SriChalanya i1T Academy (09-08-20_Jr-Super 60_Jee-Adv_2017-P1_UTA-04_Q'P CHEMISTRY Max.Marks:61 SECTION ~1 (MULTIPLE CORRECT ANSWER TYPE) This section contains 7 multiple choice questions. Each question has 4 options (A), (8), (C) and (0) for its answer, ‘out of which ONE OR MORE than ONE option can be correct. Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases. 19. 0.2M 100 mI NaOH is mixed with 0.4M; 100 ml HCl solution. Determine energy released during the reaction Givens H* (aq) +O" (aq)—9H,0()at=—57.5 KImol” 1150) B) 1150 KJ C) 2300 J D) 2300 KJ 20, Its known that carbon monoxide reacts exothermically with hydrogen gas to form methanol at 400°C, in the presence of a catalyst CO, + 2H) —2CH,OH,,, +heat A mixture of carbon monoxide, hydrogen gas and methanol placed under conditions describe above achieves equilibrium in a closed container. If the reaction temperature is changed to 450°C, then which of the een statements is/are correct? "Th Ay gale ands 9 \eclued The total molecules in the container increases B) The reaction rates of both the forward and backward reactions remain constant ® The average molecular mass of the gaseous mixture decreases “Wl, Miao, \ D) The average molecular mass of the gaseous mixture increases When 0.1 mole solid NaOH is added in 1 It of 0.1 M NH, (aq) then which statement is/are true? Seas @ (K, =2x10"log2=0.3) NEON Oy ee ws legree of dissociation of NH, approaches to zero roma ange in pH would be 1.85 pont x ncentrations of [Na” 0.1M, [NH,]=0.1M,[OH"]=0.2M 7A on addition of OH” K, of NH, does not changes |” ‘Sec: Jr. Super60 ‘Space for rough work Page 10(09-08-20_Jr-Super 60_Jee-Adv_2017-P1_UTA-04_Q'P ly: (HH) is equal to AH, of H, (g) 2 = ow oY/AHt,[H,(e)] is equal to aH,[1,0(0)] at300k ONES AM 4 From the following phase diagram of sulphur, select the correct statements(s) — Pressure (atm) G8 3 95 114 119 154 yt Vo Temperature (°C) A) At 1 atm and wren > Gs moroive) [G # Gibb's function] 7 & 10 atm and 154°C Gyn) > G¢monoctinic) = Gig) KR XS C) AYA atm and 114¢ Gyn) % Gstigy Gach elting point of monoclinic 'S’ increases on increasing pressure ae y & Zoyy Cn FS x ‘Space for rough work Page IT SriChahanya iT Academy 22. Select the correct option(s) — ee, AH, = Enthalpy of formation Ye — WAN > AH, = Enthalpy of atomisation A \. AH, = Enthalpy of combustion ¥ 2dwelA) AH, = Bond dissociation enthalpy qe A) AH,(H(g)) is equal to AH, of H,(z)74 ° B) AH,, (HH) is equal to AH, if H(z)? A, +l © (4) —> Pio) ay 2° (wo) ‘Sec: Jr. Super60SriChaltanya i1T Academy (09-08-20_Jr-Super 60_Jee-Adv_2017-P1_UTA-04_Q'P 24. The equilibrium constant K,, and K,, for the homogeneous gaseous reaction Aq=22B and Ce=2D+E respectively are in the ratio of 1:9. If the degree of dissociation of A and C be equal then the ratio of total pressure at these equilibrium is: A)25 oh C1: D)5:6 (a) 10 ml of a weak acid (HA) solution is 20% dissociated in water. This solution is completely neutralized Wouor 210M NaOH solution. Which of the following is/are correct about the solution: (og 2 = 0.3) {H of weak acid (HA) solution was 3.4 we dissociation constant of weak acid (HA) was 1x10~ ¢ ‘pH of solution after addition of NaOH is 7.5 D) K, (hydrolysis constant) of the salt is 1x10” SECTIONAL (INTEGER ANSWER TYPE) This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive). Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases. 26. Tmlof 1 mol/L hydrochloric acid was diluted to 100 mL with watery10 mL of 4, _ this solution was further aluted to 100 mL with water. What is the prTof the final solution says lt Gi) The enthalpy of hydrogenation of benzene ig(49.)kcal/mol while its resonance energy is 37.8 kcal/mol. The magnitude of enthalpy of hydrogenation of DX cyctohexene in Kcal/ molis? Asolution mixture of 0.01 M HCooH (K, =2%10=} and 0.01 M HCI has concentration of Hicoo- equal to xx10" in scientific notation. Find the value of (given VI7 =4.12) lume calorimeter, 3.5g of a gas with molecular weight 28 was burnt In excess oxygen