jas | Metal Acetylacetonate Complexes: | Preparation and Characterisation | scp cH,COCICOEN pal ine oid [Scientia | caucocnicocn, = Ws erscocnooet a | “The reling anion ana 8 gan towards mt ns fring compen in sich lipid issu bonded the meal ough bob onsen tars, hence Forming merce ing 02). “, * Pe we. | ey “so "New ° nd wd | tn prowl he comple soe rye sd a neta vo has metalion | ee nang ntccty MICH {COHHCOCH ACV,COCH,COCH, + MT" = at" + MICH,COCHCOCH), o In the comple, snes the MOG stmembered rings ae planar and contin 6 ‘Geto they uy teped a wey sate Im M{HCOCHICOCH com Paes the MO, aay eahera a Cu(CH,COCHCOCH,) the C10 0p {are ana a in O(CH)COCHCOCH). th VOs groups ager yam a pre acct, ein elton on pa orgaic ae he det Son sn cba th ye ene fr 9). «hind ae ay eee a compo whch ton es this experiment. ou wl prepare apd pene metal comple ons renee stot ths) a8 Sen the compares ins mia comps ‘ing thin jer chromatogra You wll meet Hand °C NM sta pada year epreernte arp Spc Sey Pecans 1. Vana pet V0, te 2. Gydobeanes Manne, 2, All origi wate from eilistons met be pie nthe wae ‘oes proved permet 2) Meal Aycan oe Tigh nos 100m con Mask (cane 00 mol of acento ngs roping ite taal the aint te se A840 om feted water flowed by 8 co Sal de aon soliton (8 NH,OH). Dare 3 {0005 rl sain spe [S04 6H,0 8 30 om al id ‘ste To the alost clear elt afte stmt aceaetane slton poe ‘kona wth shaking fer compete do ofthe seactne check te pH ing ‘es pope pt piper) and he ston il ee a rhe sal ons of Sen damon sls ant tinea mus Allow tad for mint, Fler off he cea lured prac the water pump wa th {Won ofl dle water apd nck yor 1 mater "ptr th dy prado weighs! sample tea ey in aa deca wear CCl, Meh te dy praia th peretge eG AP 6 CH,COCHCocH, + 51+ AlICHCOCHCOCH, ° Recylie 2 small sample c, 05) fom oedserne. The ring neder ‘foul be ced a the eater pump. waded ith Ul clde¥rne nd ‘hed dey for 5 ines Rec he meng pt (10P comple Pine cmt dled water in #50 on “Qu round nore sk and owiy tet an eal wane of cocentaed HySD, Then 2881 of cana owe y 25 fe 014ml vrai pene. V0y, Add ater od wert ‘uewer an fn ip sue fr soot 13 hours ver 2 sal buen ame ‘Presloon wile tar geen lou Cal the mare ude the ap and [hc ig coton neal daring ay sa edoe Add 6 cn of aceaeone “Tope te ste ih hakng Newaine tema trey aig ert Sn of 20 fete 1,005 150 edd wae otaind in 2 Svan cones dash ie sing the mtr sing magnetic se The els (eee shoul then be ole ne water for 5 utes eo itering at he (isp wach the keen pc ih col tid water (215m) Sky Erne puny 5 minutes then dy aacaum deseator over aryoas Cah, ‘Meh the died product elt he centage eld Eqs 087, V0, 4H + 290)" +240 1/205 o oy" +2eH,CoCH:COCH, + 2H" + VOKCHCOCHCOCH a se sl atin 5 4) of he cade, dy produc in 6m! dele (thane ean rm any edo A820 em oi tale. 40) Great te movoreand allow ttn for 10 anaes. ler of the prod a ‘heey pump and wash with cll etl 220 em’, Suck dy and rece ‘hemi pot SS Ty 1c coal ak 14 0085 pdf cei RESETS Shc rect and abe in 0 cn ie wate eg Sura ae Togs nin St prion the deep geen comin aon, ‘hing wh iene a) 00 opi Oe we Seth eng mire covet nth wah iso beak SARPCRSS cone pe Moore emperor ne se oe nay ay dat so st km pee, a Om Tce sep mrcape cyl im Aer 15 ws ng. e/Sc elon mane td rl the psc tthe water pup Do et wa SERS Sa ima eed he penne eg #208 {copNitys + HO ~ INH ¥COp 6 "6 3CHJCOCHLCOCH, + INH = SNHEFGYCHACOCHCOCH “Te es undergoes slow ols berg ammonia, whch then conta he pith acon mire ‘ashes anal sample (04g) aprox. 