{Sri ChattamalrT Academy, India 08.00-20_sr Super60_tee Main_UTM.04_@.P ‘CHEMISTRY Max Marks: 100 (SINGLE CORRECT ANSWER TYPE) This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be correct. Marking scheme: -4 for correct answer, 0 if not attempted and —1 in all other cases. 51 2. 53. 54. 55. 56. Which of the following statements is correct? 1) If 0.1M CH,COOH aqueous solution (x, =1.8%10~) is diluted at 25°c, then [a] will increase, ONC a dacntn x 2)n heating a sample of pure water P® increases. == (MK ‘ye oul pien HCI solution is less acidic than 0.1M HCN (K, yey =10") Solution <= [a7] 4) 10*M HCI aqueous solution will have pH exactly equal to 8 wig of the follgwing is correct regarding statements given. “se A 410, > FRY, (acidic strength) _» amped 1p Wea cl, > HgCl, (acidic strength) 2 ut |, > BCI, acidic strength) \__> ee ate vow >I” (basic strength) 1) TTT 2) TTF oft 4) FFTT For the reaction: Cl,,, +3F,,, =2CIF,,,;, AH =-329KJ dissociation of c! be favoured by: od NT omnes pens 1) Decreasing the ternperature, avhereasing the volume of the container 3) Adding of #, gas. jrw*? — 4) Adding of inert gas at constant volume Ww? For an isomerization x,,,-=2¥,,. The temperature dependency of equilibrium qd Xe) Be (a) wil wn is given by In K = The value of As? at 300 K is 2 R 22/R 3) 1000R 4)R Select the correct statement at ef 1) Value of K, always increases with increasing temperature * 2)f or exothermic reaction value of K, increase with decreasing in temperature 4 3) For endothermic reaction value of K;, ingreases ith decreasing in -asesiNi temperature a (, 1) 4) For exothermic reaction slope is | log K vs +) negative = pets (exw 7) negate a. Sage K, for the reaction 4 te) + By AC, + Diy iS 20 at 25°C If a container contains 1, 2, 4,5 moles per litre of 4,,, 8), Gand B,, respectively at 25°C, then the reaction shall yfroeees from left to right 2) Proceed from right to left Os }) Be at equilibrium 4) None of these SEO TSupereo ake ovarart a" Cy 4 + r‘A 58. 59, 60, 62, itamyalT Academy, india (08-08-20 _IrSuper60_Jee Main_UTM04_Q.P 57. | Which of the following expression for % ionization of a monobasic weak acid in aqueous solution at appreciable concentration is not or 1) ofA +100 Hy) . 44 Choose the correct statement among the following SS a 1) Enthalpy of formation of a compound always have positive value. y¢ 2) Standard enthalpy of formation of oH, WY <0 oe Oy Inthalpy of formation of carbon mono oxide gas at 300 K is —110 kcal/mol Then internal energy change for same process will be 109.7 kcal/mol Sa 4 4) Standard enthalpy of formation of #,>0 A ww yp] H,A is a weak triprotic acid (x, 107"). Calculate the value of pX Of 0.1MH,A(aq) Solution where pX ~-log X &X - 1)8 29 3)11 he we gh The enthalpy of neutralization of a strong mefobasic actey a sttong ea" monoacidic base is 13,700 cal. A certain monobasic weak acid is 10% ionized in a molar solution. [-the enthalpy of ionization of the Weak acid is +400 cal/mole, then what is the enthalpy of neutralization of one molar solution of the weak acid? TT 1)-T3,700 cal 3,340cal 3)-13,660cal_— 4) -13,300 cal He + OH, — H,O; AH® =-S7kJ | mol NH og [HON] =45 KF | mol essen L IF 200 mL of poy, Ba(OH), Solution is mixed in 500 mL of aM HCN solution, then heat evolved wile: 1) 600 Joule 240 Joule 3) 120 Joule (20}20 Jou Which of the following is not correct regarding standaref enthalpy of formation (4,H°) at 298K 1) A,H°(c, diamond) > 0 2) 4,1? (H",aq)=0 fo " CO,(g)=0 4) A,H°(S, orthorhombic) = 0 ‘SEC: JrSuper60 Page 11{QSriChaltanyallT Academy, India (08.08-20_1r Super60_Jee Main_UTW-04_Q.P 63. 