syrnmetrrcat alkenes :- CAR —> CH alkene on ante adtdlt.tcon tues Raceme mix . \ TRM —> trans alkane on ant? colduitton gevos (Meso cornpound ee oe te OM sy Calditton gives Meso compound. Trans Okan on addt cou eves Korcemic mix sen ‘ui Regio Selectivity > mony voqcona avar. bust selectrvele ‘Meet 23 hy - a a reqton bs takers Caty p Reaetcon un with che of dhe stexoo wiomer ui pxrherent- toes : ne O8nex possiole stexen- vere is Known tote sureetive SletcHeN . : Bo yocomte MEX and stereo Compound Ua NOt possifole For : cis & sexe chumuial stooetion , tine prurcues must howe possible stoxrowsomers . (sigxen Aultekive | Stéruo spoci4re ) a seus SERMON RACLON- on, Oty ' ekiard ft annenie, Lynttsed See mm eee caharyat 7 AQ, oriataaho ta ed ee Hes 0 — nm " os 42 favevred Hy over hans Ute # New \ . — a Hurt tyQis oA US ye 7 XQ e ot 3. Reactron win wien pstoduct Mechowsm - aingte step as O steseno Liomer . us on, 3 Hs Be Hor XN 3 nck @\ Ve 7 - H ‘\ \ 4 as {ne (ower wz % \ augetromest: \ : a3 Bx Swipe 3 Been cxcowded =e BH acta Ht, Br is fs e—e . a . 3 @. Bu oH oH @ % @. 4, Bx. 7H k BK H Bx sil a 3 Ny #. Gives gnanttomer, = ( Racemie misc) aeHg H os ng “a we A c-ct ra \ a eS oh, Bx CH, Oe eu tH, By as H tH, Bx be thy M Ut, Ag Bx # Bx haya H Bx . tty S—" =p Unsymmne tte aaenes . MOMONTUyS: 3 Hs 4 Ot. TE Unsym 5 OF a ‘ " , Mae Cze + Be, 41, c—c¢ psuacuk f PratX vol ter Al Ca Hy Hex | coh, Att ov syn eu ge Rovere = 3 mix te Addisfon (syn or Anti) of 8 Gish oH Oty Be sunny emaerte, Kune Ly & gous A TOCLIKG wine oH OH, Bx Be GH, l ‘ a, Oy op BX K H Be Macks be u Ht BoeSEX0O- spoci.hre saaction :- Stato anteerive RACH (oy). Reaekton in whith steuo.ucmieuic xeacteunt preteen - ally qives one e Aine stexcots omer ax produes, Og th CH os ee aa tee wk Be, Bs ”. BX, bx Ha Bx " " oH. Cty h SiPOLDspOLde and, stoxepaeleckive ae Race mix . + ROLCOMUC j tH OH, \ + Moyo Ose eon, fo a Pl Nee’ , Ba eat PK. Rockeon a t - tintive® W wit Pat le 4 m4 a e oukene . / : ; “ee 7" “aN to ¢ — eng No churat e nr Kt \ ee yy | so NOE Kiiow volt . alk Nia pestis Nelttur sterpgetecreve nos stexoospacl qué will finds Pa ‘ j " “ a au OHy- o— ¢ — er 7 Pn, O18 3 | 4 ‘iy Syn aatdiséion | | | te tel, bebe Meso compound, , Zz Atuoseteettve . | | AU sterecospret4re meaetions are also stexensctectiie DUA OM stoupeleetie suactions axe aot stoxtospec’ gid + Addition ep cosine Gor, , tect, ) et Foon. vb vee) “ ofozometnane" CtyNy —A—s TO, + Nl, Aormaseon i : f simp Copttoent Ketone tHee=0 —4> tH, + 00 Simple caxtene can be singlet tose) stsuiptes Singlet ease Lifer —__, ‘Tripser carbone. / tnt e Sicuble a POs an Ny fe , : FCO as abun Aungler corcoene are, HEKOD A bet + Hee -: Singlet cortene - addition takes place un single Srep- bl cH. a. CH, 3, 3 tet Cay yA Vv / oy, tte