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MODULE 2: DIFFUSION
LECTURE NO. 3
r -r
r = 2 1 z + r1 (2.24)
z 2 - z1
The Equation (2.24) is then substituted in the flux Equation to eliminate r and
then the Equation is integrated and obtained as:
z2 PA2
NA dz -D dPA
π
z1 r2 - r1
2
= AB
RT 1- P /P
PA1 A
z + r1
z 2 - z1
Or
N A 1 1 DAB P P PA2
ln (2.25)
4 r1 r2 RT P PA1
Thus the steady state Equation becomes as follows where NA and Z are
variables:
DAB P
NA ( PA1 PA2 ) (2.26)
RT Z PBM
Where
PB2 PB1 PA1 PA2
PBM (2.27)
ln( PB2 / PB1 ) ln[( P PA2 ) /( P PA1 )]
Assuming a cross sectional area of 1 m2, the level drops dZ meter in dt sec, and
ρA(dZ.1)/MA is the kmol of A that has been left and diffused. Then
A (dZ .1)
N A .1 (2.28)
M A .dt
Substituting the Equation (2.28) in Equation (2.26) and integrating, one gets
A
ZF
DAB P ( PA1 PA2 ) tF
MA Z0
Z dZ RT PBM dt
0
(2.29)
A ( Z F2 Z 02 ) RT PBM
tF (2.30)
2 M A DAB P ( PA1 PA2 )
The Equation (2.30) represents the time tF for the level to drop from a starting
point of Zo meter at t = 0 to ZF at t = tF.
From the Fick’s law of diffusion, the rate of diffusion can be expressed as:
(2.31)
P -D dP NA
N A 1- A = AB A where N A =
Ptotal RT dr 4πr 2
-RTN A dr dPA
Ptotal (2.32)
PA -D AB dPA 2 NA
Ptotal PA
= where N Ar =
4πD AB
Ptotal RT dr 4πr 2
N A dr dPA
Ptotal RT N A dr dPA
AB r
2
Ptotal PA Ptotal (2.33)
4DAB r 2
( Ptotal PA )
-RTN A 1
r2
(2.34)
-RTN A 1 1 Ptotal PA2
ln
4πDAB Ptotal r1 r2 Ptotal PA1