IONIC PRODUCT OF WATER

Increase in temperature causes Kw to increase because ionization of water is endothermic

process,increase in temperature decrease the pH of pure water because [H +] increases
Important points to remember

That is intial concentration and concentration at equilibrium are approximately same

Because
CH3COOH is
monoprotic

Change in concentration we can find from [H +]

because [H+] are formed after dissociation
As the extent of dissociation is very small (4 x 10-4) change in
concentration of CH3COOH (Initial)≈ at equilibrium
If Ka is small means
extent of
dissociation also
small ,because Ka
value depends on
ion concentration
Therefore intial≈
change
WA + SALT OF STRONG BASE OR WB + SALT OF STRONG ACID

Weak acid so more concentration of

CH3COOH High concentration of CH3COO-
 No effect of dilution because only H2O concentration increases

Salt hydrolysis Salt hydrolysis is defined as the process in which a salt reacts with
water to give back the acid and the base. ... Salt hydrolysis may be defined as the
reaction of the cation or the anion of the salt with water to produce acidic or basic
solution

(MOH  M+ + OH- ) (HA  H+ + A- )

Because salt formed is from strong acid and strong base

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Ex : CH3COONH4 + H20 CH3COOH + NH4OH

An acid-base titration is an experimental procedure used to determined the unknown

concentration of an acid or base by precisely neutralizing it with an acid or base of
known concentration. ... It is filled with a solution of strong acid (or base) of known
concentration.
Indicators