FORM TP 2019004 | est cove 01212010 JANUARY 2019 CARIBBEAN EXAMINATIONS COUNCIL CARIBBEAN SECONDARY EDUCATION CERTIFICATE? EXAMINATION (CHEMISTRY 2 Paper 01 — General Proficiency I hour 15 minutes 18 JANUARY 2019 READ THE FOLLOWING INSTRUCTIONS CAREFULLY. ‘This test consists of 60 items. You will have 1 hour and 15 minutes to answer them, In addition to this test booklet, you should have an answer sheet. Kach item in this test has four suggested answers lettered (A), (B), (C), (D). Read each item you are about to answer and decide which choice is best. On youranswer sheet, ind the number which corresponds to your item and shade the space having, the same letter as the answer you have chosen, Look at the sample item below. ‘Sample Iter ‘The SI unit of length is the swer (A) met @®DO0 (B) newton (C) second (D) kilogram ‘The best answer to this item is “metre”, so (A) has been shaded. Ifyou want to change your answer, erase it completely before you fill in your new choice. When you are told to begin, turn the page and work as quickly and as carefully as you can. Ifyou cannot answer an item, go on to the next one. You may return to that item later. You may do any rough work in this booklet. Figures are not necessarily drawn to seale. ‘You may use a silent, non-programmable calculator to answer items. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright © 2018 Caribbean Ex: All rights reserved. 17191 OTANTIARY 2010oa 1 Which of the following processes Item 4 refers to the solubility curves in the demonstrates that matter is made up of following diagram, minute particles? Masot 120 Potassium nitrate 9) Diffusion crys (B) Capit that 100. (C) _ Distillation dissolves (D) Evaporation in 100g 89. of water rams) 6g 2. Inthe notation }3Cl, the subscript 17 cl, pt Sodlum represents the « chloride ® + atomic number eS ‘potassium suat (B) oxidation state (C) mass of a mole of atoms I (D) _ atoms in a mole of molecules oa iD Too ‘Temperature (°C) 3. From the table below, which of the 4. ‘The salt whose solubility changes to the substances represented by the options, GREATESTeextentinthe temperaturerange A, B,C and D, is MOST likely'sodium 0°C to 60°C is _ chloride? (A) sodium chloride Blectrical 2 potassium nate 5 Conduetivit potassium sulfat Substance = ea aaweons (D) hydrated copper(I!) sulfate State_| State (A) 2600 Yes No Which of the following substances supplies (B) 444 No No. protons as the only positive ions in aqueous 1465 No, Yes solutions? «by oe] No. ‘Yes (A) salt B) Base & Acid (©) Alkali 6 Crystals of sodium chloride are BEST described as @ ionic (B) metallic (C) molecular (D) — macromolecular GO ON TO THE NEXT PAGE, 0121201 0/JANUARY 2019t -3- ‘The ionic equation for the reaction between an acid and a carbonate is represented by (A) 2H"(aq) +CO,*(@a) - HCO, (oq) (B)_ H'(aq) + CO,*(aq) > H,CO,(aq) © 2#eq+C0,-(aa) > CO,@) + 4,001) (D) —H*(aq) + CO," (aq) > CO,(g) + H,0(1) When 100 em? of 2 mol dm* hydrochloric acid (in excess) are added to 5.0 g of granulated zine, hydrogen gas is evolved ata certain rate, If 5.0 g of powdered zine were used instead, the rate of production of hydrogen gas would (A) _ increase because of the greater concentration of powdered zine’ (@) increase because of the increased surface area of powdered zine ©) decrease because of the decreased surface area of powdered zine (D) decrease because of the lower solubility of powdered zine An element, X, has an electronic configuration 2, 8, 1. At which of the following positions is the element in the periodic table? : (A) Period 1 Group I B) Period 1 Group II © Period 3 Group I (DY Period 3 Group 11 