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Why Some Students Don't Learn Chemistry

Chemical Misconceptions
Mary 6. Nakhleh
Purdue University, West Lafayette, IN 47907

Many students at all levels struggle to learn chemistry, integrated cognitive structures of chemical knowledge.
but are often unsuccessful. Diswvering the reasons has The information students use to wnstruct their concepts
been the target of many studies. One possible answer that comes from two sources: public knowledge, as presented in
is beginning to emerge is that many students are not con- texts and lectures; and informal prior knowledge from ev-
structing appropriate understandings of fundamental ewday experiences, parents, peers, commercial products,
chemical concepts from the very beginning of their studies and the common meanings of scientific terms (41.
(I).Therefore, they cannot fully understand the more ad-
vanced concepts that build upon the fundamentals. Misconceptions
In this article, I first present a cognitive model of learn-
ing chemistry. Then I discuss students' chemical miscon- Since students do build their own wnce~ts.their con-
ceptions (their inappropriate understandings) in terms of structions of a chemical concept sometimes h&r from the
a fundamental wncept-the particulate, kinetic nature of one that the instructor holds and has trled to oresent. Gar-
matter. Finally, the implications of these findings for in- nett et al. (5)state that these different wncepts have been
struction are considered. variously described by different researchers as precoucep-
tions (6), misconceptions (6), alternative frameworks (71,
A Cognitive Model of Learning children's science (a), and students' descriptive and ex-
planatory systems (9).
Research in students'conceptual knowledge of chemistry
is based on a model of learning in which students construct In this paper the term "misconception" means any con-
their own concepts (2.3). According to the cognitive model cept that differs from the commonly accepted scientific un-
of learning, during instruction learners generate their own derstanding of the term. Once integrated into a student's
meaning based on their background, attitudes, abilities, cognitive structure, these misconceptions interfere with
and experience. subsequent learning. The student is then left to connect
new information into a cognitive structure that already
The Learning Cycle holds inappropriate
.. . knowledge. Thus, the new information
cannot be connected appropriately totheir cognitive struc-
Learners selectively attend to the flow of information ture, and weak understandinm - or misunderstandings . of
presented, and their prewnceptions determine the infor- the concept will occur.
mation to which they pay attention. Then the brain ac-
tively interprets this selected information and draws infer- Current Work on Chemical Misconceptions
ences based on i t s stored information. The newly Most of the work that has been done on misconceptions
generated meanings are then actively linked to the learn- in chemistry was done relatively recently-in the 1980's.
er's prior knowledge base. Misconceptions in physics and biology have been more in-
Thus, learning is viewed as a cyclical process. First, the tensively studied. Thus, misconceptions in chemistry rep-
new information is compared to prior knowledge. Then it resents a fertile field for investigation.
is fed back into that same knowledge base. This article synthesizes recent findings about the chem-
Cognitive Structures ical misconceptions of students from the elementary and
middle school level through the undergraduate level. Most
Thus, acwrding to the wgnitive model, students build of the misconceptions that have been identified reveal a
sensible and coherent understandings of the events and weak understanding of the currently accepted model of
phenomena in their world from their own point of view (3). matter. In this model, matter is composed of small, mobile
In this paper, these coherent understandings are referred particles such as atoms, molecules, and ions. Thus, the
to as cognitive structures (4). Since these coherent under- particulate and kinetic aspects of the current model of
standings are in place, words such as "atom" and "nentral- matter are used as a framework for presenting the findings
ization" are actually labels that stand for elaborated cogni- of the studies.
tive structures stored in the brain (3). Although this description of the cognitive model of learn-
ingis brief, it can be seen that this model is a powerful tool
Concepts and Propositions that can aid in developing and understanding cognitive
These elaborated cognitive structures are themselves structures. This model is a part of Bodner's theory of con-
composed of interrelated wncepts. Each concept itself is structivism that is dealt with in more detail in ref 10 than
formed by a linked set of simple, declarative statements is possible in this article.
called propositions that represent the body of knowledge
the student possesses about that concept (4).An example Student Conceptions of the Particulate Nature of Matter
of a proposition is the statement "An atom contains a nu- Students of all ages seem to have trouble understanding
cleus." and using the scientifically accepted model that matter is
Concepts, therefore, are considered to be the set of prop- made of discrete particles that are in constant motion and
ositions that a person uses to infer meaning for a particu- have empty space between them (11, 12). Indeed, an ac-
lar topic, such as the nucleus of an atom. These wncepts ceptable concept of the particulate nature of matter lays
are then linked with the students' other concepts to form the foundation for understanding many chemical concepts:

Volume 69 Number3 March 1992 191


chemical reactions; the effects of pressure, volume, and
temperature on gases; changes &state; dissolving; and
equilibrium (13).Unfortunately, many students from all
age groups appear to view matter as being made of a con-
tinuous medium that is static and space-filling.

