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Abstract
The original firing temperatures of porcelain pieces unearthed from Tengxian Zhonghe kiln, Rongxian Chengguan
kiln, Beiliu Lingdong kiln and Guiping Xishan kiln from the Song Dynasty (960–1279AD) of Guangxi were preliminarily
studied by thermal expansion method. The experiment results show that the average firing temperature of Zhonghe
kiln is 1186 °C (standard deviation 59 °C), the firing temperature relatively concentrated and low. The average firing
temperature of Chengguan kiln is 1233 °C (standard deviation 46 °C), with the majority above 1200 °C, indicating that
the kiln had a high and concentrated firing temperature. The average firing temperature of Lingdong kiln is 1250 °C
(standard deviation 87 °C), the firing temperature are in a broad spectrum. The firing temperatures of Xishan kiln are
mostly over 1300 °C (average 1307 °C, standard deviation 75 °C), which are generally considered very high, and the
highest one it can go up to 1456 °C, which is the highest firing temperature of ancient Chinese ceramics known to
date. Compared with the firing temperature of porcelain in other regions of China in Song Dynasty, it can be con-
cluded that the high-temperature technology of Guangxi porcelain kilns was equal to or even advanced than other
kilns. In the light of these findings, we conclude that the ancient Guangxi region of China did not lag behind the
central plains in terms of ceramic firing technology and culture.
Keywords: Thermal expansion method, Song Dynasty, Greenish-white porcelain, Firing temperature
Introduction and research aim kilns for porcelain production not a single kiln) include
The porcelain industry in Guangxi boomed during the Tengxian Zhonghe kiln, Rongxian Chengguan kiln and
Song Dynasty (960–1279AD), and dominated by two Beiliu Lingdong kiln in the Beiliu river basin, the Guip-
kiln systems of celadon and greenish-white porcelain. ing Xishan kiln and Weiyang kiln in Guiping area and
The celadon kiln sites are concentrated in northern the Tudong kiln in upper reaches of the Wusi river.
Guangxi, mainly producing porcelain with cyan glaze The geographical locations of the four kilns (Tengxian
and green glaze. The greenish-white porcelain kiln sites Zhonghe kiln, Rongxian Chengguan kiln, Guiping Xis-
are concentrated in the southeast of Guangxi, consist- han kiln and Beiliu Lingdong kiln) studied in this paper
ing of three distribution areas: Beiliu river basin, Guip- are shown in Fig. 1. According to archaeological materi-
ing and the upper reaches of Wusi river. There are more als and studies, Zhonghe kiln existed between the mid-
sites in Beiliu river basin than the other two areas. The dle Northern Song Dynasty (960–1127AD) and the late
main kilns (a whole production center comprising several Southern Song Dynasty (1127–1279AD) [1]; Cheng-
guan kiln emerged at about the same time or a bit ear-
lier than Tengxian Zhonghe kiln, which began in the
*Correspondence: b20180621@xs.ustb.edu.cn
2
middle Northern Song Dynasty, and ended in the middle
Archaeometry Laboratory, Guangxi University for Nationalities,
Nanning 530006, Guangxi, China Southern Song Dynasty, the late Northern Song Dynasty
Full list of author information is available at the end of the article through the early Southern Song Dynasty are its heyday
© The Author(s) 2019. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License
(http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium,
provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license,
and indicate if changes were made. The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/
publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated.
Tong and Wang Herit Sci (2019) 7:70 Page 2 of 10
Fig. 1 Geographical distribution map of main greenish-white porcelain kiln sites of Song Dynasty in Guangxi, China
Fig. 3 Incised decoration jar of Chengguan kiln (now is in the Sampling information
Rongxian Museum) Ten samples from the Zhonghe kiln were selected, which
were collected at four different sites: Lishankou, Ping-
touling, Feimaling, Feimaling primary school and Zhi-
maping. Six samples from the Chengguan kiln were
kilns. In the aspect of studying and determining the fir- selected, which were collected from the substation and
ing temperature of ancient ceramics, various methods rosin factory. Six samples from the Lingdong kiln were
and equipments were utilized including the magnetic selected, which were collected from Lingdong kiln Y1.
susceptibility method [9, 10], Mössbauer spectra [11, Ten samples from the Xishan kiln were selected, which
12], thermogravimetric differential thermal analysis [13], were collected from Xungao kiln site and Guanchong
scanning electron microscope [14], electron paramag- kiln site near the park and Guishan village kiln site near
netic resonance measurement [15–17] and the thermal the Guiping distillery. Some sample pictures are shown in
expansion method. The thermal expansion method has Fig. 4. The sample number is a combination of kiln name,
been considered the most precise and direct to measure collection site and serial number, such as TZH-LSK-1,
the firing temperature of ancient ceramics to date [18]. in which TZH is the abbreviation of Tengxian Zhonghe
In 1959, Terrisse first introduced this method to the field kiln, and LSK is the abbreviation of Lishankou, the col-
of archaeology on the firing temperatures study [19]. In lection site. LDY is the abbreviation of Lingdong kiln Y1.
