South Pasadena * AP Chemistry: Name, Period 13 ¢ IMF’s, Liquids, and Solids 3 ‘Surface tension ina liquid is due to the fact that a) bomen ple ener i B) guarentee tne oy ©). PE is increased for molecules at the surface 6) tase mens a el dice @oaletieaioe In which one of the following will dipole-dipole attractions ply the most significant role as the Sntermlcclae attracts? ‘aye! BY HO evade Mach oe e-NHy Hpi: DS Kr ace. With which type of substances do London dispersion forces play the most significant role? 3) polar molecules €)) non-polar molecules b) metals '¢) network compounds ©) lonie compounds ‘The heat of vaporization of HyS, at its boiling point (61°C) is 1838 fmol, What mass-of HoS can be ‘vaporized (at its boiling point) with 100 kJ of energy? 9 00x Fe st b) 341 oH wreaths Which one fae follomng subanoes exits the strongest intermolecular forces of altrastion’? ay Cte DICHOH — -Beses DD CHAR Sar Say CHC! py. pun- ey CH? pst For which substance would you predict the highest featofvapriation? Stony crt A BYP, bth giF (a)\Nal oF Bro ‘pee, PRACTICE TEST 7. Which of the following will change the equilibrium por pressure of aliquig? ON] Tey (Ay, Heat up or coo! avn the liquid Ht “Increase the Volume ofthe container Fil-Change the pressure above the liquid (3h Lonly d) Land {it enly bp Land Hoty: ©) [and Tl only 1 LM ond tt 4. Which of ihe following statements describes @ substanee above its critical point? substance ean be liquefied bb) the vapor and liquid phase become ‘indistinguishable _S} the substance experiences no intermolecular internetions _AlY there isa distinet phase boundary between the ‘iquid and vapor ©) all ofthe above 9. At what temperature will the fiquid (whose vapor pressure is shown below) boil ifthe air pressure is 20 40 geno ayamec (fb) soc) THE) LOC {6} the liquid-will not boil at this pressure 10, Which one of the fatlowi correct intermolecular force of attraction? ONH3.....ichen el... dipole-di @ dat eee11. ‘Thevapor pressure graph of an unknown liquid is 17, The phase diagram of a substance és given below. shown below. Which of the following statcrments What occurs when the substance is heated fiom, about this liquid islare true? 100" Cto 120 °C at 3 atm pressure? teoe Fe) “Ck. This Hiquid has weaker IMF's than water {CI The liquids normal boing point is around 20/60 200. 120 75°C. temp eC) IM, The lig bois at eoom temperature when the it freezes pressure is dropped to about 0.25 atm. ch mila 8) Hand Itonly 8) Lonty hange occurs 8) only ey Bell and lt ¢) Land tt 18. A typical phase diagram fora substance is given below, At what point on the diagram do solid and 12, How much enenty does require to melt 25.0. liquid exist at equitibriv? benzene, CgH,? The hest of fusion of benzeme i 2.37 kdieno. [rr mass = 78.0 pmo) a) $250 (079 -739e% by $93 Kd 2) momeofthess eS ©) 625k ay bed Cthe,, B5vgfatley ar 13, What type of sols) oi coain cova — 4) molecular —d)potwork ) metallic )} all but “8” — ©) tonic ap MeHeDs 19, Which one of the following as solids has a crystal 14, Which type of sold generally hes the highest structure containing discrete (separate) molecules? wile - a ay potty fF earborundum, SiC abo! a) metallic a ee Dy glass amt Oye ) ionic 4) network OF guar ge y Dacre) ale ral 15. Which substance below exhibits the weakest MPs? 20. The heat of sublimation of a compound equals 2) Fs, 8) 802 (Ord Ss 9) Pe ‘heat of fusion plus heat of vaporization eet Pj ese “by heat of ionization plus heat of crystallization me nae Be 16, During the condensing of liquid, de kinetic energy. and the potential energy a) stays the same, increases: iy ineeases, decreases AY 1S) then “<}_ increases, increases . a) decreases, stays the same (* sis te same, de TCS 9)_heat of vaporization minus heat of fusion @)_ heat of vaporization plus heat af crystallization ©} beat of exysial lization plus heat of vaporization21. The normal boiling point of a liquid is 100°C at | atm pressure, f% 1) fs the temperature at wihich the vapor pressure is Lamm, = HOM, o _AY is the temperature at which liquid and vapor are in equilibrium AY 7s the temperature at which the vapor pressure ccquals the external pressure. AY” is the temperature at which there is a continuous formation of gaseous bubbles i the liquid UN 122. ‘The vapor pressure ofa liquid increases with an increase af temperature. Which of the fallowing st explains this inerease? } The average kinetic energy of molecules is greater, thus more molecules can enter the saseous state, b). The number of gaseous molecules above the liquid remains constant but these molecules have preater averaze kinetic energy. €) the faster moving motecules in the liquid exert 4 greater pressure. 4) All the molecules have greatér kinetic enereies, ©) The intermolecular forces between the molecules becomes less at higher temperatures, 23. Which of the following indicates very strong intermolecular forces of atfraction in liquid? AT. A very low boiling point. BJA very low critical temperature LAT’ A very low heat of vaporization. @ ‘very low vapor pressure. ‘A very low surface tension, 24. The compounds Br2 and IC! have almost identical molecular weights, yet [CI boils at 97°C and Bry boils at 59°C, ‘The best explanation for the difference is S830 ICL is an ionic compound and Bry is opvatent. ‘BL ICL is a nonpolar molecule and Bra is paar. Avi ICL has a longer bond than that in Bry .? ICL has a measurable dipole moment (is polar) and Br3 does not (is nonpolar). ei ICI has a stronger bond than that in rp.“ HOARD ol 7s 25. In some compounds the hydrogen ator is covalently bonded to one atom and simultaneously attracted to another atom in anather molecute by an clectrostatic interaction. ‘This interaction can occur when hydrogen is bonded to acer psi fe)N ac Fee 26. Which af the fallowing compounds shows an tbnormal boiling point due to hydrogen bending’? CHJNH, dy CHCL emery ane ey CH:SH °) Br 27. Which of the following has the lowest point? HO wed) Hye a, bS sath gy -NHy He=oe bse | 28. Which of the following would be expected to have highest heat of vaporization? HO Lig c) HE GAS b) Nib G42 dd) allthree are the sane 29. Which element is considered a covalent/network solid? ayCr b}O e) Xe (GB ee) Na wlch gy poh a Cette 30, Which ong of the following compounds has intermolecular forces different than the others? 4) quutz.Si0.-) Cigeaiey b) Ctdinmons) @} silicon carbide, SiC ©) eatbou dioxideCOr i, igtt Cavite nyehote Answers 4 oa fe] sfe] fe] fe 2.Aa | le | wfe | «A | a[o | ue] w[e B 4[e] 2/3 | 20/4 hk s.[p | 3[e | a.[e D 6.[o | [> | 2.04 <| lala |ote) ate | fe | 4.[ >