B a, PAS " H # a a | yas a " pry CtigNs 4 5 aad nse 4 /\/ ‘i, ; oH, ‘ : ery ps “Ht, OA OH = eH ~ ct Seieihy a Nod + —e re Cond wig) AA ZN TN Cea] trons) 7 a x on 4 . tte OH Makes the, solvent . mou: Fey trplet Stes, un $e, dase vat ues 4 eq un aLGEAe ok Hels Cth, 1 ADEN E marten, ss 5 OLC. KOH A s . it u SHOE wit Us ov trong Os a wee Couple City ——b UN EAS AWK . TRO. CHOH . i" ¢ i — Addison of alkyt qroup :- (readout exagt la punpieteon) adaitien secretion | . oy is Augen «Orang MTR Ge Ott a P= Oy Oe . u uy Rayhourton - ‘ ua! Mos ot came — CH, — OH = OH, eye ah —t wy ; rE CH a Hydvercoerbo xx feutcon 3. Muunes xoaek wish 00 od Mp0 o& Hugh temporotuce and pomauce to sundrge Wydbuoraschonytatdon : = 300% R-ch = Ht CO +H,O ——>—> pio Ba oP oom ROO6. iy 2 aa) and Roe Hy clvuvatie tse abechar™ Races °o v rer TWie ester 4 RSH Rech eH, lgofomep C0) ony-pezes | Me Woe temp. and at hz n tne : presence Casa) ~ ausyeats an Wa presure 4 un . Atkunes + s. ' indoczo nydroformuytarion with oo and Hy . | OXO prucess * Roe tent yy a (tos ? | ; cn —0H,— CHO. . i z “wot, apa R aS Oa Ct Pus seactron ¢ | | co” Cade icon of Atlante - Hero). 702 Cr Pl ork oes Recetion op an acide meolium . : Reaeton with atolenyde oH wats So On- cH, feno| ret R- Cte OH — rR mH a Sete o Ho0 \ | ROHS Oy ch on R BF Che Ov Vinge oy ge on f oes Oty = PPT SEH Posen on 76 = OE OOH on, ‘ Cote eH = GR, > og, eto cH et OnE Cy wa ut Cte chp Habolactonisation s- aaerone- neuhalt formed whon ¥- 8 - sunsoduratedt seokiogi aid gives ‘henkackom xeon dlton sxaction, with & baw ad halogen Scar te,— ty “ey > ZAeen Mirela : Fd vane oP Ny x NATeDy , . , CM, Cat Hy My? COON ~ ay cH, * OH Oy My Se 0 o |: Qe vy; gv" Ny ¢ Og CH ~ Oy Fey oN CH, 1 Nye 0 : \ . P ¢ Mire caudau'tion s - > MUU 6 pousauckss NOL ponerbas 4 bpredues wstur WO 94d At ade Br den't mreack With 140 pening HOBT ivy 6 PO adaidion produch ate witn Br and some oe with Hoes v ime Yynodtuet Br on OHy-eH = ttc, Stag Ha? ‘ : gH = oo > Uf Ot oH. CH, - CH CHE dirs \ i + - a 3 Cos’ sow) (aajou) Bro 9 Hod. " I a Hol Chey EE OH CHB + tye ot HBF Moyox c staple ivtexmediate) xa 4 NOL * r eit = Ko 4 Hy res Ea Tse + Cte cH — crate (Trace & a") we ty Thott te. { a Ot oH — eH Br Wadiacon & Ox ( x*s OFF) biornennturr ye OK ies aedeate Cs = HOX \ Nal \ ta Ro eet, =<" Re ey ms Raduetion 6 atlkone :- Move Subs alkene aye more Habu ad Syn adduton “Uny Ore ies pe ene —> Regetiviity Loss supstcaatent alkenes axe moxt steve than more sulsetituted DUUE nn ons baplsogenatte ~ were MLO (Masta? High =H Cy tn =eHeg > (OH,),¢ =C (Hy), Uy oH A a 7 - a Ho shi rrelecules spoutie Z we Bg are Sy Ug rac an {Wendiag RaMrUtOUY, oHy~ FTO en, Takes piace foro rm 1 an Pas lnrresemect atte \ 5 Product Sey products wy e—ut= er, (2.8tops) Oe possiv(e