70cm" of aig dane, a reduce thet sat al th yang 2-3 atebue eee sae ol tng on 1 seam a in ne coped ad then allow 1 a ine deep oede a he wate pup Sik hen eerie te ‘eeing pot aiMe compe Dae 265 001 ma of manganese) core tay (MnCl 410), and g (O05 ma of sda cre in 10 cn of ied weet Ad 1 (6.01 ma facccion and shat he mise befor ane. porte eth magnet string» ction a 052g 0003 rl posi: permanant 2 em! fds wae ensue Bat the KB comply dre ase roping ppt fort sion wach sho se 10" mints), for farther 1 mites a tena iar anne solution of 3g (2 0045 nosh cate in 25 tied wae Whi sl rng, beat ‘he resng dick mate 092 Bot plat een and 30 €or 1 me monitor he leper ning 3 sit se thermometer ‘emprare Flr ff 3 dhe cer pp the ery dar ales! lack pot od shih 6b of alee we Sick dy far mates tin tum dear over anos CCl, Weigh the iy pod nd ced he et "The tachi of th repaint. firs the Mi) ame farmed cag fan (10) Te manga thera he mange ‘ft permanganate ve mangas 1a. nate the era homer Eg (3) Mai" +s 2CHCOCH,COCH, ~ 2H" + MnfcHYCOCHCOCH, ‘0, nov «exo SMa “ SMa" +0; SCH COCH,COCH, {00 7H" + SMaCH,COCHCOCH), 13) ‘The purpose odin sce mare the ad reed snes sid feat dg) 7H «7¢H.COO™ + 7eH,00011 wy 4 thi preparaten, the potassium permanganate ste ling component on bh peemage sso be ed tel KOs hes el pou aout 02g othe dy crue poe contain 75 cn coal ok, | 12a efelobenane and bon rama | mate Pe somal fs ‘lin the nek a he aso aa cdr Allo te we ste fir seconds ee carly decanting ry sl esi sn slr 100 ‘onal fk Reheat fr I iat enor comple ation Yel dng 4c? ‘flight pele bp. 406) Col don tora tempest smd hon at futher in ae wer bth fr 1 mites Flr of the wes pt ck “stows eles, wash with 10 em af light pole kyo 3 mt ‘er cid he meting | 21 en cr Coa [ 89 compan ey Diaohe 33. (2 0012 meb of fund ot) chlonde hewhydete {Wey 6,0} i925 cn'o cel water Aad oer per fIs mines eh ‘on 24g (2 0058 mal acetone a 10 cn etal heap he on ung lage map stir Ad the resin lod ed mare vt 2 penal ofS mimes ssn of $1 po dum ae fn Ise ofl “ler maintaining te rng thong. At thie pos ed cytline sd ‘oul pepe Het he tle apy sout 80 using sho pate on "he tmperane with «shot ster temo sh Kea thi ergo fr 15 mines sll maining Taped suring Cool oom temperate unde the tap ad thoy ae ter tt Fae fhe pradut te mates pomp. Kash ‘th 0c ofl sted water apd sc dy fr 1 mites Tomy fa. Shum descr oe snares CaCl, Weigh te dy pod oder engl (gh) ‘The sos aaa eae he acl led: tc ai ica weak 2 015), Fe SSCH,COCHCOCH, + SH FecHRCoCHCACK, 0) 3H «3€14¢00° = scHjcoon. a5) Weigh 02 got the did cre prt ine 225 cm! conka ap eda 3 em? sled ater Warm oo a stem tha 8d methanol dope maining es ‘heating tlhe repro ut detent ane ater oT 1 mines, ler a seme pnp sock ey for 1 es an ily ey 0 ‘cum destetr or sai Cx, Rec the ting pn 2 empl ‘igh no 1 cone ask 25 gc. 021 eo) of sat atenateand ad 20 (0.20 mao ath atane Hest the mre abet 90°C 0 bea eth cominuus sing Monitor the tempertare oh shor sem ence While intaning th emperatice sound 80°, a8 drop 9c 108 roger tion wing dropping pent Cove ask wth wath le berwe 10; anos. The whe stor a the HO, slaton shuld ocupr stout alan hour Sing thule santaiedtraghoa the seston nd hen “orafurter 1 mines Cl nantes ahr Me ie te dar een produc tthe ate pup sky fr 5 mms edhe yin en Toc Weigh hey ruc arch pening el (ge. 7 an Inte preparton he Cf compe oe tng Ei (0, Ta {a complex then ne the Pdogen pero Eg. 1) and he veal ‘slhrcty ay be writen 8 (20,4 2CHYCOCHCOCH, + 0, H50 + CafEHLCOCHCOCHY, (16) 2c +40) + 20042080 om, ae26004 + BEHCOCH,COC +0 + }eateescoeHoCI + 200; + ‘Ade 3 of he deed produc 10 emf nen an at for oS nes vase bth Alm stl fo shut sate apd oe eat he wry {Eat stonintos Wl Bak thougha sal gf cton wos conaine nk fier ann Rees! hewn nl then ns 0 crt gh pec {ip jen Cop oom tempera hen a ee ah 8m Wee the wat psp sd was heels wih 0. ad gh ea. a compen “ia sno 0.025 mk cope rid te (Cals 2810 in Bem fied ater