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    Periodic Classification Ques

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    Newbie Magician

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    PERIODIC PROPERTIES ~ Level O , >| Periodic Table 1. ° Which is not similar characteristic(s) about the electronic configuration of Be, Mg, Ca? (a) All the atoms have a pair of s-clectrons in their outermost energy level (b) All the atoms contain a pair of p-electrons in their outermost energy level (©) All are alkaline earth metals (d) All are of second group of the periodic table The elements with atomic number 117 and 120 are yet to be discovered. In which group would you place these elements when discovered ? (a) 17,2 (b) 16,4 (© 15,3 (@) 18,2 The most electropositive element possesses the electronic configuration : (a) [He] 2s’ (b) [Ne] 3s” (© [Xe] 6s? (d) [Xe] 6s? Which one of the following elements shows both positive and negative oxidation states? (a) Cesium (b) Fluorine (© Iodine (@ Xenon . The number of elements present in fifth period is : (a) 18 (b) 32 On) (d) 24 Which of the following arrangements shows the correct order of decreasing paramagnetism? (a) N>Al>O>Ca (b) N>O>Al>Ca ( O>N>Al>Ca @ O>N>Ca>Al . The outer electronic structure of lawrencium (atomic number 103) is : (a) Rn 5f!37s?7p? (b) Rn 5f6d" 7s! 7p? (© Rn5f"7s!7p? (d) Rn 5f!*6d!75? The elements with the lowest atomic number that has a ground state electronic configuration of (n — 1) d®ns? is located in the : (a) fifth period (b) sixth period (©) fourth period (d) third period 10. 1. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 9. . esponds to elements of group 16. Which of the following sets of atomic numbers core Cees 2 (a) 8, 16, 32, 54 (d) 10, 16, 32, 50 hich are 8, 16, 34, 52 , ts which are liqui The some rumbers of the metallic and non-metallic elemen Aid rpg temperature respectively are : (@ 80, 35 @ 5587 (by 33,87 aes shows one ofthe following ty, In te periodic table, metallic character of the elements shovis end (a) Decreases down the group and increases across the pen A (©) Increases down the group and decreases across the perio (©) Increases across the period and also down the group (@) Decreases across the period and also down the group Nucleus of an element contains 9 protons. It’s valency would be : @1 () 2 © 3 @s Transition metals are not characterized by : (a) fixed valency (© high melting and boiling points Sodium generally does not shown oxidation state of +2, because of its : (a) high first ionisation potential (b) high second ionization potential (©) large ionic radius (@) high electronegativity Which of the following pairs of molecules have the almost identical bond dissociation energy? (a) F, andH, (b) N, and CO (O Fy and, (@) HF ando, He orcing to modern periodic law the properties of elements repeat at regular intervals when the elements are arranged in order of : (b) coloured compound (@) tendency to form complexes (@) decreasing atomic number () increasing atomic weight (©) increasing atomic number (@ decreasing atomic weights Gite the symbol of the elements of lowest atomic number that hae three 2p electrons : (a) Mg (@) P ON @ si In the fourth period of the periodic table, how many elements contain one or more 4i electrons? (a) 2 (b) 18 ©o @ 6 Assuming that elements are formed to complete the seventh per} ue fumber of the alkaline earth metal of the eighth period? Poe What Would be the ator (a) 113, (b) 120 © 119 (d@) 106 Which of the following represents an excited state of an atom? (a) [Ne] 3s?3p° 452348 (b) [Ne] 3523p° asl gq (©) [Ne] 3s?3p° 4s23q! @) 157252255341 Choose the correct statement regarding transition elements? UND 22. 