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The Cause and Influence of Self-Cementing Properties of Fine Recycled Concrete Aggregates On The Properties of Unbound Sub-Base
The Cause and Influence of Self-Cementing Properties of Fine Recycled Concrete Aggregates On The Properties of Unbound Sub-Base
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Technical paper
Abstract
The use of coarse recycled concrete aggregates (CRCA) in conjunction with Wne recycled concrete aggregates (FRCA) as sub-
base materials has been widely studied. Although research results indicate that it is feasible to employ both CRCA and FRCA as
granular sub-base, the inXuence of the unhydrated cement in the adhered mortar of the RCA on the properties of the sub-base
materials has not been thoroughly studied. Generally, it is known that the strength of the sub-base materials prepared with RCA
increases over time. However, this mechanism, known as the self-cementing properties, is not well understood and is believed to be
governed by the properties of the Wne portion of the RCA (<5 mm). This paper presents an investigation on the cause of the self-
cementing properties by measuring X-ray diVraction patterns, pH values, compressive strength and permeability of various size
fractions of the FRCA obtained from a commercially operated construction and demolition waste recycling plant. Their inXuence
on the overall sub-base materials was determined. The results indicate that the size fractions of <0.15 and 0.3–0.6 mm (active frac-
tions) were most likely to be the principal cause of the self-cementing properties of the FRCA. However, the eVects on the proper-
ties of the overall RCA sub-base materials were minimal if the total quantity of the active fractions was limited to a threshold by
weight of the total Wne aggregate.
© 2006 Elsevier Ltd. All rights reserved.
0956-053X/$ - see front matter © 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.wasman.2005.12.013
C.-S. Poon et al. / Waste Management 26 (2006) 1166–1172 1167
be used in mould bricks and blocks since workability is not FRCA was blended with CRCA to produce the sub-base
important for these dry concrete mixtures (Poon et al., materials in conformance with Hong Kong speciWcations
2002; Poon and Chan, in press-a). (Works Bureau, 2002). The blended sub-base materials
Alternatively, the use of FRCA in conjunction with were compacted at their optimum moisture content before
CRCA as granular road material has been widely the California bearing ratio (CBR) and permeability tests
reported (Chini et al., 2001; Park, 2003; Nataatmadja and were carried out to evaluate its overall performance. Fur-
Tan, 2001; Poon and Chan, in press-b). Park (2003) con- thermore, the inXuence of the variability (i.e., using labo-
cluded that 100% RCA (both coarse and Wne) can be used ratory prepared concretes with diVerent grading curves)
as base and sub-base materials for supporting a concrete of the FRCA on the self-cementing characteristics of the
pavement. Nataatmadja and Tan (2001) reported that the sub-base was also investigated in the last part of this
performance of the sub-base materials prepared with both study.
CRCA and FRCA was comparable to that of natural sub-
base materials. Poon and Chan (in press-b) reported that 2. Materials
it was feasible to use RCA and crushed clay brick as an
unbound granular sub-base. Although these research Natural aggregates (NA), with nominal sizes ranging
results have demonstrated the feasibility of using FRCA from 40 to <5 mm, which comply with the grading limits of
in sub-base, the inXuence of the unhydrated cement that BS882 (British Standards Institute, 1992), were used to pre-
remains in the adhered mortar of the FRCA on the prop- pare the sub-base material that served as the control. The
erties of the sub-base materials has not been thoroughly properties of the NA are summarized in Table 1.
studied. Recently, Arm (2001) found that the stiVness of Recycled concrete aggregates, with nominal sizes rang-
the unbound base/sub-base layers made with crushed ing from 40 to <5 mm, were used. They were sourced from a
demolished concrete increased as time increased. How- commercially operated construction and demolition waste
ever, the same phenomenon, referred to as self-cementing recycling facility in Hong Kong. The properties of the RCA
properties, did not occur for the natural base/sub-base are summarized in Table 2.
layers. Generally, the density of NA was higher than that of
This study aims to explore the fundamental causes of RCA. Due to the adhered mortar, RCA exempliWed a
the self-cementing properties of the Wne portion of RCA higher water absorption value compared to that of NA.