Misconceptions of Matter as a Continuous Medium


I n one of the earliest studies on student understanding
of the particulate nature of matter (11,121,students from
elementary school to the university level were tested con-
cerning their acceptance of the particle model as it applies
to gases. The results revealed that over half ofthe students
from junior high to senior high to university level held con-
cepts that were consonant with a perception of matter as a
continuous medium, rather than as an aggregation of part- Figure 1. Arepresentation of students'concept of the microscopic na-
icles. ture of a solution of HCI.
Differential Acceptance
Misconceptions of Atoms and Molecules
The authors also present evidence that the components
of the particulate model of matter were differentially ac- Grade 12
cepted:~hemost readily accepted parts of the model were Griffiths and Preston (171interviewed grade 12 Cana-
those closest to observable phenomena. dian students to investigate their understanding of the
For example, the representation of the liquefaction of concepts of a molecule and an atom. The students were di-
gases as a coalescing of particles was accepted by a t least vided into three groups-"academic science", "academic
70% of the students at the junior high level and beyond. nonscience", and "nonacademic nonscience". Griffiths and
Here the particle explanation does not conflict with observ- Preston identified 52 misconceptions. Among these mis-
able bulk phenomena. However, only 40% of the students conceptions, the five listed below were held by half the stu-
in the same group accepted the concept that particles in dents in the sample.
the gaseous phase have empty space between them. This That molecules are much larger than they probably are.
concept is not obvious from observable bulk phenomena. That molecules of the same substance may vary in size.
That molecules of the same substance can change shapes in
Grade 9 differentphases.
Krajcik (14)interviewed grade 9 students and asked That molecules have different weights in different phases.
them to draw how the air in a flask would appear if they That atoms are alive.
could see it throueh a verv wwerful maenifvim elass. He Figure 2 is a representation of the common misconception
found that 14 of &e 17 s s e n t s held aconknio& model that molecules expand when they are heated.
of matter. These students did not draw air as comvosed of
tiny particles. Instead, they simply drew wavy lines to rep-
resent the air in the flask.
Grade 10
Ben-Zvi, Eylon, and Silberstein (15)used a question-
naire to investigate the beliefs about matter held by 300
grade 10 students who had been studying chemistry for
half of the academic year. The questionnaire asked stu-
dents to comoare the orooerties of two atoms: one taken
from a piece if copper kr;, and one that had been isolated
from the eas that formed when the comer wire vaoorized.
Figure 2. A representation of students'conceptthat molecules expand
~ e a r l y h a l of
f the students believed 'that the buik prop- when heated.
erties of the substance-such as electrical conductance,
color, and malleability-were also properties of a single
atom. Apparently, although the students could use the In addition, the "academic science" group exhibited an-
terms "atom" and "molecule", they could not relate these other set of misconceptions to a far greater degree than the
terms to the particulate model of matter. This indicates other groups. Specifically, 30-70% of the academic science
that the students still held their older, continuous model of group held the following five misconceptions.
matter. They had merely added the particulate model to That water molecules were composed of solid spheres.
their continuous one. That pressure affects the shape of a molecule.
That molecules expand when heated.
Grade 11 That the size of an atom depends on the number of protons it
has.
Nakhleh (16)interviewed grade 11 chemistry students That collisions between atoms alter atomic sizes.
who were in the last quarter of the academic year. These
students had recently completed a unit on acids and bases. GriEths and Preston argue that these misconceptions
I n this study, it appeared that 20% of the students still could have risen as a result of instruction.
held a simplistic, undifferentiated view of matter.
University Level
When asked how a solution of a n acid or a base would
appear under a very powerful magnifying glass, these stu- At the universitv level. Cros et al. (18)interviewed first-
dents drew waves, bubbles, or shiny patches. Figure 1 is a year undergraduates regarding their conceptions ol'atoms.
revresentation of a solution as viewed from this continu- Thev found that students were aenerallv auite successful
ous perspective. in naming the parts of a n atom or a nucieui. However, the

