write your name hero 2 - Sumame ‘Other name 1 - Centre Number Candidate Number Pearson Edexcel International Advanced Level : 7 ~ Chemistry International Advanced Subsidiary/Advanced Level Unit 2; Energetics, Group Chemistry, Halogenoalkanes and Alcohols Sample Assessment Moterials for first teaching September 2018) Fape: Races Time: 1 hour 30 minutes WCH12/01 (You must have: Total Marks Data Booklet, scientific calculator, ruler Instructions @ Use black ink or black ball-point pen. Fill in the boxes at the top of this page with your name, centre number and candidate number. Answer all questions. ‘Answer the questions in the spaces provided = there may be more space than you need. ‘Show all your working in calculations and include u appropriate. where Information © The total mark for this paper is 80. © The marks for each question are shown in brackets use this as a guide as to how much time to spend on each question. f@ In.questions marke with an asterisk (6), marks will be awarded for your ability to structure your answer logically, showing how the points that you make are related oF follow on from each other where appropriate © There is a Periodic Table on the back page of this paper. Advice © Read each question carefully before you start to answer it. © Tryto answer every question © Check your answers if you have time at the end. coon HUMINT, Fonson Fdencel international Aavanced Subsidiary/Advanced Level in Chemistry B reat eee cement Materials lssve | ~ September 2017 © Pearson Education Limited 2017SECTION A Answer ALL the questions in this section. You should aim to spend no more than 20 minutes on this section. For each question, select one answer from A to D and put a cross in the box X. If you change your mind, puta line through the box 3¢ and then mark your new answer with a cross X. 1. Which alkane has the highest boiling temperature? — CA 2,2-dimethyipropane — 1 B -2-methylbutane - butane oc — Ko pentane (Total for Question 1 = 1 mark) eS 2. Which is the order of increasing boiling temperature? HH HH HH HH W= H—-C—C—C—CHO—-H X= Hee HO OH HH HH wk HH HH HH OHH Hc L0H H—-C—C—C—C-H HH HH HH/O-H «= — Oa yzxw - ve YKZW - Oc wxzy - Op xwyz (Total for Question 2 = 1 mark)3. Which statement is not explained by hydrogen bonding? _SETA alllGroup 1 hydroxides are soluble in water (1B _ many simple alcohols are soluble in water [CE the density of ice is less than the density of liquid water at 0°C 1D the melting temperature of water is abnormally high (Total for Question 3 = 1 mark) z 4 Which compound is hydrolysed most rapidly?) / f gle TA 1-chloropropane / ran 3 (OB 1-chlorobutane + We- ec— chy; [1€ 2-chloro-2-methylpropane 7 (2D 2-chlorobutane c\ (Total for Question 4= 1 mark) 5. Give the systematic name for the following molecule. Ne E-1-bromo-2-methylbut-2-ene E-2-methyl-1-bromobut-1-ene £-1-bromo-3-methylpent-2-ene (XD E1-bromo-2-methylbut-1-ene (Total for Question 5 = 1 mark) == Gas y™ —_ “ 6r Pearson Edexcel international Advanced Subsidiary/Advanced Level in Chemistry Bp si son Education Limited 2017 ample Assessment M: Issue 1 - September 2017 © a WMI1-bromobutane reacts with alkali: CH,-CH;-CH.-CH.Br + OH” > CHs-CH,-CH,-CH,OH + Br The mechanism and type of reaction is: A electrophilic addition GB electrophilic substitution © © nucleophilic addition [SD nucleophilic substitution (Total for Question 6 = 1 mark) Which of the following compounds could be oxidised to a carboxylic acig by refluxing with potassium dichromate(VI) and dilute sulfuric acid? CH; ‘ CH, —C—CH—CH, > CH, O—-H CH, OB CH,—-C-O-H cH, O © CH,—CH,—CH—CH, O-H cH, & ° CH, —C—CH,—O—H cH. (Total for Question 7 = 1 mark) Pearson Edexcel international Advance Sample Assessment Materials - issue 1 - September 201 ryiadvanced Level istry 'earson Education Limited 20178 Astudent made the following statements about trends going down Group 2. Which statement is correct? CIA the thermal stability of the nitrates decreases (1B the thermal stability of the carbonates decreases [AC the solubility of hydroxides increases 5] D the solubility of sulfates increases (Total for Question 8 = 1 mark) 9 Acolourless solid, Q, was warmed with sodium hydroxide solution. A gas was— evolved which turned damp red litmus paper blue. What is solid Q?