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Dangerous Goods
Emergency
Action Code List
2017
London: TSO
Online
www.tsoshop.co.uk
The publication is produced by NCEC (National Chemical Emergency Centre). NCEC is part of
Ricardo-AEA Ltd. Registered Office Shoreham Technical Centre, old Shoreham Road, Shoreham-
by-Sea, West Sussex, BN43 5FG. Registered in England and Wales No.8229264.
This publication is produced with the co-operation of the Home Office and builds on the previous
publication, in the same name, produced by them and published by the Stationery Office Limited.
© Ricardo-AEA Ltd 2017
All rights reserved.
ISBN 978 0 11 754160 3
Printed in Great Britain on material containing 75% post-consumer waste and 25% ECF pulp.
Printed in the United Kingdom by TSO
J003292724 C12 04/17
1 Règlements Internationales Relatif au Transport des Marchandises Dangereuses par Chemin de Fer
2 Accord Européen Relatif au Transport International des Marchandises Dangereuses par Route
Section 3: A
pplication of Emergency Action Codes for the
Emergency Services 17
Interpretation of Codes 17
Extinguishing Media 18
Personal Protection 18
Violent Reaction 19
Contain/Dilute 19
E “Public Safety Hazard” 21
Acknowledgements 199
1.1 Introduction
1.1.1 Emergency Action codes (EACs), also known as Hazchem codes,
are for the use of the emergency services in conjunction with
Emergency Action Code Cards. EACs indicate to the emergency
services actions that may be necessary, during the first few
minutes of an incident involving dangerous goods, should the
officer in charge of the incident deem it necessary to take
immediate actions.
1.1.2 This document shall not be used for the purposes of markings on
the orange coloured plate without reference to the Carriage of
Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (CDG 2009), as amended; or of the Carriage of
Dangerous Goods and Use of Transportable Pressure Equipment
Regulations (Northern Ireland) 2010 (CDG 2010), as amended;
and ADR/RID. The fact that a United Nations (UN) number and
emergency action code (EAC) for a given substance are shown in
this document does not necessarily mean they should be used for
the marking of road tankers, rail tank wagons or tank containers
used for the carriage of that substance. An annotation (1) in the
EAC column of Section 4 indicates that it is not applicable to the
carriage of dangerous goods under RID or ADR.
1.1.3 This document contains all items listed by the United Nations
in their publication “Recommendations on the Transport of
Dangerous Goods Model Regulations (nineteenth revised
edition)” with the exception of substances in UN Class 1, i.e.
explosives. EACs are not allocated to radioactive materials and
these are annotated (2) in the EAC column of Section 4 of this
document.
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INTRODUCTION TO THE EMERGENCY ACTION CODES 7
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8 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
CLASS 2 – Gases
Toxic gases
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INTRODUCTION TO THE EMERGENCY ACTION CODES 9
CLASS 4.3 – Substances which, in contact with water, emit flammable gases
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10 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
1.2.3 The following are marks that may appear on vehicles during the
transport of dangerous goods and would appear in addition to
the danger labels at 1.2.1.
Mark for elevated temperature substances Dangerous goods packed in limited quantities
DANGER
DO NOT ENTER
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12 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
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DISPLAYING EMERGENCY ACTION CODES 13
P R S T W X Y Z
P P P P P W W W W
R P R P R W X W X
S P P S S W W Y Y
T P R S T W X Y Z
W W W W W W W W W
X W X W X W X W X
Y W W Y Y W W Y Y
Z W X Y Z W X Y Z
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14 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
Letter ‘E’
2.2.7 The letter ‘E’ shall be included as the third character in the
multi-load emergency action code if it occurs in the EAC of any
of the dangerous goods to be carried. If the letter ‘E’ does not
occur in any of the EACs of the dangerous goods to be carried,
the EAC shall be just a two character code determined from
paragraphs 2.2.2 to 2.2.6 above.
Example:
2.2.8 The following is an example of how to calculate the emergency
action code for a multi-load.
There are three substances to be carried as a multi-load,
having emergency action codes of 3Y, 2S and 4WE.
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DISPLAYING EMERGENCY ACTION CODES 15
Letter ‘E’
The third substance has an ‘E’ as a third character and therefore
the multi-load shall also have an ‘E’.
The resultant emergency action code for the three substances
carried as a multi-load shall therefore be 4WE.
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16 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
Personal Protection
3.1.4 Where the second character of the EAC is S, T, Y or Z normal
firefighting clothing is appropriate, i.e. self-contained open
circuit positive pressure compressed air breathing apparatus
conforming to BS EN 137 worn in combination with fire kit
conforming to BS EN 469, firefighters’ gloves conforming to
BS EN 659 and firefighters’ boots conforming to Home Office
Specification A29 (rubber boots) or A30 (leather boots).
