9/28/2017

KULIAH ESSO
• IR :
– bedanya nujol mull, KBr, neat
– Bedanya amina primer, sekunder dan tersier
• 1H NMR :
– Coupling constant
• Alkena
• Pada orto, meta dan para
• 13C NMR:
– DEPT 45, 90 dan 135

1
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Coupling Constants

• Distance between the peaks of multiplet

• Measured in Hz
• Not dependent on strength of the external
field
• Multiplets with the same coupling
constants may come from adjacent groups
of protons that split each other.
=>
3

Values for
Coupling Constants

=>

2
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a c
H
C C
H
Complex Splitting
Hb

• Signals may be split by adjacent

protons, different from each other, with
different coupling constants.
• Example: Ha of styrene which is split by
an adjacent H trans to it (J = 17 Hz) and
an adjacent H cis to it (J = 11 Hz).
=>
5

H
a
H
c Splitting Tree
C C
Hb

=>

3
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SINTESIS 6-
NITROVERATRALDEHIDA
Hasil dan Pembahasan
Spektra 1H-NMR
4, 5
4
5

2 9 proton
3
5 tipe proton

2
1 3

Analisis 1H-NMR (CD3OD) Senyawa 1a

Doan dan Tran (2011)
D β F
-C=C-  Doublet, J = 15,50 Hz
B C

α
E F
C A
A
j = 15,55 Hz j = 15,55 Hz
1,09

α
3,09
1,07

E
1,04

1,07

β H2O
B F
2,11

7,7 7,6
CD3OD
7,4 7,3 7,2

C 8,0
2,04

F C
D
1,00

αE B
β D
6,9 6,8

12 11 10 9 8 7 6 5 4 3 2 1 0 8
Pergeseran Kimia (ppm)

4
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DEPT-135 DEPT Spectra

DEPT-90

DEPT-45

CH CH2 CH3
C normal C-13 spectrum

Quaternary carbons (C) do not show up in DEPT.

DEPT-90

DEPT-135

O
CH3

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Simulated DEPT Spectra of Ethyl Phenylacetate

O

O
DEPT-135

O
DEPT-90
O

DEPT-45

Normal C-13 spectrum

A C4H8O2

6
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C7H7Br P-

O-

M-

C4H8Cl2
B

7
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H-NMR C10H12O

10 8 6 4 2 0
PPM

C-NMR C10H12O

200 180 160 140 120 100 80 60 40 20 0

PPM

8
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MS C10H12O

1H-NMR C8H16O2
D F

A B
C

9
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13C-NMR C8H16O2

4
2 3 6

5
1

MS C8H16O2

43

71

57
27
101
15 87
144
129

10