stable) () (b) (A base is a proton acceptor) Basicity due to lone pair (of electrons) on the nitrogen(s) (1) EITHER. Lone pair of the nitrogen bonded to the benzene ring is much less basic (1) Because lone pair of the nitrogen bonded to the benzene ring interacts with Joverlaps the r electrons of the ring () OR _ one pair of nitrogen bonded to the alkyl groups more basic (1) Because of the positive inductive effect of the (three) alkyl groups (1) (0) (i) Equilibrium mixture is formed (so yield is low) (et) PCI; /phosphorus(V) chloride / phosphoruspentachloride / PCIs /phosphorus(|II) chloride / phosphorus trichloride / SOCl; /thiony| dichloride / thionyl chloride (1) Intermediate is 4-aminobenzoyl chloride / el HAN Add ethanol (1) 23. (d) (i) "f oH ir D D ne. be ES tye7 Noha —e A—>H Hea H Ms All5 peaks correct () Any 3 oF 4 correct (2) Any 2 correct (a)Page 6 of 6 In HPLC there will be one peak for each component of the mixture OR — In HPLC there would only be one peak if pure () In nmr the peaks due to impurities are more likely to be hidden by peaks of the main compound /indistinguishable from background noise (eh)