I.N.D.I.A.

MSDS
INDUSTRIE CHIMICHE S.p.A.
Nona Strada 55/57
I - 35129 Padova
Tel. +39.049.807.61.44
Fax +39.049.807.61.46 AMPLAT
export@indiapesticides.com Latest updating 19/07/07
www.indiapesticides.com

1.IDENTIFICATION OF THE PRODUCT AND THE COMPANY Special protective devices: Suitable outfit
1.1 Name AMPLAT
1.2 Use EC insecticide for public health use 6.ACCIDENTAL RELEASE MEASURES
Public Health Product – Ministry of Health Reg. No. 14306 Precautions for people Avoid contact with eyes and skin. Block the access to
1.3 Company identification I.N.D.I.A. INDUSTRIE CHIMICHE S.p.A. contaminated areas. Do not stand against the wind.
Address Nona Strada 55/57 35129 Padova Removal of ignition sources: Do not smoke
Phone +39.049.807.61.44 Respiratory protection: Protective mask
Fax +39.049.807.61.46 Dust control: Not applicable
e-mail address of the competent laboratorio@indiapesticides.com Prevention of contact with eyes Wear gloves and safety goggles
person responsible for the MSDS and skin:
Website www.indiapesticides.com Environmental precautions: Keep away from drains, surface and underground
1.4 Emergency contacts Centro Anti Veleni Ospedale Niguarda Milano waters. Avoid contamination of foodstuffs
+39.02.66101029 Methods of cleaning up: Absorb onto either sand, fossil flour or other inert
material. Collect the contaminated inert material into
2. HAZARD IDENTIFICATION tight containers and dispose of according to
Classification: Harmful. May cause lung damage if swallowed. indications given at section 13.
Causes serious eye damage. Very toxic to aquatic
organisms 7. HANDLING AND STORAGE
Main chemical and physical hazards Not envisaged 7.1 Handling: Wear suitable protective gloves and safety goggles. Do
Adverse effects not inhale the product.
- for health: The product may be irritating to eyes, skin and the 7.2 Storage: Store the product in aired premises, away from heat
first respiratory tracts. Ingestion may be sources, flames and sparks, equipped with liquid-
dangerous because small amounts of solvent may collection tanks
reach the respiratory tracts and cause pneumonia 7.3 Particular uses:
or lung oedema. Pyrethroids are not highly toxic
to people but the ingestion of large amounts of 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
product may affect the Central Nervous System. 8.1 Exposure threshold values:
Paresthesia, hyper-excitability, tremors may ACGIH
appear following the blockage of nervous TLV-TWA 100 mg/m3 (naphtha)a
transmission caused by pyrethroids. The inhalation active ingredients: not available
of the product may cause drowsiness, headache TLV-STEL
and dizziness. Critical effects Lungs, central nervous system
- for the environment: The concentrated product is toxic to the aquatic Control procedures
environment but the product diluted at 8.2 Exposure control
recommended rates is far less dangerous 8.2.1 Professional exposure control
Other hazards 8.2.1.1 Respiratory Protection Mask
8.2.1.2 Hand protection Gloves
3. INFORMATION ON INGREDIENTS 8.2.1.3 Eye protection Goggles
Substance % EINECS NO. CAS NO. SYMBOLS R PHRASES 8.2.1.4 Skin protection Not applicable
Cypermethrin 93% 5 257-842-9 52315-07- Xn, N 20/22-37- 8.2.2 Environmental exposure control: Use the product according to sound working
(cis/trans 40/60) 8 50/53 practices. Follow the instructions given on the
Tetramethrin 92% 2.5 231-711-6 7696-12-0 N 50/53 product label. Do not leave product residues and
empty containers in the environment. Dispose
Piperonyl Butoxide 12.5 200-076-7 51-03-6 N 50/53
according to instructions given in section 13.
88%
Emulsifiers 11 Xi 41
9. CHEMICAL AND PHYSICAL PROPERTIES
Petroleum naphtha 69 265-198-5 64742-94- Xn 65 9.1 General information
5 Physical state Liquid
Colour yellow
4. FIRST-AID MEASURES Odour aromatic
After inhalation: Remove patient to fresh air. If patient feels 9.2 Important information for human health, safety and the environment
unwell consult a physician pH Not available
Contact with skin: Flush skin immediately and thoroughly with soap Boiling point > 150°C
and water. If irritation persists apply an Flash point >62°C
antihistaminic lotion or vitamin E. Consult a Flammability Non flammable
physician. Explosive properties Not available
Contact with eyes: Flush immediately and thoroughly with water for Combustive properties Not available
at least 15 minutes. Consult a physician Vapour pressure Not available
After ingestion: Do not induce vomiting and do not administer Comparative density 0.93 g/ml
liquids. Consult a physician. No antidotes exist Solubility Emulsifiable
for intoxication by pyrethroids. A symptomatic Octanol/water partition coefficient Log kow 3.8-4.8 (solvent)
treatment is required. Viscosity 5.28 cps
Specific first-aid means to be Antihistaminic lotion Evaporation time Not available
available on workplace: 9.3 other information

