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nA nB

a. ∆ Gmix=RT ( ln X A + ln X B )
n n
5 4
= 0,082 . 298 ( ln 5+ ln 4)
9 9
= 24,436 (0,556 . 1,609 + 0,44 . 1,38)
= 24,436 (0,894 + 0,6072)
= 24,436 (1,5102)
= 36,903

∆ Smix = −R ¿
= -0,082 (32 . ln 32 + 41 . ln 41)
= -0,082 (32 . 3,46 + 41 . 3,71)
= -0,082 (110,72 + 152,11)
= -0,082 (262,83)
= -21,56

∆ Hmix = ∆ Gmix+T . ∆ Smix


= 36,903 + 293 (-21,56)
= 36,903 – 6317,08

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