(<5 mm) and its possible eVects on the properties of the The strength of the aggregates was tested in terms of the
overall RCA sub-base materials. The X-ray diVraction 10% Wnes value. This test provides a measure of the resis-
patterns, pH value, compressive strength, toxicity charac- tance of aggregates to crushing under a gradually applied
teristics leaching procedure (TCLP) and permeability compressive load. The results revealed that the resistance to
were initially investigated for the FRCA. After that, the crushing of NA was higher than that of RCA. Nevertheless,
Table 1
Properties of natural aggregates (NA)
Test methods Properties Aggregate size
40 (mm) 20 (mm) 10 (mm) <5 (mm)
3
BS 812 Part 2 Density-saturated surface dry (kg/m ) 2622 2660 2577 2579
Density-oven-dry (kg/m3) 2594 2644 2562 2492
Water absorption (%) 1.06 0.57 0.59 3.51
BS 812 Part 111 10% Wnes – soaked (kN) – 190 – –
BS 812 Part 121 Soundness (%) – 97.5 – –
BS 1377 Part 3 Water-soluble sulphate content (g/L) – – – 0.025
Table 2
Properties of recycled concrete aggregates (RCA)
Test methods Properties Aggregate size
40 (mm) 20 (mm) 10 (mm) <5 (mm)
3
BS 812 Part 2 Density-saturated surface dry (kg/m ) 2487 2546 2580 2310
Density-oven-dry (kg/m3) 2411 2493 2523 2093
Water absorption (%) 3.17 2.17 2.29 10.3
BS 812 Part 111 10% Wnes – soaked (kN) – 109 – –
BS 812 Part 121 Soundness (%) – 96.3 – –
BS 1377 Part 3 Water-soluble sulphate content (g/L) – – – 0.032
1168 C.-S. Poon et al. / Waste Management 26 (2006) 1166–1172
the soundness and water-soluble sulphate content were 3.2. Tests for sub-base
similar for these two materials.
After the preliminary assessment of the FRCA, the
3. Test methods FRCA was blended with the CRCA in accordance with the
speciWcations in Hong Kong to produce the sub-base mate-
3.1. Assessment of FRCA rials. Aggregates with various nominal sizes were blended
in such a way that the 40, 20, 10 and <5 mm aggregates,
A series of tests was conducted to evaluate the proper- respectively, constituted 20%, 10%, 40% and 30% by mass
ties of the FRCA. These tests included X-ray diVraction, of the total aggregates for the sub-base. The optimum mois-
pH value, compressive strength, toxic characteristics ture content was Wrst determined for the blended materials.
leaching procedure (TCLP) and permeability. The X-ray The CBR test was then conducted in both soaked and
diVraction patterns and pH value analyses were carried unsoaked conditions in accordance with BS 1377-4 (1990)
out for the smallest three size fractions of the Wne RCA to evaluate the bearing properties of the RCA sub-base.
(i.e., <0.15, 0.15–0.3, 0.3–0.6 mm). For the pH value mea- The results were subsequently compared with those of the
surement, 5 g of the FRCA and 100 ml of distilled water sub-base prepared with natural aggregates.
were simultaneously added into a 200-ml glass Xask with a The conventional permeability test uses a mould with
screw lid and were automatically mixed on a shaking internal dimensions of ⭋100 £ 130 mm. It was only suitable
table. The pH values of the solution were measured at 10, for measuring the imperviousness of the materials with a
20, 40, 60, 120, 180 and 4320 min after the mixing process maximum size of 10 mm or less, which cannot represent the
had begun. The TCLP test was carried out to assess the real condition of a road sub-base which generally contains
potential risk posed by the RCA from leaching of toxic aggregates up to the size of 37.5 mm. In order to assess the
constituents. In the test, the FRCA was extracted with inXuence of the self-cementing properties of the FRCA on
acetic acid solution for 18 h at a 20:1 liquid-to-solid ratio the permeability of the overall sub-base material, the sub-
(L/kg). The extract was analyzed to determine if the base materials were therefore compacted in a 150 mm3
FRCA possessed leachate toxic constituents. The RCA mould to determine the inXuence of the FRCA on the per-
was considered hazardous if the concentrations of the meability of the overall sub-base materials.
constituents in the leachate exceed the regulatory level
prescribed by the US Environmental Protection Agency 4. Results and discussion
(EPA) (Conner, 1990).
