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If it hasn't been used for a while (like 15 years?) then the NiCds are
likely deader than a door nail and will not accept a charge since they
are totally shorted. Bad NiCds is very likely all that is wrong with
the calculator.
If your calculator has a pack that plugs in inside the back with 2 AA
NiCds and some circuitry, then it is the same.
Inspect the circuit board for corrosion and other obvious damage.
Unless the calculator was stored in a damp area, it should be fine.
The batteries will probably have crusty white stuff on the positive
ends. They are bad. Don't even bother trying to zap them.
If these tests are successful, the calculator is likely fine and you
just need a new set of AA NiCds with solder tabs to make it as good as
new.