23. 24, 25. 26. 27. 28. 29. 32. 33. 34. Which one of the following is a different Pair? (a) Li, Na () Be, B: » Ba © N, As d) 0, Ai The element having electronic configuration [Kr]4d"° 4 f" 5525p6 a ee to: ) a , (b) p-block (©) d-block (d) f-block ich element is named after the name of a planet ? (a) Hg (b) Po © Pu @ Ra Zn and Cd metals do not show variable valency because : (a) They have only two electrons in the outermost subshells (b) Their d-subshells are completely filled (c) Their d-subshells are Partially filled (d) They are relatively soft metals An element whose IUPAC name is ununtrium (ut), belongs to : (a) s-block element (b) p-block element (©) d-block element (d) Transition element Which of the following is not a representative element ? (a) Tellurium (b) Tantalum (©) Thallium (@) Astatine Period number and group number of "Tantalum" (Z =73) are respectively : (a) 5,7 () 6, 13 (6,5 (@) None of these Which of the following pair of elements belong to the same period? (a) Mg and Sb (b) Ca and Zn (c) Na and Ca (d) Ca and Cl Consider the following electronic configuration of an element(P) : [xe]4f'*5d" 6s? Then correct statement about element 'P' is : (a) It belongs to 6th period and 1st group (c) It belongs to 6th period and 3rd group Which of the following metal is most electropositive (metallic) in nature ? (b) It belongs to 6th period and 2nd group (d) None of these (a) Be (b) Rb (©) Mn (@ Tl Which of the following species contains maximum 'd,,' orbital electrons ? (a) Cr (b) Fe* (©) Cu* (d) Both (a) and (b) ation between atomic number (Z) and i following graph is correct represent er (@Z) Which oe ee Jectronic configuration : (n - )d*ns' 7] magnetic moment of d-block elements? [Outer el ge ge £2 gs gg BE 3 3| Be BE o eA @ BE og / Bl / Be Hl = — — = z / a is" ium" .ct statement regarding element is that: of an element is "Unununium then corret ardin men eeane transition element (b) it belongs to 8th period in periodic table (os eansit (d) it is a non-transition element (c) it is transition element 35. 36. 37. 38. 39. 40. 41. increases fron 7 jod and increases from top, e perio 0 be across th “a ation energy (iv) Metalic Gi) ight Which property decreases from left 1018 in group? jvity (iii) Ionisa a o svomic radius il) Blectronegativil « sl ‘ i I (a) @ only oS (© (@, ii) and Gv) ) dQ: i JJements P an‘ Consider the following informatio} tel yn about Group number Period number fa a 3 d by P a is: Then formula of the Gere formed by (PQs ony ae electronic ae must represent 2 eras opt ae aa (d) 1s?,2s72p* (©) 1s?,2s?2p*,3s? A compound contains three elements Pa and C. e ie and C = ~2, then possible formula of the compot : a ase (@) A,(B,C)> () Ag(BC4)2 (© A2(BC3)2 oe a Consider the following four elements, which are represented according to long form y periodic table. idation number of A = +2, 5 a [wix[z] Here W,Y and Z are left, up and right elements with respect to the element ‘X’ and ‘X belong to 16th group and 3rd period. Then according to given information the incorrect statemer regarding given elements is : (a) Maximum electronegativity : Y (b) Maximum. catenation property : X (©) Maximum electron affinity : Z (d) ¥ exhibits variable covalency Which of the following sequence represents atomic number of only representative elements? (a) 55, 12, 48,53 (b) 13, 33, 54,83 (©) 3, 33, 53, 87 (d) 22, 33, 55, 66 The ground state electronic configurations of the elements, U,V, W, X, and Y (these symbs! do not have any chemical significance) are as follows : U_ 1s?2s?2p9 V_ 1s72s?2p°3s! W 1s?2s*2p%3573p? X 1s?2s?2p°3s?3p%3d5 4s? Yy 15°2s?2p°3s73p93d" 4s24p6 Determine which sequence of elements satisfy th e followi (® Element forms a carbonate which s not decommonsne eseemen Gi) Element is most likely to form coloured ionic i Be eating (iii) Element has largest atomic radius ae (iv) Element forms only acidic oxide 42. 