1963, Roberts explained in detail the structure of the
thermal dilatometer, the specific operation and analysis Sample preparation
methods of temperature measurement [20]. In the 1960s, The sample preparation sequence is as follows: clean-
Tite proposed the theoretical hypothesis of this method ing → drying → photographing and recording → cut-
[21] and then used it to determine the firing tempera- ting → grinding the end and bottom surfaces. The sample
ture of ancient ceramics from different periods, which was further cut into rod-shaped rectangular pieces with
had been found in Turkey, Iraq, Nigeria, England, China, a length of 25 mm and a width of 3–5 mm. In order to
and other countries [22]. In 2012, Pee et al. found that the ensure that the pushrod, gasket, and samples expand or
variation in particle size for raw materials could lead to contract in the same straight line during the heating pro-
different shrinkage rates and changing starting tempera- cess, the two end faces of the sample should be absolutely
ture of shrinkage in the reheating process even with the parallel to each other, and the bottom face and two end
same original firing temperature [23]. In 2018, Tong and faces should be flat and smooth.
Wang systematically studied the method by taking into
account multiple factors including temperature rising
Method and experiment
rate, material type, sintering degree, and determination
Method
curve selection [24, 25].
Thermal expansion method is based on the following the-
The purpose of this paper is to study the firing tem-
oretical hypotheses: When a ceramic material with a cer-
perature of the greenish-white porcelain unearthed from
tain firing temperature is heated from room temperature
Song Dynasty kilns in Guangxi, China by using the ther-
to its original firing temperature, the material exhibits
mal expansion method and to provide scientific data for
normal reversible thermal expansion; If the temperature
Tong and Wang Herit Sci (2019) 7:70 Page 4 of 10
However, there is uncertainty for this method. For exam- 25% [26], which is similar to the content of Al2O3 in the
ple, the temperature rising rate, types of ceramic mate- ceramic material selected in the simulation experiment.
rial, degree of sintering, determination curve selection Therefore, in the final temperature measurement results
and different analysis methods will bring uncertainty of these 10 samples, the dL curve was used as their deter-
to the measurement results. In addition, some ceramic mination curve, which means that the starting point of
materials internally will undergo phase transition or net shrinkage on the dL curve was the measured value.
generate gas at a specific temperature, and the expan- The content of A l2O3 in Chengguan kiln porcelain body
sion or contraction accompanied by phase transition or is similar to that in Zhonghe kiln porcelain [26], so the dL
generated gas will cover or affect the net shrinkage, thus curve was also selected for the determination curve. In
bringing uncertainty to the determination of the final the 6 samples of Lingdong kiln, except LDY-5, other por-
result. Fortunately, to determine the final firing tempera- celain samples are similar in porcelain body to Zhonghe
ture we have done a large number of simulated experi- kiln and Chengguan kiln porcelain, but slightly darker
ments under various conditions, and now we have a new in color. Therefore, the dL curve is again selected as the
understanding of the rule of uncertainty of temperature determination curve for temperature measurement
measurement results, and can receive the results (the results of all samples except LDY-5. The LDY-5 porcelain
uncertainty is within 17 °C) close to the actual firing tem- sample belongs to low-aluminum clay material type, and
perature by a calibrating procedure and formula [24]. low-aluminum clay materials in the simulated tempera-
ture measuring experiment show that with a heating rate
Experiment of 5 K/min, if the measured value of the dL/dt curve falls
The "correction + sample" mode was selected for sam- between 1080 and 1200 °C, the measurement is accurate
ple testing, and the softening point detection was set based on the measured value of the dL/dt curve [25]. The
to prevent the sample from melting and contaminate temperature measurements of many porcelain samples
the sample holder at a high temperature. The "correc- from the Xishan kiln were higher than 1250 °C deter-
tion + sample" mode can deduct the expansion of the mined by the dL/dt curve. According to the simulation
instrument system itself automatically during the test- experimental study, the measured values determined by
ing and can reflect the expansion or contraction of the the dL/dt curve under the heating rate of 5 K/min were
sample at high temperature more accurately. Prior tem- clearly higher than 1250 °C or lower than 1080 °C, so the
perature measurement simulation experiments show that correction formula T = 1.13732Tm-161 (T is the final
more accurate temperature measurement results can be determined value and Tm is the measured value) should
obtained for ceramic materials with higher aluminum be used [24]. Therefore, when the final temperature
content at higher temperature rate. The optimal heating measurement results are determined, some should be
rate of the high alumina-ceramic material (Al2O3 con- corrected as required.
