Professional Documents
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Section 1. Identification
Product name : Spent Catalyst (Various)
Synonyms : Zeolitic Silica, Alumina Catalyst
Relevant identified uses of the substance or mixture and uses advised against
Product use : By-Product
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 1/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. If
experiencing respiratory symptoms: Call a POISON CENTER or physician. IF
SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth.
IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before
reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : Powder.: May form combustible dust concentrations in air.
classified
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 2/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Specific hazards arising : Powder.: May form combustible dust concentrations in air.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products metal oxide/oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 3/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 4/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
molybdenum trioxide OSHA PEL 1989 (United States, ACGIH TLV (United States,
3/1989). 4/2014).
TWA: 10 mg/m³, (as Mo) 8 hours. TWA: 10 mg/m³, (as Mo) 8
Form: Total dust hours. Form: Inhalable fraction
OSHA PEL (United States, 2/2013). TWA: 3 mg/m³, (as Mo) 8
hours. Form: Respirable fraction
TWA: 15 mg/m³, (as Mo) 8 hours.
Form: Total dust
cobalt oxide - ACGIH TLV (United States,
4/2014).
TWA: 0.02 mg/m³, (as Co) 8
hours.
nickel monoxide OSHA PEL 1989 (United States, ACGIH TLV (United States, NIOSH REL (United States,
3/1989). 4/2014). 10/2013).
TWA: 1 mg/m³, (as Ni) 8 hours. TWA: 0.2 mg/m³, (as Ni) 8 TWA: 0.015 mg/m³, (as Ni) 10
hours. Form: Inhalable fraction hours.
OSHA PEL (United States, 2/2013).
TWA: 1 mg/m³, (as Ni) 8 hours.
Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
controls or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 5/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 6/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : Causes damage to organs through prolonged or repeated exposure. Once sensitized,
a severe allergic reaction may occur when subsequently exposed to very low levels.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 7/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
cobalt oxide - 15600 high
nickel monoxide - 5613 high
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 8/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Transport - - 9 9 9 9
hazard class(es)
Special
provisions
A97, A158,
A179
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 9/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 10/11
Spent Catalyst (Various) HollyFrontier Refining & Marketing LLC
International regulations
International lists : Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: All components are listed or exempted.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Taiwan inventory (CSNN): All components are listed or exempted.
0 Flammability
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of : 12/29/2014.
revision
Date of previous issue : No previous validation.
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
manufacturer, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of
the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 12/29/2014. Date of previous issue : No previous validation. Version :1 11/11