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ABSTRACT:
The presence of arsenic (As) has been reported across the globe in drinking water sources, Asia
being the most significantly affected area for arsenic contamination around the world. In Asia
around 100 million people are at risk of arsenic contaminated water sources and more than
700,000 cases have been reported for arsenic related diseases.
Many research studies have been conducted for arsenic contamination, furthermore many studies
are being carried out but still there is significant lack of knowledge about the prevalence and
impact of arsenic and its epidemiology in under developed countries like Pakistan. The focus of
this study is on the rural areas of Sindh using ground water as major source of drinking water. In
Pakistan groundwater arsenic concentration has reached up to 1100 μg/L compared with WHO
limits of 10μg/L internationally and 50μg/L for Pakistan.
In the province of Sindh, around 36% of the population is exposed to arsenic contamination
above WHO limits. Therefore, keeping in view the catastrophic situation, a study on arsenic
prevalence in the district of matiari has been conducted to identify presence of arsenic in ground
water. 85 water samples were taken from district matiari from hand pumps and boring and did
field analysis for salinity and total dissolved salts (TDS). Further, the samples were brought in
water testing and surveillance laboratory, LUMHS, Jamshoro where samples were tested for
turbidity and arsenic. Arsenic presence was tested by Merck arsenic kit for 0.00-0.5 mg/L. The
concentration for arsenic was estimated by visual comparison of the reaction zone of analytical
test strip with the color scale. From the total of 85 samples, 60 samples are positive for arsenic,
and among those 22 samples are positive above WHO criteria for Pakistan (0.05mg/L or50μg/L).
This research is part of the efforts taken to evolve and develop a community based awareness of
arsenic hazards and sustainable arsenic mitigation system by establishing spatial and temporal
prevalence of arsenic in the study area.
INTRODUCTION:
The consumption of contaminated water
Water is the most important and basic over long periods of time is the primary
necessity for the human life. Without water route of human exposure to arsenic. Though
life can’t exist and as the population of the a lot of research has been carried out still
world is increasing the supply of safe and there is dearth of knowledge on the presence
healthy water has become a great concern. and distribution of arsenic in water. The
This is the important debate for both policy presence of arsenic in water poses many
makers and international organizations health hazards. Among them the common
dealing with the subject of water shortage effects are skin lesions, skin cancer, itching,
and safe water supply[1]. Among the safety night blindness, lung cancer, renal cancer,
and quality of water, arsenic has been one of bladder cancer, colonic cancer, peripheral
the important components in contamination neuro-pathology and vascular pathology
of drinking water specifically in the south (Blackfoot disease).
East Asian region. Considerable literature
has been published in recent years on the Arsenic is an environmental contaminant
presence of arsenic in groundwater being that imposes a high risk of morbidity and
utilized by humans around the globe and mortality. There may be many areas in
particularly in Asia. Arsenic has been Pakistan that are not tested yet and may
identified in the underground water sources yield high concentrations of arsenic. This
of south East Asian countries and most particular study was motivated by previous
prominently in Bangladesh, along with research studies conducted in rural areas of
India, Pakistan and Nepal. In this research Punjab and Sindh and aims at evaluating
our main focus is on Pakistan. arsenic concentration determining the spatial
distribution of this contaminant in Matiari
The main source of drinking water in district and ultimately gauging the incidence
Pakistan is ground water. Majority of people risk in the environment of local community.
use the water without any treatment or
filtration so it gives rise to a number of Literature review:
water based diseases. Arsenic is a naturally
occurring element and widely distributed in Many studies have been conducted
earth crust in the form of inorganic arsenic worldwide as arsenic has become a very
compounds[2]. Here we have collected important aspect of environment and
samples from district matiari of Pakistan. community based research. Arsenic has been
found as underground naturally occurring
District Matiari consists of three talukas, substance contaminating drinking water
Matiari, Hala, and Saeedabad. It is sources and giving rise to mass poisoning, as
connected to district Jamshoro in the west, arsenic is still undetected in majority of
Nawabshah in north, Sanghar in the east and areas and proper steps are needed to free the
Hyderabad in south. In the present work, we water of arsenic. Among the research being
have sampled UC Matiari, UC Hala, UC carried out, Asia is the most significantly
Bhit Shah, UC Nasarpur, and UC Faqir affected area, and in particular, south East
Nuthiani of district Matiari [3]. Asia.
