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RUMUS
RUMUS
φ
( [ C3 H 6 ] ) =
d [ C 3 H 4 O ] +d [ C2 H 4 O 2 ] + d [ C 3 H 4 O 2 ]
k 2 [ C3 H 6 ] +k 4 [ C 3 H 4 O ]
¿
k 1 [ C 3 H 6 ] −(k ¿ ¿ 4 +k 5 ) [ C 3 H 4 O ]+ k 3 [ C 3 H 6 ] + k 5 [C 3 H 4 O ] + k 2 [ C 3 H 6 ]+ k 4 [ C3 H 4 O ] ¿
k 2 [C 3 H 6 ]+ k 4 [ C 3 H 4 O ]
¿
( k 1 +k 3 + k 4 ) [ C 3 H 6 ]
k 2 [ C3 H 6 ] +k 4 [ C 3 H 4 O ]
dφ
=
d
d [ C 3 H 6 ] d [ C3 H 6 ] [
( k 1 + k 3+ k 4 ) [ C 3 H 6 ] ]
REAKSI I
[C3 H 4O ] d [ C3 H 4 O ]
φ
( [C3 H6 ] ) =
d [ C 3 H 4 O ] + d [ C 2 H 4 O 2 ] +d [ C 3 H 4 O 2 ]
k 1 [ C 3 H 6 ]−( k 4 +k 5 ) [ C 3 H 4 O ]
¿
k 1 [ C 3 H 6 ] −(k ¿ ¿ 4 +k 5 ) [ C 3 H 4 O ]+ k 3 [ C 3 H 6 ] + k 5 [C 3 H 4 O ] + k 2 [ C 3 H 6 ]+ k 4 [ C3 H 4 O ] ¿
k 1 [ C 3 H 6 ]−( k 4 +k 5 ) [ C 3 H 4 O ]
¿
( k 1+ k 3 +k 4 ) [C 3 H 6 ]
k 1 [ C 3 H 6 ] −( k 4 + k 5 ) [ C 3 H 4 O ]
dφ
=
d
d [ C 3 H 6 ] d [ C3 H 6 ] [
( k 1 +k 3 +k 4 ) [ C3 H 6 ] ]
2
dφ
=
d
d [ C 3 H 6 ] d [ C3 H 6 ] [ k 1 [ C3 H 6 ] −( k 4 + k 5 ) [ C 3 H 6 ][ O 2 ]−[ C 3 H 6 ] 2 [ O 2 ] −[ C3 H 6 ]
( k 1 +k 3+ k 4 ) [ C 3 H 6 ]
[O ]
3 2
]
REAKSI II
[ C 3 H 4 O2 ] d [ C 3 H 4 O2 ]
φ
( [ C3 H 6 ] ) =
d [ C 3 H 4 O ] +d [ C2 H 4 O 2 ] + d [ C 3 H 4 O 2 ]
k 2 [ C3 H 6 ] +k 4 [ C 3 H 4 O ]
¿
k 1 [ C 3 H 6 ] −(k ¿ ¿ 4 +k 5 ) [ C 3 H 4 O ]+ k 3 [ C 3 H 6 ] + k 5 [C 3 H 4 O ] + k 2 [ C 3 H 6 ]+ k 4 [ C3 H 4 O ] ¿
k 2 [C 3 H 6 ]+ k 4 [ C 3 H 4 O ]
¿
( k 1 +k 3 + k 4 ) [ C 3 H 6 ]
k 2 [ C3 H 6 ] +k 4 [ C 3 H 4 O ]
dφ
=
d
d [ C 3 H 6 ] d [ C3 H 6 ] [ ( k 1 + k 3+ k 4 ) [ C 3 H 6 ] ]
2
[ ]
dφ
=
d
d [ C 3 H 6 ] d [ C3 H 6 ] [ k 2 [ C3 H 6 ] +k 4 [ C3 H 6 ][ O 2 ]−[ C 3 H 6 ] 2 [ O 2 ]−[ C3 H 6 ]
( k 1 +k 3 +k 4 ) [ C3 H 6 ]
O
3 [ 2]
]