tent ≥ 26.4%) used in the simulation experiment is 7.5 K/ Figures 6 and 7 show the two special thermal expan-
min [24]. Among the 32 porcelain samples in this test, sion curves in this temperature measurement study.
RCG-BDS-1 and RCG-SZC-1 samples have an extremely The measured values determined by the dL curve and
delicate and white porcelain body, and the content of the dL/dt curve in Fig. 6 are quite different from each
aluminum in porcelain bodies is equal to or even higher
than that of the high-alumina materials in the simulation
experiment [26]. Therefore, the temperature rising rate of
the above two porcelain samples are set at 7.5 K/min; The
aluminum content of the remaining samples are slightly
lower or lower than that of the high-alumina ceramic
materials used in the simulation experiment, so the heat-
ing rate are set as 5 K/min.
Results and discussion
The experimental study on the simulated temperature
measurement of high-alumina ceramic materials (Al2O3
content ≥ 26.4%) with high kaolin content shows that
the starting point of net shrinkage on the dL curve is the
most appropriate final temperature measurement result
[24]. The Zhonghe kiln porcelain body is white and deli- Fig. 6 Thermal expansion curve of TZH-LSK-1 sample (description as
in Fig. 5)
cate, and the content of A l2O3 in porcelain body is about
Tong and Wang Herit Sci (2019) 7:70 Page 6 of 10
of pottery at 920 °C to that of printed hard pottery at firing technology in the Song Dynasty. This is a signifi-
1080 °C in the Shang and Zhou Dynasties (circa 1600– cant result. There still remain questions such as why so
256 BC), the gradual temperature increase heralds the many porcelain kilns developed in the Song Dynasty in
first breakthrough of high-temperature technology in the Guangxi, a borderland region of China and why those
history of Chinese ceramics [30]. In the Tang Dynasty greenish-white porcelain kilns managed to develop those
(618–907AD), the average firing temperature of north- superb firing knowhow. Perhaps the greatest signifi-
ern white porcelain was about 1240 °C [30], which was cance of this paper is that it raises more questions whose
considered the second historical breakthrough in the answers require further scientific research.
high-temperature technology of Chinese ceramics. In
the Song Dynasty (960–1279AD), the average firing tem-
Abbreviation
perature of the porcelain in the official kilns was as high DIL: dilatometer.
as about 1270 °C [31], and that in some folk kilns, such
as Xianghu kiln in Jingdezhen and Dehua kiln in Fujian, Acknowledgements
Not applicable.
was also high, and could reach 1230 °C [32] and 1260 °C
[30] respectively. The average firing temperature of por- Authors’ contributions
celain from Hutian kiln in Jingdezhen and Jizhou kiln in CMW created the study idea and oversaw the whole work. YDT conducted all
the experiments including the data analysis and drafted the manuscript. Both
Jiangxi are relatively low, below than 1200 °C [33, 34]. The authors helped revise the manuscript. Both authors read and approved the
research results of this paper show that the average firing final manuscript.
temperature of the Song Dynasty Zhonghe kiln, Cheng-
Funding
guan kiln, Lingdong kiln, and Xishan kiln in Guangxi The study is funded by the natural science foundation of Guangxi (2018GXNS-
were up to 1186 °C, 1233 °C, 1250 °C and 1307 °C respec- FAA294094); Reform and innovation program of degree and postgraduate
tively. The comparison between the average firing tem- education in Guangxi university for nationalities (gxun-chxjg201701).
perature of kiln in the Song Dynasty in Guangxi and that Availability of data and materials
in other parts of China shows that the firing temperature Not applicable.
of Zhonghe kiln is basically the same as that of Hutian
Ethics approval and consent to participate
kiln and Jizhou kiln, and the average firing temperature is Not applicable.
below 1200 °C; The average firing temperature of Cheng-
guan kiln is similar to that of Xianghu kiln, about 1230 °C; Competing interests
The authors declare that they have no competing interests.
