% AMBITION Institute for IIT-JEE / NEET / BOARD CHEMISTRY TEST PAPER 1. For the reaction, 2H1(g) <= .) of HI(g) is related to the equilibrium constant, K, by expression HQ) + 1,9) the degree of dissociation (A) 1+2VK, Tar 2K, ® hk ®A-S ai, ©) 2. The equilibrium constant for the reaction, 280,(g) + 0g) == 2S0,(g) at 1000 K is 3.5. What would be the partial pressure of ‘oxygen gas, ifthe equilibrium is found to have equal moles of SO, and SO,? (A) 0.285 atm (8) 3.5 atm (C) 0.35 atm (D) 1.87 atm 3. For the reaction, NH,COONH,(s) —— 2NH,(g) + CO,(9) The equilibrium constant K, = 2.9 10 atm? at T K. The total pressure of gases at equilibrium when 1.0 mole of reactant was heated at TK will be (A) 0.0194 atm = (B)_ 0.0388 atm (C) 0.058 atm (D) 0.0667 atm 4. Enough solid NH,HS and LiCI.3NH, are heated in a closed vessel at 100°C and the following equilibria are established. LICI.3NH,(s) == LICI.NH,(s) + 2NH,(g) NH,HS(s) == NH,(g) + H,S() IF K, for the first equilibrium at 100°C is 9 atm? and the total pressure of the system is 12 atm, then the K, for second equilibrium would be Addres: Riveter srs (A) 9 atm? (®) 27 atm? (C) 3 atm? (D) 81 atm? 5. Thereactions,PCI,g) = PCI,(@) + Cl,(g) and COCI,(g) CO(g) + CI,(g) are simultaneously in.equilibrium in an equilibrium box at constafitivolume. A few motes of CO(g) are later introduced into the vessel. After some timenthe new equilibrium concentration of (A) PCI, will remain unchanged (8) PCI, will become less (©) PCI, will become tess (©) COCI, will become less 6. Which of the following graph represents an exothermic reaction? 4 if (©) nk yo (0) mK, Lo a 1 T T 7. Consider the following rea C(s, diamond) — C(s, graphite) + heat and choose the correct option. (A) An increase in temperature will shift the equilibrium to the right, and so will an Increase in pressure. B-24 Dwarka More Metro Station Gate No. 02, New Delhi, Phone No. 9871860442AMBITION TEST PAPER 10. aL. 12. 13. (8) An increase in temperature and pressure will shift the equilibrium to the left. (C) An increase in temperature will shift the equilibrium to the left and on increase in pressure to the right. () Any increase in temperature and pressure will not shift the equilibrium. ‘The solubility product of BaSO, is 15 «10% at 18°C. Its solubility in water at 18°C Is @ 15x10 (@15*109M © 387x10"M —(0)387x10°M |. Which of the following solution will have pH value close 101.0? (A) 100ml of M/10 HCI + 100 ml of MP0 NaOH @_SSmlof M/OHCI + 45 miof M/ONaOH (©) 10ml of M10 HC! ¥90mi of M/10 NaOH © One litre of a saturated solution of CaCO, is evaporated to dryness due to which 7.0 mg of residue Is left, The solubility product for CaCO, is 75 ml of M/5 HGl + 25 ml of M/5 NaOH A) 4.9.x 108 (8) 4.9104 © 49104 @M 49107 What will be the K, value of a weak base (BOH) of which a 0.1 Msolution has a pH of 8, when It is half neutralized with 0.1 MHNO,? A) 10° ®) 10 © 0 oO ‘The rapid change of pH near the stoichiometrié point of an acid base titration i the basis of indicator detection. pH of the solution is related to ratio of the concentration of the conjugate acid (HIIn) and. base (In’) forms of the indicator by the expression (HIn} Jog UH") - ok, — pH (A) 8 gry PRP (B) les ny log Ut) pa (©) 08 iajgy = PH PK Un") jog 1 - ok, - pH (D) log [Hin] P,P ‘The molar solubility (in mol L~) of a sparingly soluble salt MX, iss. The corresponding solubility product is K,, .s is given in term of K, by the relation, 14, 16. 