43. 44. 45. 46. 47. 48. 49. 2 @vwyu y (b) VxYwW jvwyx @vxwu When n ‘sium burns in air, compounds of magnesium formed are magnesium oxide and : () Meany (b) Mgco, (c) Mg(NO,), (a) Mgso, Which of the following ions is most unlikely to exist? (a) Li (b) Be © B (d) FE A,B and C are hydroxy-compounds of the elements X, Y and Z respectively. X, Y and Z are in the same period of the periodic table. A gives an aqueous solution of pH less than seven. B with both strong acids and strong alkalies, C gives an aqueous solution which is strongly ine. Which of the following statements is/are true ? IT: All the three elements are metals. IL: The electronegativities decrease from X to Y to Z. Ill : The atomic radius decreases in the order X, Y and Z. IV :X, Y and Z could be phosphorus, aluminium and sodium respectively. (a) 1, IL, II only correct (b) 1, III only correct (c) Il, IV only correct (d) U1, IML, IV only correct La (lanthanum) having atomic number 57 is a member of : (a) s-block elements (b) p-block elements (©) d-block elements (@ flock elements If the aufbau principle had not been followed, Ca (Z =20) would have been placed in the : (a) s-block (b) p-block (©) d-block (d) feblock What is the atomic number of the element with the maximum number of unpaired 4p electrons? (a) 33 (b) 26 (©) 23 (@ 15 ‘The electronic configuration of four elements are : @ [kr]ss* (I) [Rn]s f'*6d" 7s” (IID [Ar]3d"° 4s?4p> (IV) [Ar]3d® 4s” Consider the following statements : (@ I shows variable oxidation state (ii) I is a d-block element (iii) The compound formed between I and III is covalent (iv) IV shows single oxidation state Which statement is True (T) or False (F)? (a) FTFF (b) FTFT (©) FFTF (d) FFFF ; If period number and group number of any representative element(s) are same then which of the following statement is incorrect regarding such type element(s) in their ground state? (Period number and group number are according to modern form of periodic table) (a) The possible value of principal quantum number is 2 (b) The possible value of azimuthal quantum number is zero (c) The possible value of magnetic quantum number is 1 ST . Id be paramagnetic , Is increase from Be ¢ 50. ie ‘ofthe following properties of the alkaline ae iard 0 Bay : (i) Atomic radius (ii) Ionisation energy aaa i) (a) @ and Gi @ @ Gi and Gi) “4 (c) Gi) and (iii) ‘h for the position of element in Periodic Labjp 51. Which of the following is the incorrect mate! (a) [Ar}3d°4s? > 4" period, 6" group (b) [Kr]4d"° +> 5" period, 12" group (© [Rn]6d?75? + 7" period, 3 group (d) [Xe]4f!45d?6s? > 6" period, 4 group 52. Which of the following anion has smallest radius? . (a) H~ (b) F> (c) Cl” (d) Br 53. The ionic radii of Li* ,Be?* and B* follow the order : (a) Be? >B* >] j* (b) Lit >B* >Be** (© B* >Be* >1it (d) Li* > Be* >B* 54. Among Na* , Ne and F~ which is largest in size ? (a) Na* (b) Ne (©) FO (d) all are equal 55. Which of the following atom or ion has smallest size? (a) F (b) F~ (c) O (d) N 56. The single covalent radius of P is 0.11 nm. The single covalent radius of Cl will be : (@) smaller than P —(b) greater than P —(c) same as P (@ twice of P 57. Which of the following is arranged in decreasing order of size? (a) Mg®* > Al* > 02 (b) 07 > Mg > al (c) Al > Mg?