192 Journal of Chemical Education


students were much less successful when they attempted and Harris (23) found that many Spanish students, rang-
to describe the interactions of these particles. The students ing in age from 12 to 18 years, hild an Aristotelian view of
tended to invoke a simplistic Bohr model of the atom in gases as weightless substances. Therefore, they wuld not
their explanations. correctlv oredict the weicht of a sealed container in which
Cros et al. interpret these fmdings to mean that the stu- a liquidwas evaporated."students believed that the gases
dents' knowledge tended to be formal and qualitative, had lost mass and weight and that this was the reason
"with a worrying lack of wnnection with everyday life". A they rose. The authors concluded that one of two explana-
followup study (19) found that students'ability to explain tions was oossible: Either these students could not com-
the interactions of subatomic particles had improved only prehend .j&etic theory, or they understood the theory but
slightly despite a year of university study could not apply it to explain the behavior of gases.
Stavy (24) corroborated these findings and determined
Misconceptions of Molecules and Intermolecular Forces that students acquire the full particulate, kinetic model of
a gas slowly-usually one to two years after the subject
Grade 12
has been taught during formal instruction. Students in
Students apparently have similar difficulties with com- grades 4-7 phmari~yexplained gases in terms of exam-
prehending the bonding and structure of covalent mole- ples. Students in grades 7 and 8 often referred to gases as
cules (20). Peterson and Treagust used a paper and pencil a form of matter, even though they had been taught the
test to study the understanding attained by grade 12 particulate theory of matter in grade 7. However, in grade
chemistry students concerning simple covalent molecules, 9, students began to explain gases in terms of the particu-
such as HF. They identified eight misconceptions that late theory of matter after a two-year time lag.
dealt with bond ~olaritv.molecular shaoe. molecular DO- Stavy also notes that the students did not apply the par-
larity, intermolechar forces, and the octet rule. ticulate model consistently. Students apparently found it
Within these categories, 2&34% of the students held a t dimcult to explain solids and liquids in terms of the partic-
least one misconception. The data indicate that 74% of the ulate model, but they could do so for gases. She suggests
students could not correctly apply valence-shell electron- that the particulate model for gases is less counter-intu-
pair repulsion theory to identify structures of molecules. itive, and thus more understandable, than the particulate
For examole. 25% considered only the re~ulsionof bonding model for solids or liquids.
electron &I&, and another 22%eonsidered only the effect A series of studies have investigated concept learning as
of nonbonding electron pairs. Another 27% decided that it oertains to eases (25-27). These studies involved univer-
bond polarity determined the shape of a molecule. How- siiy freshmanufrom three universities from the East Coast,
ever, 78% ofthe students could correctly answer a test item the Midwest. and the West Coast. In eachcase. the number
designed to test their understanding of the principles of of students kho could solve traditional gas law or stoichi-
this theory. ometry questions was much higher than the number who
Also, the students tended to identify intermolecular could answer the conceptual questions. The differences in
forces with the covalent bond within the molecule. They performances were generalls large.
did not seem to be aware of the general difference in mag- - For example, on one stoichioietry problem 66% of 323
nitude that exists between the strength of a covalent bond students could answer a traditional question, but only 11%
and the strength of an intermolecular force. A number of could answer the conceptual question. Students were not
students also believed that the number of electrons in the able to move from their algebraic knowledge - of gas
. laws to
valence shell of a nonmetal atom equals the number of w- a particulate model of gas&.
valent bonds formed by that atom.
Students' Conceptions of the Kinetic Aspects
Misconceptions of Phase Changes of the Particulate Model of Matter
Consistent with their hazy ideas about atoms and mole- Research is also beginning to show that many students
cules. students also aooear to have difficult^ exdainina also hold a static, rather than kinetic, conception of the
phase changes. ~ s b o k e a n Cosgrove
d (21)fo&d ihat stul particulate model of matter. The evidence for this asser-
dents, rangingin age from 8 to 17 years, described the bub- tion is that students have been shown to encounter diffi-
bles formed by boiling water as being made of air, oxygen, culty in the following three areas.
or hydrogen. Many also had great difficulty in explaining Students a h n are unable to state that balanced chemical
how a saucer held over the boiling water became wet and equations represent the rearrangement of atoms (28,291.
why it dried offwhen it was removed from the steam. In- Students have difficulty in recognizing and describing in-
terkstingly, Osborne and Cosgrove report that the students . " or chemical chance (2932).
stances of obvsical
could ~enerallyuse the wrms "condensation" and "evapo- Students envision chemical equilibria and steady state as
ration? .owever, under further questioning, the students essentially static conditions (33, 34).
could not explain what these terms meant.
Bodner (22) administered a conceptual knowledge test to Misconceptions of Chemical Equations
entering chemistry graduate students over a three-year Many students perceive the balancing of equations as a
period. His data indicate that even some graduate stu- strictlv algorithmicexercise. Yarroch ,281 interviewed high
dents, who majored in chemistry, may still have difficulty schooich&stry students on how they balanced the xi&-
understanding some concepts. For example, one of the ple equations used to describe reactions such as
questions told students to assume that a beaker of water
has been boiling for one hour. The students were then N, + H, + NH,
asked to state tce composition of the bubbles rising to the These students were ranked by their teachers as A and B
surface. Out of 120 students. 25% reported that the bub- students, and they were interviewed during the last quar-
bles were made of air or oxygen or hydrogen. ter of the school sear.
Misconceptions of Gases All of the students succe~sfullybalanced the equations.
However, half of them wuld not draw a correct molecular
Work on students'conceptions of gases also supports the diagram to explain the equations in the microscopic sys-
assertion that many students, across a wide range of ages, tem. Although the unsuccessful students were able to draw
hold an inappropriate model of matter. Furio Mas, Perez, diagrams with the correct number of particles, they