The average firing temperature of Lingdong kiln is close
to that of Dehua kiln, about 1250–1260 °C; The high-tem- Author details
1
perature technology of Xishan kiln is clearly advanced, Institute of Culture Heritage and History of Science & Technology, University
of Science and Technology Beijing, Beijing 100083, China. 2 Archaeometry
since its average firing temperature reaches 1307 °C, and Laboratory, Guangxi University for Nationalities, Nanning 530006, Guangxi,
is more than 30 °C higher than that of official kiln in the China.
Song Dynasty. The above comparative analyses indicate
Received: 12 April 2019 Accepted: 29 August 2019
that the high-temperature technical level of Guangxi por-
celain kilns in the Song Dynasty is equal to or even better
than that of other Song Dynasty porcelain kilns in China.
Considering the fact that Guangxi was in a remote south- References
ern border area, and far from the culture and economic 1. Wei RY. Greenish white porcelain from Guangxi in Song Dynasty. Jingdez-
center in ancient China, its high-temperature technology hen’s Ceram. 1993;3:11–4 (in Chinese).
2. Jiang TY. General theory of Guangxi archaeology. Nanning: Guangxi Sci-
was a remarkable achievement. ence and Technology Press; 2012 (in Chinese).
3. Zhang SQ. The Song porcelain kilns at Guiping. Guangxi Acta Archaeo-
logica Sinica. 1983;37:501–19 (in Chinese).
Conclusions 4. Cheng L, Ding XL, Feng SL, Cheng HS, Zhang WJ, Fan CS. PIXE analysis of
Though a large of number porcelain kiln sites have Chinese ancient greenish white porcelain. Nucl Instrum Methods Phys
been discovered in Guangxi, few scientific research has Res Sect B. 2006;244:409–11.
5. Cheng L, Li MT, Wang JL, Li RW. The study of ancient porcelain of Hutian
been conducted. In general, the porcelain discovered in kiln site from five dynasty (902–979) to Ming dynasty (1368–1644) by
Guangxi in the Song Dynasty is not as much important INAA. J Radioanal Nucl Chem. 2015;304:817–22.
as contemporary famous porcelain manufactured from 6. Zhu TQ, Wang CS, Wang HM, Mao ZW. The preliminary study on kiln
identification of Chinese ancient Qingbai wares by ICP-AES. J Cult Herit.
north or other regions of China. However, the results of 2010;11:482–6.
this study indicate that the firing technology of greenish- 7. Zhu TQ, Sun WD, Zhang H, Wang HM, Kuang GR, Lv L. Study on the
white porcelain of Guangxi did not lag behind other areas provenance of Xicun Qingbai wares from the northern Song Dynasty of
China. Archaeometry. 2012;54:475–88.
in China in the Song Dynasty. Some kilns of Guangxi 8. Ming CF, Yang YM, Zhu J, Guan L, Fan CS, Xu CQ, Yao ZQ, Kenoyer JM,
were even in a countrywide leading position in terms of Song GD, Wang CS. Archaeometric investigation of the relationship
Tong and Wang Herit Sci (2019) 7:70 Page 10 of 10
between ancient egg-white glazed porcelain (Luanbai) and bluish white 23. Pee JH, Lee EM, Kim GH, Kim YJ, Kim KJ, Gang GI, Jung DS, Katsuki H.
glazed porcelain (Qingbai) from Hutian Kiln, Jingdezhen. China J Archaeol Evaluation of firing temperature of the Bangsan Porcelain. Key Eng Mater.
Sci. 2014;47:78–84. 2012;512–515:666–70.
9. Rasmussen KL, De La Fuente GA, Bond AD, Mathiesen KK, Vera SD. Pottery 24. Tong YD. Multi-factor analysis of firing temperature measurement by
firing temperatures: a new method for determining the firing tempera- thermal expansion method and its application to Guangxi ancient
ture of ceramics and burnt clay. J Archaeol Sci. 2012;39:1705–16. ceramics [Master dissertation]. Nanning: Guangxi University for Nationali-
10. Kostadinova-Avramova M, Jordanova N, Jordanova D, Grigorov V, ties; 2018 (in Chinese).
Lesigyarski D, Dimitrov P, Bozhinova E. Firing temperatures of ceramics 25. Wang CM, Tong YD. The simulation experiment research of the thermal
from Bulgaria determined by rock-magnetic studies. J Archaeol Sci Rep. expansion technology in determination of the firing temperature of
2018;17:617–33. ancient ceramics. Sci Technol Eng. 2018;18:86–91 (In Chinese).
