Product Name: ACETONE Revision Date: 08 DEC 2010 Page 1 of 10 SAFETY DATA SHEET TAT Petroleum Pte Lid [SECTIONT PRODUCT Product Name: PRODUCT AND COMPANY IDENTIFICATION ACETONE COMPANY IDENTIFICATION ‘Supplier: ‘TAT PETROLEUM PTE LTD 9 JALAN PESAWAT Singapore 619367 24 Hour Environmental / Health Emergency DAY EMERGENCY: +65 6305 94653 Telephone NIGHT EMERGENCY: +85 97198783, Supplier General Contact +85 63094633 Local Contact: _ - Country Company Name EMERGENCY TELEPHONE | EMERGENCY TELEPHONE NUMBER NUMBER During Office Hours After Office Hours China [TAT PETROLEUM (GUANGZHOU) LTD +86-20-3882-7697 Hong Kong | _ TAT PETROLEUM (HK) PTE LTD $82-21217086 +862.65962164 Korea | TATKOREA PETROLEUM CO. LTD $82-2-706-8816/7 +82-11-216-8868 Vietnam | TAT PETROLEUM VIETNAM CO, LTD. '+84839308380 "484903742460 [SECTION2 HAZARDS IDENTIFICATION GHS CLASSIFICATION OF THE SUBSTANCE OR MIXTURE PHYSICAL HAZARDS. Explosives Flammable gases Flammable aerosols Oxidizing gases Gases under pressure Flammable liquids Flammable solids Solfreactive substances Pyrophoric liquids Pyrophoric solids and mixtures Not applicable. Not applicable, Not applicable. Not applicable. Not applicable. Category 2 Not applicable. Not applicable. Not classified. Not classifiedProduct Name: ACETONE Revision Date: 08 DEC 2010 Page 2 ot 10 Sel-heating substances and mixtures ‘Substances and mixtures, which in contact ‘with water, emit flammable gases ‘Oxidizing liquids Oxidizing solids Organic peroxides Corrosive to metals HEALTH HAZARDS Acute toxicity: oral ‘Acute toxicity: skin ‘Acule toxicity: inhalation (gas) ‘Acute toxicity: inhalation (vapour) ‘Acute toxicity: inhalation (dust) ‘Acute toxicity: inhatation (mist) ‘Skin corrosionvinitation Serious eye damage/eye irritation Respiratory sensitization ‘Skin sensitization Germ cell mutagenicity Carcinogenicity “Toxic to reproduction Specific target organ toxicity (single exposure) Classification not possiole. Not applicable, Not applicable. Not applicable. Not applicable. Not classified Not classified Not classified Not applicable, : Not classified Not applicable, Classification not possible. Not classified Category 28 Classification net possible Not classified Not classified Not classified Category 2 Category 3 (respiratory initaion, anesthetic action) ‘Specific target organ toxicty (repeated exposure) : Category 2 (blood) Aspiration hazard: Category 2 ENVIRONMENTAL HAZARDS ‘Aquatic toxicity (acute) ‘Aquatic toxicity (chronic) GHS LABEL ELEMENTS : PICTOGRAMS SIGNAL WORD: DANGER HAZARD STATEMENTS Highly flammable liquid and vapour. Causes eye irtation, Suspected of damaging fertility or the unborn child Not classified. Not classified. May cause respiratory iritation or may cause drowsiness or dizziness,Product Name: ACETONE TAT > P+, 4, Revision Date: 08 DEC 2010 TAT Petroleum Pte Lid Page dot 10 May cause damage to organs blood through prolonged or repeated exposure May be harmful if swallowed and enters airways, PRECAUTIONARY STATEMENTS Prevention ‘Obtain special instructions before use, and DO NOT handle until all safety precautions have been read and understood, Keep away from heat/sparks/open flames/hot surfaces, ~ No smoking. Keep container tightly closed and take precautionary measures against static discharge; ground/bond container and receiving equipment. Use explosion-proof electrical /ventitating/lighting/ equipment or non-sparking tools. Use only outdoors or in a well-ventilated area and DO NOT breath mist/vapours. Wash hands, face, and other necessary parts thoroughly, and gargle the throat after handling. ‘Avoid touching on skin as much as possible during handing Use personal protective equipment; protective helmet/eye protection/face protection/respirator/protective gloves/protective clothingfprotective boots as required Response, {n case of fire: use plenty of water, dry chemicals or Co2 gas distinguisher. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes, Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice! attention if eye irritation persists. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting, Immediately call a POISON CENTER or doctor! physician. IF exposed or concemed, or if you feel unwell: Call a POISON CENTER or doctorphysician, In case of leaking: absorb or cover with dry earth, sand or other non-combustible material. Refer to Emergency Response Guide (ERG number 127) as supplemental if special measures are immediately needed. ‘Storage Keep container tightly closed. Avoid direct sunlight, open flame, ignition. Store in a coolwell ventilated area, Store locked vp. Disposal ‘Transferred to a licensed disposal contractor. DO NOT REUSE THE CONATINER FOR ANY OTHER PURPOSE. DISPOSE OF IN ACCORDANCE WITH APPLICABLE LAWS AND REGULATIONS, OTHER HAZARDS WHICH DO NOT RESULT IN GHS CLASSIFICATION ‘This liquid is easily evaporated and form explosive mixture which is heavier than ar.” Acetone has very low ignition point; even 4% water solution has it at $4 oC. 1) Signifcant symptoms ‘This quid and vapour irate eyes and skin. High exposure or prolonged inhalation has anesthetic effect. Inflammation of eye and skins, drowsiness and vomiting are observed. ”Product Name; ACETONE T. r n Pte Lt pa 08 DEC 2010 AT Petroleurr te Lid age 40 ‘Summary of envisioned emergencies it may happen to explosion hazard if this product enter the sewage system.” [SECTION ‘COMPOSITION / INFORMATION ON INGREDIENTS [Shemicar Name © TeRSr [RCETONE [erat [Sections FIRST AID MEASURES ] INHALATION Remove to fresh air immediately. f breathing and voting, let the face sideways. If breathing is dificult or not breathing, let out the clothing and give artificial respiration (or give oxygen). Keep the affected person warm and at rest, Get medical attention immediately. SKIN CONTACT Immediately remove contaminated clothing and shoes. Flush skin with large amounts of water, clean off with soap and water. Get medical attention if symptoms develop, EYE CONTACT Immediately flish eyes with plenty of water for several minutes and get medical attention Part eyelids with fingers to assure complete flushing. Check for and remove contact lenses if easily possible. INGESTION Do NOT induce vomiting. Hazard may increase due to volatile liquid. Get medical attention immediately. Rinse mouth with water i possible, Never give anything by mouth to an unconscious person. ‘When vomiting spontaneously, incline the body to avoid inhaling to respiratory tract. Keep the affected person warm and at rest. MOST IMPORTANT AYMPTOMS, ACUTE AND DELAYED: This liquid and vapour initate eyes and skin, High density vapour has anesthetic effect intvaled or inhaled persistently. Inflammation of eye and skins, drowsiness and vomiting are observed. [SECTIONS FIRE FIGHTING MEASURES 1 EXTINGUISHING MEDIA Appropriate Extinguishing Media: water fog, alcohot resistant foam, dry chemical, CO2, andy sand. UNSUITABLE EXTINGUISHING MEDIA : waterjet FLAMMABLE PROPERTIES : This product has explosion hazard with ignition. Evacuate immediately.Product Name: ACETONE TAT Petroleum Pte Revision Date: 08 DEC 2010 Page bot 10, lid Fire Fighting Equipment: Respiratory and eye protection required for fre-ighting personnel Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used forall Indoor fires and any significant outdoor fires. Carton Oxides Hazardous Combustion Product: [SECTIONS ‘ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS. Keep unnecessary and unprotected personnel away. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8, Keep upwind, evacuate downwind. ENVIRONMENTAL PRECAUTIONS ‘Do not let this chemical enter the environment. Do not flush into sewer, river or any body of water. CONTAINMENT/CLEAN-UP METHODS ‘Absorb or cover with dry earth, sand or other non-combustible material and transfer to sealable containers. Large spills: Dike far ahead of liquid spill for later disposal (SECTIONT HANDLING AND STORAGE HANDLING Technical Measu Use with adequate ventitation. Keep away from heat, sparks, and flame. Use explosion-proof electrical equipment. Take precautions against build-up of electrostatic charges. Avoid contact with eyes, skin, and clothing. Wear appropriate personal protective equipment. Provide hand and eye wash station near work area. Wash thoroughly after handing. Precautions, Use under local exhaust ventilation when handling at high temperatures or if user operation generate dust, Follow ‘good industrial hygiene practices for