compm ) (ueetstg wndant | econ ound fu meuy proeliicts woe - to d 28 Gi gtneo), Htg0 Bena : Wh) Now = a Cte +The “Tetra ryan Yanan Yearrangement = TPH 4 OW 3 | se a cane 20y sy ov ui, ae Onit addlidcon nk OW UW WJ Solvent “RN Fhe Radice uive ? “ * Steceochenuutry Hydxoboratran — an’ be Sbrectic . ANA oxydertton 80)" THE Sat “Beta, my Teaeangematt MPa OH” ag cot, . Mosunrierleqe cal . OF WOR. ¢ Peocuct i sane tbe cohot) #0,H0° on Cnet ewotl Cavebeeaier ae gy | Ontoumunotion. ‘ k | 5 ! arm Hs HO “Syn aden” os He Additfon @ vo, Ht ry p ce v2 ey —tHo® ep a Oe OM — Ot = cy, aa Ge: ¢ Me Ota + OH OH 4 CH, Comarseny vgornan® oH on (Majox) Comin). Fea he Ms \ fine ~ Uy Ot en = ey neta, mk oy Gen ‘ saa t a 0-3 -on ce q §—talaye ingdvtngen subphadeHy 1 Os, | wie di ence Bul [OAD Ha? THE agg oH — OH 2 WW) NaBH,, OH” | \ tom ; nei OH KR NaBtr i ; vo mavekovtKOV ey OW Hin OO ad.uucon of Auyninm sion + = i a Mechanism \ H,0 Steps - + {te Oryrercu Hg (OAe), ——> Ae + tgs ° c ~ Ht) qemrmon Qo we Ss 7H yt S 9 oterveded. Hy more stovis _ al + on sec, 13g hs Baa Oe Oy + Hone Hg ——> eno Feat — en, Oe / Trough eyelte Patky rosie we” P et fevers SUUULp » a tget-B- t croweleed “HY ee i wee (no ¢@) a frocronal 4 v0 eb enough +0 pull the CH, OH sc Pr eteratle CHa ed OH CH, bud nOt sufficient I to un CUen i SEAAKAI GE Mr Hg-e- a * Postal pasidcue cnaxge ai dQudloped on gat ee Bi fe carton atom wie us ein for Hue 90 Astoek op se Muctgopllle - : He OH a ' . . 2 3 bbe a ayprmedd 9 ti will ei -eh— eto, undugo — \ Step 2 ~ Demoxeweeltion HgocoeH te ae PE Nagi, 1 OH” vt Ot CH — Ch eH, Nase OH OL tH CH — 3 i o Hydnile HOCH, \ fg-0-C-t, Wransfor, + Hg een e008 don comes 2itior akove tox) below : ue a, om-DM dngs nos awe any stexcoehuinus -OveRIL) ma dite mex cuey Ow uy adda to te moat eeourded positronti ‘ (| (i te Q oeeelreak IMC Merzose pocedkuet oh the fettowving seecction ) 4 WNglOnAa ato, AY ei a W ABE, 4 ON en a) CY — O Monkowitkou voitnout ) Ae any suonsargenent ee OH Y) NaBH, . oF ae OK Gdeltd to She most wtowoled ) . positron « YY Gagne, te rar (YY 9 LA, Ualorananome KA oD on WH awit, , op- D. 9 DA 1)bgl Oe P20 THF (®) Nap, OF op Atkony MELCUMCHON curd dumusccuakon s- dup ghey aiROW3 THE AV OR Ui) NOBH, 9 oH” ho AG (i) BHgy THE (i) Hg, OH x ¥ de, me come from Bitoy canredeat Coxbon (Teuninate), dag = J i ~ Ane ‘a uso ? Ly - ateaanese AMK Addon . . * one moleeele aya at Me Of Big Be si hyelrot en 3 moltenty of cut 8 bonals to toeminal ¢ oy ot ae (we crowded @ . NR osu, Sdap 4. Aydsoberatien . do| eX y Ry’ " Sapo -onudladn :- ae eval Rob + 0-0-H, ‘i si ache, gf ae —0-H “Hw vond wnt cekes (a0 +oK" 40-09) TU vil wit tive €° aus |. og and 3h bend _ EN CLEA « o-R vrai i GOMWS4A2s Boron Vv we Fs we) R- veR ou? OR OR a | Nef 1 B+ ROH <— ko" + R_-B~OW | rong bac o =e mete proton Rs = \ - 2 A Ne GQ. Weise the product of the plowing SROaLtEON - the Ho mero eompennre SRO bor we ae wom acteting 2 oltth wand eee “Otto Cries veacenud mix) . ¢ not QROK +a BO F) M An oH H OHO Ob actdeet opp O SS oH “uty gop Ce ew ‘ee br (0 Hg 9 THE 4 > /\4 W) HO, 4 OD- ‘5 H iO) Bee, @ 50, 5 OT Ho 9 LA i. gL bh ni ak > AK {syn eataitéon) W) 90, son VAG o Bp. ti oyea sare YO D ' CY ws, i) BHs ieee op~ Ore TAY —tot tL (i) m9, 00> N( e) oD Not oudlrsing Roetien a Ee Bosane s - Tnstcadk of Dit, Br 22 aelded Ooracitcon AA Li Bias HE, Fe * V4 = iz ti Kt Si Hydvarren ; Se inp SiR: Prue ataing Fi prota Otlop on chow Unstead OF OH pur K ote sp ff WwW AG Siete, tHe AY oad @) co,cook D H NA i) Bits 5 WW) Otgcooe | yp Sees, | Mo 12+ 2 CoOnfasiing IN y th bn “ Wi agna, Nacit Mwy cauping dy RB undexgars Coupling to form RR wut fi) Bits error, (diy rer Hyo ny wa ~—Y oo Pi ge cepa Oxidation & atkene - * Mite Onuclarson :- Orudloaon witout tre cloawage - Sear gb % oases a Mikel oxidation giver :- Noo” (my bode Sines aN. iN 1 | aoldtuch oH OW Rpoxide. ub- vicinal dod - Eponrde forma bon AlKUNe With silver Oxtale (Os) joles ( bostn oxgauue (ox) snorgante) wunduego ontdlatcon cto om oporicle . q Pex-c.crdlt peuoy bond) . Oty eH= eH ets EE Oty on CH tH Se Micha ut. ily cy on R \ Os, Wrest > Nyt D | | Dowl + re + ROO TS be ‘ our at =r Late ae ee) Sy proton | o Of 3 4) 4490 (ox) MPa nas ae (er) MbPBA ROQOO Hf - : boomD @) Repo ogame poco pox wan BY aud aeCh, o-w~ 3 Nut 4 TOMY buat Ido potent an Titanium vio peroxide ‘ A) NMP “Mea nin monger i ote Rowurmie Yeas misror Stowochemishy- Oean ture, STA nl fran eLOWe or mixture . " blow os alkene . Vues. dealysis po. Wy Epowide ; n Reimar et tet? ReoH — eH —R! ) | oH “+ Yor gertcng trou vretned chat > “form eporiele on ‘ —> Tun hydrolyze Rett=et—p lt) Ag.0 3 a-ut—at-e. i U) #504 4 | ad (4) a0, an ouidarron & Werinak Oio 2 eee Ta Ovicllagy Wt = Fy y : ' inf eee Old alk. Knino,, Cute) oF @) NaH sa, 4 He0 fetlowed ty nyeeeetys Osimtum Tetra oxtate ® 8) Oso, WH) Nag So, 4 H50 : . RoOR=eH — Re UO KRING OHS Reg gi Sum adaixeon rw J off quoup OH oo Michamin » RRR R-cH- GH —R 0 . Hoe Ee if : oo Sg epil J \o- Mr Y Sous ° 0 [we R-th-CH-R. \ | on OH.‘ erunwainy ~ Musocompounel - Optreatty ‘nackte « Wy & R ee Nuon” — gar 0 \/ ss b, on OOH é% dors f \ \ on On x, [eagroong (4x) i‘ k= ~ om . iv “wR To oxymercUHahten » if ateohot oH JB aed ivigtecch Of Hy 9 AT ety : us foxmed, * St Orddation + Strongat omtizing agent + - Hos QUE. kino, will break, she sie and. pe bend 40 form eoxxesponding oxi Feed prrooludt cH CH = tH Wot atk. Kino, . a ip =aien, > aencnor (Teuundle 4 "a ons ox dlzod to " econ) BN ; Yok QU. KIMnIb, Ct, Spy Ee a os os 3 we Max. oxidizod Oy + CH cH 00H state 2s ketone . 