QNo. Solutions 4. | Answer (2) Ezquibrium constant of a reaction is constant at a given temperature 2. | Answer 2) ‘The value of K varies with temperature, 3. | Answer @) k= KR 4. | Answer (4) 5. | Answer (4) n> 0, 90K, > K. 6. | Answer (2) k= Kx (RTS 0.61 = K, « (0.0621 * 523) K, = 28.19 (moll) 7. | Answer (8) TEES "HST 2 0.2x2 _ tH1-°3? -02 os 1-32-04 tHs]-3-2-1 =f.2- 4 -BA04 go ‘Aakash Educational Services Ltd. Fegi] Office: Aakash Tower, Pot No.4, Sector 11, Dwatka, New Delhi 75 Ph OTT 47629456 aeEquilibrium (Solutions) Board & Competitive Exam. QNo. Solutions 8. Answer (8) Answer (3) 10. Answer (3) ‘When one of the products (CO,) escapes out, the reaction goes to completion, 1 Answer (2) 12, Answer (2) NI He} 18. Answer (4) Number of mclas per unit volume increasas in the forward direction. 14, Answer (2) 46. Answer (1) «, - PPI IF ___ 027 x.) (.1-0.1922 -0.2F 001 16. Answer (3) 17. Answer (2) 2HKg) == Hg) + b(9) Initial pressure 0.2 o 0 018 018 2 2 = 008 am 0.08 aim (Decrease in the pressure of HI = 0.2-0.04 = 0.16 atm) 0.08 atm 0,08 atm (0.04 etm Ateguilibrium 0.04 ‘Aakash Educational Services Ltd. Fegi] Office: Aakash Tower, Pot No.4, Sector 11, Dwatka, New Delhi 75 Ph OTT 47629450 22°Board & Competiive Exam. Equilibrium (Solutions) QNo. Solutions 18, | Answer (1) ‘ 2NH, —= N, +3H, oe K N,+0, == 2NO % 3H, + 3 0; == 3H,0 KEG? 2NH, + $0, <= 2NO+3H,O;K= Kx Kx Ke ot kk, # IK? K 19. | Answer@) NH + HO —== NH,’ + OH Atstat 016M ar) Ateguiliium 0.18 -x x x INRETOH] x? ET aaeag seo Neglect xin the denominator 285 0.15 1,75 x 10-5 = 2.62 * 104 1.62% 10% mov. 20, | Answer (1) Pro Bro.) ZAG" (product) ~ AG”(reactant) 2AG"(NO2) ~ AG*(N;O,) =2%50-100=0 Now, AG = AG’ ~ 2303 RTIogQ, ae AG =0-2.303 x 8.3 x 298 ogi. 5705.8 J (AG = Negative) So, the forward reaction is spontaneous. 21 Answer (4) “Aakash Educational Services Ltd. Regi Offos Aakash Tower, Pot No.4, Sector 11, Dwarka, New DeIN-7 PhOTI 47029456, m3Equilibrium (Solutions) Board & Competitive Exam. No. Solutions 2, | Answer(t) k= KART" Herean=3-2=41 23. | Answer (3) AGG) + 389) —= 4019) hital concentration c c oO Atequilibrium e(1—a) (1-30) doc (1 —a)= deo Megat ccremaiiceT ane WWee(t-a)= eg} [B1=e(t -3a)= 1-2-2) z c= oe 5 24. | Answer (3) Hye — HI Sine intial number of moles of Hy ard re same At oquitium 1 = [hd Be nie? KM oe ye xa7e= tH oe (Ht Thus, (LP < (HIP or fk] < (Hl 25. | Answer (3) Here an= n,—n,=0 Hence, no effect of pressure. “Aakash Educational Services Ltd. Regi Offs Aakash Tower, Pot No.4, Sector 11, Dwatka, New DeIN-75 PhOTI 47029450, viBoard & Competiive Exam. Equilibrium (Solutions) QNo. Solutions Answer (4) Xe0F, + 2HF — Her, HOsKe = X00, + XeF, —— XeOF, + Xe0,F,;K” = Ky X00, + HF —= Xe0,F, +H,0;K KEK RK Anewer (1) x, -1P (AJB) 1.5418 (On changing concentration, equilibrium constant deas not change. Anewer (2) visa og 22 matt ‘At equilibrium (efter 50% dissociation) IN,O,]= 0.05 M1, [NO_]= 0.1 M INF _(04F. IN,O,} 0.05 ait Answer (1) at Answer (3) Answer (8) KEK, * Ky Ky ‘Aakash Educational Services Ltd. Fegi] Office Aakash Tower, Pot No.4, Sector 11, Dwarka, New Delhi 75 PhOTT 47623456,Equilibrium (Solutions) Board & Competitive Exam. QNo. Solutions 33. Answer (1) Praia! 0x08) Crgo09F K~ Posie) K, Answer (4) K=KRTE! — aneng—ng et] KyekxReT Thus, K, = K, only when RT= 1 T= =12.18K th 008 Bia Answer (1) ‘Suppose at equilbrium, Peo, =P atm. Then Py.,= 2p atm, we are given that + 2p = 3atm pe tatm i.e, Poo, atm; Py, =2 atm K,= Puna? * Poo: = @P x 154 Answer (2) 37. Answer (1) Answer (1) Hy +h —= 2H 104 o tox tox & ‘Aakash Educational Services Ltd. Fegi] Offos Aakash Tower, Pot No.4, Sector 11, Dwarka, New Delhi 75 Ph OTT 47629456Board & Competiive Exam. Equilibrium (Solutions) ano. — 20. | Answer‘) CHCOOH —= CH,COO- +H" wig tote COO IN] ka 15 x105= (Coo IH HON = HY eon 24g x19e MIEN] Keo AS™108= HEN] CN + CH,COOH == HEN + cH,C00" HONIICHCOO]_ Ky _ 15x10 4. ioe [CH,COOHJ[ON-] ~ Kp ~ 4.510 a0. | Anewer@) 