clean-up. ‘Safe Handling Advice Do not handle until all safety precautions have been read and understood. Prevent leak and spill. Avoid vapour formation. Do not fall, drop, shock or drag the container, Avoid contact with eye, skin or clothing. Avoid inhalation and ingestion. Use only in well-ventilated area or outdoors, STORAGE Storage Consitons Protect from direct sunlight. Keep away from heat, flame, and all sources of ignition, Store in a dark and wellventiated area, Keep container tighty closed. Dissipate static electricity during transfer by grounding and bonding containers and equipment. -Entryrothe-storage-blace-snoucr be-resincted4o-authorz60-person Neha anesProduct Name: ACETONE troleum Pte Lt Revision Date: 08 DEC 2010 Pagesot 10 [SECTIONS EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS ‘ACGIH-TLV__; 500 pom (TWA), 750 ppm (STEL) OSHAZ-1 PEL": 1000 pom (2400 mg/m") ENGINEERING CONTROLS Provide general ventilation. Use closed system or local exhaust ventilation, Provide safety shower and eye wash station near work area, PERSONAL PROTECTIVE EQUIPMENT Respiratory protection : Chemical cartridge respirator with an organic ‘vapour catidge. Hand protection Protective gloves. Eye protection Safety glasses or goggles, face shies. Protective clothing Safety helmet, protective clothing, safety boots, sand apron. [SECTIONS PHYSICAL AND CHEMICAL PROPERTIES. PHYSICAL STATE liquid APPEARANCE, : eolorless clear liquid ODOUR characteristic and imitating odour. ODOUR THRESHOLD 200-450 ppm ' PH Not available BOILING POINT. 56.5 °C 2) MELTING POINT = 95 °C 3) FLASH POINT - 20 °C 2) IGHS Flammable liquids Category 2)? AUTOIGNITION TEMPERATURE: 465°C ) FLAMMABLE LIMITS. 2.213 volt (air) EXPLODABILITY Notavailable. SPECIFIC GRAVITY 08° VAPOUR PRESSURE 24 kPa (at 20 °C) 3) VAPOUR DENSITY 2.0 (air = 1) SOLUBILITY ‘miscible in water. ® Log Pow -024? Viscosity 0.426 mm2/sec*Product Name: ACETONE oleum Pte Ltd Revision Date: 08 DEC 2010 TAT Petroleum Pte Ltd Page 7 of 10 [SECTION 10 ‘STABILITY AND REACTIVITY ] STABILITY: Stable under normal conditions CONDITIONS TO AVOID: High temperature, air, direct sunlight, MATERIALS TO AVOID: Strong oxidisers HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 HAZARDOUS REACTIONS: The substance can form explosive peroxides on contact with strong oxidants such as acetic acid, nitric acid, hydrogen peroxide. Reacts with chloroform and bromoform under basic conditions, causing fire and explosion hazard. Attacks plastic.” (SECTION7T "FOXICOLOGIGAL INFORMATION ] ‘ACUTE TOXICITY Oral rt LDS0 >5,000 mg/kg [GHS Not classified] ” skin rabbit cose >6,000 mg/kg [GHS Not classified] ” Inhalation (Vapour) rat C50 32,000 ppm(75.8 mg/L) [GHS Not classified] ” ‘SKIN CORROSIONARRITATION Rabbit Not corrosive to skin. (twas classified as out of Category from the statement of having no stimulativeness on rabbit skin)” ‘SERIOUS EYE DAMAGEIEVE IRRITATION : RabbtSevere [GHS Category 26] ” RESPIRATORY SENSITIZATION/ SKIN SENSITIZATION : Guinea pig Maximization test Negative ” IGHS Not classified] ” (GERM CELL MUTAGENICITY in vivo test chromosome aberration tests Negative ® [GHS Not classiieg]” CARCINOGENICITY :ACGIH Ad [GHS Not classified] ” TOXIC TO REPRODUCTION itis reported of slight developmental toxicity (decrease of embryo weight) in rat high concentration exposure (11000 ppm (20 mg/L}) and of the decrease of embryo weight and the ingrease of late embryo absorption rate in mouse high concentration exposure (6600 ppm (15,6 mall)” [SHS Category 21 2Product Name: ACETONE AT Petroleum Pte Lt Revwsion Date’ 08 DEC 2010 TAT Petroleum Pie Lid Page Sct 10, ‘SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Irritation in the human throat Is caused by 1200ppm exposure, that irritation is caused in the nasal cavity, throat and trachea by 1190 and 2400mg/m3/6h exposure to humans, and that initation was caused in the throat by 1000ppmiah. exposure, And the descriptions that a male who drank 200ml fell coma (recovering his consciousness in 12 hours), and that a worker exposed to 12000ppm experienced headache, dizziness, leg weakness and fainting. the descriptions. that a male who drank 200 mi fell coma, recovering his consciousness in 12 hours, and