ACCURA Sampling Device

Fully Automated Analysis of Gaseous and Pressurized Liquid Hydrocarbon

Streams for ElemeNtS, MultiTek and Gas Chromatography Analyzers.

Technical Offer
2019.1

Enjoy AC’s 35+ Years of Experience in Solution Based Gas Chromatography

• Easy to use
• Dedicated Turn-Key Solution
• Superior Chromatographic Performance
• Long term performance in your lab

www.paclp.com
Copyright

Copyright © 2019 by Petroleum Analyzer Company, L.P.

All text, graphics, design, and other works contained herein are the copyrighted works of Petroleum Analyzer
Company, L.P (PAC). All rights reserved. Any redistribution or reproduction of any materials contained herein
is strictly prohibited without the express written permission of the copyright holder.

The PAC trademark, the PAC service mark, PAC’s logo trademark, the AC Analytical trademark, the XLNC
trademark and Petroleum Analyzer Company, L.P.’s distinctive color trademark as used on its instruments and
in these materials, are trademarks, service marks, registered trademarks, and/or registered service marks of
Petroleum Analyzer Company, L.P. in the U.S. and other countries and are its sole and exclusive property.

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Other trademarks contained within these materials are the property of their respective owners.

Information

The information contained within these materials is subject to change without notice. PAC makes no
warranties or guarantees, either expressed or implied in these materials, including the warranty of
merchantability or fitness for a particular purpose. At any time, PAC may modify these materials, its
instruments or its programs without notice and subsequent versions of these materials may contain different
information. These materials could contain technical inaccuracies and/or typographical errors.

PAC does not assume responsibility for the accuracy of any translation of these materials.

About PAC

PAC develops advanced instrumentation for lab and process applications based on strong Analytical Expertise
that ensures Optimal Performance for our clients. Our analyzers help our clients meet complex industry
challenges by providing a low cost of ownership, safe operation, high performance with fast, accurate, and
actionable results, high uptime through reliable instrumentation, and compliance with standard methods.

Our solutions are from industry-leading brands: AC Analytical Controls, Advanced Sensors, Alcor, Antek,
Herzog, ISL, Cambridge Viscosity, PSPI, and PetroSpec. We are committed to delivering superior and local
customer service worldwide with 16 office locations and a network of over 50 distributors. PAC operates as a
unit of Roper Technologies, Inc., a diversified technology company and a constituent of S&P 500, Fortune
1000, and Russell 1000 indices.

Publication Date: November 22nd, 2019

Document Number: Accura LPG-Gas Sampling Device Technical offer 2019.1

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Contents
1. System Description .............................................................................. 4
2. Technical Requirements & Specifications .................................................. 7
3. System Configuration ........................................................................... 9
4. Spare Parts ....................................................................................... 12
5. Consumables..................................................................................... 13
6. Calibration and Reference Standards ....................................................... 13
7. Specification ..................................................................................... 14

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 ACCURA Sampling Device

1. System Description
Injecting a pressurized petroleum stream into an analytical system such as a Gas Chromatograph (GC)
or MultiTek is a challenge.
Uncontrolled self-expansion of the Liquid sample can lead to discrimination effects, which impacts
method precision negatively.

PAC now offers a dedicated solution for accurately injecting pressurized samples into GC and
Elemental analyzers. The PAC ACCURA vaporizes the sample under controlled conditions, maintaining
full sample integrity.
ACCURA providing excellent precision and accuracy, and is extremely simple to operate. Moreover, it
will tell the operator when line pressures are low enough and it is considered safe to disconnect the
sample bomb from the inlet, providing unsurpassed safety.

The PAC ACCURA Propylene/LPG Sample Introduction Device is based on a temperature controlled
expansion of the sample.
A few ACCURA Highlights:
• ACCURA respects the sample integrity: More reliable data with best Accuracy and Precision
Sulfinert treated sample path.
• ACCURA automates the complete sampling cycle - All Temperature and Pressure parameters
are stored including sample pressure and atmospheric pressure (Elemental only)
• ACCURA makes things simple
• Repeated injections for Elemental analyzers (Max 47 per run)
• ACCURA offers additional safety benefits: In-line pressure monitoring signals operator when
it’s safe to disconnect

➔ ACCURA is Simpler, Safer and more Reliable!