* > 07 (d) Al* > 0? 3 vig 58. The correct order of increasing atomic radius of the following elements is: *(a) SPb* >pb ©) Pb> Pb 5 py at (©) Pb>Pb** > Pb @ Pb** > pbs py 61. Incorrect order of radius is : aa : (a) Sr™* te pm 0) ND Co* >Co* >Co (@) Ba2* Ti>V>Cr (b) Co>Ni>Cu>Zn (©) S* >Cl >0* >N* (d) None of these 63. The radius of which ion is closest to that of Lit ion? (a) Na* (b) Be* (©) Mg** (d) Al* 64, The set representing the correct order of ionic radius is: (a) Na* > Mg” > Al* > Li* > Be?" (b) Na* > Lit > Mg > Al®* > Be* (©) Na* > Mg” > Lit > Al > Be? (d) Nat > Mg?" > Li* > Be** 65. In which of the following pair, both the species are isoelectronic but the first one is large in size than the second? (@) s*,07 (b) clr, s? (© F>,Na* (@ N*,P> 66. The correct order of ionic size of N*,Na*,F~,Mg”* and O* is : (a) Mg >Na* >F> >0* (b) N> > 07 >Na* >Mg® (©) Mg” 07 >F> >Na* Gd* >Bu* >Lu* (b) V7 >v* ov ov (¢) TI >In* > Sn* >Sb* (d) Kt > Sc > V5 >Mn7* » lonisation Energy 70. The first, second and third ionisation energies (E, ,E, and E,) for an element are 7 eV; 12.5 eV and 42.5 eV respectively. The most stable oxidation state of the element will be: @ +1 (b) +4 © +3 @ +2 71. Element having highest LR value is: (a) Ne (b) He (© Be @N 72. The order of ionisation potential between He* ion and H-atom (both species are in gaseous state) is: (a) LB He*) = LR (b) LR (He*) < 12 () (OQ Le He*) > 2 (@) cannot be compared 73. Which of the following metal is expected to have the highest third ionization enthalpy? (a) Cr (Z=24) (b) V (Z=23) (©) Mn (Z=25) (d) Fe(Z=26) 74. Second ionization potential of Li, Be and B is in the order : (a) Li> Be >B (b) Li > B > Be (©) Be > Li>B (@) B>Be>Li 75. 76. 77. 78. 79. 80. 81. 82. 83. 84. 85. 86. 87. —y because : ‘The ionization energy of boron is less than that aw ee (a) beryllium has a higher nuclear charge than bor« e (b) beryllium has a lower nuclear charge than boro! ao (©) the outermost electron in boron occupies a 2p-orl (@) the 2s and 2p-orbitals of boron are degenerate 4 210 kJ mol, The first four LE, values of an element are 284, 412, 656 and 3: The Ube, valence electrons in the element are : () one (b) two (© three (@) four The first I.E. of Na, Mg, Al and Si are in the order : ; (a) Na < Mg < Al < Si (b) Na < Al < Mg < Si (© Na < Al < Si < Mg (d) Na > Mg > The ionization energy will be higher when the electron is removed from : (a) s-orbital (b) p-orbital (©) d-orbital (A) orbital Which of the following isoelectronic ion has the lowest ionization energy? | @ K* (b) cv (©) Ca (@) s* Amongst the following elements, the highest ionization energy is : (a) [Ne] 3573p! (b) [Ne] 3573p (©) [Ne] 3573p? (@) [Ar] 3d'° 4574p The ionization potentials of Li and K are 5.4 and 4.3 eV respectively. The ionization potent of Na will be : @) 9.7ev (b) Liev © 4.9ev (@) cannot be calculated Which of the following electronic configuration is associated with the Diggest jump betwee the second and third ionization energies? (a) 172s?2p? (b) 15?2s*2p%3s!_—() 15225229352 (d) 1s?2s?2p! The second ionization energy is maximum for : (a) boron (b) beryllium (©) magnesium (@) aluminium A large difference between the fourth and fifth ionization energies indicates the presence of: (a) 5 valence electrons in an atom (b) 6 valence electrons in an atom (©) 4 valence electrons in an atom @ 8 valence electrons in an atom For which of the following reaction AH? value is equal to the first ionization energy of Cais? (a) Ca*(g) —> Ca**(g) +e () Calg) —s Cat(g) se (c) Ca(s) —+ Ca*(g)+e (@) Cag) —, Ca” (9) 420 Ionization enthalpy