Volume 69 Number 3 March 1992 193


seemed unable to use the information contained in the co- 5 . Chemieal interaction occurs.This is a category where ac-
efficients and subscripts to construct the individual mole- ceptable answers would be found. Typically the student
cules. These students represented 3Hz as would say that oxygen in the air reacted with the copper
pipe to form a wpper oxide coating on the pipe. For the
000000 other question, they think that the steel wool burned be-
cause oxygen wmbined with the inn. At best, only 15%of
rather than as the students in the study could answer the last problem
00 00 00 correctly.
Figure 3 illustrates students'lack of understanding of the All of the above categories except the last one represent
DurDose of coefficients and suhscri~tsin formulas and bal- responses that show that the student lacks a n understand-
;need equations. ingof the following underlying conceptions.
That matter is composed of particles.
That these particles are in constant motion.
That these particles can react with each other by breaking or
forming bonds.
A static representation of chemical change was also
found bv Ben-Zvi. Evlon. and Silberstein (29). Thev asked
grade i0 students, &ho bad been studying chemikry for
half a vear. to draw what thev thoueht the followine elec-
Figure 3. A representation of students'concept ofthe microscopic na.
ture of the reaction between nitrogen and oxygen.

Ben-Zvi, Eylon, and Silberstein (29) agree that balancing


and interpreting equations is a formidable task. As an ex-
ample, they performed a task analysis on the combustion
of hydrogen, as represented by the equation They found that 58% of the students drew static represen-
2HzW + Oz@) + 2HzO(g) tations. Only 38% drew any kind of dynamic representa-
tion. In fact, one student specifically noted on the drawing
Thev - A. .
" areue that an a m r o ~ r i a t einternretation of this
equation requires that a learner understand many things:
that the "2" in front of the "K"didn't mean anything molec-
ularly because it was used for balancing purposes only!
the structure and physical state of the reactants and prod-
ucts, the dynamic nature of the particle interactions, the Additive Changes
auantitative relationshins amone the ~articles.and the
A Ben-Zvi, Eylon, and Silberstein (29, 35) also note that
iarge numbers of particl& involved. some students seem to have .an additive model of reaction:
Compounds are viewed as being formed by simply sticking
Misconceptions of Chemical Change fragments together, rather than as being created by the
Static us. Dynamic Models breaking and reforming of bonds.
For example, when asked if NO could be formed by a re-
Many students also invoke static models to explain action between 0 2 and Nz, a student explained that they
-
chemical chanees. Andersson (30) studied students. rang-
mg in age from 12 to 15 years, from Sweden where chem-
.. could not because neither O2 nor Nz could be decomposed.
This type of answer is consistent with a static model of
i s t instruction
~ starts in made 7 or 8. At least 90ci ofthe matter. Figure 3 also illustrates students' misconception
stuients had studied oxid&ion. that chemical reactions are simply additive.
He asked the students to explain the appearance and
disappearance of substances in a chemical change. As an Chemical us. Physical Changes
example, he asked students Stavridou and Solomonidou (32) studied Greek students,
Why doshiny copper waterpipes tarn dull and tarnished? ranging in age from 8 to 17 years, as they attempted to
-
classifv events as nhvsical chanees or cbemical chanees.
Their data indicati that over half of their students incur-
What happens when a nail ~ U S ~ S ? rectlv classified a chemical chanec as "no chanw."The au-
thor; note that these students seem to use :very static
He found that the students'answers tended to fall into the model for these events.
following five categories. They also report that these students seemed to focus on
this raw, studcntr a n simply unin-
1 . It's just that way. I n the "external manifestationd nfthr nhenomena. which led
kre9tt.d in the change. lt'sjust something that they nouce them to incorrect conclusions in thii case. An interesting
happens. finding, which has not been reported elsewhere, is that
2. Displacement h m one physieal loeation to another some of the students who did have a concept of change
occurs. In this category students envisioned that a coat- nonetheless seemed to think that only physical changes
ing simply materializes, either from the air, as with rust were reversible. Thus, to them, chemical changes were al-
on a nail, or from the water inside the pipes. ways seen as irreversible.
3. The material is modified. In this view, students argue
that what appears to be a new substanee is actually the Misconceptions Concerning Equilibrium
original substance-just in a modified form. An example
of this would be when a student thinks that the wpper Sidedness and Dynamism
pipe simply turns dark due to heat. They think that it Gussarsky and Gorodetsky (34) used word associations
continues to be the same substance, although it does look
different. to probe the understandings that grade 12 Israeli students
4. 'Pansmutation ocrure Students in this category would held of chemical equilibrium. They found that students
explarn that steel wuol gam* weight as it burns becawe tended not to perceive the equilibrium mixture as an en-
the steel wool is changed into carbon, which is heavier. In tity; rather, they manipulated each side of the cbemical
this view, atoms simply change into a new kind of atom. equation independently, as if it were a balance. These au-