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 Back panel
Left panel

Right panel

45 -150°C
Inlet Filter To Analyzer
Vaporizer

(Liquid and Gas) From Analyzer

Pressure sensor
( 0-4000 kPa)
Sample vent
Rotameter
Relief valve
3200kPa Purge vent
Purge valve

High pressure; Liquid and Gas side Low pressure; Gas only side

Figure 1: Plumbing Schematic ACCURA for GC

Right panel Back panel

Supply
MFC
Maximum
45-150 °C 8bar / 87 PSI
Left panel

1 To Analyzer
45 -150°C 2 6

Inlet Filter
3 5
Vaporizer 4

Sample in Gas loop 10mL

From Analyzer

(Liquid and Gas)

Pressure sensor
( 0-4000 kPa)

Rotameter Sample vent

Relief valve
3200kPa
Purge vent
Purge valve

High pressure; Liquid and Gas side Low pressure; Gas only side

Figure 2 Plumbing Schematic ACCURA for Elemental

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True Turn-Key Solution

The ACCURA Sampling Device is a true Turn-Key Solution when configured with MultiTek or Gas
Chromatograph. The solution is fully configured, pre-tuned to application (when connected to GC or
MT in order), calibrated with qualified reference materials and tested before delivery.

This allows for fastest installation by one of our global support team members, and a very smooth
integration into the lab workflow. The ACCURA can also be delivered as an add-on to an existing
MultiTek, ElemeNtS or Agilent GC.

Method Compliancy

The ACCURA allows for doing analyses according typical gas and LPG analysis methods such as
D2163, ASTM D6667, ASTM D7551 and EN 17178.

Sample scope

The ACCURA is intended to be used for the vaporization of liquefied petroleum gases (liquids under
pressure) prior to analysis by Multitek, ElemeNtS or GC. Liquefied Petroleum gases (LPG) typically
are Hydrocarbon mixtures that consist of Propane, Butane, Isobutane, Butylenes, Propylene and
traces of heavier Hydrocarbons. Concentration of Pentane and heavier Hydrocarbons must be lower
than 2 volume % (ASTM D-1835-18a).

Main Features

• Data with highest accuracy and precision, uncompromised sample integrity

• Simple to use
• Maximum safety for operators.
• Can be used for MultiTek and GC, Gas and liquids.
• Repeated injections in one run (MultiTek only)

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2. Technical Requirements & Specifications

GENERAL INFO
Fully Automated sampling device for Analysis of Gaseous and Pressurized
ACCURA
Liquid hydrocarbon streams in conjunction with MultiTek and Gas
Chromatography.
Allows for analyzing LPG and gaseous
samples according methods such as:

ASTM D2163 UOP 539

ASTM D1945 UOP 373
ASTM D1946 UOP791
ASTM D2504 UOP 936
ASTM D2505
ASTM D2593 ISO 6974
Method Compliancy ASTM D2712 ISO 6975
ASTM D4424 ISO 7941
ASTM D5303 ISO 19739
ASTM D6228
ASTM D6667 GPA 2261
ASTM D7551 GPA 2286
GPA 2186
GPA 2177
EN ISO 7941
EN 15984 EN 27941 IP 405

OPERATION
Analytical principle Back pressure regulated controlled vaporizer.

Software Controlled via touchscreen and GC/MT

Software functions • Full control of system.

• Analyzes Gas and LPG with same system.
• All pressures are digitally monitored by method.
• System indicates when sample can be removed safely (green LED)
• Analyzing of LPG with Gas calibration
• All important parameters are logged at time of injection
• Multiple loop injections (Elemental only, max 47)
• Readout of Sample device pressure (BOM)
• Semi-automated flushing
• Hot mixing (increases peak resolution)
• GC Remote control, Elemental serial Control.
• T/P Controls in °C/F, bar/psi/kPa.
APPLICATION RANGE

Sample Type LPG and Gaseous samples with internal pressure up to 30 bars (435 psi)