that a worker exposed to 12000 ppm experienced headache, dizziness, leg weakness and dead fart.” ‘SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) By the examination using volunteers, the significant increase in white corpuscles and an eosinophil and the significant reduction of a phagocytosis of a neutrophil were observed in the exposure group with 500 ppm, 6 hours/day for 6 days. In the examination using the rat and the mouse, although it was a dose greatly beyond guidance limits, the similar haematological changes ike in humans was admitted. Since in other examination using a rat and a mouse, each is over the guidance limits, and there is also no example of a report in humans, they were not adopted as a classification basis.” [ASPIRATION HAZARD “The calculated dynamic viscosity is 0.426mm"/sec and there was not the animal data of chemical pneumonia, however, it was the ketone of under C13, therefore it was classified into Category 2. [(GHS Category 2) (SECTION? ECOLOGICAL INFORMATION 1 AQUATIC TOXICITY (ACUTE) fathead minnow icso 100 mgi/96 hr [GHS Not classified)” (ther information PERSISTENCE/DEGRADASILITY: BOD 84% 20days AQUATIC TOXICITY (CHRONIC): [GHS Not classified]? BIOACCUMULATION POTENTIAL: Low (According to Log Pow = -0.24)Product Name: ACETONE Rewsion Date: 08 DEC 2010 7 Page Sof 10 TAT Petro (SECTION 7S. DISPOSAL CONSIDERATIONS: 1 WASTE FROM RESIDUES ‘Whatever cannot be saved for recovery may be burned in an approved incinerator or disposed in approved waste facility. Ensure compliance with local, state, federal and national regulations. CONTAMINATED PACKAGING Emply the container completely before disposal [SECTION 14 TRANSPORT INFORMATION UN class +3 (Flammable liquids). UN number UNt080 Shipping name Acetone Packing grade u [SECTION REGULATORY INFORMATION a SINGAPORE, ENVIRONMENTAL PROTECTION AND MANAGEMENT ACT AND ENVIRONMENTAL PROTECTION AND MANAGEMENT REGULATIONS : This product is subject to the requirements in the actiregulation. WORKPLACE SAFETY AND HEALTH ACT & WORKPLACE SAFETY AND HEALTH (GENERAL PROVISIONS) REGULATIONS “This productis subject to the SDS, labeling, PEL and other requirements in the actiregulation, MARITIME AND PORT AUTHORITY OF SINGAPORE (DANGEROUS GOODS, PETROLEUM AND EXPLOSIVES) REGULATIONS, ‘This product is subject to the requirements of this regulation, (CHEMICAL WEAPONS PROHIBITION ACT ‘This product is subject to the requirements of this act. FIRE SAFETY (PETROLEUM AND FLAMMABLE MATERIALS) REGULATION ‘This product is subject to the usage, transportation and storage requirements of this regulation UNITED STATES: TSCA STATUS ‘This substance is listed on the TSCA Inventory. CERCLA Reportable Quantity : $000 tbs. SARA Title It SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: None. SECTION 311/312 HAZARDOUS. CATEGORIES Fire hazard, immediate health hazard, Delayed health hazard. SECTION 313 TOXIC CHEMICALS: None. EEE EEESEESEEEProduct Name: ACETONE Revison Dat: 08 C2010 TAT Petroleum Pte Lt CALIFORNIA PROPOSITION 65 This product contains no chemicals known to the state of California to cause cancer, EUROPEAN UNION EU STATUS ‘This product is listed in EINECS (EC No. 200-862-2). Labeling according to EC Directive : Hazard Symbols : F- Highly Flammable Xt Irritant Risk Phrases R11 Highly flammable. R36- Iritating to eyes. RG6- Repeated exposure may cause skin dryness or cracking, R67-Vapours may cause drowsiness and dizziness. Safety Phrases '$8- Keep container in a well-ventilated place. 'S16- Keep away from sources of ignition - No smoking. '$26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 'S46- If swallowed, seek medical advice immediately and show this container or label. [SECTION 76 ‘OTHER INFORMATION REFERENCES 1) Dangerous Goods Handbook(1931) 2) GHS Classifications of Regulated Chemicals (Nationa! Institute of Technology and Evaluation, Japan, 2007) 3) International Chemical Safety Cards (ICSC) 2007 4) I-house data ‘To the best of our knowledge, the information contained herein is accurate. However, we cannot assume any labilty whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitabilty of any material is the sole responsibilty of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.