cotained in T90c coical isk. drpuieoer pevid of 30min 4 clon ofS cm 2 005 ma} of sceocdone in 10cm Tethaol. lle mining coneat sing. Ad tthe vsalng mit andor see cn dled water nex pte mn Hes the i fhe ok BC oa hot pls fr 19 utes sl mating apd sing {Momo empertue witha bat tem thermore Coot foo tenet ftv and te Inne wats tt Tae ff te Mey po at he mae mph eth 100 cn? aco led trad sch dy fic 1S ae be Fee ding ina nen 3 TDC. Weigh he ry prod and recor the percentage vitae, us 1cH,Coct,Comt, + 24° + cxlcHycoctcoct, 0 “he sds sate ddd to nee the H Mera ac ads weit (t5p-2, 1 ¢H,C00" ~ cH,CooH 0) “about 02g the dd cre pra ota i 2 100 ccna ask ad 2S cm el methanol ni? aiebuyping pales lace al ker fan the eck the ak oc et conte adel on a ear at fr 5 rine ‘Gefly dcat aywli esde he ue ator seo 3 can 10 Ask ‘ning tut co hot methine Ca oom temper ber Hing ff thefie grey nll the water pap Ws ith ite cea thal Sedma pm ‘Sta nlf yur re prin peda nection 1) Thin taper Chrmalogpy te fetal Acetone Compe ‘he is wef eligi entabliing eter the numberof open ina Fine o aber ars gen euanceepre. Fries ts pos ‘ie byconparcon wit we uitanc esa he en the al 196 Ae! cto Comes [88 ompanets Te eatonay pac is wal shes (80) fuming (09) read SURES ile ahs gh pte ran sama ced Se Wha tnt an mrp emcee fo enitn of cous co Peat cpm unt hte male pane ca be ay ull Pei caknors educa ton te frm a ery small pe “Chappe! wag» het tgp tb. nhs rpeiment mime Auda atcdyometed whe welt comple eed seats coparson mh spies of the pore metal cytes. ‘pet cacophony npn et cae ob nthe Sorsogapy othe compe ons wou Bence Tonal wisn sins, ne conti ite em ace inn pie fm VOR CO Mae aa a" om SSR erm tf er ona cna oe We pa comps abo dae dboretane Dew rein it Mit toraetm pring tee pes oats demons Per Shore nkroen re sd ep nares ot the a sng sone an 2m nS The push be ne aba om ‘aE hace ete ple ach slo le pte ed naa "Pine seca ete NO} Cran Cu can be espted pe i te eee act peat rsoting 05 om deh of 1 sein nat CH, roid na Wieser te) ensuing Sat hep of he create iste ine cp Ale on fo 30 mina, afer nich ine SEGA iomcteld testes ese mayo he lite Meare Rie rec Sjr able hs th he apr lus ue he copenion of ) Nuclear Mog Resonance Spear of Reacts te ths section te "and MC NMR spc fone damagetc metas ler ACHSCOCHCOCT and acne sl ae enamine sd ase Tobe Nespas ot fie erie he pr wee ined ng sere pale nguences, Nove ht al dhe "Caper howe the HC cw Sing aspen ond not dae tm he neal secu al tps of eb ton (ly My CH and guteray Ce pel. In he DEVT sec ‘Mum te eanans ee sunt re sspessd ad hoe de 1 Hs ate Tivened ie the DEPTI0 sperm. oly the resonances ve © CH apPet Tee tur peso bon ernment ee ete ‘Tan fe he NC ecru of ACH ;COCHCOCHG) (Fg. 3161) ad. ea agama tha hc anda al syne and quan (0) meat ‘Tevet, sign he rvnances Not tig He spectrum of Bis complex (Pe 3102, sone tc, ah toad enlace he eee rpuded ae comple of HH and 5C NMR pea ay Be RET in Sms wath owe ofthe ahi comple mie festester ne cnet ALCACOOHCOC she Me spam Fig. 3163) an ang the resonances de othe eal amet 1 companion wih Figure 361 hen si the eo resonant, Fraly 2 {he pec Fg 4) gs by comparison nh Figure 162 anc cate the ket end ta. 116 meat nce Cams [187 Te rg 1062 The Hamre MOMCOOOC 4, Mee Spc of ict isAoin Compe hems ai ncn conics ening Fh te ™% a8) deny he composition fhe ons 2/10. 98,72 30d 4, and age ‘uterine Suggest also hey mightarse. presto the sues of Teton haog a=.pe] end re Cea e wae wee TTS 3262 th ¥cwipanon fOcOOmOCH tng ten den emt 216 a Att Co re N64 Thoms COCO cig then and ee os, “The mass pect of th lumina comple Alaa) conan he flowing ™% n19) ia "0 toting /.24 25 6. Sae op he ions harng "226 6 td 12. Set Sear e ie ang ‘owe omposion (HALO