41. Answer (3) 42, Answer (3) a3, | Answer) 44, | Anower@) 45. | Answer () Seetion-B ano. Sotuton 1. | anewor¢t) = 10% maximum Greater the value of ’ indicates reaction is moving towards completion, Answer (1) Nag) + 3He = 2NH3(g) (On dition of inert gas (A), reaction starts moving in the backward direction ‘Answer (4) Ale) = 23(g) + 36(9) Answer (1) ‘The value of equiliorium constant (K, or K.), only changes with temperature ‘Aakash Educational Services Ltd. Fegi] Office Aakash Tower, Pot No.4, Sector 11, Dwarka, New Delhi 75 Ph OTT 47629450, apeEquilibrium (Solutions) Board & Competitive Exam. QNo. 5 ‘Answer (4) AG = AG? + 2.903 RT log Q- fa, AG= ac" Answer (4) CO(g) + H20(g) = CO2(g) + Hala) Ang=0 Ko= KART)" Keke Answer(1) PCI.(g) = PCh(a) + Ch(a) D-d dn-7) 104.25-4 2-7) =d=58 = 08- ‘Answer (4) 280,(g) + O2(g) = 280.(g) Ky=3.8 Poo, Poo, =P. Pan) EPao, =Pso.| Po, = 0.285 Answer (2) H:0(6) = H.0() Reaction will proceed in forward direction on increase in pressure. 10. ‘Answer (3) PO,” +H + HPO,” " Answer (2) HAS H+ A IH] 2A] ‘Smaller the value of Ks, more will be pH ‘Aakash Educational Services Ltd. Fegi] Offoe Aakash Tower, Pot No.4, Sector 11, Dwarka, New Delhi 75 Ph OTT 47629450Board & Competiive Exam. Equilibrium (Solutions) QNo. 12 18. Answer (2) NV (Resulting) = N-V3—N-Ve 50 <0.2%2 75 = 0.087 N of OH Hence, maximum change of pH. Answer (2) HCl + NeQH == NaCl + HO M,=0.3,M,= 01M V1 = 26, Vo= 26 ml Mv =758-25 i 400 M=008=[H'] 14. Answer (4) H:S0,+ NaOH = Na,SO,+H:0 ‘meq, of resulting solution = meg, of NaQH — meq, of HS. NV= 100-10 90 000 [OH ]= 9 107 pOH = —log [OH] =2-log 9 = 20.95 = 1.04 pH = 14—1.04= 12.95 Ne 16. Answer (2) are ® NsO(g) = 2NOAa) to 4 ° Atequlibium1—a 2a Total = (1 +4) [-a=03 Total moles (M2) = (1 + 0.2) 212 end = 4 By equation () 1 Pe, 75300 7.2 600 Pe=2.4.atm ‘Aakash Educational Services Ltd. Fegi] Office Aakash Tower, Pot No.4, Sector 11, Dwatka, New Delhi 75 Ph OTT 47623450,Equilibrium (Solutions) Board & Competitive Exam. QNo. 16. Answer (2) S0s(9) = 80,69)+ 4 Ox) Mimgo, = 60 (observed at equilibrium) ia DoS. oS, an) z 40-30 3015-1) on) 30.08 2 =0.86 17, Answer (1) CiH.COOH + NaOH = C,H.COONa + H-0 [Acid] = [Salt at equilorium — pf slog Sattl PH= 8 og a 42=—logK, +0 K.=6.31 x 10% 18. Answer(1) [ow 107 $ pOH ==Iog [OH] =—log 2 107 = pOH = 7-log2.0=7-0.3010 => pOH = 6.7 19. Answer (2) ‘Water and AgCl don't have common ion, therefore solubilty will be maximum. But the concentration of AgNO, is 0.05 which is maximum therefore solubility wil be least. Answer (3) B= 10M [OH ]=107M=28 [. S=5 x 10" Ba(OH), = Ba® + 20H" Ss 28 Kena? 2 Keo 4x 6x 103)? = Kep= 600x 10°=6 x 107M? ‘Aakash Educational Services Ltd. Fegi] Offoe Aakash Tower, Pot No.4, Sector 11, Dwarka, New Delhi 75 PhOT# 47623450, a0 -Board & Competitive Exam. Equilibrium (Solutions) Section-C QNo. Answer (1, 2,3) Na(g) + 2H,0(@) + heat == 2NO(9) + 2H2(0) According to Le-chatelier's principle in above equation On in increase in concentration of N2, reaction will be fonvard and more NO will be formed and on decreasing concentration of H., reaction will move in forward direction Answer @, 4) (On increase in volume at constant temperature, pressure decreases and on decreases in pressure, reaction always shifts in the direction where more number of moles are present, Inthe following reacton PCie(g) = PCs (g) + Cle) On increase in volume, reaction will proceed in forward direction ‘And on inerease in concentration of PC, reaction will proceeds in ferward direction. Answer (1, 3, 4) HAS == H+ AD K,,=Gof aye 0 HAs HAD ane ® Answer (1, 2,3) 4,2, Sare the buffer solution. Answer (1, 2,4) ‘The value of equilibrium constant only changes with temperature and at equilibrium AG = 0 Answer (2, 3) HoPO; —H"> HPO,” Acid Conjugate base. ‘In water, on increase in temperature it produces more H" ions. “Aakash Educational Services Ltd. Regi Offs Aakash Tower, Pol No.4, Sector 11, Dwatka, New DeIN-7s PhOTI 47029456, an