The compressive strengths of Wve size fractions of the The X-ray diVraction patterns of the three size fractions
FRCA were determined: <0.15, 0.15–0.30, 0.3–0.6, 0.6– (<0.15, 0.15–0.30 and 0.3–0.6 mm) of RCA are shown in
1.18 mm and <5 mm (overall). The materials were mixed Fig. 1. The results indicated that C2S and C3H2S3 (C–S–H)
with water using a trowel at room temperature such that a were detected in the RCA samples. Because C2S is a less
water-to-solid ratio of 0.5 was obtained. They were then reactive compound compared to C3S (Newman and Choo,
cast into copper moulds (⭋40 £ 80 mm) and compacted 2003), it cannot be completely hydrated even after a long
under a pressure of 200 MPa until no water was extruded. curing time. It probably explains why C2S was still detected
The surface of the compacted sample was leveled before in the RCA samples. However, the presence of C2S gradu-
placing the specimens in a fog tank at two diVerent temper- ally vanished as the size of RCA increased. The results
atures of 25 °C (N-curing) and 65 °C (S-curing) for a 7-day revealed that the <0.15 mm fraction of RCA could be a
curing process. After the 7-day curing stage, the specimens highly possible cause of the self cementing properties of
were removed from the tank and demoulded prior to test- RCA as this fraction contained the highest amount of C2S.
ing. The tests were designed to show the potential size frac- Although C2S was not detected in the 0.3–0.6 mm fraction
tions of the FRCA, which contributed to the increase in of RCA, the pH value (Fig. 2) of the solution prepared with
strength or stiVness as reported by Arm (2001). The frac-
tions 1.18–2.36 mm and 2.36–5.0 mm were not included in
C3H2S3
13000
bind together after compaction. 11000
The permeability test was carried out for the FRCA using
C2S
9000
the falling head method (Head, 1994). The FRCA was ini-
7000
tially compacted at its optimum moisture content in a mould 0-0.15 mm
5000
with internal dimensions of ⭋100 £ 130 mm. The measure-
3000
ment was done immediately after compaction, after a 7-day 0.15-0.30 mm
1000
S-curing stage at a temperature of 65 °C and after a 10-day 0.30-0.60 mm
curing regime which comprised a 7-day S-curing stage at a -1000
10 20 30 40 50 60
temperature of 65 °C and a subsequent 3-day air curing
2-Theta
period. A reduction in the permeability was a manifestation
of the occurrence of the self-cementing phenomenon. Fig. 1. X-ray diVraction patterns of diVerent size fractions of FRCA.
C.-S. Poon et al. / Waste Management 26 (2006) 1166–1172 1169
7D_N-Curing
1.4 Cd <1.0 ND ND
1D_N-Curing Cr <5.0 0.003 0.006
1.2 Pb <5.0 0.010 0.009
1 Hg <0.2 ND ND
Se <1.0 ND ND
0.8 Ag <5.0 ND ND
0.6 ND, not detected.
0.4
0.2 Table 4
CoeYcients of permeability of samples
0
0-0.15 0.15-0.30 0.30-0.60 0.60-1.18 0-5 Fine aggregate Immediately 7-day S-curing 7-day S-curing
Sieve size (mm) after compaction + 3-day air curing
Fig. 3. Compressive strength of samples prepared with diVerent size frac- NA (cm/s) 6.593 £ 10¡6 4.950 £ 10¡6 4.610 £ 10¡6
RCA (cm/s) 3.828 £ 10¡4 2.563 £ 10¡5 7.195 £ 10¡6
tions of FRCA.
1170 C.-S. Poon et al. / Waste Management 26 (2006) 1166–1172
60
5. Further assessment of the variability of the Wne RCA on
the self-cementing characteristics
40
In order to assess the variability of the Wne RCA on the
20 self-cementing characteristics of the sub-base materials, a
laboratory prepared Grade 45 concrete was crushed into
0.01 0.1 1 10 100
0
the Wne aggregate (RCA-16L) at the curing age of 16 mo in
Sieve Size (mm) our laboratory using a laboratory impact crusher. Due to
the diVerent crushing conditions, the grading of the FRCA-
Fig. 4. Grading curves for the sub-base materials.