3 2 >—<_ meataniin, aero Nf ESN + HCOOH * aan Behaves With i tke ata o. Atuae beomeiey vt ake od v COI vottla 1¢ tos us Taormina alletne . me. LRN Kivindg | Hoo ~ 0-H (0) | oxicdizes fusttiut Cag H,0 9 UHH LOOH + C0, + Hy.- an ox a > ig agert &* O50, and Nao, t ; 5 TE oxidizes alkene iro caschonyt compound. Onty ately clea wn a NOT, ReH CHO Mt ecoHt ax sy fk not Ose y NOLO, 40 StH ens: 6 : S=o+ PS d 08% 4 Nari “a — CMyCHyCHO + HOHD . 1, 00d MUN, Leni Reagent veg maiats atkane ito einer oas u ImiRROAe 6 Contenatic acid and fon compoused or) 7X Set cco + hig 20H Ost Se< AS tng, — jankun Psercess z_ . " attiunes leone Pea ef ceveCanyt cempererele g M : Votked uintis caxbonye conrpounds by ovidlascon with Pela (Palachiune dulerde) gh apne ids lay, wn aie ond tet ) a Afpenes| | Ur 4 mettranol Peete’, ax 3: Oig= HH, <— 22 ——_, at tho». ys Meanet 3 Bat teemnidl ” Guag Cust, . produce: * at Aldeliyete Lonty un CORE Of cecuy ere) “Ye — oxidation as @ Ororintyss cS ‘ : > 455- dipolax addiston of ozone to an aleone ‘sesubls wn tHe Josemation @® mnaboxonide, 5 wth Js dunstable 4 henee nae to Wile Ozenide whith JB Wighhy swactile and explosive in a; > Re Tae ay dhe posunee OF Cyt, Os a-zatverd so prevent Crptosion amd help an seeactran_s Pranide ui daaved. 40 give cise caren? compounds (ox) Compound and eaten as oe ( a sein a Cabenn | R R Neel £0 e ré yt a \ ? 1\, Sta ae “wawange ” / i Tix susagart 4 P haawting? RUS cay @ te ante puventin Muolozet aa a from uundeegornn) ts Povodurets, : k a * saxely Redueed ee Nera F ae | ton be of Atta Yreduueng Ks VF 7 ateoviol Md wr te agents © Satie val awe wed >» valor ahwent) (ASHRAAY BPRing wu Chequed W forms oridira Meelauwsm product : 7 (oxen) , oe , * Many . yes tt Colts Q "ret a > Ad — BN veh adeetronic J \ Oty # | | ott, WC ; e woelege we EN op? £9 (19: Ar 43 o.) Yo! ef Bipolore @ Na Addstcon. A ; Cals bins i 4 NY 0 CMs | Heo + “eso P x 40 A oe , % | 5 o—o0 ay How mony intexmediate exenides are pessillt 7 “< amg © degrade : wes Cats ~ SS | tx Oy | og | Pe =o 9 @ ard, tats wig a aN + NY 0 t ¢ ; 66 ¢ ety, — © wap ea ib ranch wictouk” -4-— 3 oromdes aree possible onidoung ; wi two formed by auf.a gt aymmetrtent aldehyele a ! Le soune both sides : | soOnly 4 oxonile possible . ceactsit cxoviotyses 3- “Prendlutee us convenyt vampound. »*< toe it : @) Ho, 2 ang | Sin nog a ~ Prepdltlck 1 etsner cardhany te aut (ar) Ketone ry w og Gag Pro reget “Siete Beka oe + Ogee ; Pana OB id ot ONG eg eee 2en,cook Agsiing wy ANE pHteacner OF tty &) Aq, OOH AY fia J on e00it “( ncgone) oe ACY que 2 mate " tou gtk Sebordl < “ ; ae sh A Sewage - when ps oxo w given — ~b Berakall trie aeuble bonds . @ Weite tne pers % Hae hitiay = : | ne eS ¥ Ne Ltt "yh pene pe aenor + aed \/tB0W anya UW { . eo, cry