SUPPLY & CONNECTIONS

Gas type For Elemental: Helium/Argon 4-5 bar (See site prep)
For GC: none

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 Gas Supply Connections Elemental: From Device, To Device, Vent Out, Sample In, He/Ar in.
GC: From Device, To Device, Vent Out, Sample In
All connections are 1/8” Swagelok, male. MultiTek connections are Sulfinert-
treated.
POWER REQUIREMENTS
Voltage 110-230 Vac
Frequency 50- 60 Hz, 240VA
Current 20 Amp
Power Maximum 240 VA
Maximum additional heat dissipation from this new equipment is 820 BTU / hour or
864.000 joules /hour. This measurement represents the heat given off when all
heated zones are set for maximum temperatures.
Fuse Ratings 6.3A T (2X)
IP class IP21
Safety class Class I
Over voltage category CAT II
INTERFACE SPECIFICATIONS
Display 4,3” TFT Touchscreen
Reading distance 10°, < 1m
KNOWLEDGE REQUIREMENTS
Required knowledge Basic analyzer knowledge (GC or Elemental)
level of user
Customer Laboratory / Bench space, Environmental, Power and Gas requirements available on
responsibilities installation (See site preparation)
Operator availability on installation
ENVIRONMENTAL CONDITIONS
Operating temperature Recommended Temperature: 15 to 40 °C (59 to 104°F)
Humidity Recommended Relative Humidity 5 to 80% at 31°C (89F), and 5 to 50% at 40°C (104F),
all non-condensing.

Altitude Recommended : up to 2000 meters

Storage temperature -40 to 70°C (-40 to 158°F) at 5 to 95% humidity, non-condensing
Sound pressure level 50 dBA
PHYSICAL SPECS
Dimensions 200mm *480mm (7.87” * 18.9” )
Recommended Bench 400mm*580mm (15.7 “ * 22.8”)
Space
Weight GC version: 12 kg (26lb)
MT version: 15 kg (26lb)
SAFETY & ERROR PREVENTION
User Error Prevention System indicates by LED when line pressure is low enough to remove the pressurized
sample container
Pressure Relief valve Pressure Relief valve opens at 30 bar (435 psi) inlet pressure
Minimum Sample 2 bar (29 psi)
Pressure

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3. System Configuration

Instrument Configuration and factory installed options

P/N Description

36.00.001 Accura, for MultiTek, 120/230V

Hardware
Mainframe ACCURA Sampling Box
Inlets/Outlets Sample In, Vent Out, From/To device,
He/Ar In.
Vaporizer Max 150°C
Injection 6 port Sampling Valve, with 10 ml std
valves sample loop
Connections 1/8” male Sulfinert

Included/Pre-installed

Startup kit*

System Testing Documentation

System Operation Manual

Not Included / To configure separately

Calibration standards (Cylinders)

Regulators for calibration gases

MultiTek

*Startup kit contains, connection materials to and from

GC/MT, power cable to region, 0.5µm Sulfinert treated
sample inlet filter and communication cable

** Requires Pyrotube P/N 71323 to be installed in MT,

order kit 101475 or tube 90178-2 if needed.

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 P/N Description

36.00.002 Accura, for GC, 120/230V

Hardware
Mainframe ACCURA Sampling Box
Inlets/Outlets Sample In, Vent Out, From/To device,
He/Ar In.
Vaporizer Max 150°C
Injection valves Needs configuring in GC
Connections 1/8” male

Included/Pre-installed

Startup kit*

System Testing Documentation

System Operation Manual

Not Included / To configure separately

Sampling valve (to be configured in

GC)

Calibration standards (cylinders)

Regulators for calibration gases

Gas chromatography

* *Startup kit contains, connection materials to and

from GC/MT, power cable to region, 0.5μm
Sulfinert treated sample inlet filter and
communication cable

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 P/N Description

36.00.003 Accura, for ElemeNtS, 120/230V

Hardware
Mainframe ACCURA Sampling Box
Inlets/Outlets Sample In, Vent Out, From/To device,
He/Ar In.
Vaporizer Max 150°C
Injection 6 port Sampling Valve, with 10 ml std
valves sample loop
Connections 1/8” male Sulfinert