01212010/JANUARY 2019 10. a. Items 10-1 refer to the four sets of properties represented by the options A, B, C and D below. Relative | Approximate Charge Mass @m[ oo 1 |® ° © a1 o ) 0 2 | In answering Items 10-11, each option may bbe used once, more than once, or not at all. Which of the properties above refer to a neutron? Which of the properties above refer toa proton? iN GO ON TO THE NEXT PAGE12. Two solutions are to be mixed in order to demonstrate an endothermic change. Which of the following techniques would be MOST appropriate? (A) Taking mass readings ‘Taking temperature readings (©) Monitoring the pH of the solutions (D) Carefully observingcolourchanges 13, Sulfur and oxygen are in the same group of the periodic table because (A) they can react with each other (B) they can form covalent compounds © _ they have the same number of ¢lectrons in their outer shell (D) _theatomic number of sulfuris 16 and the relative atomiemass of oxygen is 16 ‘Item 14 refers to the reaction represented by the equation below. CH,COOH + C,H,OH — CH,COOC,H, + H,0 ethanoic acid + ethanol > ester + water 14, How many moles of ethanoic acid are required to produce 0.5 mol of the ester? (A) 0.05 05 Qt @) 2 15. Which of the following compounds is covalent? (A) Potassium chloride Calcium chloride @ Hydrogen chloride Magnesium chloride 16. 17. 18, 19. 20. Items 16-17 refer to the following acids. (A) Ethanoie acid (B) Hydrochloric acid (©) Nitric acid (D) Sulfuric acid In answering Items 16-17, each option may be used once, more than once, or not at all Which of the acids above has a basicity of 2? Which of the acids above is weakly ionized in aqueous solutions? Which of the following reacts with an acid, liberating a gas which turns lime water (A) Methyl orange (B) Barium chloride (©) Calcium carbonate (D) Magnesium metal Which of the following gases shows NO reaction with moist litmus paper? (A) Ammonia (B) Hydrogen (©) Sulfur dioxide (D) Hydrogen sulfide Which of the following properties increases across Period 3 of the periodic table? (A) Atomic number (B) Atomic radius (C) Tensile strength (D) Metallic character GO ON TO THE NEXT PAGE24, 22, (is) 9 2. Item21referstothe followinginformation. 24. ‘A solution of iron(II) sulfate was added until in EXCESS to a solution of barium nitrate, The precipitate produced was filtered off and water was added to the residue in the filter paper. The colour of the precipitate produced was 28. (A) yellow (B) brown (© green (D) white What mass of oxygen atoms contains the same number of moles as 112 g of sulfur atoms? [RAM: 0 = 16; § = 32] 26. (A) 056g (B) 5.608 © 56.008 (D) 560.00 g Item 23 refers to the following diagram. 27. @) a) %) electrons ‘The bond between the two carbon atoms is (A) single (B) double (©) triple (@) dative 01212010/JANUARY 2019 Which of the following halogens isa liquid ‘at room temperature? (A) Iodine (B) Fluorine (© Bromine ©) Chlorine ‘A catalyst increases the rate of a reaction because it (A) _ binds irreversibly with the reactants (B) binds reversibly with the reactants (©) __ provides an alternative route of higher activation energy (D) provides an alternative route of lower activation energy Which of the following reactions occurs between propene and bromine? (A) Addition (B) ‘Substitution (©) Precipitation (D) Condensation FeCl, and FeCl, are two chlorides of iron. Which of the following statements about these two chlorides of iron are true? 1. The percentage of iron by mass in the two chlorides is different. II Thecolours of the aqueous solutions of the two chlorides are different. Il The aqueous solutions of the two