fare 4 0% , | ft \ Gyno,zn ecko None, age aM te ge Oo fHnyontays 3 OWL? Hooo, 3 W 03 ay it ! ‘Bet W zn, Ho an a HO He Ong 0 03 mal “any & i Gi) 2n,H_0 ro ae a tO -, ots thy 9 te “4, (pt, F tee |* t : _ Aap ; dito “ (i)tpo,2zn = HeHOF viene 7 q a TT age) ati oy o ° types og HHO peeeat cH0 - CH Ht Sis i. +2 ® iy #20 Wor, i 4 heutng as qe wu dueeive “6 | 0) gor | wl » Or ae fe Bios WG NAB OWLOMALL BL aan’ t be fsnd UL =ez Ul, 24,2000 + Wy Atuylue haLogenatton .o4 : ‘ u B Pr Eee wth, -~ NCSy Co YN ‘Ay Reagent asec - &e0, ¢- Rephoreed, cWtytic hydrogen 40 0, hydbeoragl gaoup ps A Ao petro ozonolys a 2— Peclicteng tne ; ay patie yen 's atructuns from tin. osumula AR OK —9 OK D0 + eto-eo —_, rotting ‘My , « Reegpee — wneatur . ~ aston Joomeczactton :- Catig “My Mkones undergo Asomwcisation wi ane pecavmen 6 anhydxous Md, and a. send I Teuminal atkene gas converted into nen-soumninal sts letanchat alone qs converted into mere branched 2G at Alls AY —_ PPS rescges 3 poeta es , . . diff-axniino Polymoctection s-° oo tm aa pi Ne pee \ oe i peuonee © either anid, loase (ox) see 6 ‘aus “pm pelymen. Polymers have sequtax sapsaing Gina iyeners : eee Sy non, =o, —Pemmade, foe a ad2. | ew lo? |) 1 = oo ALBYNES : Pexpention + by eintnation —e "0 %y dehalegenation et =e MEO, pecer | | x Xx * by hginiinpeetion Be o® R-C=aC-R ta if . A R-cH CHR = % { ee —aekoH peoncd ney Beko Rp sreasttoh “ (nove serge Tos oh ae as atkiyt A. (vinyt hawde) rey _ min, Rest-h: 1 x genvoved rand ox sees ules ir double end +réple bond . re Teaming amynes cree Qeiduie uh nate - ‘Si R-CaC-H ———> rcec? ye t a acidic Niydeogen * Propertios ef eukiynes.cvee cute to ree ; ’ 7 Redd norteseg whe?! sa gee = Pannier €P m- bond feidte natu ] > Recetion wid bdae . To far eee fos sak, Resch MA pcs P an Sodium Atkynite . Audie narwne CHE CH > CHCECH > Oty OHCs At & sept ne chau Wwigthnt . aeidsé nae V ye tor T obferk @9 © neson NO, Nad = eatat CES a8 Bate ( «°) tee Pua > aeons on anu nase Nucleophite. Haake nowwide . 7 9 BR easy to Res One® , RK) ———» R-cwe-R mt a Nucleopinile . a 4° (or) 2° sentctukin ‘ a at, Reauon Hy Rca OnOy CM. \ tr Hae On, RCE CH Boag aiminadion . “i Oxganometattte compound 2- RMX, RU | “raja SURG aataen proton. R-Ceetuy Rmgx ——» RH + R-cacmgk T, gen.ui suteancd , ie vd a 40 it 3 prowabty an ouwcine (0, 40 64) (Rui bw ) Ree daly xu |—_, RH+ R-cschy i casey pete 2 a ru Yo a ptt we dug a onaege EinANE cerfoun con vas a poewat Soe Motel atkunide = Texmenal alkyne will eeact with ammoniaeal rghos Jo ooun sitver atkynide (wiate ppt) Croten's aewagent) R-tecag® white Pre R-¢=e-H Ree tut Bsn ppt "Test wuseck to ‘Souminal reese Au’ Yeuew ppr/ a Gjeicken ppt and. alieonos - * somathing nok sedeting as not @ propet ~peceemt _tte0 > R-C=ECH + MO| Reaettons