Included/Pre-installed

Startup kit*

System Testing Documentation

System Operation Manual

Not Included / To configure separately

Calibration standards (Cylinders)

Regulators for calibration gases

ElemeNtS

*Startup kit contains, connection materials to and from

GC/Elemental, power cable to region, 0.5µm Sulfinert
treated sample inlet filter and communication cable

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4. Spare Parts

P/N Description Qty

10.10.222 Valve, Relief, 1/4", 24-50 bar, assy 1

10.10.254 Pressure regulator, KCP, treated – (vaporizer) 1

36.01.304 Vaporizer assy, treated 1

10.11.240 Valve, 2/3, NO, assy 1

10.10.104 Bulkhead union, 1/8”, SS 1

40.02.016 Temperature sensor, IC 1

20.10.003 Thermostat, Bi-metallic, NC, 65C 1

20.15.105 Fan 24V (40 x40 x 20mm), assy 1

10.11.241 Valve, 2prt, 86 Bar, assy 1

36.01.154 PCB, Accura, inclusive touchscreen 1

40.01.057 Heater/Sensor set, 24V/60W, Pt100 1

40.02.013 Pressure Sensor 0-40 Bar, assy 1

20.08.101 6.3A T fuse 2

21040.003 Ferrule, Delrin®, 10 pcs reduction 1/8”to 1/16” 1

10.12.014 Rotameter, 0-500 ml/min, no valve 1

10.20.132 MFC, Mass Flow Controller, 1-50 mls/min 1

10.25.029 Valve, rotary, 6-port 1

10.10.104T Bulkhead union, 1/8”, SS Treated 1

35.01.425 Motor & Actuator for Valve 1

10.35.027 O-ring, Viton, 013, 10,82x1,78 1

10.45.044 Spider for jaw coupling, 19mm 1

31054 Ferrule, Teflon, 1/4, 10 pcs 1

10.10.222 Valve, Relief, 1/4", 24-50 bar, assy 1

10.10.254 Pressure regulator, KCP, treated – (vaporizer) 1

10.11.240 Valve, 2/3, NO, assy 1

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 10.10.104 Bulkhead union, 1/8”, SS 1

20.79.033 INSULATION JACKET, FOR VAPORIZER 1

20.79.034 INSULATION, FOR VALVE & SAMPLE LOOP BLOCK 1

40.02.023 Cable, communication, Accura for ElemeNtS 1

5. Consumables

P/N Description Qty

71238T Filter. 0.5 Micron Treated 1

6. Calibration and Reference Standards

AC reference materials are designed and produced to be intrinsic part of your laborator y quality system.
They are used for testing the equipment and application prior to delivery and for qualification on -site during
installation. After that they offer you a full QC-program for the lifetime of the instrument.
AC offers a range of materials to calibrate your system, ‘certified finished products’ and other QC checks
that will hold up in any QC-audit.
Most often these materials have been part of extensive Round Robin tests in the industry, and have ensured
successful installation of hundreds of AC lab-solutions.

• A Full range of liquid calibration standards, QC checks and ‘finished product’ reference materials.
• Round Robin tested, certified & proven values
• Stringent Quality Control on manufacturing, storage and shipping
• MSDS
• All samples come chromatograms and a comprehensive booklet to guide you to a better QC system in
your lab

Part number Description QTY

Special Gas or LPG Standards can be ordered on request through our Applications group.

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7. Specification

Description

Sample Range LPG, compressed streams, light Hydrocarbon gas

mixtures.
Min Sample Pressure
2 bar (LPG/Gaseous)
Max Sample pressure
30 bar / 435 psi (relief valve protected)
Max Vaporizer Temp
150°C/ 302 F

Accuracy: Within uncertainty of Gas cylinder (<5%)

Repeatability GC: <1% RSD

Measured as absolute Peak Area Ethane, n-Pentane @ 5-90%

concentration

MultiTek: < 2% RSD for S @ 300 ppm

< 2% RSD for N @ 200 ppm

Discrimination <1%

(Measured as relative difference in RRF Ethane – Accura vs LSV

injection)

Linearity Multi-Injection (Multitek only) <5%

(Measured as max deviation on relative response for n run series

against a single injection.