_— ~~ rs — Pe fy NS CLA NaNO, - dy Ses ? cle Nac =) w Wad BD cao ( AJ Wa J TAB NHC wile Question 9 = 1 mark) 10 Which test is used to show that sodium chloride solution contains chloride ions? TA damp blue litmus paper turns red (1B. damp blue litmus paper is bleached (1 dilute hydrochloric acid followed by silver nitrate solution gives a white precipitate (XD dilute nitric acid followed by silver nitrate solution gives a white precipitate (Total for Question 10 = 1 mark) 7 we | Hos ene 2 . Hess whee | OS) ae fare [ae \N OB agng Pearson Edexcel international Advanced Subsidiary/Advanced Level in Chemistry ‘eptember 2017 © Pearson Education Limited 2017 1111 Compound X gives a red flame test colour and a white precipitate on addition of dilute hydrochloric acid followed by barjuim chloride solution. Which compound is X? Oa calcium chloride goby cs a dt s B lithium sulfate~ geo sent” > AZ ors (© potassium sulfate 4 JD strontium chloride ie yt De ni for Question 11 = 1 mark) 12 Which process explains the flame colour produced by the compounds of Group 1 elements? A. absorption of visible light eneray as electrons are promoted to higher eneray ey L Wee (1B. absorption of visible light energy as electrons are removed from gaseous atoms we C_ emission of visible light energy as electrons return to lower energy levels gy CD emission of visible light energy as electrons are added to gaseous ions (Total for Question 12 = mark) 13. When chlorine is reacted witK hot concentrated potassium hydroxide, the chlorine undergoes disproportionation>— What are the oxidation states of chlorine in the products? A -tands3 clg¥ \kolk K(k © KE Clos * Wes x B -land+5 “4 [! 1 ¢ +and-1 ; = ° G D +land +5 a a ate® (Total for Question 13 = 1 mark) Kel\Ox Tiss a=. ev (+5) piewel - & = Be Pearso Sample Assessment Materials - Issue 1 ‘excel International Advanced Subsidlary/Advanced Level in Chemistry september 2017 © Parson Education Limite‘Teer beers “a ve} OT Be HBr + Wr See > 6H) So2 +(e 14 What are the gaseous products formed, other than water vapour, when concentrated sulfuric acid Is added to potassium bromide? 1A. bromine and sulfur dioxide only : — [1B bromine, hydrogen bromide and hydrogen sulfide only —_ 1S. €. bromine, hydrogen bromide and sulfur dioxide only ~ 5] D bromine, hydrogen bromide, sulfur dioxide and hydrogen sulfide only _ (Total for Question 14 = 1 mark) atl 15 Zinc metal reacts with copper(l) sulfate solution. The equation for the reaction is: / Zn(s) + CuSO,(aq) > ZnSO.{aq) + Culs) A= -210kI mol (a) What is the temperature rise, in °C, when excess zinc powder is added to 50cm’ of ‘copper(Il) sulfate solution containing 0.0025 mol of copper(tl) ions? - g Kj acl [Assume the specific heat capacity of the solution is 423g" °C"). Auz=- —] BA as tH —_— OB 105 e~2le e\-So x42 KAT — de 250 — ~eezs K\laes D441 p9028 - — (b) The reaction of zinc with coppetl sulfates best classified asi, P -2 Uf Hh ao a - ta ¥ tafsoq —» “H/SAA © AN (IA. disproportionation —_ os i +? 1B neutralisation re all — wf Be Bn SLC redox <2 _ 1D thermal decomposition _ : (Total for Question 15 = 2 marks) tal reacts with hydrochloric acid. Which change in condition would pT Vv haven cfecton the initial rate of this reaction? T* 9 Pr Ya an increase in the volume of acid solution SK 5 Ce 4 CB adecrease in the temperature of the acid solution |) bate Cnet. © anincrease in the surface area of the magnesium “I — (1D a decrease in the concentration of the acid solution | / — (Total for Question 16 = 1 mark) Pearson Edexcel international Advanced Subsidiary/Advanced Levelin Chemistry B Sample Assessment Materials - Issue 1 - September 2017 © Pearson Education Limited 201717 The diagram shows the general shape of a Maxwell-Boltzmann distribution curve for Ahe particles present in a reaction mixture. Number of particles with energy, E E, Energy, € (a) How does the peak change when the temperature of the reaction mixture is