Classes for

M. Sc. (Chemistry) SEM – IV

CEM 403 (Advanced Inorganic Chemistry IV)
Inorganic reaction mechanism

Dr. Joydeb Manna

Lecture-1 Mahishadal Raj College
Mahishadal, Purba Medinipur
Inorganic reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
Reaction mechanism
 Questions
1. What are inert and labile complexes? Give examples. 4
2. Discuss the different types of mechanisms (D, A, Ia and Id) involved for ligand
substitution in inorganic chemistry. 4
3. What is trans-effect? 2
4. What are the factors affecting the rate of octahedral substitution? 2
5. Give an evidence to prove that the octahedral substitution is usually dissociative in
nature. 3
6. Square planar substitutions are associative in nature. -Explain. 2
7. Substitution in square planar complexes are stereo-retentive. -Explain. 2
8. In octahedral complexes, the intermediate geometry can leads to either retention of
geometry or isomerization. –Explain. 3
9. [(H3N)CoNCS]2+ + H2O →[Co(NH3)5H2O]3+ +NCS- is 100000 times slower than
replacement with NO3-. Explain. 2
10. White down the Eyring equation with its significance. 3