>0.99

Correlation on Multi-injection calibration curve.

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Company profile
PAC / AC Analytical Controls® (AC) is the recognized leader in specialty chromatography analyzer
solutions for petroleum, petrochemical and refinery, gas, and natural gas analysis markets. Our
analytical innovations have defined instrumentation standards since 1981 across the entire spectrum
of hydrocarbon-based product streams, including gasoline, naphtha, crude oil, residues, and various
gaseous products such as natural gas and liquefied petroleum gas (LPG).
AC is also a recognized partner for any custom-engineered GC solution. Our team is dedicated to
designing, building and testing quality solutions, fully tailored to your needs.

Application testing
AC instruments and solutions are built to the highest standards using proven and robust hardware
based on the Agilent Technologies platform. AC Analytical Controls® is certified under ISO 9001:2008
standards. Before the system leaves the AC Analytical Controls B.V. facility, the following items are
checked:

Leak testing
The complete system is pressurized both in on and off position of the valves, including the
sample loops present. The system will not exceed a pressure drop of more than 10 kPa in 10
minutes.

Hardware control test

The system is checked for functioning of all hardware present. This includes checking heated
zones, flow and pressure control modules, detectors and valves (if present).

Analytical performance test

This AC customized analyzer is fully checked on its analytical capabilities. As standard, the
instrument is tuned to achieve proper component separation and is calibrated on the
components of interest. Any additional performance parameters can be tested on request, such
as detection limit, repeatability, resolution etc.

The results of this factory test are documented and shipped with every instrument for future
reference. The documentation includes:
• Analysis description
• Startup procedures
• Actual settings
• Hardware description
• Sample preparation and sample handling
• Method description
• Test Results

Application warranty
AC analysers are covered by application warrantee; this is additional to the standard hardware
warrantee of 1 year. This means that besides making sure the hardware is functional, also the
analytical performance of your analyser is guaranteed allowing your lab to generate reliable data
from the moment of commissioning. Application warrantee is valid from one year and can be
extended by the purchase of a services contract.

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Factory acceptance testing
A Factory Acceptance Test (FAT) allows for verification of the instruments performance to the
agreed specifications at the AC factory by means of calibrations or sample analysis prior to
shipment. Such acceptance test needs to be requested and ordered separately.
The factory acceptance test procedure is documented in the AC quality system and includes the
following steps:
• Overview of the ordered hardware and if applicable the software
• AC representative explains the details of the AC application
• Analysis of a control sample for this particular application
• Analysis of a customer sample for this particular application
• Evaluation of the complete analysis and test results
• Comparison of the results with the agreed specifications
• Signing the Factory Acceptance Documents for approval

Any non-conformity to the agreed specifications will be resolved by AC before shipment of the
analyser.

Installation & familiarisation

The instrument is installed at the customer’s facilities by a trained AC engineer. After the engineer
has verified instrument functionality, reference samples will be analysed to check instrument
performance according to the agreed specifications.
A customer representative is required to be present during the installation. After instruments are
installed and performing OK, the AC engineer will familiarize the customer or its representative
with the instrument. This makes sure that after the engineer leaves site, the instrument is ready for
routine operation and the customer is aware how to operate the analyser for this purpose.

After sales support

AC Analytical Controls also offers you a full range of support tools to ensure the analytical integrity
and performance of your analyser, such as consumables and spare parts, calibration and reference
samples, classroom and on-site training, service contracts, modem support and the AC Response
Center service.

AC Response Center
The AC Response Center is a help desk, operated by our service engineers and application specialists
and is a key support tool. Unlimited, free of charge remote assistance by the AC Response Center is
included with the instrument purchase and is valid for the lifetime of the instrument. Because the
results of the detailed applications testing are stored in our database, our engineers are usually able
to quickly identify any issues with your application by comparing settings and results. As a result,
advice to laboratory staff on how to proceed can be quickly provided. This offers a unique
advantage for our customers, and experience has shown that close to 90% of support calls can be
resolved remotely. This means you do not only save on labour costs for service visits but also
significantly improve instrument uptime.

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