lus to 7-bond HO YY % Etectrophitie addtcon . ie 3 * Nurcteopiniec addition . e # Onideutton # oxonolysis % Tsomeusatcon | * couphing seeactions - eltetrophitue addition 9 n Reactev icky n : ‘ Mkone > mkyne - R-Ut=@ty + \/R-c=eH fre i oa : 3 ot cextboeation a loss ctaabte Hon aye os “pans ane more stemetive tonostds Efectrophilre Addition Reaettous (ERR). R-c= ch tm wx ¢ eae Ro = OH R-C= CHK R-C= HX atkenol x \ la (ese stat). Ama o5 wx | sae | . 1 ss 5 ! R-¢— cnx ea R- CORK, 2 LS i? 6 x x condition feo ent tole mere stable —> prnenod f In ROG » rUseLLopiuile > hxnmatie compounl gets aslded* ~> 493 dial ee Nuctcoptritre adelition seaction ~ > Miyne undergoes a api adduiscon wish strong as wal OS with week wuctenphiite . > Wit strong eae alt pane Rt. » R-CEC-R— R-CHE-R RO® strong nucleo plale caxbomton (RZ).HAO CAMnOE Wat actd ov to atky nes i Mteds, hrrouy metal rome W Crtarty st . / | A Heec-y —ta0 48g. cheno ° Hy, 2 Teumninat Alkuyne.'s ~ Only one ketone ab joned - 1 ues oH te Hf, ay dary He . 0 Hy 9 i Symmetricat Alkane 7 Onky one ketone 11 Lites ; 0 Si “Reeze-e —H2tat Re CHR gS, vnsendiniat Ahkipne 2= Two agent wotones met . R-C=EC—-R ha + R- onge oR! ' Pradlrek mayor steduiek 5 : - i ae OA, OH st a ae a He a 3 3 stale o ~o> Loam nt Wao ~er a Oh OCH = — OCH. tS ee Phe ety 3 * ie 3 Ags,exe, (0) Ut @- Lene ®) x 2/5 PdS Og tin “— Ones oy foages o~cH- coy AE mcg a z oP a aes thee 309 MPH caceecn — 2s A ya ne 3 CHSC ecmge SE aes uy ond 2, Hs v 0 ny a eau i u sunt. HgTe “Git ¥ ME Aye ey (Sassi on znng (ta), g. (nar) ¢ : Grow) No Pesce eis =e eH yc ee NO mi a ee dusiarnyt borane" / Mydseobovation aie f pied gece en tne tin sdk Ue) ” boyon C ears ot {ising yTHE R-aw= : = ch, ‘ (W) NoBry 407 be ae \{ “Toutompcan sia Hy : to from aldthy te —— Hy sxoptacedt win S105, Rey CHO. | 7 *, * a da Wee i) SideBH 9 THE R-CH= CH, i) cHcoon Oxiclertion + - hot m Rez eR! et ale KIMI. Repu + eleoott | Reese EK: King Ren + Cy + H4O (ormé avid leas ontidhized fuxkher). Oxonolysu 3- R-e=c-p 0s _, pce -R () H,0, 27 : i W Reductie ozonptusu Otkatone 1 ) ©. reser! —WSs_ pee + Rie wap *—_ —L (wild 0.) re R-Cet-R a RG-GR neem hy Reece! Ss ak ae | MT ich A Yon | Tyometiscttion :— , A a : Wn, wit Wr tones yarn wn sine presenee @ aie. KOH Cor) 928 converted into teeminek a R-c=e-ap Qle. KOH ee Te. sp ceiyaze 3 tweak baie) R-tt.-e = CH | [ating boat R-e= 0% 2 . (Sat) > Teominal alkyne t sundagoos Bomsusation sto fuminat alkyne (oot) oltene . ‘fen men — Choo t= Oke. KOR. 1a Ue 2 ~~? Hes cme + Chet serch Ong ator. : 4 | | th mild aciclic medium , Clyne undergo dtedurebeve coupling sto dose lene: j ust On ac fen » MORAL ww getten : seemolled Reduction op atkunes > Reduction op alkenes. am Foxy tp acld tt aUY —e=c=ct— > eum diene [adjacent ik rULtcekeve