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Baran Group Me Ming Yan ‘Sulfur in Organic Synthesis ‘otfosr2016 {Sutturis not just fat oxyger Electronic config: [Ne] 35°3p* a fone nenee ie § peatent sutur Compounds ri Electrons per shel: 28.6, RH a Melting pont 239.4°F (115.2°C) (rm (atcohon % Discovered: 2000 BC. i s. ee yt aty Atomic mass: 32.085 oR Natural form: Sp : (suinae) (otnen EPMA Over 400 alovopes (Dieu on (ysroperoxie) (Satins ester oR’ °. (sulfenate ester) HN, Se Ro_oR wer x tsumiine (ava et) an ° ° ececea why whe ae cateuson tor won . . counted bon rkse Re OR! ne {thiol ester) (ester Re tilon ety thet) "rte Sure, ° wee ° < PE | ge crt Ak TERE an ESA | Pate Pon] at TS esozon || Bg, wre | ok 36 ROsoz0R Redox neutrot__ NR erN\-S\No1 inthe laboratory didnot find the odours intolerable” Ming Yan Thiy! Radicals: Til radests ready 24d oleins the Thokene Couping Reaction onder J Org. Chom, 2008, 74,4427 “Thi radials can bo iat rom thi wth AIBN, peroxides, Mn, Fi, sc oe ‘co rr Ccoroy, J Am. Cher Soe 1967, 9, 2758: Mak Hel Crim, Act 1968, 61, 648, Reverataty makes aly sues good real acceptors: ‘oreors: wu aD ES San yore [dm, Chom, Soe 2008, 127, 5342 Sulfur in Organic Synthesis Baran Group Meeting ‘otfosr2016 Enantoselectve radial eytzaon va thy euany! adcole Doe. aren ° Hana De" Co,sn G00 Molonpaiah” ao 81 05% 0) “ee Maruca, Nat Cam, 2094, 6.702 Reversi pertains to ineractions wih le oxygen pHs (3 0) . "Pens woaom) Me | wAAK 2 Ne Bact Org. Chem 2008, 70, 96:8 Parxerazalinormadate canbe rearanaed Protos OH sites oH a Tf soit ion | ‘sen RAR eo uso”? Yosnda, 1 00. Chom Baran Group Meeting Ming Yan ‘Sulfur in Organic Synthesis ‘otfosr2016 a a Od este o> Risen Re my radeste eat ray with sontetes ge ee RAR ws Ws! ameesing the mod adc wee SC To Leelee, os) acn, Syl 1990, 55 J. Or. Chom. 1984, 59,752 Generation of ay radiate That medited hydroaminatin: FO A cost 2 GE Om ass ns & Se He sions Frsione, HSN OMe), (01%) Ming Yan Thlocerbenyie ‘rae isualy ol generated sends oe, a Noni) pf NOY EL por. “Sue Protoemistyof iocrbonye ae el . Sulfur in Organic Synthesis ey Went lsat, Baronet adel hry, Eehannor ae Baran Group Meeting ‘otros/2016 ‘3. Photochemisty of locarbonys| Dihietopezine Dithianes and disulfides Seneraton of ont hse Pada, Ory, Lett 2002, 4, 1695 Not covered: Carbon! Umpotung hough atiene ‘Sulfenie acids and esters Marin Reazangement Perici to Cephatesporn Balovin,Tevahedron 2000, 56, 6053, Paths ale Pika Ming Yan gee whAne™ &e8 Jot, 8 com! oho, a 808,085 mano Soon cats oye sos QO ¢ ee Cane, fl wo e orn Si or acl racirso As Qs) AE. ens? ‘alo, Hae Chim Act 2003, 06,3179, ony Sulfur in Organic Synthesis 2, om), Ncenord adel gonarated na smiareshion: Newcomb, Terahogron Lt 1985, 246877 Review: Syn Org Chom. Jpn 2004, 62.574 COnidave Mannich Resco 'eu®sgpn wore pores core arm) Baran Group Meeting ‘0109/2016 wes Z al ” onsd 804% g pra) sass a Laws mg HEED Oa ht oy Pn (25% overall) e x ~n ae ata -cerlane mae uch J. Am_ Chem S06 1874, 96,3382 Baran Group Meeting Ming Yan ‘Sulfur in Organic Synthesis 01/09/2016 Sea eR ener oa , ; lod 10. ‘eyo! Lt - 298 se Btls: LB nyc octane (4 = ae eo © arm ior mi wu em ws shee The peculiar case of pyridine omc Par hse 1 <_< (1 "ou : ome a : A " mo ° Oxidative Initiation: Feldman ‘ras ot aooemeptaatin =o fm ese aoe egen She ivan: Sule ae ‘char adohyce Me O. IRC 234] coke awa. J Org chor 2002 67,8828 Me (40%, 90% ey Salo, Angew. Chom. Ed 2002, 41,9671 Baran Group Meeting Ming Yan Sulfur in Organic Synthesis ‘otros/2016 A serenaptous indole G# fctonatzaton Interruptog Pummerer Reactions H,poome wy de ae oe ogee Mo Prive @ Raney Ni te 4 Pion, Tot Lot 999,40, 4899 auido, J Aor Chom, Sox. 2013, 195, 7912 Mes comme Intropton by carton nusteophies Nae rto-tyitonirose coupling se interception of Swern intrest by sons OS BE Qn BE eA :. (, Ee Rp Srus meMcHcn ger atime mvercopton by hateronutacphies er an, COR, ayers se , ay Pu ao) enyso Berm, Sammy Brinn | me oR SESS of “op, “ep ete Ac soca uate a = — a OF, te Ming Yan Sulfur in Organic Synthesis Baran Group Meeting ‘otrosr2016 Chl sutoxises in tte synhesc we 8 Y RO (ise Meo" ° Cavicularin: ee isi is : wAAA ve ite 2 3 | Didehydes ta ten Ose at Lat 9980, 2 ty mi, mse Baie, Th (64% 06) Bash Ong. Cher 2060, 6 25s8, ‘Sulfur dion Percyte ‘and sulfinie acid derivatives “gE Gren) stoned ese, rin 94 en ee ee ee coy ta 00 2549 gb a ek 2S 8 i Ligaen reaangemert Ming Yan Sulfur in Organic Synthesis ra80 ho ° EO OE OT ge {i Po HOW Prone “eo Y yan Gianainas So; ser Taarimet\y 9 gH SOsMe Ye Toe ii is aon eo at oth ue Oe © yses pb Nong? os tong’ “IN sey Loe Nie Baran Group Meeting ‘otros/2016

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