11. Gao ZY, Chen SH, Chen XD. Mössbauer study of the Ru porcelain of Chi- 26. Zhou BY. Scientific research on Bluish white Porcelain from Zhonghe kiln
nese Song Dynasty and Yuan Dynasty. Hyperfine Interact. 1994;91:663–8. in Guangxi [Master dissertation]. Nanning: GuangXi University for Nation-
12. Tominaga T, Takeda M, Mabuchi H, Emoto Y. Characterization of ancient alities; 2016 (in Chinese).
Japanese roofing tiles by ’Fe Mössbauer spectroscopy. Archaeometry. 27. Peng CL. The Song dynasty kiln site in Lingdong, Beiliu city, Almanac of
2007;20:135–46. Chinese archaeology. Beijing: Cultural Relics Press; 1996 (in Chinese).
13. Bayazit M, Işık I, Issi A. Investigating the firing technologies of Part-Roman 28. Lu XK, Li WD, Luo HJ, Han LS, Wang HM, Li Q. Scientific research of Xing
potsherds excavated from Kuriki (Turkey) using thermal and vibrational kiln. Scientia Sinica. 2012;42:1204–21 (in Chinese).
spectroscopic techniques. Vib Spectrosc. 2015;78:1–11. 29. Gao AS. Some thoughts on the firing temperature of porcelain. Collec-
14. Bertolino SR, Fabra M. Provenance and ceramic technology of pot sherds tors. 2006;13:33–40 (in Chinese).
from ancient Andean cultures at the Ambato valley. Argentina Appl Clay 30. Li JZ. History of science and technology in China ceramic volumes.
Sci. 2003;24:21–34. Beijing: Science Press; 1998 (in Chinese).
15. Yves B, Bruno D, Sandrine C, Jean-Victor Z. Electron spin resonance and 31. Wang HM. Comprehensive scientific analyses of porcelains of the Song
dilatometric studies of ancient ceramics applied to the determination of Dynasty [PhD dissertation]. Hefei: University of Science and Technology
firing temperature. Jpn J Appl Phys. 1998;37:4367–72. of China; 2010 (in Chinese).
16. Felicissimo MP, Peixoto JL, Bittencourt C, Tomasi R, Houssiau L, Pireaux JJ, 32. Ouyang RF. Comparative study on the evolution from white porcelain in
Rodrigues-Filho UP. SEM, EPR and ToF-SIMS analyses applied to unravel five dynasties to greenish white porcelain in Song Dynasty in Jingdezhen
the technology employed for pottery-making by pre-colonial Indian [Master dissertation]. Jingdezhen: Jingdezhen ceramic Institute; 2014 (in
tribes from Pantanal, Brazil. J Archaeol Sci. 2010;37:2179–87. Chinese).
17. Cano NF, Ribeiro RB, Munita CS, Watanabe MS, Neves EG, Tamanaha EK. 33. Wu JM, Wu L, Ding YZ, Yuan F, Fang T. Chemical composition and
Dating and determination of firing temperature of ancient potteries from technological characteristics of brown, Northern Song Dynasty pointillist
São Paulo II archaeological site, Brazil by TL and EPR techniques. J Cult porcelain pillows of the Jingdezhen Hutian Kiln. Sci Conserv Archaeol.
Herit. 2015;16:361–4. 2017;29:41–46 (in Chinese).
18. Zhu J, Zhang Y, Wang T, Zhao CH, Yu JC, Glascock MD, Wang CS. Deter- 34. Li QJ, Xu LBY, Zhang ML, Wu L, Wu J. Analysis of structure and properties
mining the firing temperature of low-fired ancient pottery: an example of greenish white porcelain belong to Jizhou Kiln in Song Dynasty. China
from the Donghulin Site, Beijing. China Archaeom. 2013;56:562–72. Ceram. 2018;54:48–53 (in Chinese).
19. Terrisse JR. Study on the technique of the sigillated earthenware. Assoc
Roman Ceram Archaeol. 1959;2:63.
20. Roberts JP. Determination of the firing temperature of ancient ceramics Publisher’s Note
by measurement of thermal expansion. Archaeometry. 1963;6:21–5. Springer Nature remains neutral with regard to jurisdictional claims in pub-
21. Tite MS. Determination of the firing temperature of ancient ceramics lished maps and institutional affiliations.
by measurement of thermal expansion: a reassessment. Archaeometry.
1969;11:131–43.
22. Tite MS. Determination of the firing temperature of ancient ceramics by
measurement of thermal expansion. Nature. 1969;222:81.