Page # 33 ELECTROCHEMISTRY

ANSWER-KEY
Exercise-I

1. C 2. B 3. B 4. B 5. D

6. D 7. C 8. A 9. A 10. B

11. A 12. A 13. B 14. A 15. C

16. C 17. D 18. C 19. C 20. C

21. C 22. C 23. B 24. A 25. D

26. B 27. A 28. A 29. D 30. B

31. C 32. A 33. B 34. C

35. A–PQ, B-PQ, C-QR, D-PS

Exercise-II

1. CD 2. BCD 3. AB 4. BC 5. AD

Exercise-III

1. (a) 2Ag + Cu2+ 2Ag+ + Cu, (b) MnO4– + 5Fe2+ + 8H+  Mn2+ + 5Fe3+ + 4H2O
(c) 2Cl– + 2Ag+ 2Ag + Cl2, (d) H2 + Cd2+  Cd + 2H+

2. (a) Zn|Zn2+||Cd2+|Cd, (b) Pt|H2|H+||Ag+|Ag

(c) Pt|Fe2+, Fe3+||Cr2O72–,H+, Cr3+ |Pt

3. 1.61 V 4. 1.35 V 5. – 0.80 V, NO

6. 0.53 V, disproportionation 7. –0.0367 V 8. E = 1.159 V

9. KC = 1.864 × 10107, Gº = – 611.8 kJ 10. n=2 11. E = 0.059

12. EºCell = + 0.01 V, ECell = – 0.0785 V, correct representation is Pb|Pb2+(10–3M)||Sn2+(1M)|Sn

13. [Cu2+] = 2.97 × 10–12 M for E = 0 14. E = – 0.81 V 15. 0.52 V, 0.61 V

16. 0.0295 V 17. 0.0295 V 18. pH = 4 19. KC = 7.6 × 1012

20. KC = 1.96×1026 21. Kw  10–14 22. Eº = 0.7826 V 23. – 1.30 × 103 kJ/mol

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 ELECTROCHEMISTRY Page # 34

24. (a) 6.02×1022 electrons lost, (b) 1.89×1022 electrons gained, (c) 1.80×1023 electrons gained

25. (a) 0.75 F, (b) 0.69 F, (c) 1.1 F 26. (i) 54 gm, (ii) 16.35 gm

27. 1.023 × 105 sec 28. 0.112 L 29. Rs. 0.75 x

30. (i) 2.1554 gm ; (ii) 1336.15 sec 31. 115800C, 347.4 kJ 32. t = 193 sec

33. A = 114, Q = 5926.8C 34. Final weight = 9.6g, 0.01 Eq of acid

35. t = 93.65 sec 36. 60% 37. 1.825 g

38. 2M 39. 419 S cm2 equivalent–1

40. 0.00046 S cm–1; 2174 ohm cm 41. (i) 6.25 × 105 ohm, (ii) 1.6×10–6 amp

42. 0.0141 mho g equiv–1 m2, 0.141 mho m–1 43. (i) 232 Mho cm2 mol–1 , (ii) 116 Mho cm2 equivalent–1

44. 523.2×10–4 mho cm2mol–1 45. 0.865 46. (i) 390.6 S cm2 mol–1 (ii) 12.32 %

47. 1.33×10–4 gm/litre 48. 8.74×10–11 mole2/litre2

49.  = 0.435, k = 6.7×10–4 50. (i) 6.98 (ii) 1.08×10–14

PROFICIENCY TEST
Q. 1
1. T 2. F 3. T 4. T 5. T

6. F 7. T 8. T 9. F 10. T

11. T 12. T 13. T 14. F 15. F

Q. 2
1. 0.66cm–1 2. O2 3. increase 4. higher

5. O2 & H2 6. Electrolyte concentration cell

7. Cr2O72–(aq.), Cr3+(aq.), H+|Pt 8. Pb(s) + PbO2(s) + 2H2SO4  2PbSO4(s) + 2H2O()

  dE  
9. Hg2Cl2(s) + 2e–  2Hg(l) + 2Cl–(aq.) 10. H = nF  T 
dT   E
   

11. inert, i.e., should not interfere with net cell reaction

12. Salt bridge or porous partition 13. zero 14. Eºred cathode

15. Amount, rate 16. reduction process 17. Oxygen

18. 2.5 × 96500 C

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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 Page # 35 ELECTROCHEMISTRY

Exercise-IV

1. [Cu2+] = 10–4M 2. pH = 6.61 3. Ka = 6.74 × 10–4 4. 1.39 V

5. –0.46 V 6. (ii). 1.27 V, (iii) 245.1 kJ 7. Eº = – 0.22 V

8. h = 2.12 × 10–2, Kh = 1.43×10–5 M 9. 0.95 V 10. Ksp = 1.1 × 10–16

11. [Br–] : [Cl–] = 1 : 200 12. Eº = – 0.1511 V 13. –0.037 V

14. 1.536 × 10–5 M3 15. 1.66 V 16. –1.188 V 17. Eº = 0.71 V

18. Kr = 8.227 × 1063 19. 0.372 V, –0.307 V 20. K = 10268

21. Tl+ = 10–8 ; Co3+ = 2 × 10–8 22. 43.456 g

23. 42.2% 24. V(O2) = 99.68 mL, V(H2) = 58.46 mL, Total vol. = 158.1 mL

25. 57.5894 gm 26. 1.9 million year 27. 1.21 × 105 coulomb

28. (a) – 0.124V, (b) 7.1, (c) calomel electrode 29. –0.167 V

30. 0.1456 ampere 31. 3.29 cm 32. 4.25 × 10–2 metre 33. 0.1934 gm/litre

34. Ksp = 7.682 × 10–17 35. E = 0.395 V

Exercise-V

1. KC = 6.26 × 10–7 2. Ksp = 2.287 × 10–12 3. A

4. B 5. 7.95 × 10–5 M 6. decrease with time 7. C

8. B 9. C 10. Hº = – 49987 Jmol–1, Sº = – 96.5 Jmol–1 K–1, s= 1.47 × 10–5

11. A 12. C 13. 0.05 M 14. B 15. KC = 1010

16. B 17. (a) Eº = 0.59 V, log10Ksp = – 10, (b) 52.8, 10–6 moles 18. A

19. A 20. D 21. 55 S m–1 22. B 23. D

24. D 25. C 26. D 27. B 28. ABD

29. AB 30. B 31. C 32. D 33. B 34. D

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-hr.motioniitjee@gmail.com