194 Journal of Chemical Education


thors soeculate that the method used to teach LeChate- The other group could manipulate the symbols to solve
lier's principle, if it is applied by mte, may even strengthen LeChatelier problems but incorrectly thought that equilib-
this inabilitv to treat the eauilibrium mixture as a whole. rium meant that there was no dynamic interchange be-
The studekts also failed understand the dynamic na- tween the components of the system. They maintained
ture of equilibrium. They assumed that reaching a bal- that dvnamic interchange occurred onlv when a svstem
anced condition, as described in their text, meant that no was stressed and that t6e interchanges-ceased when the
further reaction was occurring. The authors note that stu- new equilibrium point was reached.
dents confused everyday meanings for equilibrium with
chemical equilibrium. To the students, "equilibrium" Implications of These Misconceptions
meant physical balance like riding a bicycle, or mental bal- Creating a cognitive structure of a &mplex body of
ance, or balance in the sense of weighing. In any of these knowledge such as chemistry is not easy, and it is small
everyday uses of the word, the state of equilibrium is char- wonder that students from middle school to colleee level
acterized by a static, balanced condition. find chemistry difficult. Obviously, no amount of Fnstruc-
They also note that equilibrium problems are often tion will help a student who is not determined to work, but
hiehlv abstract. and the algebraic manioulations can be the research presented in this article does have several im-
pekokaed by rote. heref fore, students i o not automati- plications for instruction on anv level.
- -
callv understand what mani~ulatinealeebraic svmbols or
other symbols really means in relation to the actual chem- First. a ~ ~ a r e n t there
lv are orofound misconceotions in
ical svstem heine studied. Furthermore. the mi sconce^- the mind; bfmany students frbm a wide range oicultures
tions Eegarding sLdeduess and dynamismseem to be re&- concernine the articulate and kinetic nature of matter.
t a n t to instruction. The authors recommend directly Some of tgese n&conceptions persist even up to the grad-
confronting these misconceptions in instruction. uate level.
Therefore, educators should help students begin to under-
Reaction Rates and Concentrations stand the differences between atoms, molecules, and ions.
Australian high school chemistry students have also ex- Students also need help discerning the conditions under
hibited miscouceptions of equilibrium, even aRer instruc- which each term is appropriate. Students should be re-
tion (36). In an interview, students were required to ex- minded that if they can't explain a concept in molecular
terms, then they really don't understand it.
pla~nand p a p h the changes that can occur in the reaction
rates and the roncentrations during the following reaction Second, apparently students do not spontaneously visu-
betweennitric oxide and chlorine to form nitrosyl chloride: alize chemical events as dynamic interactions. Without an
understanding of the kinetic behavior of particles, many
2NO(g)+ C12(g)$ 2NOCl(g)+ heat topics in chemistry do not make conceptual sense and are
learned by rote.
The students revealed misconceptions that relate to both
the articulate nature of matter and to the dvnamic nature Therefore, students must be helped to realize that certain
of cAemical reactions. Fully 50% of the students held that . " assumotion of a kinetic model