Note: Boots conforming to Home Office Specification
A30 (leather boots) may not provide adequate chemical
resistance and therefore caution should be exercised in the
use of these boots.
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18 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
Violent Reaction
3.1.6 Where the second character of the EAC is a P, S, W or Y there
is a danger that the substance can be violently or explosively
reactive. This danger may be present due to one of the following:
■■ Violent or explosive decomposition of the material involved,
including ignition or friction.
■■ The ignition of a flammable gas or vapour cloud (this danger
exists for all flammable gases and flammable liquids with a
flash point below 60°C).
■■ The rapid acceleration of combustion due to the involvement
of an oxidiser.
■■ A reaction with water which is itself violent, and may also
evolve flammable gases.
3.1.7 The actual danger present can be determined from the vehicle
placards or by reference to the United Nations Class in this
document or another appropriate source, e.g. fire control.
Contain/Dilute
3.1.8 Where the second character of an EAC is W, X, Y or Z
spillages, contaminated fire and decontamination run-off
should be prevented from entering drains and surface and
groundwaters. Where the second character of the code
is P, R, S or T and there is an immediate threat to people,
spillages and decontamination run-off may be washed to
drains with large quantities of water. In such cases due care
must be exercised to avoid unnecessary pollution of surface
and groundwaters and wherever possible control measures
such as the sealing of drains should be employed. More
detailed advice on pollution control techniques and equipment
can be found on the ‘Environmental Protection‘ pages of
the Published National Operational Guidance Programme
(http://www.ukfrs.com/guidance/published-guidance).
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APPLICATION OF EMERGENCY ACTION CODES FOR THE EMERGENCY SERVICES 19
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APPLICATION OF EMERGENCY ACTION CODES FOR THE EMERGENCY SERVICES 21
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NUMERICAL LIST OF DANGEROUS GOODS 23
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24 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
Column 5: Hazards
4.1.12 This is sub-divided to show the primary hazard of the substance,
which determines the Class into which the substance is assigned,
and, where appropriate, the subsidiary risks. The classifications
identified are those adopted by the United Nations Committee of
Experts on the Transport of Dangerous Goods and on the Globally
Harmonised System of Classification and Labelling of Chemicals,
and are as follows:
Class 1 – Explosives (Note: not included in this document)
Class 2.1 – Flammable gases
Class 2.2 – Non-flammable, non-toxic gases
Class 2.3 – Toxic gases
Class 3 – Flammable liquids and desensitised liquid explosives
Class 4.1 – Flammable solids, self-reactive substances and solid
desensitised explosives
Class 4.2 – Substances liable to spontaneous combustion
Class 4.3 – Substances which in contact with water emit
flammable gases
Class 5.1 – Oxidising substances
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NUMERICAL LIST OF DANGEROUS GOODS 25
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NUMERICAL LIST OF DANGEROUS GOODS 27
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NUMERICAL LIST OF DANGEROUS GOODS 29
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NUMERICAL LIST OF DANGEROUS GOODS 35
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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NUMERICAL LIST OF DANGEROUS GOODS 37
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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NUMERICAL LIST OF DANGEROUS GOODS 41
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR (3) Various
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR (2) Radioactive material
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR (2) Radioactive material
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR (2) Radioactive material
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
(1) Not applicable to the carriage of dangerous goods under RID or ADR
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(1) Not applicable to the carriage of dangerous goods under RID or ADR
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Alphabetical List of
Dangerous Goods
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ALPHABETICAL LIST OF DANGEROUS GOODS 141
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ALPHABETICAL LIST OF DANGEROUS GOODS 143
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ALPHABETICAL LIST OF DANGEROUS GOODS 159
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ALPHABETICAL LIST OF DANGEROUS GOODS 163
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ALPHABETICAL LIST OF DANGEROUS GOODS 167
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ALPHABETICAL LIST OF DANGEROUS GOODS 169
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NITRIC ACID, other than red 2031 NITROCELLULOSE, with not 2557
fuming nitric acid more than 12.6% nitrogen by
dry mass, MIXTURE, WITHOUT
NITRIC ACID, RED FUMING 2032 PLASTICIZER, WITH OR
WITHOUT PIGMENT
NITRIC OXIDE, COMPRESSED 1660
NITROCELLULOSE with ALCOHOL, 2556
NITRIC OXIDE AND DINITROGEN 1975 not less than 25% alcohol
TETROXIDE MIXTURE
NITROCELLULOSE WITH WATER 2555
NITRIC OXIDE AND NITROGEN 1975 not less than 25% water by mass
DIOXIDE, MIXTURE
Nitrochlorobenzene, see 1578
NITRILES, FLAMMABLE, TOXIC, 3273 3409
N.O.S.