decreased? he shaded areas A and B are the areas under the Peak position Peak height - f A shifted left higher - os shifted right higher -_ oc shifted left lower = =D shifted right lower (8) The activation energy of an upeais reactions represented by the vera line, E,, on the horizontal axis curve on either side of the line £,. How do the two shaded areas change, if at all, when a catalyst is added? Area A Area B me: oA increases decreases - K B decreases increases — © nochange no change - oo increases increases Sample Assessmant Materials - Issue 1 Pearson Edexcel Internat (Total for Question 17 = 2 marks) nal Advanced Subsidiary/Advanced Level in Chemistry ‘September 2017 © Pearson Education Limited 201718 The equilibrium reaction shown in the equation was studied by placing the components into a sealed glass container. 2NO.g) = N.0.(g) At equilibrium, which of the following statements is not true? [IA the concentrations of the NO,(g) and N,0,(g) both remain constant CB the total number of molecules is constant Ke the forward and reverse reactions have both stopped > GD the rate of the forward reaction is equal to the rate of the ES reverse reaction (Total for Question 18 = 1 mark) TOTAL FOR SECTION A = 20 MARKS ‘ational Advanced Subsidlary/Advanced Level in Chi le Assessment Material ‘eptember 2017 © Pearson Edu:SECTION B Answer ALL the questions. Write your answers in the spaces provided. 19 2-methylpropan-1-ol has the skeletal formula: L OH ae (a) 2-methylpropan-1-ol can be converted to 1-bromo-2-methylpropane. Give the reagents and conditions used for this reaction. Reagents Conditions Ls f (b) 1-bromo-2-methylpropane can be converted back to 2-methylpropan-1-ol by t heating with aqueous alkali. A student suggested the following mechanism for the reaction, CH, H CH, H lle il CH,—-C—C~ Br ———> CH-C——C—OH + ‘Br | rod HLH HoH OH” Identify and correct the three mistakes in the mechanism shown. s° ot ) | or — e Byr dipee vevecedy of shold by C-Bl arte! Phe cto Ol ts full he Pienedl= toc ol ta Lean SOM ONT 5 of ‘oll be foun? Oo ?f (©) 1-bromo-2-methylpropane can be converted to 2-methylpropene. y Give the reagents and conditions used for this reaction. Reagents Conditions (. (Total for Question 19 = 7 marks) of H VY cus ul " ews Iu | _ ——" =eecd = e* we cece col M ‘ ny | 4 Br) 4 Subsidiary/Advanced Level in Chemistry September 2017 © Pearson Education Limited 201720 Ethanedioic acid is a solid diprotic acid. A student used ethanedioic acid in a titration to _ find the concentration of a potassium hydroxide solution. % ‘The equation for the reaction is: aa x mn) 2KOH + (COOH), > (COOK); + 2H,0 (a) Calculate the mass of ethanedioic acid that should be used to make 1000¢m’ of a 0.0500 moldm” solution in water. Give your answer to an appropriate number of significant figures. [Molar mass of ethanedioic acid = 90.09 mol”). 4k 2 Jeo Yoos 2eaprad fore 90.0X0 +05 =415 4 (b) A student decided to check to see if phenolphthalein was a suitable indicator for this titration. The student measured 400cm’ of the 0.0500 mol dm” ethanedioic acid into a beaker and added a few drops of phenolphthalein indicator. Calculate the minimum mass of solid potassium hydroxide that should be added to produce a colour change fe Aad = Aloe YooS 2 0 ora fore He Kol coezxe 0-04 2 Hass = ovo} x [3a + \ bet] = 2-244 F Cee)"(c)_ A ftudent used a 0.0500 moldm” solution of athanedicic acid to find an accurate shceraration of pecasium Hyssdaeseuiion which was know & have aD approximate concentration of 0.1 moldm”’. Describe a roca to obtain reliable titration results using standard “Oy Rinse pipatl. wh dist Led vile, fr oy, Harediote 08, measare Coclain Vp cf Lhe ted hp Aerlet ee hd a 5 eul.