Cao 500 mol/m^3

t 5 hrs or 300 mins

Assume n: 1 2
t, min Ca, mol/m^3 lnCa/lnCao 1/Ca
0 1000 0.69314718056 0.001
100 500 0 0.002
200 333 -0.4064656084 0.003003003
300 250 -0.6931471806 0.004
400 200 -0.9162907319 0.005
-0.9732207055 0.99999963928

m 1E-05 = (n-1)*ka
ka 1E-05
Find Xa after 5 hours:
Shift Solving:
Ca 200 mol/m^3
Xa = 1 - Ca/Cao
Xa 0.6
 P1 P2 1
T1 = T2 25+273 =
Trial n 1 2 1.9
T, min P, atm Pa, atm lnPa 1/Pa 1/Pa^0.9
0 1.25168 1.25168 0.22448664895 0.79892624313 0.81706389195
1 1.14 1.02832 0.02792640264 0.97245993465 0.97517946098
2 1.04 0.82832 -0.1883557258 1.20726289357 1.18473622307
3 0.982 0.71232 -0.3392280303 1.40386343217 1.3570391452
4 0.94 0.62832 -0.4647056882 1.59154570919 1.51927784401
5 0.905 0.55832 -0.5828230043 1.79108754836 1.68968260541
6 0.87 0.48832 -0.7167843503 2.04783748362 1.90618891314
7 0.85 0.44832 -0.8022480158 2.23054960742 2.05859397683
8 0.832 0.41232 -0.8859555321 2.42530073729 2.21967320228
9 0.815 0.37832 -0.9720148806 2.64326496088 2.39842768781
10 0.8 0.34832 -1.0546336815 2.87092328893 2.58356522025
15 0.754 0.25632 -1.3613286151 3.9013732834 3.40483252576
20 0.728 0.20432 -1.5880678867 4.8942834769 4.1756126833
r -0.960981471 0.99988977731 0.99947324486
=

m 0.2064786518 = (n-1)(ka/(RT)^n-1)
 P2 Po 1.25168 atm
100+273 Pao = YaoPo 1.25168
2.1
1/Pa^1.1
0.78119122415
0.96974799238
1.230217888
1.45230337912
1.6672511578
1.89857822743
2.20001193502
2.4168687984
2.64997733011
2.91309581228
3.19024287303
4.47032662583
5.73664574974
0.99962016502
-0.5

1)(ka/(RT)^n-1)
T 1030 K R 0.08206 L-atm/mol-K
P 1 atm

Po (mmHg) Po (atm) t1/2 (sec) Cao lnt1/2 lnCao

52.5 0.069078947368 860 0.000817291484 6.756932389248 -7.10951475294
139 0.182894736842 470 0.002163876501 6.152732694704 -6.13585398941
290 0.381578947368 255 0.004514562484 5.541263545158 -5.40044699956
360 0.473684210526 212 0.005604284463 5.356586274672 -5.18422389109

Slope -0.728787852 = (1-n)

n 1.728787852
Intercept 1.610117876
Notable Formulas:
ble Formulas:
CV decomposition

trial n 0 1 2 0.1
t Xa (1-Xa) -ln(1-xa) 1/(1-xa) (1-xa)^0.9
30 0.32 0.68 0.385662480812 1.470588235294 0.706737313724
53 0.5 0.5 0.69314718056 2 0.535886731268
100 0.73 0.27 1.309333319984 3.703703703704 0.307770781807
r -0.9921814788307 0.999988442207 0.995070282539 -0.99365138111
m 0.01318275143

m = (n-1)kCao^(n-1) = k = 0.01318275143
CVBR combination

Po in mmhg t1/2 Po in atm Cao = (YaoPo)/RT lnt1/2 lnCao

354 81 0.465789473684 0.0025827561019 4.394449154672 -5.95889819366
340.5 102 0.448026315789 0.0024842611658 4.624972813284 -5.99777998121
288 140 0.378947368421 0.0021012253033 4.941642422609 -6.16523462666
202 224 0.265789473684 0.0014737760808 5.411646051855 -6.5199274094

m -1.68470153
b -5.535358867
at t1/2, Xa = 0.5
T= 826 C or 1099 K
Equal amounts so:
Yao 0.5
Ybo 0.5
m = (1-n) = -1.68470153
n 2.68470153
To get k:
Run Cao, mol/L t1/2, min lnt1/2 lnCao
1 0.025 4.1 1.41098697371 -3.6888794541
2 0.0133 7.7 2.04122032886 -4.3199912438
3 0.01 9.8 2.28238238568 -4.605170186
4 0.05 1.96 0.67294447324 -2.9957322736
5 0.075 1.3 0.26236426447 -2.5902671654
6 0.025 2 0.69314718056 -3.6888794541

m for runs 1to 5 -1.012869844 = (1-n)

n= 2.012869844
Intercept -2.352874715
for run 6:
CVBR
Trial n: 1 1.5 2
t(min) Ca(mol/dm^3) ln(Ca) 1/Ca^0.5 1/Ca
0 2 0.69314718056 0.707106781187 0.5
5 1.6 0.470003629246 0.790569415042 0.625
9 1.35 0.30010459245 0.860662965824 0.740740740741
15 1.1 0.095310179804 0.953462589246 0.909090909091
22 0.87 -0.13926206733 1.072112534838 1.149425287356
30 0.7 -0.35667494394 1.195228609334 1.428571428571
40 0.53 -0.63487827244 1.373605639487 1.88679245283
60 0.35 -1.0498221245 1.690308509457 2.857142857143
To check: r= -0.99101173167 0.99990666532 0.992589635215

SLOPE 0.01640415166 =(n-1)*ka

ka= 0.03280830333 L^0.5/(mole^0.5-min)
 1.4 1.6
1/Ca^0.4 1/Ca^0.6
0.757858283255 0.659753955386
0.828613504335 0.754272042068
0.886883331421 0.835217795281
0.962593502656 0.944418289322
1.057285555453 1.087147442266
1.153349107782 1.238628806259
1.289109034699 1.463640702255
1.521853271601 1.877410201403
0.999487916095 0.999663576965

L^0.5/(mole^0.5-min)