ade positrons ae C=e-C-c—cec—s Isolated diene . eee ee (ods) . cges ma idl aaa (altoenete positions axe olienes Bolated dienes, ~¥ offect disiaines Amol wx _baseel "hypore en nse AA {econ ue watt 0% . \ugaien’ $p? coxrben whan at 4 “age “cs iz Wulps in stabil ty Dienes ¢- —t= BOE stable 4155 af SAIS AZ 2 moles HX Dhonds sucet c ae ae, x agent & BY nae eT ane FN a ON, AC +O a~? ganuates 9 K Ra Saree © did) proctuels ‘492 -addition ‘addition © © mh a to, a es (emmjugan, Wet ating s ee NY WY wai ea addition) Stable «Raonanee . pour MOVE Arcrtte clue coxboeation ou rae ork Be ara @ kinette yroetuct \ EB ér. C prode jomd product ae fast) (going shough ) Tne ody neunte : pyoduet MOE tom b> move oncxgy to motectles. (less favoured) “he secaction going Hrroughh most stable caxbocation wi Kinet Controlled seeackion and. i us Pawoused at Lovee tomperaduee Or 8S Ty th HOGUURLS Lasser. Eg (activation Enexgy) . ‘The olnwe product ut known as aa controled. ee oF high tomers . 70 (NI 8 -t0% par IV > 60. Moyose ;0\4 30°C 4 es more energy iter n 4 Addison cee ee aaPALeah ee prodtuck . 0m OH MES stele produ domp U8 Pp ted | ea a SS! ab a mere stone oO Reonance |e Be" ana. E Ad -#. 20h, “ 3 pororude . elul @ > nee radical mechanim + HCly@ oprions = @ pions ) aX OL oO (b) &® br on re pen EAs writ — __@ - 8 Re Crt " 6 6 rnemlorxed. sei Ls ® ater Balti br on PcEae A> He eey ww . : PEO Oo Divs Ardler Reachion 2 _— aeageae ost seagate done with once Was l—c Stexeoeumuatnt bf tet cubstyate ak otttatnect wos Ane rr Odut eh. Olnun swostrates ate - anyG, How many of he touowring gives witte rene of bo a Q 2 Con x wit, be % | Ane “, AS berg om eye o x tng ae Whichever compound = on devas praca ts vB age, ee Lenny : ch. . . : = 6g dram pon whit pe Onty wen eon get ne snore Jb ibid] 6p winibe ppt. jpsurmatcon. s ere Loon KMNnO, - nok alkaline —® 2 onside ns FS 3 wid oa: a mg one ‘ te N04, Barco Whe or H Kmund, ~ acidic, —® eb Trust 0 rig . Alaa Aor sce ” « & mee No of oxouit MUWEAY CeO vodymuuth eal :- ° ° tt a® i +R “grt ae oR ope protonatt ) Foyt wenwene ( Acytium ws I and - R) o Moles Goyt loner e° defret ent fo BRINZUAL unclexgaes etter acu tation M meee Not eye Benz. . e a) . T cy eas me 5- ” Ree aay wee. SUBCAION 9 Ro Bo: -& Ney ei 4 L uw si quanttty bur us auylation laxge cunta. ace Sh * me waed . © MCh 262 he on <_liae Ot Osu: lone pair-ef 2” on 0 ea t 4 Met, axtachee) + PaCoH),+ RQ: making th vesey meanckive | x Fay any orion i not posaitole lectin aoyt eenzene ub Less sractive Hon * Puptium don will Not sundlergo suasetaunge ment a NoTE :- Solvent LUused- wy’ Feeleteotayt's xedeiron ua Nitrbenzene as JE Js | ey 8 Renaeg agent, aS Sige ma seat - | Stents - Anibing us Nok oO =8 0 0 O. 3 = eae al votetedrousing fe tly - pone” wg st :