-oASs. bud her ese, te © aod ell i) Rinse ee a diy L will Ket aldion,, lon ¢ Kit eg gelation vats Rele.Sl lee copie. : yee ee lo ae Mea wnt Cod er Kanye to oe x ails preloucd. vel“. Lo TA peed her ect dl Wests) ald Dow (ws 258 iF hod ph pe (Total for Question 20 = 10 marks) Pearson Edexcel international Sample Assessment Materi Limited 201721 Sodium hyd?ogencarbonate can be decomposed to sodium carbonate by heating to A about 300°C, ‘The equation for the reaction is: 2NaH{CO,(s) > Na,CO,(s) + COXg) + H,0(0) (@) Give a reason why it is not possible to measure the enthalpy change for this reaction directly. es bseld xt {s. diy Lib fo, ywasasarn.. AT... hea clog: a] = volen sop in. hahis sale / ? fi (b) (i) State what is meant by the standard enthalpy change of formation. (ii) Complete the Hess cycle that you would use to determine the enthalpy change for this reaction from the standard enthalpy changes of formation. Am aM, ate a7 (-\90\-b) +(-\8\c) 2 4 Qt 6 zl BD "earson Edexcel International Advanced Subsidiary/Advanced Level in Chemistry ‘Sample Assessment Materials - Issue 1 - September 2017 © Pearson Education Limited 2017(ii) Calculate the standard enthalpy change for the thermal decomposition of sodium hydrogencarbonate, using the information in the table and your completed cycle. Include a sign and units in your answer. Standard enthalpy changé of formation, y eopeund AH /kdmok NaHCO,\s) 950.8 “ Na,COs(3) =11307 coyg) ~3935 H.0() ~285.8 (iv) Use your answer to (by) to draw an enthalpy level diagram for this reaction, labelling the axes provided. Biasef ken (Total for Question 21 = 11 marks) Pearson Edexcel International Advanced Subsidiary/ Sample Assessment Material22 Three compounds, A, B and C, each have the same molecular formula C.H,,O and are known to be alcohols. (2) The infrared spectra of compounds A, B and C are shown. Compound A 100 Transmittance f | (06) 505 | 0 T + T T T 4000 \ 3000 2000 1500 1000 500 Wavenumber/cm"' Compound 8 100 Transmittance i — i oO 2 4000 3000 2000 1500 1000 500 Wavenumber/cm” Pearson Edexcel international Advanced Subsidiary/Advanced Level in Chemistry Sample Assessment Materials - Issue 1 - September 2017 © Pearson Education Limited 2017Compound C 100 Transmittance _ l cl 0 ' T T 4000 3000 2000 1500 1000 500 Wavenumber/cm” (i) Identify one feature, common to all three infrared spectra, which shows that A,B and Care all alcohols. B45O-.3.26.0.6r%' ees (ii) State, giving a reason for your answer, ifit is possible to identify each of these three alcohols on the basis of the infrared spectra alone. ~ iW Wf iy j add 3 allcheS contalns pet possi he Co-w> (ma Ucs'dne bond Pearson Edexcel International Advanced Subsidiary/Advanced Level in Chemistry Sample Assessment Materials - Issue 1 - September 2017 © Pearson Education Limited 2017(b) The mass spectra of the compounds A, 8 and C are shown, Compound A 100-4 80-4 Relative 604 intensity 404 205 0 lu sl Wedpeerereer 10 20 30 40 50 60 70 80 90 m/z Compound B 1004 804 Relative 60>) intensity 404 20 | 0 sorting rritherrey + 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 m/z Compound C 100-4 804 Relative 604 intensity 404 204 o+ + ~ Hrerrep ate py 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 m/z BD Pearson Edexcel International Advanced Subsidiary/Advanced Level in Chemistry Sample Assessment Materials - Issue 1 -September 2017 © Pearson Education Limited 2017(i)_ Identify one feature common to the mass spectra of compounds A, B and C which shows that the molecular formula is CH,.0. eS CA Wied 24 nebo ton pee AX(Z Alot Lb =44 (ii) Using the fragmentation patterns, a student proposed that: compound A is butan-2-ol compound B is butan-1-ol compound € is 2-methylpropan-2-ol State how the appearance in the spectra of the following peaks s student's conclusion —~ the fragment causing the peak at m/z& 45 for compount (A NOW=445 the fragment causing the peakat m/z = 31 for comppund | i ts be C—-G td oW CH2 oh ash UT ie \ the fragment causing the peak at m/z = 59 for compound, 1c a (tle Leoyt=.5.4 He- Gey | OW Pearson Edexcel international Ad Sample Assessment Materials id Subsidiary/Advanced Level in Chemistry september 2017 © Pearson Education Limited 2017 sue 1(©) To help with the identification of compounds A and 8, the student decided to mix each of them with potassium dichromate(VI) and dilute sulfuric acid solutions, and then distil the mixture immediately. (i) Identify, by name and structural formula, the organic compound present