chlorides do not conduct electricity. {A)__ Land I only (B) Land Hil only (©) Mand only (D) I, Wand Hil GO ON TO THE NEXT PAGE,28, 29, 30. a When solid lead nitrate is heated, it decomposes giving off nitrogen(1V) oxide and oxygen. The BALANCED equation for this reaction is (A) 2PD(NO,),(s) > 2PbO0(s) + 4NO,(g) + O,(8) (B) __ PB(NO,),(s) > PbO(s) + NO,(2) + 0,(8) (©) PL(NO,),(8) — PbO(s) + 2NO(g) + 0,8) (PD) 2PL(NO,),(s) —> PbO(s) + 2NO,(g) + 0,(8) ‘When a metal atom becomes an ion, it Item 31 refers to the following apparatus which is used to measure the relative (A) gains electrons and is oxidized conductivity of various substances. (B) gains electrons and is reduced (C) loses electrons and is reduced 6 VDC supply (D) _loses electrons and is oxidized —li (5}-Bulb solution of sodium hydroxide is neutralized by the addition of dilute hydrochloric acid. Graphite Graphite rod ‘The results obtained are used to plot the graph rod below. ‘Substance under investigation Q 31. If substances containing one mole of solute per dm? are investigated, which substance should cause the bulb to glow BRIGHTEST? ‘Temperature (°C) (A) Water (B) Ammonia (C) Sulfuric acid (D) _Bthanoic acid ‘Volume of acid added (em’) Which of the points on the graph above represents the neutralization point of the reaction? (A) P : ®) Q © R @) Ss GO ON TO THE NEXT PAGE,Items 32-33 refer to the following diagrams which represent bonding as it occurs in certain compounds. ° Ch) " | C8) GD In answering Items 32~33, each option may be used once, more than once of not at all, 32, Which of the diagrams illustrates bonding in chlorine? 33. Which of the diagrams illustrates bonding in oxygen? GO ON TO THE NEXT PAGE, 01212010/JANUARY 201934. 36. 8. Item 34 refers to the reac RCOOH(aq) + NaOH(aq) > RCOONa(aq) + H,0(1) represented by the equation below. Which of the following processes correctly describes the reaction above? (A) Decomposition (B) Neutralization (C) Precipitation (D) Reduction item 35 refers to the following informati 37. ‘Acompound when treated with concentrated hydrochloric acid gives off greenish-yellow ‘gas which bleaches moist red litmus paper. The gas given off is (A) chlorine ' (B) sulfur dioxide (©) hydrogen sulfide (D) nitrogen dioxide Which reaction involves the boiling of a fat or oil with aqueous sodium hydroxide 38. (caustic soda)? (A) Hydrolysis (B) Dehydration (C)__ Saponification (D) __Esterification 39. ‘A current of 5 amperes was passed for 193 seconds through a solution of copper(I) sulfate using copper electrodes. [RAM: Cu = 65; Faraday’s constant, F=96 500 C mot] ‘The mass of copper that would be gained at the (A) anode is 0.005 g (B) cathode is 0.005 g () anode is 0.325 g (D) cathode is 0.325 g The compound ethene is described as being unsaturated. This means that the (A) carbon atoms in ethene are linked by single bonds (B) carbon atoms in the molecule are very reactive (©) molecule contains at least one double ‘bond (D) molecule has insufficient hydrogen atoms Which of the following metals will react MOST vigorously with dilute acid? (A) — Copper (®) Iron (© Lead ©) Zine GO ON TO THE NEXT PAGE,40. Which of the following methods is used for the extraction of aluminium? (A) Electrolysis of its molten oxide (B) Reduction of its oxide using coke (©) Blectrolysisofits aqueous chloride (D) Reduction of its oxide using carbon ‘monoxide | : 44, 41. Which of the following metals is an important constituent of chlorophyll? (A) Tron (B) Copper (©) Caleium (D) Magnesium 42. Which of the following options lists ALL in the extraction of “(A) Air, iron ore and limestone (B) Air, coke, iron ore