at 298.0 K. The temperature of the calorimeter was \ found to increase trom 298.0 K to 298.45 K due to the combustion process Given that the heat capacity of the calorimeter is 2.5K, the numerical value for the heat of combustion of the gas in kimol” at constant volume is? ‘Sec: Jr. Super60 ‘Space for rough work Page 12SriChalanya IIT Academy (09-08-20_Jr-Super 60_Jee-Adv_2017-P1_UTA-04_Q'P 30. The degree of dissociation of HI at a particular temperature of 0.8. Calculate the volume (in litre) of 1.6 M Na,S,O, solution required to neutralize the iodine L present in an equllibrium mixture of a reaction when 2 moles each of H,, and I, are heated in a closed vessel of 2 It capacity. SECTION ~ Ill (SINGLE CORRECT ANSWER TYPE) This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, ‘out of which ONLY ONE option can be correct. Marking scheme: +3 for correct answer, 0 if not atfempled and -1 in all other eases. ‘Answer Q.31, Q.32 and Q.33 matching the information given in the three columns of the following table. Since the enthalpy of a substance can change with the variation of temperature and pressure, It is essential that reactants and products of a reaction are present at the same temperature and pressure while computing the enthalpy change during the progress of a chemical reaction. When all the chemical species in a chemical reaction are present in the respective standard states, the enthalpy of reaction is spelled as standard enthalpy of reaction. Column =I Column =I Column = Ill At 298 K At298 K AT 298K AHP = DIV(AVH) 1 (8) C0, (8) | i | AH? = A,H° | P Xv (AHH) pec a2 AH= Yvon 1) 4H,(e)+41 (eh) | ii] AHe=AcH? | oe | endo ee AH? = Yiv(AaeH) ps ML 28(5)+30,(g} 8,0, (8) ii} AH°<0 |R ~ _ Xv (Ao) peu See: Jr. Super60 “Space for rough work Page 13 : : R.,R$ abhesreo FH, KH) Ai 7c) a ~ rW R= ‘ 3 > um combein ae (Wy) S.0qR er BD AHWR Goat} W 7 OB) gap |‘SriChaltanya tT Academy 09-08-20_Jr.Super 60_Jee-Adv_2017-P1_UTA-04_Q'P AHE= DV(ACH pecan IV} Pycanig *503(g)—9P,0,,(3) Jv] AHHe>0 | s] y “Ev(aa),_ sah (a) Which of the following matching is correct: | Go VOY BoM’ How Zoom Which of the following matching is incorrect @w iil) (Q 1) Git) (R) x Ow 0% who > -wepned Which of the following matching is correct NN —* pr MQ swo O, Cy) @ ®y IV) (ii) (S) A Answer Q.34, Q.35 and Q.36 matching the information given in the three columns of the following table. When we deal with material equilibrium in a closed system, the system is ordinarity not isolated, Instead, it can exchange heat and work with its surroundings. Under these conditions, we can take the system Itself plus surroundings with which if interacts to constitute an isolated system, and the condition for material equilibrium in the system in then maximization of total entropy of the system plus its surroundings. cole Column =I Column = Hil Column -1 A,H.-tnthalpy change | A,H - Gibb’s energy change PHASE during the process during the process Equilibrium AS Entropy change | 4S; Entropy change of eh ot diuring the process system plus surrounding ¢ Favourable condition for 1 | o& ranix AH>0 p_| forward process is high Pel ya, temperature and highs H,0,, =H, ) e pressure KT Favourable conditions for "| Hg =—.0,,_| | At? 2 | bac rocess is lay_| ¢ See: Ir. Soper60 ‘Space for rough work \ 2 eye Page 14 e eas Aored wy % ys Sy o Foxcov Ky =} BS 429 wy a |F <. Aes NeeZlPue 1 RY ale LG Mee Y uy!ron Sri Chalanya iIT Academ 09.08-20_1 Super 60_dee-Adv,2017-P1_UTA‘O4 QP ‘or a ri? at pr a us AS>0 ‘At equilibrium "") 1,0, —H,0,, Wy AS> ® | AG=0 and A,G°=0 Ai SRT and coal pressure { equilibrium wie «do fs v[AS<0 5 |/\.G--0 and AS,,..-0 sasantite) Cs mond) ee f att Jord 7, 0 34. Which of the Following is correct match: AVNMOAOs, BONAR COMMP)s» got Oy 35. Which of the following matching is incorrect AWM OY (UD Gill) Rg) (IV) (iv) Sy, D) (WG) (S) YZ 36. Which of the following,matching is correct A) () OQ), ohn () @y, C) (IV) (ill) (S) 5B) (U) Gilt) (R) 0 ‘Sec: Jr. Super60 ‘Space for rough work Page 15