tonics relate to an underlvine
of matter: the hehawor o f g s s r r , phase chances, solution
the concentrations of reactants and products were gov- chemistry, equrlibrium,el~ctrwhernistry, and general chem-
erned by a simple arithmetic relationship. Most often they ical reactions.
thought that the concentrations of the products equal the
conc&trations of the reactants a t eqklihrium. The au- Third, the cognitive model of learning implies that mis-
thors a r m e that this misconception was based on the fact conceotions can occur when students come for instruction
that they do not understand how the coefficientsin a chem- holdiig meanings for everyday words that differ from the
ical equation are used in the equilibrium expression.
&a&, this finding offers additional evidence that stu-
-
scientific meanine. For example.
& ."heat" and "temoerature"
are commonly used scientific terms for which students
dents do not have extensive or securely based knowledge hold persistent misconceptions (3843).
concerning how to regard and apply the symbolism of a
chemical equation. Also, over half of the students ex- .Therefore, educators should intrbduce scientific terms by
pressed the belief that when an equilibrium was disturbed, emphasizingthe differences between the everyday meaning
and the more precise scientificmeaning.
the initial result was that the rate of the favored reaction
would he increased and that the rate of the competing re-
verse reaction would be decreased. This also implies that
-
Fourth. leamine is much more difficult if students must
master different definitions for the same phenomenon. For
students have a poor understanding of the dynamics of an example, students who take both physics and chemistry
equilibrium system. might become confused over the opposing views of electri-
cal flow through a circuit (5).The same authors also note
Approaching LeChatelier Problems that reduction and oxidation can be defined in various
Finally, Kozma et al. (37) studied the understanding of terms: as a chame in oxidation number: as a -gain or loss of
equilibrium that college freshmen had attained. They gave oxygen; or as thegain or loss of electrons.
students from introductorv chemistrv courses a written.
constructed-response test chat probedqtheirunderstanding -.
Therefore. educators need to be esoeciallv orecise when ex-
plamnp topm that have multrple definuians. Krajrik 113)
of equilibrium concepts. Students were also required to has rrwewrd srvrml srudics of traehmg conceptual change
verbalize their thoughts as they worked through the test. that illustrate these points.
Kozma et al. used the students' verbal commentary and
their written answers to identify two groups of students A helpful course of action would be to include questions
whose conce~tionsof eouilibrium were inconsistent vnth on examinations that specifically probe for misconcep-
the scientificconceptio~ tions. This would accomplish two goals. Educators would
One group had an acceptable understanding that equi- have a more accurate estimate of students'actual cognitive
librium involves a dynamic exchange among the compo- structures, and students might give more serious thought
nents of the system, while the concentrations are held con- to understanding the conce~ts.Students would then have
s t a n t . However, these students could not use t h a t a better chance i f becoming meaningful learners of chem-
knowledge to solve LeChatelier problems. istry

Volume 69 Number 3 March 1992 195


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