of an atom is equal to : ‘a) electron gain enthalpy of the cation avi : (© ionization enthalpy of the cation HA none negativity ieee From the ground state electronie configuration of the elemens given below, pick up the with highest value of second ionization energy : " Paes karate (b) 1572527 63.1 ee? (@) 152252955 88. An clement has successive ionization enthalpies as 940 (first), 2080, 3090, 4140, 7030, 7870, 16000 and 19500 kJ mol”. To which group of the periodic table does this element belong? (a) 14 (b) 15 (c) 16 (d) 17 89. ane second ionization potential of elements is invariable higher than first ionization potential yecause : (a) The size of cation is smaller than its atom (b) It is easier to remove electron from cation (c) Ionization is an endothermic process (@) None of above 90. The first, second and third ionisation energies (E, ,E2 & E) for an element are 7eV, 12.5eV and 42.5eV respectively. The most stable oxidation state of the element will be : (a) +1 (b) +4 Or. (a) +2 91. Which of the following electronic configurations represents a sudden large gap between the values of second and third ionisation energies of an element? (a) 1s?,2s?2p? (b) 1s? 2572p 3573p? (© 1s? 2s2p° 3s?3p? (d) 1s?,2s?2p° 3s? 92. Which of the following atomic species has maximum ionisation energy? (a) O° (b) S~ (c) Se (d) Te~ 93. The correct order of I.E.p. is: (a)Na>F>O>N (b)O>F>Ne>N () Ne>O>F>N (d)O>Ne>F>N 94. Which of the following transformation requires least energy ? (a) Fg > Fy) te (b) Py —> Pyy +e (© Sq 7 Sq) te @) Clg) > Clg) +e" The correct values of ionization enthalpies (in kJ mol”) of Si, B Cl and $ respectively are : (a) 786, 1012, 999, 1256 (b) 1012, 786, 999, 1256 (c) 786, 1012, 1256, 999 (d) 786, 999, 1012, 1256 95. >» Electron Affinity 96. The amount of energy released on the addition of an electron in outermost shell of an atom is called : (a) ionization enthalpy (c) electronegativity 97. To which of the following atom, addition of electron is most difficult? (a) Radon (b) Nitrogen (c) Oxygen (d) Radium 98. Which of the following processes involves absorption of energy? (a) S(g)+e" —> S(8) (b) S +e" —> 7) (©) Clg +e —> (a) (d) None of these (b) hydration enthalpy _(d) electron gain enthalpy ~ 99. Arrange N, O and S in order of decreasing electron eran a S>O>N © n> o> s ae oe highest electron affinjy, 100. Among the following configurations, the element which a ity ig. (a) [Ne] 3s!3p? (b) Ne] 35" Ls saa © [Ne]3s3p4 (@) [Ne] 3573p°3d" 4s ta 101. The increasing order of electron affinity of the electronic configurations of element jg @ 18725726353 p5 (I) 1s?2s' 2p" : (U1) 1572s?2p$ (IV) 1s72s72p°3s @ IF>s>0 (b) F>O>S>Cl (F>Cl>s>0 @ Cl>s>O>F 105. The process requiring absorption of energy is : (a) N—>N- (b) F—> F- (cl cr @ Ha p|_Electronegativity 106. The electronegativity of the following elements increases in the order : (@) C CH, > SiH, (b) Hydration energy : Al* > Be2* >Mg** > Nat (©) Electrical conductance : Fj, > Cleag > Sieg (d) Magnetic moment : Ni* > v3 5 572+ i 108. Correct expression of "Allred and Rochow’s" scale is : (a) Electronegativity =0.744 2 of +0359 7 4 2 (b) Electronegativity =0359 7 +0744 ft (c) Electronegativity = 0.359 Zt. , 0.744 r (d) Electronegativity =0.359 Ze +0.744 r »| Hydration Energy 109. The hydration energy of Mg”* ions is lesser than that of : (a) Ale (b) Ba” (©) Na* (d) None of these 110. Among the following, which has the maximum hydration energy? (a) OH” (b) NH} © F @ H" 111. Which of the following is arranged in order of increasing radius? (a) K* (aq)

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