August 2012, Volume 3, No. 4
International Journal of Chemical and Environmental Engineering
Figure 1 Countries affected on the current global scenario on arsenic contamination emphasizing on Asia [3]
Among the studies conducted around the more contents were tested and most
globe, maximum work is done over of them exceeding the normal WHO
Bangladesh as arsenic is considered to be at criteria [5].
very high and alarming levels for both III. M.M.H Khan, et al ‘Magnitude of
health and environmental aspects. Arsenic Toxicity in Tube-well
Drinking Water in Bangladesh and
I. Allan H. Smith, et al ‘ Its Adverse Effects on Human
Contamination of drinking-water by Health Including Cancer’ reported
arsenic in Bangladesh’ reported more that in Bangladesh 59 districts out of
than 50% population of Bangladesh 64 have been already affected by
using contaminated water and out of arsenic in underground drinking
2022 samples around 35% are more water, where this particular source of
than 50 μg/L and 8.4% samples are drinking water is the main source for
alarmingly high at around 300 μg/L 97 percent of the rural people [6].
[4].
II. Seth H. Frisbie, et al ‘The Along with this many studies have been
Concentrations of Arsenic and Other conducted on the health and environmental
Toxic Elements in Bangladesh’s effects of arsenic as it has become the most
Drinking water’ took samples from widespread mass poisoning particularly in
112 tube wells of Bangladesh and Bangladesh. Among few other areas where
around 50% samples have arsenic research has been done, South America has
concentrations above the WHO also shown very high concentrations of
guidelines, along with arsenic 30 arsenic in the groundwater.
August 2012, Volume 3, No. 4
International Journal of Chemical and Environmental Engineering
RECOMMENDATIONS
2. Water Management:
Screening of all tube wells
should be undertaken.
Figure 7 Samples above normal TDS level As testing facilities should be
available at an affordable cost.
CONCLUSION:
Groundwater pumping rate
should be minimized for
This research is part of the efforts taken to
irrigation.
evolve and develop a community based
awareness of arsenic hazards and sustainable
arsenic mitigation system by establishing
3. Alternative sources of drinking
spatial and temporal prevalence of arsenic in
water: innovative alternative sources
the study area. From the data collected and
such as, pond sand filters, infiltration
analyzed, the samples collected from district
galleries, or rain wells, and in some
Matiari have given alarmingly high
places even rainwater harvesting can
concentration of arsenic in the drinking
be adopted to alleviate the arsenic
water ranging from 0.005-0.25mg/L. And it
disaster.
shows that this water is very unsafe for
human consumption and efforts should be
4. Use of surface water: Existing
taken to decrease it, provide alternate source
surface water could be purified by
and educate the community.
filtration and chlorination, and even
by ultraviolet disinfection or solar
radiation and can be used in drinking
and other house hold purposes.
August 2012, Volume 3, No. 4
International Journal of Chemical and Environmental Engineering
REFERENCES
Appendix
Table 1.1(table of all parameters tested)
S.NO. Sampling Area Source Turbidity NTU Salinity % TDS mg/L Arsenic mg/L
1 UC Matiari Kacho Hand pump 42 1.8 2028 0.005
2 UC Matiari Kacho Hand pump 0 1.6 1981 0.005
3 UC Matiari Kacho motor pump 0 2.5 3718 0.025
4 UC Matiari Hand pump 0 1.4 1792 0.005
5 UC Matiari Kacho Hand pump 0 3.1 3819 0.05
6 UC Matiari Kacho Hand pump 0 2.7 3723 0.1
7 UC Matiari Memon Colony motor pump 0 0.4 535 0.005
8 UC Matiari Memon Colony Hand pump 0 3.3 4065 0.05
9 UC Matiari Memon Colony motor pump 0 1.6 1995 0.01