5. FIRE-FIGHTING MEASURES 10. STABILITY AND REACTIVITY

Suitable fire-fighting means:
Forbidden fire-fighting means:
Special exposure risks:
Carbon dioxide or dust extinguisher
water
In a fire toxic fumes containing nitrogen oxides,
hydrocyanic acid and carbon monoxide may be
released
10.1 Conditions to avoid Stable under normal conditions. Keep away
from direct sunlight
10.2 Materials to avoid Plastics, oxidising substances
10.3 Dangerous decomposition products: Not available
 MSDS

AMPLAT
Latest updating 19/07/07

IATA Class 9
11. TOXICOLOGICAL INFORMATION
Health-hazardous effects 15. REGULATORY INFORMATION
Target organs See section 3 Classification Harmful
Symptoms See section 3 Hazard symbol Xn, N
Toxicity of the formulated product LD50 acute oral rat 2780 mg/kg (calculated) Risk phrases R65 harmful: may cause lung damage if swallowed
Toxicity of active ingredients R41 Risk of serious damage to eyes
Inhalation toxicity LC50 R50/53 : very toxic to aquatic organisms, may
LD50 acute oral rat LD50 acute dermal cause long-term adverse effects in the aquatic
(4h) environment
Cypermethrin 250-4150 mg/kg >4920 mg/kg >2.5 mg/l Safety phrases S2 Keep out of the reach of children.
Tetramethrin >5000 mg/kg >5000 mg/kg 2.73 mg/l S23 Do not breathe gas/fumes/vapour/spray .
Piperonyl Butoxide >7500 mg/kg >7950 mg/kg >5.9 mg/l/ S51 Use only in well-ventilated areas.
Naphtha >5000 mg/kg >3000 mg/kg >12 mg/l S24/25 Avoid contact with skin and eyes
Contact with eyes and skin Irritating. May cause serious eye damage S26 In case of contact with eyes, rinse
Immediate, delayed and chronic effects resulting from short and long-term exposure: immediately with plenty of water and seek medical
Sensitisation: May cause sensitisation advice
Carcinogenicity: Available data show no specific hazards S62 If swallowed, do not induce vomiting: seek
Mutagenicity: Available data show no specific hazards medical advice immediately and show this
Toxicity on reproduction: Available data show no specific hazards container or label
S60 This material and its container must be
12. ECOLOGICAL INFORMATION disposed of as hazardous waste.
12.1 Ecotoxicity The product is toxic to aquatic organisms S61 Avoid release to the environment. Refer to
12.2 Mobility The a.i. are immobile in soil. In water they link to special instructions/safety data sheets
suspended particles. The solvent evaporates
quickly Sale and usage restrictions: For professional use
12.3 Persistence and degradability Cypermethrin is rapidly degrade in water by UV
rays. Tetramethrin has a very long half-life (2 16. OTHER INFORMATION
years). The solvent is biodegradable Integral text of R phrases: R20/22 Harmful by inhalation and if swallowed
12.4 Bioaccumulation potential Cypermethrin: BCF 420 R37 Irritating to respiratory system
Tetramethrin: BCF 20 R41 Risk of serious damage to eyes
Piperonyl But: BCF 90 R65 Harmful: may cause lung damage if swallowed
12.5 other adverse effects R50/53 Very toxic to aquatic organisms, may
Aquatic toxicity Other ecotoxicity Bee toxicity cause long-term adverse effects in the aquatic
Cypermethrin (96 h) 0.0020 mg/l Wild duck >10000 Highly toxic environment
(brown trout) mg/kg Other information DISCLAIMER OF LIABILITY. The information in this
Tetramethrin (96 h) 0.069 mg/l Wild duck >1000 mg/kg Toxic MSDS was obtained from sources which we
(perchis) believe are reliable. However, the information is
Piperonyl But. (24 h) 5.3 mg/l (carp) Starling >100 mg/kg provided without any warranty, express or implied,
regarding its correctness. The conditions or
13. DISPOSAL CONSIDERATIONS methods of handling, storage, use or disposal of
Handling of product in excess and of waste See sections 7 and 8 the product are beyond our control and may be
Suitable disposal methods (product) Dispose of as toxic waste beyond our knowledge. For this and other
Suitable disposal methods (empty containers): Dispose of as toxic waste reasons, we do not assume responsibility and
expressly disclaim liability for loss, damage or
14. TRANSPORT INFORMATION expense arising out of or in any way connected
UN no. 3082 with the handling, storage, use or disposal of the
Packing group III product. This MSDS was prepared and is to be
Technical name Environmentally hazardous substance, liquid, n.o.s. used only for this product. If the product is used
(contains cypermethrin, tetramethrin and piperonyl as a component in another product, this MSDS
butoxide) information may not be applicable
Transport classification Bibliography: The Pesticide Manual
ADR/RID Class 9 HSDB Hazardous Substances Data Bank
IMO Class 9 MSDS of raw materials