16L was diVerent compared to that of the commercially
produced RCA as shown in Fig. 5. One may notice that the
respectively. Due to the high water absorbability and the quantity of the active size fraction (0.3–0.6 mm) of the
lower particle density of RCA compared to those of NA, FRCA-16L was about twice as much as that of the FRCA,
the optimum moisture content and maximum dry density while the quantity of the <0.15 mm fraction was similar
of the RCA sub-base were, respectively, higher and lower between the FRCA and the FRCA-16L. For FRCA and
compared to those of sub-base materials prepared with NA. FRCA-16L, the total quantities of the active size fraction
The CBR test was carried out in both soaked (after a 4- (<0.15 + 0.3–0.6 mm) weighed 28.5 and 42.3% of the total
day soaking period) and unsoaked conditions. The results Wne aggregate, respectively. Due to the high quantity of the
(Table 5) showed that the bearing strength of the sub-base active fraction and the relatively young age (more C2S and
materials prepared with RCA was lower than that of NA unhydrated cement grains) of the concrete from which the
sub-base. Compared to the unsoaked condition, the soaked FRCA-16L was derived, it was expected that the compres-
condition did not aVect the strength of both sub-base mate- sive strength of the FRCA-16L was higher than that of the
rials. Furthermore, both materials showed negligible swell FRCA. Fig. 6 shows the comparison between the compres-
(i.e., <0.07%) after a 4-day soaking period and should not sive strength of FRCA-16L, FRCA and FRCA prepared
cause any Weld problems during saturation condition. In with the addition of 1% unhydrated cement by weight of
Hong Kong, a CBR value of >30% is considered suitable to the FRCA at various curing ages. As expected, the com-
be used as the sub-base. The results indicated that the use of pressive strength of the FRCA was lower than that of the
100% RCA is adequate to be used as granular sub-base FRCA-16L. However, the compressive strength of the
materials FRCA-16L was still much lower than that of the FRCA
The blended sub-base prepared with the RCA was sub- when 1% unhydrated cement by weight of the FRCA was
jected to a 7-day S-curing regime at 65 °C prior to the per- added.
meability measurement. The measured coeYcient of Nevertheless, it was expected that the permeability of the
permeability was found to be 2.67 £ 10¡1 cm/s for the RCA sub-base would be greatly aVected by the quantity of the
sub-base. For comparison purposes, the permeability of the active size fractions in the FRCA-16L. Therefore, before
sub-base prepared with NA was also measured; however, the permeability test was carried out for the sub-base in
the NA sub-base was not subjected to a steam curing
regime because it was found that steam curing did not have
a signiWcant impact on the permeability of the Wne NA and
the self-cementing eVects were never considered for the NA
sub-base. The corresponding coeYcient of permeability for
the NA sub-base was found to be 2.29 £ 10¡1 cm/s. Due to
the porous nature of the RCA, a higher coeYcient of per-
meability of the sub-base prepared with RCA should be
expected when compared with the sub-base prepared with
NA. However, the more permeable nature of the RCA sub-
Table 5
Results of CBR test
Unsoaked (%) Soaked (%)
NA 85 83
RCA 66 66 Fig. 5. Sieve analysis of FRCA and FRCA-16L.
C.-S. Poon et al. / Waste Management 26 (2006) 1166–1172 1171
Katz, A., 2003. Properties of concrete made with recycled aggregate from Poon, C.S., Chan, D. Feasible use of recycled concrete aggregates and
partially hydrated old concrete. Cement and Concrete Research 33 (5), crushed clay brick as unbound sub-base. Construction and Building
703–711. Materials, in press-b.
Limbachiya, M.C., Leelawat, T., Dhir, R.K., 2000. Use of recycled concrete Poon, C.S., Kou, S.C., Lam, L., 2002. Use of recycled aggregate in molded
aggregate in high-strength concrete. Materials and Structures 33, 574– concrete bricks and blocks. Construction and Building Materials 16
580. (5), 281–289.
Nataatmadja, A., Tan, Y.L., 2001. Resilient response of recycled concrete Poon, C.S., Shui, Z.H., Lam, L., 2004. EVect of microstructure of ITZ on
road aggregates. Journal of Transportation Engineering 127 (5), 450– compressive strength of concrete prepared with recycled aggregates.
453. Construction and Building Materials 18 (6), 461–468.
Newman, J., Choo, B.S. (Eds.), 2003. Advanced Concrete Technology Con- Shayan, A., Xu, A., 2003. Performance and properties of structural con-
stituent Materials. Elsevier. crete made with recycled concrete aggregate. ACI Materials Journal
Park, T., 2003. Application of construction and building debris as base and 100 (5), 371–380.
subbase materials in rigid pavement. Journal of Transportation Engi- Topcu, I.B., Sengel, S., 2004. Properties of concretes produced with waste
neering 129 (5), 558–563. concrete aggregate. Cement and Concrete Research 34 (8), 1307–1312.
Poon, C.S., Chan, D. Paving blocks made with recycled concrete aggregate Works Bureau, 2002. SpeciWcation facilitating the use of recycled aggre-
and crushed clay brick. Construction and Building Materials, in press-a. gates. WBTC No. 12/2002, The Hong Kong SAR Government.