10 UC Matiari Memon Colony motor pump 0 2.9 4419 0.025
11 UC Faqir Nuhthiani Hand pump 0 1.2 1582 0.005
12 Bughio Muhalla UC Bhit Shah motor pump 0 1.2 1589 0.005
13 Bughio Muhalla UC Bhit Shah motor pump 0 0.7 969 0.005
14 Bughio Muhalla UC Bhit Shah motor pump 0 1.7 2430 0
15 Bughio Muhalla UC Bhit Shah motor pump 0 1.1 1342 0
16 Bughio Muhalla UC Bhit Shah motor pump 0 1.4 1722 0
17 Tambooro Chowk UC Bhit Shah motor pump 0 2 2670 0
18 UC Matiari Memon Colony Hand pump 0 0.4 516 0.005
19 UC Matiari Memon Colony Hand pump 0 3.1 3820 0.005
20 UC Matiari Memon Colony motor pump 0 4.1 5318 0.005
21 UC Matiari Memon Colony motor pump 0 0.4 501 0.01
22 UC Matiari Memon Colony motor pump 0 3.1 3818 0.005
23 UC Matiari Memon Colony motor pump 0 0.4 498 0.01
24 UC Matiari Memon Colony Hand pump 0 2.9 3517 0.01
25 UC Matiari Noor Shah Colony Hand pump 64 0.4 548 0.01
26 UC Matiari Noor Shah Colony Hand pump 0 0.4 485 0.01
27 Bhit Shah motor pump 0 0.8 1014 0
28 Bhit Shah motor pump 0 1.4 1771 0
29 Bhit Shah motor pump 0 1.4 1736 0.005
30 Bhit Shah motor pump 0 1.6 2319 0
31 Bhit Shah motor pump 0 1 1272 0.005
32 Pir Noor Shah Colony; Matiari Hand Pump 0 1.9 2418 0.05
33 Pir Noor Shah Colony; Matiari motor Pump 0 0.4 533 0.01
34 Pir Noor Shah Colony; Matiari Hand Pump 0 2.2 2810 0.08
35 Matiari Stop Hand Pump 0 0.4 496 0.005
36 Matiari Stop Hand Pump 0 0.4 520 0.005
37 Matiari Stop motor pump 0 0.4 481 0.005
August 2012, Volume 3, No. 4
International Journal of Chemical and Environmental Engineering
S.NO. Sampling Area Source Turbidity NTU Salinity % TDS mg/L Arsenic mg/L
38 Mosque; Matiari Stop motor Pump 0 0.4 489 0.005
39 Matiari Stop Hand Pump 48 0.5 579 0.1
40 Govt. School; Matiari Stop Hand Pump 0 0.5 654 0.1
41 Matiari Stop Hand Pump 0 0.5 720 0
42 Tamborochowk; Bhit Shah Hand Pump 0 1.3 1673 0
43 Tamborochowk; Bhit Shah Hand Pump 0 2.2 2720 0
44 Dargah; Bughiomohalla; Matiari Hand Pump 0 1.1 1389 0
45 Bughiomohalla; Matiari Hand Pump 0 2.5 3815 0
46 Bughiomohalla; Matiari Hand Pump 0 1.2 1498 0
47 Noor Shah Colony; Matiari Hand Pump 0 2.1 2780 0.01
48 Noor Shah Colony; Matiari motor pump 0 0.4 554 0.05
49 Noor Shah olony; Matiari motor pump 0 1.2 1519 0.05
50 Noor Shah Colony; Matiari motor pump 0 0.4 488 0.01
51 Noor Shah Colony; Matiari motor pump 0 0.7 844 0.025
52 Noor Shah Colony; Matiari Hand Pump 99 2.7 3728 0.005
53 Noor Shah Colony; Matiari Hand Pump 0 3.1 3910 0.01
54 Noor Shah Colony; Matiari Hand Pump 0 3 3780 0
55 Bhit Shah Hand Pump 0 2.7 3721 0
56 Bhit Shah Hand Pump 0 3 3785 0
57 Bhit Shah Hand Pump 0 3.5 4210 0
58 Bhit Shah Hand Pump 0 3 3670 0
59 Bhit Shah Hand Pump 0 1.6 2310 0
60 NasarPur Motor Pump 0 0.4 506 0.25
61 NasarPur Motor Pump 0 0.4 511 0.25
62 NasarPur Hand Pump 0 0.4 528 0.25
63 NasarPur Motor Pump 0 0.8 1198 0
64 NasarPur Motor Pump 0 0.3 427 0.1
65 NasarPur Motor Pump 0 0.4 496 0.1
66 NasarPur Hand Pump 0 1.8 2792 0.005
67 NasarPur Motor Pump 0 0.3 419 0.25
68 NasarPur Motor Pump 0 1 1218 0.1
69 NasarPur Motor Pump 0 0.3 400 0.25
70 NasarPur Motor Pump 0 0.3 374 0.1
71 NasarPur Hand Pump 0 0.4 491 0
72 NasarPur Motor Pump 0 0.5 567 0
73 NasarPur Motor Pump 0 0.4 484 0.005
74 Matiari motor Pump 89 0.3 358 0.025
75 UC I Hala Hand Pump 0 0.3 425 0.025
76 Matiari motor pump 0 1.6 2311 0.025
77 New Hala motor pump 0 0.9 1.84 0.1
August 2012, Volume 3, No. 4
International Journal of Chemical and Environmental Engineering
S.NO. Sampling Area Source Turbidity NTU Salinity % TDS mg/L Arsenic mg/L
78 New Hala motor pump 0 0.5 634 0.01
79 New Hala motor pump 0 0.5 672 0
80 UC I Hala motor pump 0 1.6 2317 0.01
81 UC I Hala Hand Pump 0 1.4 1750 0
82 UC I Hala Hand Pump 0 1 1167 0.05
83 Talabulmola colony hala Hand Pump 0 0.9 1084 0.1
84 UC I Hala motor Pump 0 0.5 716 0.05
85 UC I Hala Hand Pump 0 0.5 627 0