Solid state: Solid crystals part 1

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Sodium Chloride
Caesium Chloride
Zinc sulphide
NaCl type (6 : 6) Rock salt

rNa+
_______ = 0.52 Experimental Value
rCl-
NaCl type (6 : 6) Rock salt
Cl- is at FCC lattice.
NaCl
NaCl
 NaCl (1 : 1)
● Distance between two nearest Cl- ion is =

● Distance between two nearest Na+ ion is =

● Distance between two nearest Na+ and Cl- ion is =

ZnS type (4 : 4) zinc blende

rZn2+
_______ = 0.30 Experimental Value
rS2-
ZnS
 ZnS (1 : 1)
● Distance between two nearest S2- ion is =

● Distance between two nearest Zn2+ ion is =

● Distance between two nearest Zn2+ and S2- ion is =

CaF2 type (8 : 4) Fluorite

rF-
0.225 < _______ < 0.414 Experimental Value
rCa2+
CaF2
 CaF2
● Distance between two nearest Ca2+ ion is =

● Distance between two nearest F- ion is =

● Distance between two nearest Ca2+ and F- ion is =

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