and limestone (©) Air, coke, eryolite and limestone (D) Coke, iron ore, bauxite and limestone 43. Which ofthe following compounds may be used to counteract the effects of acid rain on the soil? @ HS (B) C20 © co ©) 80, 0121201 0/JANUARY 2019 a Bom Item 44 refers to the following compounds. HOH H 9 feel ? ‘ —c— H— ia a. I —o— own Hn Ocyo# i P e Which of the following MOST likely identifies P and Q? P Q (A) Acid Alcohol (B) Ester (©) Alcohol (D) Alcohol GO ON TO THE NEXT PAGE-10- Item 45 refers to the following equation. HoH H OH Porn od H—~C—C=C —C —H+BR>X 1 1 u H 45. What is the correct structural formula for x? im ne A ee @ we-c—c—c—c-—H C21 170 BroOBr HO OH HOH H H i 0 fp (@) H-c—c—Cc—c—H Pore ot H oOBr Br, H HoH H H tort ©. n-c—c—cC—C—H tee Bo oH H Br HoH H H ee c—c—c—c-H ieee Hire eee) @) 46. 47. 48. 49, items 46-47 refer to the following ‘compounds. (A) CH,COOH (B) — C,H,OH (©) CH,CoocH, (D) — CH,COONa In answering Items 46-47, each option may be used once, more than once, or not at all. Which of the compounds above has a fruity odour? Which of the compounds above reacts with sodium carbonate to produce a gas which turns lime water milky? Which of the following is produced when carbon monoxide reacts with iron(II) oxide? (A) O, only (B) Feonly (©) CO, and CO only (D) CO, and Fe only Hexane is an alkane with six carbon atoms per molecule. Which of the following is the formula for hexane? A CH, @) GH, © CH, @) CH, GO ON TO THE NEXT PAGE}le Item 50 refers to two organic compounds, | and II, of molecular formula C,H,O, with the follo structures: HOH HH H i Tee ie H—C—C—C—H =H—C—C—C—oH iol | tot | H OH H HOH OH Compound I Compound It 50. Compounds | and Il are known as the (A) isomers of C,H,0 (B) isotopes of C,H, (© condensed formutae of C,H,0 (D) molecular formulae of C,H,O 51. Steel is often used in place of iron becduse it (A) _ is more susceptible to corrosion (B) has lower melting point (©) __ isstronger (D) — ischeaper 52. Which of the following statements is/are true of alkenes? 1. They react with KMnO,/H", 1, They undergo addition reactions. TIL, They undergo substitution reactions. (A) Lonty (B) Land Honly (©) Land Hl only () i Mand iit 01212010 ANUARY 2019 53. Which of the following tests can be used to inguish between an alkane and an alkene? ib ql. ML A) (B) © @) Adding bromine solution Burning Conductivity Lonly only Hl only Land III only ‘54, Whattype of reaction occurs when zine metal is added to copper sulfate solution? a) (B) © "oO Combustion Neutral Displacement Decomposition GO ON TO THE NEXT PAGE-12- During the manufacture of ethanol by 58. Which of the following is the reason for fermentation, the gas evolved adding cryolite to pure alumina in the extraction of aluminium by electrolysis? (A). turns time water cloudy (B) burns witha blue flame (A) It lowers the melting point. (©) relights a glowing splint (B) It reduces the resistance. (D) turns potassium dichromate green (©) Itreduces the current. (D) _Itprevents damage. Which of the following is a natural source of hydrocarbons? 59. Which of the following substances is a product of a halogenation reaction with (A) Carbon methane? (B) — Methane (©) Hydrogen (A) Nitrogen(IV) oxide (D) Petroleum (B) Hydrogen chloride (C) Ammonia (D) Water ALL members of a homologous series have similar 60, Which of the following compounds is NOT (A) densities formed from condensation polymerization? (B) boiling points (©) chemical properties (A) Polysaccharides (8) Polyalkenes (©) Polyamides (D) _Polyesters (D) physical prope END OF TEST IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST. 01212010 ANTIARY 2019