C 2 H 4 (g) +2 H 2 O(v) ❑ C 2 H 5 OH (v)

2 C2 H 5 OH (v) ❑ (C 2 H 5 )2 O (v) + H 2 O (v)

↔

n1 : C 2 H 4( g)= 53.7% 5% Conversión n 4 : C 2 H 4 (g)

n2 : H 2 O (v )=36.7% n5 : H 2 O ( v )

n3 : N 2= 9.6% n6 : C2 H 5 OH (v)

n7 : (C 2 H 5 )2 O (v)

n8 : N 2

mol de etanol producido

=90 %
mol de etileno consumido

Base de cálculo = 1 mol

C 2 H 4 (g) =0.537 mol

H 2 O ( v )=0.367 mol

 n 4=( 0.537∗0.95 ) =0.510 mol C 2 H 4

 n1 =( 0.537∗0.05 )=0.02685 mol C 2 H 4 consumido se asume el 5 % de conversion
mol etanol producido
 =0.9 mol etanol producido=0.510 mol C 2 H 4∗0.9
0.510 mol C2 H 4
n6 =0.02685∗0.9=0.2416 mol C 2 H 5

Balances de materia

 Carbono

2 ( 0.537 )=n4 +n 6+ n7

0.537=0.510+0.02416+ 2n 7

2.84 x 10−3 −2
n7 = =1.42 x 10 mol (C2 H 5)2 O(v)
2

 Oxigeno

0.367=n5 +n 6+ n7

n5 =0.367−0.02558

n5 =0.3414 mol H 2 O (v )

Entalpilas
T2
^ h^ °f +∫ C p dT
h=
T1

310
 h^ C 2 H 4 ( g) =h^ °f + ∫ C p dT
25

C p=40.75 x 10 +11.47 x 10−5∗T −6.891 x 10−8∗T 2+ 17.60 x 10−12∗T 3

−3

kj
h^ °f =52.28
mol

kj
h^ C H 4 ( g) =68.02
2
mol
 310

 h^ H 2 O( v ) =h^ °f + ∫ C p dT
25

C p=33.46 x 10−3+ 0.688 x 10−5∗T +0.7604 x 10−8∗T 2−3.593 x 10−12∗T 3

kj
h^ °f =−241.84
mol
kj
h^ H O =−232.27
2
mol
(v )

310
 h^ C 2 H 5OH (v) = h^ °f + ∫ C p dT
25

C p=61.34 x 10 +15.72 x 10−5∗T −8.749 x 10−8∗T 2−19.83 x 10−12∗T 3

−3

kj
h^ °f =−235.31
mol
kj
h^ C H OH =−212.16
2 5
mol (v)

310
 h^ ( C H ) O = h^ °f + h^ °v + ∫ C p dT
2 52 ( v)
25

C p=0.08945+ 40.33 x 10−5∗T −2.244 x 10−7∗T 2

kj
h^ °f =−272.8
mol
kj
h^ °v =26.05
mol
kj
h^ ( C H ) O =−206.15
2 52
mol( v)

Balance de energia

( ∑ ni hi )entra + ( ∑ ni hi ) sale+Q=0
 Q=( ∑ ni hi ) sale −( ∑ n i hi ) entra
Q=n4∗h^ C H +n5∗h^ H O + n6∗h^ C H2 4 ( g) 2 (v ) 2 5 OH( v ) +n 7∗h^ ( C H ) O −( n1∗h^ C H +n2∗h^ H O
2 52 ( v) 2 4 ( g) 2 (v ) )
Q=1.3 kj