3-NITRO-4-CHLOROBENZO- 2307
NITRILES, TOXIC, FLAMMABLE, 3275 TRIFLUORIDE
N.O.S.
NITROCRESOLS, LIQUID 3434
NITRILES, LIQUID, TOXIC, N.O.S. 3276
NITROCRESOLS, SOLID 2446
NITRILES, SOLID, TOXIC, N.O.S. 3439
NITROETHANE 2842
NITRITES, INORGANIC, N.O.S. 2627
NITROGEN, COMPRESSED 1066
NITRITES, INORGANIC, 3219
AQUEOUS SOLUTION, N.O.S. Nitrogen dioxide, see 1067
NITROANILINES (o-,m-,p-) 1661 NITROGEN, REFRIGERATED 1977
LIQUID
NITROANISOLES, LIQUID 2730
NITROGEN TRIFLUORIDE 2451
NITROANISOLES, SOLID 3458
NITROGEN TRIOXIDE 2421
NITROBENZENE 1662
NITROGLYERIN MIXTURE, 3357
Nitrobenzene bromide, see 2732 DESENSITIZED, LIQUID,
N.O.S., with not more than 30%
NITROBENZENESULPHONIC ACID 2305
nitroglycerin by mass
Nitrobenzol, see 1662
NITROGLYCERIN MIXTURE, 3319
NITROBENZOTRIFLUORIDES, 2306 DESENSITIZED, SOLID, N.O.S.,
LIQUID with more than 2% but not more
than 10% nitroglycerin by mass
NITROBENZOTRIFLUORIDES, 3431
SOLID NITROGLYCERIN MIXTURE, 3343
DESENSITIZED, LIQUID,
NITROBROMOBENZENES, 2732 FLAMMABLE, N.O.S., with not
LIQUID more than 30% nitroglycerin by
mass
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ALPHABETICAL LIST OF DANGEROUS GOODS 177
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Phosphoryl chloride, see 1810 POLYESTER RESIN KIT, solid base 3527
material
PHTHALIC ANHYDRIDE, with 2214
more than 0.05% maleic anhydride POLYHALOGENATED 3151
BIPHENYLS, LIQUID
PICOLINE 2313
POLYHALOGENATED 3152
Picric Acid, Wetted, see 1344 BIPHENYLS, SOLID
3364
POLYHALOGENATED 3151
Picrite, Wetted, see 1336 TERPHENYLS, LIQUID
Picrotoxin, see 3172 POLYHALOGENATED 3152
3462 TERPHENYLS, SOLID
Picryl Chloride, Wetted, see 3365 POLYMERIC BEADS, EXPANDABLE, 2211
evolving flammable vapour
alpha-PINENE 2368
POLYMERIZING SUBSTANCE, 3531
PINE OIL 1272
LIQUID, STABILIZED, N.O.S.
PIPERAZINE 2579
POLYMERIZING SUBSTANCE, 3533
PIPERIDINE 2401 LIQUID, TEMPERATURE
CONTROLLED, N.O.S.