at the conclusion of each of these two oxidation reactions. Organic compound Name of oxidation Structural formula of oxidation product used E Woy \\ Abu Bufinene I> ~~ é - ¢ als 7 p uk K Woy 8, butan-1-ol B ud ne { i F _ fe \ Pos ¢ \ Xt i To identify A and B, the student decided that saa her chéthical test should bbe used on their oxidation products Give a suitable reagent and expected observations that could be used to distinguish between the oxidation products of A and B. erie lien | A gives. AL dA Le. (eh YEN ee est ctl Prebbrwg 5 soled (en (Total for Question 22 = 12 marks) oridelion # — isles Kefiemr. TOTAL FOR SECTION B = 40 MARKS 9, Lit ns sh rontf At Feb ting’s slut on Pearson Edexcel international Advanced Subs Sample Assessment Materials - Issue 1 - September 2 jary/Advanced Levelin Chemistry Pearson Education Limited 2017SECTION C Answer ALL the questions. Write your answers in the spaces provided. 23 lodine monochloride, ICL is a covalent compound produced by the reaction of iodine with chlorine. lodine monochloride is a dark brown liquid at! room temperature, The equipment shown can be used to pass chlorine over solid iodine to produce iodine monochloride, ~ chlorine gas, Cl; % 2s ‘yf \ toding'soli, L When excess chlorine is passed through the U tube, the iodine monochloride reacts to produce iodine trichloride in an equilibrium reaction. (a) Write a chemical equation for the reaction of iodine with chlorine to produce iodine monochloride. Include state symbols, —»e#le i < ¢) ele lo &) Pearson Edexcel International Advanced Subsidiary/Advanced Level in Che ‘Sample Assessment Materials - Issue 1 - September 2017 © Pears:(b) The iodine monochloride molecule has a permanent dipole. Complete the following table using the electronegativity data from your Data Booklet and hence show the dipole on the diagram of the iodine monachloride molecule. Element Electronegativity cl B-o | 25 st g- 1—c (©) lodine monochloride reacts with propene to form two isomeric products. This is an addition reaction that is similar to the reaction of propene with hydrogen halides. @ pre te Gated formulae of both isomers. | 4! W i hee fad 4 a Wc ee cad = Gl \ ca 4 Ex a ft a ‘A LI DB Pearson Edexcel international Advanced Subsidiany/Adv vel in Chemise Sample Assessment Materials - Issue September 2017 © Pearson Education €fhited 2012(d) The equation for the reaction between iodine monochloride and chlorine is: Ic) + CLig) = ICs) brown liquid yellow solid (i) State and justify one precaution that must be taken when preparing iodine trichloride. (ii) Give the oxidation number of iodine in both iodine-containing compounds in the equilibrium. Hin ict + (A aed Oe) } Tin Icl, ate (-E-3-<-0} - INS (iil) lodine trichloride can also be made by reacting potassium chlor eV) with iodine in hydrochloric acid. The equation for the reaction is KClO; + 1, +GHCL > KCL + 2IC, + 3,0 Pearson Edexcel international Advanced Subsidiary/Advanced Levelin Chemistry Sample Assessment Materials - Issue 1|- September 2017 © Pearson Education Limited 2017 \(e) Chlorine gas has a molar volume of 24 000m? mol” under the conditions used in this reaction, (i) Show that the density of chlorine gas is approximately 3 gdm” % C ess) Hel, A = (il) Airhas an average density of 1.25gdm*. If the U-tube used in 23(d) is inverted, 5 shown in the diagram, the solid yellow iodine trichloride produced in the equilibrium reaction turns to a brown liquid. iodine trichloride, ICl, cle ee / cv os inverted U tube Tel cl, —=Ielxu, brew 8 (4-8) Explain this observation. Pearson Edexcel International Advanced Sub: Sample Assessment Mate tue 1 ~ September 2017 © Pearson Education Limited 2017Fotke wal fl (f) A mass of 0.64g of iodine reacted with fluorine to form 1.31 g of a fluoride of iodine. 2 Calculate the empirical formula of this compound of iodine and fluorine, \ aie (Total for Question 23 = 20 marks) TOTAL FOR SECTION C TOTAL FOR PAPER Pearson Edexcel international Advanced Subs diary/Advanced Level in Chernistry Sample Assessment Materials ~ Issue 1 - September 2017 © Pearson Education Limited 2017