4. 22022021 Assignment # 3-B Foundation Batch PHYSICAL CHEMISTRY (Topic : Chemical Kinetics) (Sub Topic : Effect of Temperature and Catalyst) (JEE-Mains & Advanced 2022) Reaction-1: A—+C Reaction-2:B —>D Select the correct option about above first order reactions : (a) Ey, > Ea, (b) by =, if P> 100°C (©) rate, = rate, if T > 10 C (@) percentage of effective collision at temperature “T for reaction, > reaction by = 1010 e500 ky = 1012 ¢-10007 ‘The role of a catalyst is to change : (a) Gibbs energy of reaction. (b) enthalpy of reaction. (©) activation energy of reaction. (4) equilibrium constant. A first order reaction is catalysed by a catalyst which decreases activation energy by 420 cal. Ifhalf life of reaction in absence of catalyst at 300 K is 20 sec., then what would be half life in the catalysed reaction at 300 K? {In 2 = 0.7] (a) 20 see (b) 10 see (©) 5 see (a) 15 see For two reactions : R-I and R-II the rate constants at 300 K and 320 K are 0.1 sec"! and 0.3 sec? respectively (for R-I) and 0.2 sec-! and 0.8 sec~! (for RAD. Which of the options regarding activation energy is correct? (a) Activation energies for both the reactions is same. (b) Activation energy for first reaction is more. (©) Activation energy for second reaction is more. (@) Activation energy for second reaction is 4 times as that of first reaction, 5. For a first order reaction rate is given by; R = K [Reactant] where K =A-e+/F", Under what conditions will the rate of the reaction be smallest? (a) Low concentration of reactant, high temperature and low activation energy. () High concentration of reactant, low temperature and low activation energy. (©) Low concentration of reactant, low temperature and high activation energy. (d) High concentration of reactant, ‘temperature and high activation energy. low The energies of activation forward and reverse reaction for Ap + By —> 2AB are 180 kJ mol~! and 200 KJ mol! respectively. The pressure of a catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ’ mol. ‘The magnitude of enthalpy change of the reaction (Ag + By —> 2AB) in the presence of catalyst will be (in kJ mol) : (a) 280 (© 300 (b) 20 (@) -20 For an elementary reaction the variation of rate constant (k) with temperature is given by the following equation. 100 logy k = 5.4 — T where ‘T’is temperature on Kelvin scale and & is in terms of sec“! Identify the incorrect option. (a) There is no finite temperature at which rate constant can be 4 x 10° sec. (b) Fraction of activated molecules will be e100" at any temperature, (©) Activation energy for the reaction will be approx 460.6 cal. (@) Rate of reaction will vary linearly with concentration of reactant. Nirmal Academy for Science Edueation (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 74589100918, If it is known that 1 out of every 4 collisions has appropriate orientation and activation energy is 2 Keal, then % of effective collisions at 500 K as per collision theory will be : (a) 25 e* () &? © (d) 0.25? 9. In the respect of the equation k = AeW#:/PTig chemical kineties, which one of the following statement is correct? (a) kis equilibrium constant (b) A is adsorption factor (©) E, is energy of activation (a) Ris Rydberg constant 10, The variation of rate constant with temperature follows the equation In = 80 ~ $2 + 207 —30In 7 based on this information, identify the most appropriate option. (a) E,at300 Kis approximately equal to 1.08 x 10° R. (b) E, will remain constant at all temperatures. (©) There is some temperature greater than 50 K where E will become negative. (4) Rate constant will follows Arrhenius equation. 11, For a certain gaseous reaction a 10° C rise of temp, from 25° C to 35° C doubles the rate of reaction. ‘What is the value of activation energy? 10 (by 2308x210 298 x308R 0.698R_x 298 x 308 f) 0.693R x 10 Go 290 x 308 @ 10 12. Following are the values of E, and AH for three reactions carried out at the same temperature : 1:E, = 20 kJ mol", AH =~ 60 kJ mol* I: E, = 10kd mol", AH =~ 20 kJ mol IT: E, =40kJ mol-!, AH =+15 ks mol If all the three reactions have same frequency factor then fastest and slowest reactions are Fastest Slowest (a) I 0 (b) 0 mL wr mL (@) can’t be predicted 2B. Milk turns sour at 40°C three times faster than at 0° C, Hence, E, in calories of process of turning of milk sour is : 319x273 313x273 49 40 2.808 x2%313x273 (1 py 2-808 2318 «278, © me ) 2.908 x2 40, 2,808 x2% 40093 © “yraxsi3 (a) none of the above 3. 14, Two reaction, A —+ products and B —> products have rate constant k, and k, at temperature T and activation eneigies E, and E, respectively. If k, > k, and E,, < E, and assuming that A for both the reactions is same then : (a) athigher temperature k, will be greater thank, (b) at lower temperature &, and ky, will differ more and k, > ky (©) as temperature rises k, and k, will be close to each other in magnitude (@) all of the above Nirmal Academy for Science Edueation (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur Contact Number : 9889655556 , 7458910091