Privaloyl chloride, see 2438
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ALPHABETICAL LIST OF DANGEROUS GOODS 183
Potassium bisulphite solution, see 2693 Potassium nitrate and sodium 1499
nitrate mixture, see
POTASSIUM BOROHYDRIDE 1870
POTASSIUM NITRATE and 1487
POTASSIUM BROMATE 1484 SODIUM NITRITE MIXTURE
POTASSIUM CHLORATE 1485 POTASSIUM NITRITE 1488
POTASSIUM CHLORATE, 2427 POTASSIUM PERCHLORATE 1489
AQUEOUS SOLUTION
POTASSIUM PERMANGANATE 1490
POTASSIUM CUPROCYANIDE 1679
POTASSIUM PEROXIDE 1491
POTASSIUM CYANIDE, SOLID 1680
POTASSIUM PERSULPHATE 1492
POTASSIUM CYANIDE SOLUTION 3413
POTASSIUM PHOSPHIDE 2012
Potassium dicyanocuprate (I), see 1679
Potassium selenate, see 2630
POTASSIUM DITHIONITE 1929
Potassium selenite, see 2630
POTASSIUM FLUORIDE, SOLID 1812
Potassium silicofluoride, see 2655
POTASSIUM FLUORIDE 3422
SOLUTION POTASSIUM SODIUM ALLOYS, 1422
LIQUID
POTASSIUM FLUOROACETATE 2628
POTASSIUM SODIUM ALLOYS, 3404
POTASSIUM FLUOROSILICATE 2655 SOLID
Potassium hexafluorosilicate, see 2655 POTASSIUM SULPHIDE, 1382
ANHYDROUS or POTASSIUM
Potassium hydrate, see 1814 SULPHIDE, with less than 30%
POTASSIUM 1811 water of crystallization
HYDROGENDIFLUORIDE, SOLID POTASSIUM SULPHIDE, 1847
POTASSIUM 3421 HYDRATED, with not less than
HYDROGENDIFLUORIDE 30% water of crystallization
SOLUTION POTASSIUM SUPEROXIDE 2466
POTASSIUM HYDROGEN 2509 Potassium tetracyanomercurate (II), 1626
SULPHATE see
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ALPHABETICAL LIST OF DANGEROUS GOODS 185
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Refrigerant Gas R 407c, see 3340 SEED CAKE with not more than 2217
1.5% oil and not more than 11%
Refrigerant Gas R 500, see 2602 moisture
Refrigerant Gas R 502, see 1973 Seed expellers, see 1386
2217
Refrigerant Gas R 503, see 2599
SELENATES 2630
Refrigerant Gas R 1113, see 1082
SELENIC ACID 1905
Refrigerant Gas R 1132a, see 1959
SELENITES 2630
Refrigerant Gas R 1216, see 1858
SELENIUM COMPOUND, LIQUID, 3440
Refrigerant Gas R 1318, see 2422 N.O.S.
Refrigerant Gas Rc 318, see 1976
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ALPHABETICAL LIST OF DANGEROUS GOODS 189
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Tars, liquid, at or above 100°C and 3257 Tetrahydro-1, 4-oxazine, see 2054
below its flashpoint, see TETRAHYDROPHTHALIC 2698
TARS, LIQUID, including road oils 1999 ANHYDRIDES, with more than
and cutbacks bitumens, with a 0.05% maleic anhydride
flashpoint not greater than 60°C 1,2,3,6-TERTRAHYDROPYRIDINE 2410
THIOCARBAMATE PESTICIDE, 2772 TNT, WETTED, with not less than 3366
LIQUID, FLAMMABLE, TOXIC, 10% water by mass, see
flash point less than 23°C TNT, WETTED, with not less than 1356
THIOCARBAMATE PESTICIDE, 3005 30% water by mass, see
LIQUID, TOXIC, FLAMMABLE, Toe puffs, nitrocellulose base, see 1353
flash point 23°C or above
TOLUENE 1294
THIOCARBAMATE PESTICIDE, 3006
LIQUID, TOXIC TOLUENE DI-ISOCYANATE 2078
THIOCARBAMATE PESTICIDE, 2771 TOLUIDINES, LIQUID 1708
SOLID, TOXIC
TOLUIDINES, SOLID 3451
THIOGLYCOL 2966
Toluol, see 1294
THIOGLYCOLIC ACID 1940
Toluylene diisocyanate, see 2078
THIOLACTIC ACID 2936
2,4-TOLUYLENEDIAMINE, SOLID 1709
THIONYL CHLORIDE 1836
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192 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
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ALPHABETICAL LIST OF DANGEROUS GOODS 193
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194 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
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ALPHABETICAL LIST OF DANGEROUS GOODS 195
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ALPHABETICAL LIST OF DANGEROUS GOODS 197
NCEC is indebted to all who have helped with the provision of information,
expertise and validation to assist with the production of this edition and
previous editions of this publication, in particular:
The Chief Fire and Rescue Adviser (part of Home Office)
Dennis Ricketts (formerly of CLG)
British Chemical Distributors Trade Association
British Compressed Gas Association
British Safety Industry Federation
Bureau Veritas
Chemical Industries Association
Chief Fire Officers Association
Department for Transport
Environment Agency
Fire Brigades Union
Fire Service College
Freight Transport Association
Greater Manchester Fire and Rescue Service
HazmatLINK Ltd
Health & Safety Executive
Her Majesty’s Fire Service Inspectorate for Scotland
Independent Consultant (Bob Cumberland)
Lancashire Fire and Rescue Service
Local Government Association
London Fire & Emergency Planning Authority
Liquefied Petroleum Gas Association
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ACKNOWLEDGEMENTS 199
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200 DANGEROUS GOODS EMERGENCY ACTION CODE LIST 2017
www.tso.co.uk
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