17. 18. 19. Ka" “ (53) (B) $=(128K,) v5, Ks . =(256K,,)" (@) $= (33) In which of the following does the reaction go almost completion? (A) A+B eC; K= 108 (B) X+¥ SZ; K=107 () P+Q=R; K=1 (D) M+N = O+P; K=107 In the equilibrium A“+H,O- (K= r © HA+OH- .0 ’ 10°). The degree of hydroly 0.001M solution of the salt is (A) 105 (B) 104 (105 (p) 106 The p" of a buffersolution is 5. It consists ofa weak acid HAafd its conjugate base A-. p& of HA is 4.699. Which of the following is correct combination of solutions present in the buffer solution? (A) 100 mL of 0.1M HA and 200 mL of 0.1 MA” (B) 200 mL of 0.1M HA and 100 mL of 0.1 MA (©) 100 mL of 0.1M HA and 200 mL of 0.2 MA" (D) 100 mL of 0.2M HA and 200 mL of 0.1 MA ‘The specific gravity of H,SO, is 1.8 g/cc and thisSolutioniis found to contain 98% H,SO, by weight. 10 ce of this solution is mixed with 350 ce of pure water. 25 mL of this dil. H,S0, solution neutralises 500 mL of NaOH solution. Then the p'' of NaOH solution is 1) 12.398 2)1.602 3) 12.699 4) 12.301 Given that AH, in Of HX and HY as 45 and 20 kJ mol-' respectively, then which of the following relation is correct? (A) pk, (HX) = pk, (HY) (B)_ pK; (HX) > pk; (HY) (C) pk, (HX) < pK, (HY) 45 = pK, (HY) + of 3) The coagulation of 100 cm? of gold solution Is completely prevented by addition of 0.25 g of (D) pk, (HX) Address : B-24 Dwarka More Metro Station Gate No. 02, New Delhi, Phone No. 9871860442 |AMBITION TEST PAPER 20. 2. 22. 23. starch to it before adding 10 mi of 10% NaCl solution, The gold number of starch is (A) 0.025 @) 0.25 © 25 © 2 For the coagulation of 115 mL of Sb,S, sol, 10 mL. of 1M NaCl is required. The flocculation value of NaCl is @ 80 (bo) 10 © a7 (@) None of these Which of the following reactions leads to the for- mation of a substance in colloidal state? (A) 2HNO, +3H,S —>38+3H,0+2NO (B) SnCl, +HgCl, —SnCl, +Hg (C) 2Mg+CO,—>2Mg0 4 (D) Cu+CuCl, —“*>€u,68) ‘As monomolecular adsorption, how much affimo- nia in mL at $.T.P. would be adsorbed on the sur= face of 25 g charcoal ? Diameter of a ammonia molecules is 0.3 nm. (A) 131535ml——(B)_ 152585 mb (©) 15879.6ml —(D)_15234.6 ml Which of the following reactions leads fo the for~ ‘mation of a substance in colloidal state? a 2HNO, +3H,S——3S+3H,0+2NO ® SnCl, +HgCl, —SnCl, +Hg 24. (© 2Mg+CO, —-2MgO+c © Cu+Cucl,Cu,Cl, At 400 K energy of activation of a reaction Is de. creased by 0.8 kcal in presence of catalyst. Hence rate will be (A) Increased by 2.71 times (Increased by 1.18 time (©) Decreased by 2.72 time ()_Increased by 6.26 times Which of the following represents the variation of physical adsorption with temperature? a) @) idvepuea 5 ~ dso © ) ‘Adeorption —> ™= Address : B-24 Dwarka More Metro Station Gate No. 02, New Delhi, Phone No. 9871860442 aw