2.7g weak acid HA (mol.wt=27/g/mol) is dissolved in water and formed 10m* ne solution. If K,,,,=10° then poi! of solution will be [Given : log4=0.6] 1) 67 2) Greater than 6.7 & less than 7.0 rere 0 less than 7.3 4) Greater than 7.3 +O, 250, Starting with 2 mole 2s0, and 64, Ina study of equilibrium 250, 1.5 mole 0, in litre flask. Equilibrium mixture required 0.4 mole KéMno, in r acidic medium. Hence x, is: ~———— wa 1) 0.2 3) 675.0 4) None of these 65. Vapour pressure of the water at 80°C is 0.467atm.What is K, of the following equilibrium? LN 49,10, 1) 0.8959 mol/L 2) 2.9x10~“moVL hows mof/L 4) 13.19 mol/L, 66. The equilibrium constant for the reaction COZ, +H,0,,, —=*C0,,, +Hy,) iS 3 at 500 K. Ina 2 litre vessel 60 gm of water gas [equimolar mixture of Co(¢) and LK H,(g)] and 90 gm of steam is initially taken. What is the equilibrium concentration of #,(g) at equilibrium (mole/L)? Ws 235 3)15 4) 0.75 67. ‘At certain temperature (T) for the gas phase reaction K, =12x10%atm 2H,0,,) + 2Cly) AHCI, + Oy, If Ch, HCI &0, are mixed in such a manner that the partial pressure of each is 2 atm and the mixture is brought into contact with excess of liquid water. What would be approximate partial pressure of ci,, when equilibrium is attained at temperature (1)? [Given : Vapour pressure of water is 389mm Hg at temperature(T)] Ns 1) 3.6x10%atm = 2) 10“ atm 3Y3.6x107atm 4) 0.01 atm 68. Following two equilibrium is simultaneously established in a container N PCly, = pers, +014 y CO. +, Is) COC, oe If some Ni(s) is introduced in the container forming 4i(Co),(g) then at new equilibrium 1) pel, concentration will increase ayaa concentration will decrease 3) cl, concentration will remain same 4) CO concentration will remain same ‘SEC: JrSuper60 Page 12{Sri Ghattanya'T Academy, India 9.0820 Superso_Js Main UTM? 69, ese Based on above find the correct statement(s) 98K is the normal boiling point of liquid co, A 70 Phase diagram of Co, 1s shown as following 217 308 Beh xy 2) AM atm & 190K co, will exist as gas_—x ‘co,(s) will sublime above 195K under normal atmospheric pressure 4) Melting point & boiling point of co, will decreas¢’on increasing pressure In the laboratory the equilibrium constant fora particular reaction can be measured at different temperatures. Plotting the data yields the graph shown. Which of the following statement is false? (Note : The néfation 4.40e-4 is equivalent to 4.4010“ edn doe Mt G J Le laws ee aed" xe 4.004 42064 4.404 4.60044 4.8004 5000-4 $200.4 1/T(K) 1) as® can be obtained from the y-intercept. an he slope of the line is equal to ww 3) The reaction is endothermic ~ 4)the standard free energy change of the reaction is positive. -——\ AY? ‘SEC: JrSuper60 Page 13‘Sri ChaltanyaiiT Academy, India (08.08-20_1r Super60_lee Main_UTM-04_.P (NUMERICAL VALUE TYPE) This section contains 5 questions. Each question is numerical valve type. For each question, enter the correct numerical valve (in decimal notation, truncated /rounded-off to second decimal place. (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30). Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases. White phosphorus is a tetratomic solid [,(s)] at room temperature and on strong heating in absence of oxygen, if polymerizes into red phosphorus as op white (g) red (g) AH" =-104kS /mol of P, Given enthalpy of sublimation [?,(s)-P.(g)].,,,,. iS 59 kJ/mol and enthalpy of atomization is 316.25 kJ/mol determine P—P bond enthalpy in red -P Joining the two tetrahedral 72. How many acids are dibasic in the givenlist. —S Laude A H,PO,,H.PO,,11,PO,,B(OH), ,H1,C,0,,1,8O,,CH,COOH , HCOOH ,11,8,0,, P.O, 73. Number of correct statements in the following i) clo; is stronger base than clo- ~¢ il) naz is weaker base than Ni, Ly ili) HF is stronger acid in HNO, solvent 7 IW :8,0, is stronger acid than #,50, v) 4,PO,is stronger acid than H,PO, ® ‘Acetic acid is differentiating solvent for strong acids 74. “The enthalpy of fusion of Ice is 6.02 kf mol”. The heat capacity of 17,0 is 4,187 gk“. What is the smallest number of ice cubes at 0’c, each containing one mole of #,0, that are needed to cool 500g of liquid water from 20°C 10 °C? (nearest integer) (% Given that: 5x9) FCO ne jAH®=-113k7 ——» QAM) GDe-t +40, >C0,, AH? =-110K7 = ——> OM in +3 One Then for 3C) + C%0,,) > 20%, +3CO,,) AH” = xx 10K ay Find the value of x